Clarkeite
A valid IMA mineral species - grandfathered
This page is currently not sponsored. Click here to sponsor this page.
About Clarkeite
Formula:
(Na,Ca,Pb)(UO2)O(OH) · 0-1H2O
Colour:
Dark red-brown, dark brown
Lustre:
Resinous, Waxy, Greasy
Hardness:
4 - 4½
Specific Gravity:
6.29 - 6.39
Crystal System:
Trigonal
Name:
Named in 1931 by Clarence S. Ross, Edward P. Henderson, and Eugene Waldemar Posnjak in honor of Frank Wigglesworth Clarke [March 19, 1847 Boston, Massachusetts, USA - May 23, 1931 Washington, DC, USA], American mineral chemist, and former Chief Chemist of the U.S. Geological Survey. Clarke studied the composition of the Earth's crust and the unit of measure, the clarke, was named as a reference to the local enrichment of a chemical component relative to an average value for the chemistry of the crust.
Clarkeite is a waxy to resinous dark brown replacement of uraninite. It is very uncommon, but is frequently misidentified with brown gummite that is dominated by schoepite-group minerals. Frondel (1956) warned: "Clarkeite is best identified by its X-ray powder pattern. It is indistinguishable from the dark brown types of oxidized uraninite ... and from dense brown types of fourmarierite and vandendriesscheite."
Unique Identifiers
Mindat ID:
1059
Long-form identifier:
mindat:1:1:1059:3
GUID
(UUID V4):
(UUID V4):
52438cc1-23e1-49d0-91bc-1490d6abcbb8
IMA Classification of Clarkeite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Na(UO2)O(OH) · nH2O
First published:
1931
Classification of Clarkeite
4.GC.05
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
C : With additional cations; with mainly UO2(O,OH)6 hexagonal polyhedra
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
C : With additional cations; with mainly UO2(O,OH)6 hexagonal polyhedra
5.4.1.1
5 : OXIDES CONTAINING URANIUM OR THORIUM
4 : AX2O7·xH2O
5 : OXIDES CONTAINING URANIUM OR THORIUM
4 : AX2O7·xH2O
7.16.32
7 : Oxides and Hydroxides
16 : Oxides of U
7 : Oxides and Hydroxides
16 : Oxides of U
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Cke | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Clarkeite
Resinous, Waxy, Greasy
Transparency:
Translucent
Colour:
Dark red-brown, dark brown
Streak:
Yellow-brown
Hardness:
4 - 4½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Conchoidal, Sub-Conchoidal
Density:
6.29 - 6.39 g/cm3 (Measured) 6.74 g/cm3 (Calculated)
Optical Data of Clarkeite
Type:
Biaxial (-)
RI values:
nα = 1.997 nβ = 2.098 nγ = 2.108
2V:
Measured: 30° to 50°, Calculated: 32°
Birefringence:
0.111
Max Birefringence:
δ = 0.111
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
relatively weak
Pleochroism:
Weak
Comments:
Orange and slightly deeper orange
Chemistry of Clarkeite
Mindat Formula:
(Na,Ca,Pb)(UO2)O(OH) · 0-1H2O
Crystallography of Clarkeite
Crystal System:
Trigonal
Class (H-M):
3m (3 2/m) - Hexagonal Scalenohedral
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 3.954(1) Å, c = 17.660(3) Å
Ratio:
a:c = 1 : 4.466
Unit Cell V:
239.11 Ă
Âł (Calculated from Unit Cell)
Z:
3
Morphology:
Massive, dense.
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0001902 | Clarkeite | Finch R J, Ewing R C (1997) Clarkeite: New chemical and structural data American Mineralogist 82 607-619 | 1997 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
5.903 Ă | (64) |
3.365 Ă | (56) |
3.195 Ă | (100) |
2.945 Ă | (28) |
2.707 Ă | (34) |
1.977 Ă | (33) |
1.8742 Ă | (19) |
1.8554 Ă | (19) |
1.6807 Ă | (14) |
1.6410 Ă | (23) |
Comments:
AM 82, p. 615; JCPDS 8-315 has extraneous and differing d-values.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47f : [Uranyl (Uâ¶âș) minerals] |
Type Occurrence of Clarkeite
General Appearance of Type Material:
Massive, without cleavage
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 96510, R6607.
Geological Setting of Type Material:
Uranium bearing pegmatite
Associated Minerals at Type Locality:
Reference:
Ross, C.S., Henderson, E.P., Posnjak, E. (1931) Clarkeite; a new uranium mineral. American Mineralogist: 16: 213-220.
Synonyms of Clarkeite
Other Language Names for Clarkeite
Common Associates
Associated Minerals Based on Photo Data:
17 photos of Clarkeite associated with Gummite | |
13 photos of Clarkeite associated with Uraninite | UO2 |
11 photos of Clarkeite associated with Uranophane | Ca(UO2)2(SiO3OH)2 · 5H2O |
9 photos of Clarkeite associated with Cyrtolite | Zr[(SiO4),(OH)4] |
7 photos of Clarkeite associated with Fourmarierite | Pb(UO2)4O3(OH)4 · 4H2O |
7 photos of Clarkeite associated with Kasolite | Pb(UO2)(SiO4) · H2O |
5 photos of Clarkeite associated with Muscovite | KAl2(AlSi3O10)(OH)2 |
3 photos of Clarkeite associated with Autunite | Ca(UO2)2(PO4)2 · 10-12H2O |
1 photo of Clarkeite associated with Curite | Pb3(H2O)2[(UO2)4O4(OH)3]2 |
Related Minerals - Strunz-mindat Grouping
4.GC. | Bobfinchite | Na[(UO2)8O3(OH)11] · 10H2O |
4.GC.10 | Umohoite | (UO2)MoO4 · 2H2O |
4.GC.15 | Spriggite | Pb3(UO2)6O8(OH)2 · 3H2O |
Fluorescence of Clarkeite
none
Other Information
Notes:
Readily dissolves in mineral acids and hydrochloric acid. Can be dissolved in very dilute acid (1 part acid to 4 parts water).
Health Risks:
radioactive
Internet Links for Clarkeite
mindat.org URL:
https://www.mindat.org/min-1059.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Clarkeite
Reference List:
Frondel, Clifford, Meyrowitz, Robert (1956) Studies of uranium minerals (XIX): Rutherfordine, diderichite, and clarkeite. American Mineralogist, 41 (1-2) 127-133
(1958) Systematic mineralogy of uranium and thorium. Bulletin Vol. 1064. US Geological Survey doi:10.3133/b1064
Localities for Clarkeite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Argentina | |
| Angelelli (1984) |
Brazil | |
| Pires et al. (2014) |
Canada | |
| Chatterjee (1977) |
Czech Republic | |
| PauliĆĄ et al. (2007) |
Hungary | |
| Koch: Minerals of Hungary |
India | |
| Singh et al. (2015) |
| American Mineralogist: 41: 127-133 |
Norway | |
| Neumann (1985) |
| Sverdrup (1959) |
| Neumann (1985) |
| Husdal (2023) |
Romania | |
| HĂźrtopanu P. et al. (2004) |
Ukraine | |
| Liventseva (n.d.) |
USA | |
| - (2008) |
| King et al. (1994) |
| King et al. (1994) |
| Frondel (1956) +1 other reference |
| Not found at this locality: Frondel (1956) +1 other reference |
| Smith (2005) |
| Rocks and Minerals |
Roger Howell Collection | |
| Ross et al. (1931) +1 other reference |
Rocks and Minerals | |
| Smithsonian Institution Mineral ... |
| Rocks and Minerals |
www.excaliburmineral.com | |
| American Mineralogist +1 other reference |
| Rocks and Minerals |
Quick NavTopAbout ClarkeiteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesCommon AssociatesStrunz-MindatFluorescence Other InformationInternet Links References Localities Locality List
Bjertnes pegmatite, KrĂždsherad, Buskerud, Norway