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Chlorothionite

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Somma-Vesuvius Complex, Naples Province, Campania, Italy
© Brent Thorne

Formula:
K
 
2
Cu[Cl
 
2
|SO
 
4
]
System:OrthorhombicColour:Bright blue.
Hardness:2½
Name:In allusion to the chemical composition, containing CHLORine and sulphur (THIO-).
This page provides mineralogical data about Chlorothionite.

Classification of Chlorothionite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:6/B.05-20
Nickel-Strunz 10th (pending) edition ID:7.BC.25

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
Dana 8th edition ID:30.1.11.1

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1
Hey's CIM Ref.:26.6

26 : Sulphates with Halide
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Physical Properties of Chlorothionite

Colour:Bright blue.
Hardness (Mohs):2½
Density (measured):2.67 g/cm3
Comment:Measured values on artificial crystals.

Crystallography of Chlorothionite

Crystal System:Orthorhombic
Class (H-M):mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:Pnma {P21/n 21/m 21/a}
Cell Parameters:a = 7.73Å, b = 6.07Å, c = 16.29Å
Ratio:a:b:c = 1.273 : 1 : 2.684
Unit Cell Volume:V 764.34 ų (Calculated from Unit Cell)
Morphology:Crystalline incrustations.

Optical Data of Chlorothionite

Type:Biaxial (+)

Chemical Properties of Chlorothionite

Formula:
K
 
2
Cu[Cl
 
2
|SO
 
4
]
Essential elements:Cl, Cu, K, O, S
All elements listed in formula:Cl, Cu, K, O, S

Relationship of Chlorothionite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
7.BC.05D'Ansite
Na
 
21
Mg(SO
 
4
)
 
10
Cl
 
3
7.BC.10Alunite
KAl
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Ammonioalunite
(NH
 
4
)Al
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Ammoniojarosite
(NH
 
4
)Fe
3+
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Argentojarosite
AgFe
3+
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Beaverite
Pb(Fe
3+
 
,Cu,Al)
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Dorallcharite
(Tl,K)Fe
3+
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Huangite
CaAl
 
6
[(OH)
 
3
|SO
 
4
]
 
4
7.BC.10Hydroniumjarosite
(H
 
3
O)Fe
3+
3
(SO
 
4
)
 
2
(OH)
 
6
7.BC.10Jarosite
KFe
3+
 
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Minamiite
(Na,Ca
 
0.5
,K)Al
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Natroalunite
(Na,K)Al
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Natrojarosite
NaFe
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Osarizawaite
Pb(Al,Cu)
 
3
[(OH,H
 
2
O)
 
3
|SO
 
4
]
 
2
7.BC.10Plumbojarosite
PbFe
3+
6
[(OH)
 
3
|SO
 
4
]
 
4
7.BC.10Schlossmacherite
(H
 
3
O,Ca)Al
 
3
[(OH)
 
6
|(SO
 
4
,AsO
 
4
)
 
2
]
7.BC.10Walthierite
BaAl
 
6
[(OH)
 
3
|SO
 
4
]
 
4
7.BC.15Ye'elimite
Ca
 
4
Al
 
6
[O
 
12
|SO
 
4
]
7.BC.20Atlasovite
K(BiO)Cu
 
6
Fe
3+
 
[Cl|O
 
3
|(SO
 
4
)
 
5
]
7.BC.20Nabokoite
KCu
 
7
Te
4+
 
[Cl|O
 
4
|(SO
 
4
)
 
5
]
7.BC.30Euchlorine
KNaCu
 
3
[O|(SO
 
4
)
 
3
]
7.BC.30Fedotovite
K
 
2
Cu
 
3
[O|(SO
 
4
)
 
3
]
7.BC.35Kamchatkite
KCu
 
3
[O|Cl|(SO
 
4
)
 
2
]
7.BC.40Piypite
K
 
2
Cu
 
2
[O|(SO
 
4
)
 
2
]
7.BC.45Klyuchevskite
K
 
3
Cu
 
3
(Fe
3+
 
,Al)[O|(SO
 
4
)
 
2
]
 
2
7.BC.45Alumoklyuchevskite
K
 
3
Cu
 
3
(Al,Fe
3+
 
)[O|(SO
 
4
)
 
2
]
 
2
7.BC.50Caledonite
Cu
 
2
Pb
 
5
[(OH)
 
6
|CO
 
3
|(SO
 
4
)
 
3
]
7.BC.55Wherryite
Pb
 
7
Cu
 
2
(SO
 
4
)
 
4
(SiO
 
4
)
 
2
(OH)
 
2
7.BC.60Mammothite
Pb
 
6
Cu
 
4
AlSb[(OH)
 
9
|Cl
 
2
|SO
 
4
]
 
2
7.BC.65Linarite
PbCu[(OH)
 
2
|SO
 
4
]
7.BC.65Schmiederite
Pb
 
2
Cu
 
2
[(OH)
 
4
|SeO
 
3
|SeO
 
4
]
7.BC.65Munakataite
Pb
 
2
Cu
 
2
(Se
4+
 
O
 
3
)(SO
 
4
)(OH)
 
4
7.BC.70Chenite
Pb
 
4
Cu[(OH)
 
3
|SO
 
4
]
 
2
7.BC.75Krivovichevite
Pb
 
3
[Al(OH)
 
6
](SO
 
4
)(OH)
7.BC.80Anhydrokainite
KMgClSO
 
4
Related Minerals - Hey's Index Grouping:

- +
26.1Kogarkoite
Na
 
3
[F|SO
 
4
]
26.2Sulphohalite
Na
 
6
[F|Cl|(SO
 
4
)
 
2
]
26.3Schairerite
Na
 
3
[(F,Cl)|SO
 
4
]
26.4Galeite
Na
 
15
[F
 
4
|Cl|(SO
 
4
)
 
5
]
26.5Connellite
Cu
 
19
[(OH)
 
32
|SO
 
4
|Cl
 
4
] · 3H
 
2
O
26.7Kamchatkite
KCu
 
3
[O|Cl|(SO
 
4
)
 
2
]
26.8Spangolite
Cu
 
6
Al[(OH)
 
12
|Cl|SO
 
4
] · 3H
 
2
O
26.9Aubertite
CuAl[Cl|(SO
 
4
)
 
2
] · 14H
 
2
O
26.10Magnesioaubertite
(Mg,Cu)Al[Cl|(SO
 
4
)
 
2
] · 14H
 
2
O
26.11Svyazhinite
(Mg,Mn
2+
 
,Ca)(Al,Fe
3+
 
)[F|(SO
 
4
)
 
2
] · 14H
 
2
O
26.12D'Ansite
Na
 
21
Mg(SO
 
4
)
 
10
Cl
 
3
26.13Anhydrokainite
KMgClSO
 
4
26.14Kainite
KMg[Cl|SO
 
4
] · 3H
 
2
O
26.15Mosesite
[Hg
 
2
N]
+
 
(Cl,SO
 
4
,MoO
 
4
) · H
 
2
O
26.16Kleinite
[Hg
 
2
N]
+
3
Cl
 
2
S
 
0.5
 · H
 
2
O
26.17Wilcoxite
MgAl[F|(SO
 
4
)
 
2
] · 18H
 
2
O
26.18Creedite
Ca
 
3
[SO
 
4
|Al
 
2
F
 
8
(OH)
 
2
] · 2H
 
2
O
26.19Lannonite
HCa
 
4
Mg
 
2
Al
 
4
(SO
 
4
)
 
8
F
 
9
·32H
 
2
O
26.20Chukhrovite-(Y)
Ca
 
3
(Y,Ce)[F|SO
 
4
|(AlF
 
6
)
 
2
] · 10H
 
2
O
26.21Chukhrovite-(Ce)
Ca
 
3
(Ce,Y)[F|SO
 
4
|(AlF
 
6
)
 
2
] · 10H
 
2
O
26.22Grandreefite
Pb
 
2
SO
 
4
F
 
2
26.23Pseudograndreefite
Pb
 
6
SO
 
4
F
 
10
26.24Sundiusite
Pb
 
10
[O
 
8
|SO
 
4
|Cl
 
2
]
26.25Caracolite
Na
 
3
Pb
 
2
[Cl|(SO
 
4
)
 
3
]
26.26Mammothite
Pb
 
6
Cu
 
4
AlSb[(OH)
 
9
|Cl
 
2
|SO
 
4
]
 
2
26.27Atlasovite
K(BiO)Cu
 
6
Fe
3+
 
[Cl|O
 
3
|(SO
 
4
)
 
5
]
26.28Xitieshanite
Fe
3+
 
[Cl|SO
 
4
] · 6H
 
2
O
26.29Nabokoite
KCu
 
7
Te
4+
 
[Cl|O
 
4
|(SO
 
4
)
 
5
]

Other Names for Chlorothionite

Other Languages:
German:Chlorothionit
Russian:Хлоротионит
Spanish:Chlorothionita

Other Information

Other Information:Soluble in water.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Chlorothionite

Reference List:Scacchi (1872) Acc. Napoli, Rendus: 203.

Bellanca (1946) Periodico de Mineralogia-Roma: 15: 33 (artificial crystals).

Zambonini, Ferruccio (1910) Mineralogia Vesuviana. 368 pp., Naples: 329 (artificial crystals).

Goldschmidt, V. (1913) Atlas der Krystallformen. 9 volumes, atlas, and text: vol. 2: 2: 151 (artificial crystals).

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 547.

Zeitschrift für Kristallographie: 192: 1-52.

Internet Links for Chlorothionite

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    Localities for Chlorothionite

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    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Italy
     
    • Campania
      • Naples Province
        • Somma-Vesuvius Complex
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 547; Lapis (1994): 5 p.13-23,58.
    Russia
     
    • Far-Eastern Region
      • Kamchatka Oblast'
    		No reference listed
    Mineral and/or Locality
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