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Campigliaite

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Formula:
Mn
2+
 
Cu
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 4H
 
2
O
System:MonoclinicColour:Light blue
Lustre:Vitreous
Member of:Devilline Group
Name:For the locality.


Devilline Group.

The manganese analogue of devilline and lautenthalite.

Classification of Campigliaite

IMA status:Approved 1981
Strunz 8th edition ID:6/D.19-03
Nickel-Strunz 10th (pending) edition ID:7.DD.30

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
Dana 8th edition ID:31.6.6.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
6 : (AB)5(XO4)2Zq·xH2O
Hey's CIM Ref.:25.2.22

25 : Sulphates
2 : Sulphates of Cu and Ag
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Type Occurrence of Campigliaite

Type Locality:Temperino Mine, Temperino, Campiglia Marittima, Livorno Province, Tuscany, Italy
General Appearance of Type Material:Light blue tufts
Place of Conservation of Type Material:Museum of Florence University #214/I
Year of Discovery:1981
Geological Setting of type material:Altered skarn deposit
Associated Minerals at type locality:
IlvaiteGypsumBrochantiteAntlerite

Physical Properties of Campigliaite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:Light blue
Cleavage:Perfect
{100}
Density (calculated):3.06 g/cm3

Crystallography of Campigliaite

Crystal System:Monoclinic
Cell Parameters:a = 21.7Å, b = 6.09Å, c = 11.24Å
β = 100.3°
Ratio:a:b:c = 3.563 : 1 : 1.846
Unit Cell Volume:V 1464.5 ų
Z:4

Optical Data of Campigliaite

Type:Biaxial (-)
RI values: nα = 1.589 nβ = 1.645 nγ = 1.659
2V:Measured: 52° , Calculated: 50°
Maximum Birefringence:δ = 0.070

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r > v weak

Chemical Properties of Campigliaite

Formula:
Mn
2+
 
Cu
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 4H
 
2
O
Simplified for copy/paste:Mn2+Cu4(SO4)2(OH)6·4H2O
Essential elements:Cu, H, Mn, O, S
All elements listed in formula:Cu, H, Mn, O, S

Relationship of Campigliaite to other Species

Member of:Devilline Group
Other Members of Group:

- +
Aldridgeite
(Cd,Ca)(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
Devilline
CaCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
Kobyashevite
Cu
 
5
(SO
 
4
)
 
2
(OH)
 
6
·4H
 
2
O
Lautenthalite
PbCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
Unnamed (Dimorph of Devilline)
CaCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
7.DD.05Felsőbányaite
Al
 
4
(SO
 
4
)(OH)
 
10
· 4H
 
2
O
7.DD.10Langite
Cu
 
4
(SO
 
4
)(OH)
 
6
· 2H
 
2
O
7.DD.10Posnjakite
Cu
 
4
(SO
 
4
)(OH)
 
6
· H
 
2
O
7.DD.10Wroewolfeite
Cu
 
4
(SO
 
4
)(OH)
 
6
· 2H
 
2
O
7.DD.15Spangolite
Cu
 
6
Al(SO
 
4
)(OH)
 
12
Cl · 3H
 
2
O
7.DD.20Ktenasite
Zn(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 6H
 
2
O
7.DD.25Christelite
Cu
 
2
Zn
 
3
(SO
 
4
)
 
2
(OH)
 
6
· 4H
 
2
O
7.DD.30Devilline
CaCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
7.DD.30Orthoserpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
7.DD.30Serpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
7.DD.30Niedermayrite
CdCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 4H
 
2
O
7.DD.30Edwardsite
Cu
 
3
Cd
 
2
(SO
 
4
)
 
2
(OH)
 
6
·4H
 
2
O
7.DD.35Carrboydite
[(Ni
 
1-x
Al
 
x
)(OH)
 
2
][SO
 
4
]
 
x/2
· nH
 
2
O
7.DD.35Glaucocerinite
(Zn
 
1-x
Al
 
x
)(OH)
 
2
(SO
 
4
)
 
x/2
· nH
 
2
O
7.DD.35Honessite
(Ni
 
1-x
Fe
3+
x
)(OH)
 
2
[SO
 
4
]
 
x/2
· nH
 
2
O
7.DD.35Hydrohonessite
(Ni
 
1-x
Fe
3+
x
)(OH)
 
2
[SO
 
4
]
 
x/2
· nH
 
2
O
7.DD.35Motukoreaite
Mg
 
6
Al
 
3
(OH)
 
18
[Na(H
 
2
O)
 
6
][SO
 
4
]
 
2
· 6H
 
2
O
7.DD.35Mountkeithite
[(Mg
 
1-x
Fe
3+
x
)(OH)
 
2
][SO
 
4
]
 
x/2
· nH
 
2
O
7.DD.35Shigaite
Mn
 
6
Al
 
3
(OH)
 
18
[Na(H
 
2
O)
 
6
][SO
 
4
]
 
2
· 6H
 
2
O
7.DD.35Wermlandite
Mg
 
7
Al
 
2
(OH)
 
18
[Ca(H
 
2
O)
 
6
][SO
 
4
]
 
2
· 6H
 
2
O
7.DD.35Woodwardite
Cu
 
1-x
Al
 
x
(OH)
 
2
[SO
 
4
]
 
x/2
· nH
 
2
O
7.DD.35Zincaluminite
Zn
 
6
Al
 
6
(SO
 
4
)
 
2
(OH)
 
16
· 5H
 
2
O
7.DD.35Hydrowoodwardite
(Cu
 
1-x
Al
 
x
)(OH)
 
2
[SO
 
4
]
 
x/2
· nH
 
2
O
7.DD.35Zincowoodwardite
Zn
 
1-x
Al
 
x
(OH)
 
2
[SO
 
4
]
 
x/2
· nH
 
2
O
7.DD.35Natroglaucocerinite
Na
 
x
Zn
 
8-y
Al
 
y
(SO
 
4
)
 
(x+y)/2
(OH)
 
16
· 6H
 
2
O
7.DD.35Nikischerite
Fe
2+
6
Al
 
3
(OH)
 
18
[Na(H
 
2
O)
 
6
][SO
 
4
]
 
2
· 6H
 
2
O
7.DD.40Lawsonbauerite
(Mn
2+
 
,Mg)
 
9
Zn
 
4
(SO
 
4
)
 
2
(OH)
 
22
· 8H
 
2
O
7.DD.40Torreyite
(Mg,Mn
2+
 
)
 
7
 
2
Mn
2+
2
Zn
 
4
(SO
 
4
)
 
2
(OH)
 
22
· 8H
 
2
O
7.DD.45Mooreite
Mg
 
9
 
2
Mn
 
2
Zn
 
4
(SO
 
4
)
 
2
(OH)
 
26
· 8H
 
2
O
7.DD.50Namuwite
(Zn,Cu)
 
4
(SO
 
4
)(OH)
 
6
· 4H
 
2
O
7.DD.55Bechererite
(Zn,Cu)
 
6
Zn
 
2
(SO
 
4
,HSiO
 
4
)
 
2
(OH)
 
12
7.DD.60Ramsbeckite
(Cu,Zn)
 
15
(SO
 
4
)
 
4
(OH)
 
22
· 6H
 
2
O
7.DD.65Vonbezingite
Ca
 
6
Cu
 
3
(SO
 
4
)
 
3
(OH)
 
12
· 2H
 
2
O
7.DD.70Redgillite
Cu
 
6
(SO
 
4
)(OH)
 
10
· H
 
2
O
7.DD.75Chalcoalumite
CuAl
 
4
(SO
 
4
)(OH)
 
12
· 3H
 
2
O
7.DD.75Nickelalumite
(Ni,Cu)Al
 
4
(SO
 
4
,(NO
 
3
)
 
2
)(OH)
 
12
· 3H
 
2
O
7.DD.75Kyrgyzstanite
ZnAl
 
4
(SO
 
4
)(OH)
 
12
·3H
 
2
O
7.DD.80Guarinoite
(Zn,Co,Ni)
 
6
(SO
 
4
)(OH,Cl)
 
10
· 5H
 
2
O
7.DD.80Schulenbergite
(Cu,Zn)
 
7
(SO
 
4
,CO
 
3
)
 
2
(OH)
 
10
· 3H
 
2
O
7.DD.80Thérèsemagnanite
(Co,Zn,Ni)
 
6
(SO
 
4
)(OH,Cl)
 
10
· 8H
 
2
O
7.DD.80UM1992-30-SO:CCuHZn
(Zn,Cu)
 
7
(SO
 
4
,CO
 
3
)
 
2
(OH)
 
10
· 3H
 
2
O
7.DD.85Montetrisaite
Cu
 
6
(SO
 
4
)(OH)
 
10
· 2H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
25.2.1Chalcocyanite
CuSO
 
4
25.2.2Bonattite
CuSO
 
4
· 3H
 
2
O
25.2.3Chalcanthite
CuSO
 
4
· 5H
 
2
O
25.2.4Boothite
CuSO
 
4
· 7H
 
2
O
25.2.5Dolerophanite
Cu
 
2
(SO
 
4
)O
25.2.6Antlerite
Cu
 
3
(SO
 
4
)(OH)
 
4
25.2.7Brochantite
Cu
 
4
(SO
 
4
)(OH)
 
6
25.2.8Posnjakite
Cu
 
4
(SO
 
4
)(OH)
 
6
· H
 
2
O
25.2.9Langite
Cu
 
4
(SO
 
4
)(OH)
 
6
· 2H
 
2
O
25.2.10Wroewolfeite
Cu
 
4
(SO
 
4
)(OH)
 
6
· 2H
 
2
O
25.2.11Kröhnkite
Na
 
2
Cu(SO
 
4
)
 
2
· 2H
 
2
O
25.2.12Natrochalcite
NaCu
 
2
(SO
 
4
)
 
2
(OH) · 2H
 
2
O
25.2.13Piypite
K
 
2
Cu
 
2
(SO
 
4
)
 
2
O
25.2.14Fedotovite
K
 
2
Cu
 
3
(SO
 
4
)
 
3
O
25.2.15Cyanochroite
K
 
2
Cu(SO
 
4
)
 
2
· 6H
 
2
O
25.2.16Euchlorine
KNaCu
 
3
(SO
 
4
)
 
3
O
25.2.17Devilline
CaCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
25.2.18Leightonite
K
 
2
Ca
 
2
Cu(SO
 
4
)
 
4
· 2H
 
2
O
25.2.19Chalcoalumite
CuAl
 
4
(SO
 
4
)(OH)
 
12
· 3H
 
2
O
25.2.20Cyanotrichite
Cu
 
4
Al
 
2
(SO
 
4
)(OH)
 
12
· 2H
 
2
O
25.2.21Woodwardite
Cu
 
1-x
Al
 
x
(OH)
 
2
[SO
 
4
]
 
x/2
· nH
 
2
O
25.2.23Guildite
CuFe
3+
 
(SO
 
4
)
 
2
(OH) · 4H
 
2
O
25.2.24Ransomite
CuFe
 
2
(SO
 
4
)
 
4
· 6H
 
2
O
25.2.26Klyuchevskite
K
 
3
Cu
 
3
(Fe
3+
 
,Al)(SO
 
4
)
 
4
O
 
2
25.2.27Poitevinite
(Cu,Fe,Zn)SO
 
4
· H
 
2
O
25.2.28Argentojarosite
AgFe
3+
3
(SO
 
4
)
 
2
(OH)
 
6

Other Names for Campigliaite

Synonyms:
IMA1981-001
Other Languages:
German:Campigliait
Russian:Кампильяит
Spanish:Campigliaita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Campigliaite

Reference List:

- +
American Mineralogist: 67: 385-393.

Internet Links for Campigliaite

Search Engines:
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  • External Links:
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  • Look for Campigliaite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Campigliaite details from Handbook of Mineralogy (PDF)
  • Mineral Dealers:
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  • Localities for Campigliaite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • New South Wales
      • Yancowinna Co.
        • Broken Hill
    Private Collection
    Italy
     
    • Piedmont
      • Alessandria Province
        • Voltaggio
    Piccoli, G. C., Maletto, G., Bosio, P., & Lombardo, B. (2007). Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo F. Eusebio - Alba, 607 pag.
    • Tuscany
      • Livorno Province
        • Campiglia Marittima
          • Temperino
    Am Min 67:385-393
    USA
     
    • Utah
      • Piute Co.
        • Tushar Mts
          • Cottonwood Creek
            • Mount Baldy District
      • Sevier Co.
    Smithsonian specimen USNM Number: 170031
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