Arupite
A valid IMA mineral species
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About Arupite
Formula:
Ni3(PO4)2 · 8H2O
Colour:
Blue to light blue
Lustre:
Dull, Earthy
Hardness:
1½ - 2
Specific Gravity:
2.85 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
Named in 1990 by Vagn Fabius Buchwald in honor of Hans Henning Arup (4 May 1928 - 19 November 2012), Director of the Danish Corrosion Center, Copenhagen, Denmark.
Unique Identifiers
Mindat ID:
379
Long-form identifier:
mindat:1:1:379:3
GUID
(UUID V4):
(UUID V4):
cd007803-0812-4f5d-93e3-1a2d2ef9b3a5
IMA Classification of Arupite
Approved
First published:
1990
Classification of Arupite
8.CE.40
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
40.3.6.8
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
19.15.1
19 : Phosphates
15 : Phosphates of Ni
19 : Phosphates
15 : Phosphates of Ni
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Arp | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Arupite
Dull, Earthy
Transparency:
Translucent
Colour:
Blue to light blue
Streak:
Light blue
Hardness:
1½ - 2 on Mohs scale
Density:
2.85 g/cm3 (Calculated)
Optical Data of Arupite
Type:
Biaxial (+)
RI values:
nα = 1.632 nβ = 1.650 nγ = 1.680
2V:
Measured: 60° to 70°, Calculated: 78°
Birefringence:
0.048
Max Birefringence:
δ = 0.048
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v strong
Pleochroism:
Visible
Comments:
X = blue, Z = colorless
Chemistry of Arupite
Mindat Formula:
Ni3(PO4)2 · 8H2O
Elements listed:
Common Impurities:
Fe
Crystallography of Arupite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Cell Parameters:
a = 9.889 Å, b = 13.225 Å, c = 4.645 Å
β = 102.41°
β = 102.41°
Ratio:
a:b:c = 0.748 : 1 : 0.351
Unit Cell V:
593.29 ų (Calculated from Unit Cell)
Z:
2
Comment:
I2/m
Crystal Structure
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Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0018468 | Arupite | Shouwen J, Wang D, Gao X, Wen X, Zhou J (2008) Poly[octaaquadi-mu-phosphato-tri-nickel(II)] Acta Crystallographica E64 m259-m259 | 2008 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
7.878 Å | (26) |
6.624 Å | (100) |
4.818 Å | (24) |
3.805 Å | (21) |
3.152 Å | (24) |
2.922 Å | (23) |
2.672 Å | (17) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47c : [Carbonates, phosphates, borates, nitrates] | |
47i : [Terrestrial weathering of meteorites] |
Type Occurrence of Arupite
General Appearance of Type Material:
Short prismatic blue crystals to 5 microns.
Place of Conservation of Type Material:
Division of Meteorites, National Museum of Natural History, Washington, D.C., USA, numbers 659, 804, 877.
Geological Setting of Type Material:
Weathered meteorite.
Associated Minerals at Type Locality:
Synonyms of Arupite
Other Language Names for Arupite
Relationship of Arupite to other Species
Member of:
Other Members of this group:
Annabergite | Ni3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
Babánekite | Cu3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
Barićite | (Mg,Fe)3(PO4)2 · 8H2O | Mon. 2/m : B2/m |
Erythrite | Co3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
Erythrite-Köttigite Series | ||
Hörnesite | Mg3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
Köttigite | Zn3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
Manganohörnesite | Mn2+3(AsO4)2 · 8H2O | Mon. 2/m : P2/m |
Monteneroite | Cu2+Mn2+2(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
Pakhomovskyite | Co3(PO4)2 · 8H2O | Mon. 2/m : B2/m |
Parasymplesite | Fe2+3(AsO4)2 · 8H2O | Mon. 2/m : B2/m |
Vivianite | Fe2+Fe2+2(PO4)2 · 8H2O | Mon. 2/m : B2/m |
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
8.CE.X | Babánekite | Cu3(AsO4)2 · 8H2O |
8.CE. | Monteneroite | Cu2+Mn2+2(AsO4)2 · 8H2O |
8.CE.05 | Chudobaite | (Mg,Zn)5(AsO4)2(HAsO4)2 · 10H2O |
8.CE.05 | Geigerite | Mn2+5(AsO4)2(HAsO4)2 · 10H2O |
8.CE.10 | Newberyite | Mg(PO3OH) · 3H2O |
8.CE.15 | Brassite | Mg(HAsO4) · 4H2O |
8.CE.20 | Phosphorrösslerite | Mg(PO3OH) · 7H2O |
8.CE.20 | Rösslerite | Mg(HAsO4) · 7H2O |
8.CE.25 | Metaswitzerite | Mn2+3(PO4)2 · 4H2O |
8.CE.25 | Switzerite | Mn2+3(PO4)2 · 7H2O |
8.CE.30 | Lindackerite | CuCu4(AsO4)2(HAsO4)2 · 9H2O |
8.CE.30 | Ondrušite | CaCu4(AsO4)2(HAsO4)2 · 10H2O |
8.CE.30 | Veselovskýite | ZnCu4(AsO4)2(HAsO4)2 · 9H2O |
8.CE.30 | Pradetite | CoCu4(AsO4)2(HAsO4)2 · 9H2O |
8.CE.30 | Klajite | MnCu4(AsO4)2(HAsO4)2 · 9-10H2O |
8.CE.30 | Hloušekite | (Ni,Co)Cu4(AsO4)2(AsO3OH)2 · 9H2O |
8.CE.35 | Bobierrite | Mg3(PO4)2 · 8H2O |
8.CE.40 | Annabergite | Ni3(AsO4)2 · 8H2O |
8.CE.40 | Barićite | (Mg,Fe)3(PO4)2 · 8H2O |
8.CE.40 | Erythrite | Co3(AsO4)2 · 8H2O |
8.CE.40 | Ferrisymplesite | Fe3+3(AsO4)2(OH)3 · 5H2O |
8.CE.40 | Hörnesite | Mg3(AsO4)2 · 8H2O |
8.CE.40 | Köttigite | Zn3(AsO4)2 · 8H2O |
8.CE.40 | Manganohörnesite | Mn2+3(AsO4)2 · 8H2O |
8.CE.40 | Parasymplesite | Fe2+3(AsO4)2 · 8H2O |
8.CE.40 | Vivianite | Fe2+Fe2+2(PO4)2 · 8H2O |
8.CE.40 | Pakhomovskyite | Co3(PO4)2 · 8H2O |
8.CE.45 | Symplesite | Fe2+3(AsO4)2 · 8H2O |
8.CE.50 | Cattiite | Mg3(PO4)2 · 22H2O |
8.CE.55 | Koninckite | Fe3+PO4 · 3H2O |
8.CE.60 | Kaňkite | FeAsO4 · 3.5H2O |
8.CE.60 | Hilarionite | Fe3+2(SO4)(AsO4)(OH) · 6H2O |
8.CE.65 | Steigerite | Al(VO4) · 3H2O |
8.CE.70 | Metaschoderite | Al2(PO4)(VO4) · 6H2O |
8.CE.70 | Schoderite | Al2(PO4)(VO4) · 8H2O |
8.CE.75 | Malhmoodite | FeZr(PO4)2 · 4H2O |
8.CE.75 | Zigrasite | MgZr(PO4)2 · 4H2O |
8.CE.75 | UM2009-11-PO:CaHZr | CaZr[PO4]2 · 4H2O |
8.CE.80 | Santabarbaraite | Fe3+3(PO4)2(OH)3 · 5H2O |
8.CE.85 | Metaköttigite | (Zn,Fe,Fe)3(AsO4)2 · 8(H2O,OH) |
8.CE.90 | Slavkovite | Cu13(AsO4)6(AsO3OH)4 · 23H2O |
Fluorescence of Arupite
Not fluorescent.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Arupite
mindat.org URL:
https://www.mindat.org/min-379.html
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References for Arupite
Reference List:
Localities for Arupite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Brazil (TL) | |
| [Mandarino +1 other reference |
Japan | |
| The Mineral Species of Japan (5th ed) +1 other reference |
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Santa Catharina meteorite, Morro do Rócio, São Francisco do Sul, Santa Catarina, Brazil