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Clarkeite

A valid IMA mineral species - grandfathered
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About ClarkeiteHide

06974580014947110364012.jpg
Frank Wigglesworth Clarke
Formula:
(Na,Ca,Pb)(UO2)O(OH) · 0-1H2O
Colour:
Dark red-brown, dark brown
Lustre:
Resinous, Waxy, Greasy
Hardness:
4 - 4½
Specific Gravity:
6.29 - 6.39
Crystal System:
Trigonal
Name:
Named in 1931 by Clarence S. Ross, Edward P. Henderson, and Eugene Waldemar Posnjak in honor of Frank Wigglesworth Clarke [March 19, 1847 Boston, Massachusetts, USA - May 23, 1931 Washington, DC, USA], American mineral chemist, and former Chief Chemist of the U.S. Geological Survey. Clarke studied the composition of the Earth's crust and the unit of measure, the clarke, was named as a reference to the local enrichment of a chemical component relative to an average value for the chemistry of the crust.
Clarkeite is a waxy to resinous dark brown replacement of uraninite. It is very uncommon, but is frequently misidentified with brown gummite that is dominated by schoepite-group minerals. Frondel (1956) warned: "Clarkeite is best identified by its X-ray powder pattern. It is indistinguishable from the dark brown types of oxidized uraninite ... and from dense brown types of fourmarierite and vandendriesscheite."


Unique IdentifiersHide

Mindat ID:
1059
Long-form identifier:
mindat:1:1:1059:3
GUID
(UUID V4):
52438cc1-23e1-49d0-91bc-1490d6abcbb8

IMA Classification of ClarkeiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Na(UO2)O(OH) · nH2O
First published:
1931

Classification of ClarkeiteHide

4.GC.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
C : With additional cations; with mainly UO2(O,OH)6 hexagonal polyhedra
5.4.1.1

5 : OXIDES CONTAINING URANIUM OR THORIUM
4 : AX2O7·xH2O
7.16.32

7 : Oxides and Hydroxides
16 : Oxides of U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
CkeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ClarkeiteHide

Resinous, Waxy, Greasy
Transparency:
Translucent
Colour:
Dark red-brown, dark brown
Streak:
Yellow-brown
Hardness:
4 - 4½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Conchoidal, Sub-Conchoidal
Density:
6.29 - 6.39 g/cm3 (Measured)    6.74 g/cm3 (Calculated)

Optical Data of ClarkeiteHide

Type:
Biaxial (-)
RI values:
nα = 1.997 nβ = 2.098 nγ = 2.108
2V:
Measured: 30° to 50°, Calculated: 32°
Birefringence:
0.111
Max Birefringence:
δ = 0.111
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
relatively weak
Pleochroism:
Weak
Comments:
Orange and slightly deeper orange

Chemistry of ClarkeiteHide

Mindat Formula:
(Na,Ca,Pb)(UO2)O(OH) · 0-1H2O

Crystallography of ClarkeiteHide

Crystal System:
Trigonal
Class (H-M):
3m (3 2/m) - Hexagonal Scalenohedral
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 3.954(1) Å, c = 17.660(3) Å
Ratio:
a:c = 1 : 4.466
Unit Cell V:
239.11 ų (Calculated from Unit Cell)
Z:
3
Morphology:
Massive, dense.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001902ClarkeiteFinch R J, Ewing R C (1997) Clarkeite: New chemical and structural data American Mineralogist 82 607-61919970293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.903 Å(64)
3.365 Å(56)
3.195 Å(100)
2.945 Å(28)
2.707 Å(34)
1.977 Å(33)
1.8742 Å(19)
1.8554 Å(19)
1.6807 Å(14)
1.6410 Å(23)
Comments:
AM 82, p. 615; JCPDS 8-315 has extraneous and differing d-values.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47f : [Uranyl (U⁶âș) minerals]

Type Occurrence of ClarkeiteHide

General Appearance of Type Material:
Massive, without cleavage
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 96510, R6607.
Geological Setting of Type Material:
Uranium bearing pegmatite
Associated Minerals at Type Locality:
Reference:
Ross, C.S., Henderson, E.P., Posnjak, E. (1931) Clarkeite; a new uranium mineral. American Mineralogist: 16: 213-220.

Synonyms of ClarkeiteHide

Other Language Names for ClarkeiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
17 photos of Clarkeite associated with Gummite
13 photos of Clarkeite associated with UraniniteUO2
11 photos of Clarkeite associated with UranophaneCa(UO2)2(SiO3OH)2 · 5H2O
9 photos of Clarkeite associated with CyrtoliteZr[(SiO4),(OH)4]
7 photos of Clarkeite associated with FourmarieritePb(UO2)4O3(OH)4 · 4H2O
7 photos of Clarkeite associated with KasolitePb(UO2)(SiO4) · H2O
5 photos of Clarkeite associated with MuscoviteKAl2(AlSi3O10)(OH)2
3 photos of Clarkeite associated with AutuniteCa(UO2)2(PO4)2 · 10-12H2O
1 photo of Clarkeite associated with CuritePb3(H2O)2[(UO2)4O4(OH)3]2

Related Minerals - Strunz-mindat GroupingHide

4.GC.BobfinchiteNa[(UO2)8O3(OH)11] · 10H2OOrth. mmm (2/m 2/m 2/m) : Pbcn
4.GC.10Umohoite(UO2)MoO4 · 2H2OTric.
4.GC.15SpriggitePb3(UO2)6O8(OH)2 · 3H2OMon. 2/m : B2/b

Fluorescence of ClarkeiteHide

Other InformationHide

Notes:
Readily dissolves in mineral acids and hydrochloric acid. Can be dissolved in very dilute acid (1 part acid to 4 parts water).
Health Risks:
radioactive

Internet Links for ClarkeiteHide

References for ClarkeiteHide

Reference List:

Localities for ClarkeiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • La Rioja Province
    • Chilecito department
      • Sañogasta
Angelelli (1984)
Brazil
 
  • Bahia
Pires et al. (2014)
Canada
 
  • Nova Scotia
    • Cumberland Co.
Chatterjee (1977)
Czech Republic
 
  • Plzeƈ Region
    • Tachov District
      • ZadnĂ­ Chodov
PauliĆĄ et al. (2007)
Hungary
 
  • Baranya County
    • PĂ©cs District
      • KƑvĂĄgĂłtöttös
Koch: Minerals of Hungary
India
 
  • Andhra Pradesh
    • Nellore District
Singh et al. (2015)
  • Rajasthan
American Mineralogist: 41: 127-133
Norway
 
  • Agder
Neumann (1985)
    • Lindesnes
      • Vigeland
Sverdrup (1959)
  • Buskerud
    • KrĂždsherad
Neumann (1985)
  • Nordland
    • Narvik
Husdal (2023)
Romania
 
  • Suceava County
HĂźrtopanu P. et al. (2004)
Ukraine
 
  • Zhytomyr Oblast
    • Korosten Raion
Liventseva (n.d.)
USA
 
  • Alaska
    • Yukon-Koyukuk Census Area
      • Sheenjek Mining District
- (2008)
  • Maine
    • Oxford County
      • Newry
King et al. (1994)
      • Stoneham
King et al. (1994)
  • New Hampshire
    • Grafton County
      • Grafton
Frondel (1956) +1 other reference
      • Groton
Not found at this locality: Frondel (1956) +1 other reference
    • Rockingham County
      • Raymond
Smith (2005)
  • North Carolina
    • Mitchell County
Rocks and Minerals
Roger Howell Collection
      • Penland
Ross et al. (1931) +1 other reference
Rocks and Minerals
      • Spruce Pine
Smithsonian Institution Mineral ...
        • Greasy Creek Township
Rocks and Minerals
www.excaliburmineral.com
    • Yancey County
      • Celo
        • Micaville
American Mineralogist +1 other reference
      • Crabtree Creek
Rocks and Minerals
 
Mineral and/or Locality  
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