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Campigliaite

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Formula:
Mn2+Cu4(SO4)2(OH)6 · 4H2O
System:
Monoclinic
Colour:
Light blue
Lustre:
Vitreous
Member of:
Name:
For the locality.
Devilline Group.

The manganese analogue of devilline and lautenthalite.

Classification of Campigliaite

Approved 1981
7.DD.30

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.6.6.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
6 : (AB)5(XO4)2Zq·xH2O
25.2.22

25 : Sulphates
2 : Sulphates of Cu and Ag
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First Recorded Occurrence of Campigliaite

General Appearance of First Recorded Material:
Light blue tufts
Place of Conservation of First Recorded Material:
Museum of Florence University #214/I
Year of Discovery:
1981
Geological Setting of First Recorded Material:
Altered skarn deposit
Associated Minerals at First Recorded Locality:

Physical Properties of Campigliaite

Vitreous
Diaphaneity (Transparency):
Transparent
Colour:
Light blue
Cleavage:
Perfect
{100}
Density:
3.06 g/cm3 (Calculated)

Crystallography of Campigliaite

Crystal System:
Monoclinic
Cell Parameters:
a = 21.7Å, b = 6.09Å, c = 11.24Å
β = 100.3°
Ratio:
a:b:c = 3.563 : 1 : 1.846
Unit Cell Volume:
V 1464.5 ų
Z:
4

Optical Data of Campigliaite

Type:
Biaxial (-)
RI values:
nα = 1.589 nβ = 1.645 nγ = 1.659
2V:
Measured: 52° , Calculated: 50°
Max Birefringence:
δ = 0.070
Image shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v weak

Chemical Properties of Campigliaite

Formula:
Mn2+Cu4(SO4)2(OH)6 · 4H2O
Essential elements:
All elements listed in formula:

Relationship of Campigliaite to other Species

Member of:
Other Members of Group:
Aldridgeite(Cd,Ca)(Cu,Zn)4(SO4)2(OH)6 · 3H2O
DevillineCaCu4(SO4)2(OH)6 · 3H2O
KobyasheviteCu5(SO4)2(OH)6·4H2O
LautenthalitePbCu4(SO4)2(OH)6 · 3H2O
Unnamed (Dimorph of Devilline)CaCu4(SO4)2(OH)6 · 3H2O
7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2O
7.DD.10LangiteCu4(SO4)(OH)6 · 2H2O
7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2O
7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2O
7.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2O
7.DD.20KtenasiteZn(Cu,Zn)4(SO4)2(OH)6 · 6H2O
7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2O
7.DD.30DevillineCaCu4(SO4)2(OH)6 · 3H2O
7.DD.30OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2O
7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2O
7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2O
7.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6·4H2O
7.DD.35Carrboydite[(Ni1-xAlx)(OH)2][SO4]x/2 · nH2O
7.DD.35Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2O
7.DD.35Honessite(Ni1-xFex3+)(OH)2[SO4]x/2 · nH2O
7.DD.35Hydrohonessite(Ni1-xFex3+)(OH)2[SO4]x/2 · nH2O
7.DD.35MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O
7.DD.35Mountkeithite[(Mg1-xFex3+)(OH)2][SO4]x/2 · nH2O
7.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O
7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O
7.DD.35WoodwarditeCu1-xAlx(OH)2[SO4]x/2 · nH2O
7.DD.35ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2O
7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2O
7.DD.35NatroglaucoceriniteNaxZn8-yAly(SO4)(x+y)/2(OH)16 · 6H2O
7.DD.35NikischeriteFe62+Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O
7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2O
7.DD.40Torreyite(Mg,Mn2+)72Mn22+Zn4(SO4)2(OH)22 · 8H2O
7.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2O
7.DD.50Namuwite(Zn,Cu)4(SO4)(OH)6 · 4H2O
7.DD.55Bechererite(Zn,Cu)6Zn2(SO4,HSiO4)2(OH)12
7.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2O
7.DD.65VonbezingiteCa6Cu3(SO4)3(OH)12 · 2H2O
7.DD.70RedgilliteCu6(SO4)(OH)10 · H2O
7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
7.DD.75Nickelalumite(Ni,Cu)Al4(SO4,(NO3)2)(OH)12 · 3H2O
7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12·3H2O
7.DD.80Guarinoite(Zn,Co,Ni)6(SO4)(OH,Cl)10 · 5H2O
7.DD.80Schulenbergite(Cu,Zn)7(SO4,CO3)2(OH)10 · 3H2O
7.DD.80Thérèsemagnanite(Co,Zn,Ni)6(SO4)(OH,Cl)10 · 8H2O
7.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2O
7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2O
25.2.1ChalcocyaniteCuSO4
25.2.2BonattiteCuSO4 · 3H2O
25.2.3ChalcanthiteCuSO4 · 5H2O
25.2.4BoothiteCuSO4 · 7H2O
25.2.5DolerophaniteCu2(SO4)O
25.2.6AntleriteCu3(SO4)(OH)4
25.2.7BrochantiteCu4(SO4)(OH)6
25.2.8PosnjakiteCu4(SO4)(OH)6 · H2O
25.2.9LangiteCu4(SO4)(OH)6 · 2H2O
25.2.10WroewolfeiteCu4(SO4)(OH)6 · 2H2O
25.2.11KröhnkiteNa2Cu(SO4)2 · 2H2O
25.2.12NatrochalciteNaCu2(SO4)2(OH) · 2H2O
25.2.13PiypiteK2Cu2(SO4)2O
25.2.14FedotoviteK2Cu3(SO4)3O
25.2.15CyanochroiteK2Cu(SO4)2 · 6H2O
25.2.16EuchlorineKNaCu3(SO4)3O
25.2.17DevillineCaCu4(SO4)2(OH)6 · 3H2O
25.2.18LeightoniteK2Ca2Cu(SO4)4 · 2H2O
25.2.19ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
25.2.20CyanotrichiteCu4Al2(SO4)(OH)12 · 2H2O
25.2.21WoodwarditeCu1-xAlx(OH)2[SO4]x/2 · nH2O
25.2.23GuilditeCuFe3+(SO4)2(OH) · 4H2O
25.2.24RansomiteCuFe2(SO4)4 · 6H2O
25.2.26KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2
25.2.27Poitevinite(Cu,Fe,Zn)SO4 · H2O
25.2.28ArgentojarositeAgFe33+(SO4)2(OH)6

Other Names for Campigliaite

Name in Other Languages:

Other Information

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Campigliaite

Reference List:
American Mineralogist: 67: 385-393.

Internet Links for Campigliaite

Localities for Campigliaite

(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
Australia
 
  • New South Wales
    • Yancowinna Co.
      • Broken Hill
Private Collection
Italy
 
  • Piedmont
    • Alessandria Province
      • Voltaggio
Piccoli, G. C., Maletto, G., Bosio, P., & Lombardo, B. (2007). Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo F. Eusebio - Alba, 607 pag.
  • Tuscany
    • Livorno Province
      • Campiglia Marittima
        • Temperino
Am Min 67:385-393
USA
 
  • Utah
    • Piute Co.
      • Tushar Mts
        • Cottonwood Creek
          • Mount Baldy District
    • Sevier Co.
Smithsonian specimen USNM Number: 170031
Mineral and/or Locality  
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