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Chalcedony

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System:TrigonalColour:colorless, white, gray, ...
Hardness:6½ - 7
Name:Mentioned by Agricola (1546) of a stone named for the town of Chalcedon, now called Kadıköy, and is a district within the city of Istanbul, Turkey.
A variety of Quartz

Depending on the context, the term "chalcedony" has different meanings.

1. A more general term for all varieties of quartz that are made of microscopic or submicroscopic crystals, the so-called microcrystalline varieties of quartz. Examples are the different types of agate, jasper, chert, chrysoprase, onyx, pietersite, etc.



Types of Fibrous Chalcedony
2. In the strict sense, and in scientific literature, "chalcedony" designates aggregates of parallely grown ("fibrous") quartz crystals of microscopic and sub-microscopic size. Based on the conspicious behaviour of thin sections of chalcedony in polarized light, at least two types can be distinguished (Michel-Lévy and Munier-Chalmas, 1892; Correns and Nagelschmidt, 1933; Braitsch, 1957; Frondel, 1978; Flörke et al. 1991):
- length-fast chalcedony, with crystallites stacked perpendicular to the c-axis. The fibers may be twisted around the elongation axis.
- length-slow chalcedony or Quartzine, with crystallites stacked parallel to the c-axis.

Both types tend to develop radially grown "fibers", resulting in botryoidal, rounded and stalactitic habits. They often show concentric banding perpendicular to the fiber orientation and are then called Agate.
Length-fast chalcedony and quartzine may be found intergrown. The crystallites are commonly polysynthetically twinned by the Brazil law (Graetsch, 1994; Cady et al 1998; Xu et al 1998).
It is not possible to distinguish the types with the naked eye. Length-fast chalcedony is far more common than quartzine.

Aggregates of randomly intergrown microscopic grains are called "microquartz" (Flörke et al, 1991; Graetsch, 1994). The more general term explained under (1) includes length-slow and length-fast chalcedony as well as microquartz.

Most chalcedony contains considerable amounts of the silica mineral Mogánite, usually between 1% and 20% (Heaney and Post, 1992). Aging slowly converts the mogánite into quartz and results in mogánite-free chalcedony (Moxon, 2004) .
Chalcedony contains small amounts of water, both as molecular water and bound in silanole (Si-OH) groups (Frondel, 1982).


3. A term sometimes used for chalcedony that is not agate, jasper or another sub-variety. Used in particular for botryoidal specimens.




Chalcedony: Agate, Mexico

Chalcedony: Chalcedony Rose, New Mexico

Chalcedony: Red Jasper, Arizona

Chalcedony: Flint Nodule, England

Chalcedony: Chrysoprase, Poland

Chalcedony: Heliotrope, Brazil




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Classification of Chalcedony

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Type Occurrence of Chalcedony

Type Locality:Kadıköy (Chalcedon), Istanbul Province, Marmara Region, Turkey

Occurrences of Chalcedony

Geological Setting:Very common.
As nodules, vein fillings, crusts in volcanic rocks.
As sinter-like crusts in low- to medium temperature hydrothermal veins.
Main constituent in silica-rich marine sedimentary rocks.
As nodular concretions and layers in limestones and marls.
As metasomatic replacement in limestones and marls ("replacement chert").
As cement in sandstones.
Replacing other minerals in pseudomorphoses.
As a fossilizing material (petrified wood, coral agate).

Physical Properties of Chalcedony

Lustre:Waxy, Dull
Diaphaneity (Transparency):Translucent
Comment:vitreous when polished
Colour:colorless, white, gray, blue, any color due to embedded minerals, multicolored specimen not uncommon.
Streak:White
Hardness (Mohs):6½ - 7
Tenacity:Brittle
Cleavage:None Observed
Less brittle than macrocrystalline quartz.
Fracture:Conchoidal, Sub-Conchoidal
Density (measured):2.6 g/cm3
Comment:varies with amount and type of impurities

Crystallography of Chalcedony

Crystal System:Trigonal

Relationship of Chalcedony to other Species

Common Associates:
Zeolite GroupQuartzOpalHematiteGoethite
Calcite

Other Names for Chalcedony

Synonyms:
CeracahtesCerachatesChalcedoneChalcedoniteChalcedononyx
Merlinite
Other Languages:
Basque:Kaltzedonia
Breton:Kalkedon
Catalan:Calcedònia
Czech:Chalcedon
Dutch:Chalcedoon
Esperanto:Kalcedono
Estonian:Kaltsedon
Finnish:Kalsedoni
French:Calcédoine
German:Chalcedon
Chalcedonit
Chalzedon
Kalzedon
Hebrew:כלקדון
Italian:Calcedonio
Japanese:石髓
Korean:옥수
Latin:Calcedonius
Latvian:Halcedons
Lithuanian:Chalcedonas
Norwegian (Bokmål):Kalsedon
Polish:Chalcedon
Portuguese:Calcedônia
Romanian:Calcedon
Russian:Халцедон
Serbian (Cyrillic Script):Калцедон
Simplified Chinese:玉髓
Slovak:Chalcedón
Spanish:Calcedonia
Swedish:Kalcedon
Turkish:Kalsedon
Ukrainian:Халцедон
Varieties:
Abakusz-köAgateAgate-JasperAgatized coralAmarillo Stone
AmberineAzurchalcedonyBall JasperBasaniteBayate
BeekiteBinghamiteBloodstoneBlue ChalcedonyBlue Lace Agate
Botswana AgateBrecciated AgateBuhrstoneCarnelianChrome-Chalcedony
ChrysojasperCloud AgateCrazy Lace AgateCreoliteCubosilicite
DallasiteDamsoniteDarlingiteDendritic AgateDiackethyst
Egyptian JasperEnhydro AgateEye AgateFairburn AgateFire Agate
Fortification AgateFossil AgateHaema-ovoid-agatesHerbeckiteIris Agate
IrnimiteJasperKeystonite ChalcedonyKinraditeLaguna Agate
Lake Superior AgateLandscape AgateMexican Lace AgateMocha StoneMoss Agate
MyrickiteNipomo AgateOnyxOwyhee JasperPastelite
PietersitePigeon Blood AgatePlasmaPlume AgateQuartzine
QuetzalitztliRiband AgateRiband JasperSardSardonyx
SeftoniteSnakeskin AgateVogelaugenachatVogelaugenjaspisWatercolour jasper
WilkiteYoungite

Other Information

Fluorescence in UV light:None in pure specimen, however green fluorescence in short-wave UV light is very common at many localities.
Other Information:Certain sub-varieties like jasper may be opaque.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Chalcedony

Reference List:

- +
Michel-Lévy, A., Munier-Chalmas, C.P.E. (1892) Mémoire sur diverses formes affectées par le réseau élémentaire du quartz. Bulletin de la Société Française de Minéralogie 15, 159-190.

Correns, C.W., Nagelschmidt, G. (1933) Über Faserbau und optische Eigenschaften von Chalzedon. Zeitschrift für Kristallographie, 85, 199-213.

Braitsch, O. (1957) Über die natürlichen Faser- und Aggregationstypen beim SiO2, ihre Verwachsungsformen, Richtungsstatistik und Doppelbrechung. Heidelberger Beiträge zur Mineralogie und Petrographie 5, 331-372.

White, J.F., Corwin, J.F. (1961) Synthesis and origin of chalcedony. American Mineralogist 46, 112-119.

Frondel, C. (1978) Characters of quartz fibers. American Mineralogist, 63, 17-27.

Frondel, C. (1982) Structural hydroxyl in chalcedony (type B quartz). American Mineralogist, 67, 1248-1257.

Flörke, O.W., Graetsch, H., Martin, B., Röller, K., Wirth, R. (1991) Nomenclature of micro- and non-crystalline silica minerals based on structure and microstructure. Neues Jahrbuch für Mineralogie - Abhandlungen, 163, 19-42.

Graetsch, H. (1994) Structural characteristics of opaline and microcrystalline silica minerals. Reviews in Mineralogy, Vol.29, Silica - Physical behavior, geochemistry and materials applications.

Cady, S.L., Wenk, H.R., Sintubin, M. (1998) Microfibrous quartz varieties: characterization by quantitative X-ray texture analysis and transmission electron microscopy. Contributions to Mineralogy and Petrology, 130, 320-335.

Xu, H., Buseck, P.R., Luo, G. (1998) HRTEM investigation of microstructure in length-slow chalcedony. American Mineralogist, 83, 542-545.

Moxon, T. (2004) Moganite and water content as a function of age in agate: an XRD and thermogravimetric study. European Journal of Mineralogy, 16, 269-278.

Patrick Schmidt, Ludovic Bellot-Gurlet, Aneta Slodczyk, François Fröhlich (2012) A hitherto unrecognised band in the Raman spectra of silica rocks: influence of hydroxylated Si–O bonds (silanole) on the Raman moganite band in chalcedony and flint (SiO2). Physics and Chemistry of Minerals 39, 455-464.

Mindat.org articles about Chalcedony

Article entries:
Boley agatesDavid Goza

Internet Links for Chalcedony

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  • Find Chalcedony on www.crystalclassics.co.uk
  • Specimens:The following Chalcedony specimens are currently listed for sale on minfind.com.

    Localities for Chalcedony

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