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Ferroselite

A valid IMA mineral species - grandfathered
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About FerroseliteHide

Formula:
FeSe2
Colour:
Steel gray to tin white with rose tint, brass yellow
Lustre:
Metallic
Hardness:
6 - 6½
Specific Gravity:
7.20
Crystal System:
Orthorhombic
Member of:
Name:
For the chemical composition.
Dimorph of:

Unique IdentifiersHide

Mindat ID:
1527
Long-form identifier:
mindat:1:1:1527:7
GUID
(UUID V4):
a799fcd3-a6b7-4a35-83b3-1a6eb8d3098f

IMA Classification of FerroseliteHide

Approved, 'Grandfathered' (first described prior to 1959)
First published:
1955

Classification of FerroseliteHide

2.EB.10a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
E : Metal Sulfides, M: S <= 1:2
B : M:S = 1:2, with Fe, Co, Ni, PGE, etc.
2.12.2.2

2 : SULFIDES
12 : AmBnXp, with (m+n):p = 1:2
3.9.9

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
9 : Sulphides etc. of Fe

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
FseIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FerroseliteHide

Metallic
Transparency:
Opaque
Colour:
Steel gray to tin white with rose tint, brass yellow
Comment:
Tarnishes to brassy tone
Streak:
Black
Hardness:
6 - 6½ on Mohs scale
Hardness:
VHN25=858 - 933 kg/mm2 - Vickers
Tenacity:
Very brittle
Density:
7.20 g/cm3 (Measured)    7.139 g/cm3 (Calculated)

Optical Data of FerroseliteHide

Anisotropism:
Strong, from greenish gray to lilac gray
Reflectivity:
WavelengthR1R2
400nm42.3%44.1%
420nm42.5%44.3%
440nm43.0%44.5%
460nm43.5%45.1%
480nm43.9%45.9%
500nm44.4%47.0%
520nm44.9%48.2%
540nm45.3%49.5%
560nm46.0%50.9%
580nm46.8%52.3%
600nm47.6%53.7%
620nm48.2%54.9%
640nm48.7%55.9%
660nm49.1%56.3%
680nm49.3%56.5%
700nm49.5%56.7%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 56.7%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White with gray-brown hue
Pleochroism:
Visible

Chemistry of FerroseliteHide

Mindat Formula:
FeSe2
Common Impurities:
Co

Crystallography of FerroseliteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pnnm
Setting:
Pnnm
Cell Parameters:
a = 4.8007 Å, b = 5.776 Å, c = 3.5850 Å
Ratio:
a:b:c = 0.831 : 1 : 0.621
Unit Cell V:
99.41 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Slender prismatic crystals
Twinning:
Stellate and cruciform twins, twin lammellae in polished sections.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0011936FerroseliteKjekshus A, Rakke T, Andresen A (1974) Compounds of the marcasite type crystal structure. IX. Structural data for FeAs2, FeSe2, NiAs2, NiSb2, and CuSe2 Acta Chemica Scandinavica A28 996-10001974synthetic0293
0020709FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA0293
0020710FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA1.7293
0020711FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA3.83293
0020712FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA8.1293
0020713FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA17.3293
0020714FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA24.4293
0020715FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA32293
0020716FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA46293
0020717FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA0.0001198.2
0020718FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA0.0001148.4
0020719FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA0.000150.4
0020720FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA3.68197
0020721FerroseliteLavina B, Downs R T, Sinogeikin S (2018) The structure of ferroselite, FeSe2, at pressures up to 46 GPa and temperatures down to 50 K: A single-crystal micro-diffraction analysis Crystals 8 289; doi:10.3390/cryst8072018Paradox Valley, Uravan District, Montrose County, Colorado, USA3.64116
0013331FerroselitePickardt J, Reuter B, Riedel E, Sochtig J (1975) On the formation of FeSe2 single crystals by chemical transport reactions Journal of Solid State Chemistry 15 366-3681975synthetic0293
0015754FerroseliteTengner S (1938) Uber diselenide und ditelluride von eisen, kobalt und nickel Zeitschrift fur Anorganische und Allgemeine Chemie 239 126-13219380293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.568 Å(100)
2.474 Å(100)
1.885 Å(70)
2.871 Å(50)
1.695 Å(40)
2.400 Å(35)
1.541 Å(35)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4
Geological Setting:
Red bed deposits of Colorado Plateau type.

Type Occurrence of FerroseliteHide

General Appearance of Type Material:
Prismatic crystals of the mineral are 0.2-0.5 mm long and up to 0.1 mm in cross-section.
Place of Conservation of Type Material:
Mining Museum, St. Petersburg Mining Institute, St. Petersburg, Russia, 46-2/1.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 69853.
Geological Setting of Type Material:
Cementing sandstones and pelites in Middle Devonian deposits.
Associated Minerals at Type Locality:
Reference:
Buryanova, E.Z., Komkov, A.I. (1955) A new mineral - ferroselite. Doklady Akademii Nauk SSSR: 105: 812-813.

Synonyms of FerroseliteHide

Other Language Names for FerroseliteHide

Relationship of Ferroselite to other SpeciesHide

Member of:
Other Members of this group:
FrohbergiteFeTe2Orth. mmm (2/m 2/m 2/m) : Pnnm
KulleruditeNiSe2Orth. mmm (2/m 2/m 2/m) : Pnnm
MarcasiteFeS2Orth. mmm (2/m 2/m 2/m) : Pnnm
MattagamiteCoTe2Orth. mmm (2/m 2/m 2/m) : Pnnm
PetƙíčekiteCuSe2Orth. mmm (2/m 2/m 2/m) : Pnnm

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Ferroselite associated with CobaltomeniteCoSeO3 · 2H2O
3 photos of Ferroselite associated with Sandstone
2 photos of Ferroselite associated with CalciteCaCO3
2 photos of Ferroselite associated with Leucoxene
2 photos of Ferroselite associated with SeleniumSe
1 photo of Ferroselite associated with Haynesite(UO2)3(OH)2(SeO3)2 · 5H2O
1 photo of Ferroselite associated with Boltwoodite(K,Na)(UO2)(SiO3OH) · 1.5H2O
1 photo of Ferroselite associated with K Feldspar
1 photo of Ferroselite associated with ClausthalitePbSe
1 photo of Ferroselite associated with BerzelianiteCu2-xSe (x ≈ 0.12)

Related Minerals - Strunz-mindat GroupingHide

2.EB.Iridarsenite(Ir,Ru)As2Mon. 2/m : P21/b
2.EB.SelenolauriteRuSe2Iso. m3 (2/m 3) : Pa3
2.EB.AndrieslombaarditeRhSbSIso. 2 3 : P21 3
2.EB.Kanatzidisite(SbBiS3)2Te2Mon. 2/m : P21/m
2.EB.05aAurostibiteAuSb2Iso. m3 (2/m 3) : Pa3
2.EB.05bBambollaiteCu(Se,Te)2Tet.
2.EB.05aCattieriteCoS2Iso. m3 (2/m 3) : Pa3
2.EB.05aErlichmaniteOsS2Iso. m3 (2/m 3) : Pa3
2.EB.05aFukuchiliteCu3FeS8Iso. m3 (2/m 3) : Pa3
2.EB.05aGeversitePtSb2Iso. m3 (2/m 3) : Pa3
2.EB.05aHaueriteMnS2Iso. m3 (2/m 3) : Pa3
2.EB.05aInsizwaitePt(Bi,Sb)2Iso. m3 (2/m 3) : Pa3
2.EB.05aKrut'aiteCuSe2Iso. m3 (2/m 3) : Pa3
2.EB.05aLauriteRuS2Iso. m3 (2/m 3) : Pa3
2.EB.05aPenroseite(Ni,Co,Cu)Se2Iso. m3 (2/m 3) : Pa3
2.EB.05aPyriteFeS2Iso. m3 (2/m 3) : Pa3
2.EB.05aSperrylitePtAs2Iso. m3 (2/m 3) : Pa3
2.EB.05aTrogtaliteCoSe2Iso. m3 (2/m 3) : Pa3
2.EB.05aVaesiteNiS2Iso. m3 (2/m 3) : Pa3
2.EB.05aVillamanĂ­nite(Cu,Ni,Co,Fe)S2Tric.
2.EB.05aDzharkeniteFeSe2Iso. m3 (2/m 3) : Pa3
2.EB.05aGaotaiiteIr3Te8Iso. m3 (2/m 3) : Pa3
2.EB.05a vCayeuxite
2.EB.10bAlloclasiteCo1-xFexAsSMon. 2 : P21
2.EB.10dCostibiteCoSbSOrth. mm2 : Pmn21
2.EB.10aFrohbergiteFeTe2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.10cGlaucodot(Co0.50Fe0.50)AsSOrth. mm2 : Pmn21
2.EB.10aKulleruditeNiSe2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.10aMarcasiteFeS2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.10aMattagamiteCoTe2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.10eParacostibiteCoSbSOrth. mmm (2/m 2/m 2/m) : Pbca
2.EB.10ePararammelsbergiteNiAs2Orth. mmm (2/m 2/m 2/m) : Pbca
2.EB.10fOeniteCoSbAsOrth.
2.EB.10aPetƙíčekiteCuSe2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.15aAnduoite(Ru,Os)As2Orth.
2.EB.15aClinosaffloriteCoAs2Mon. 2/m : P21/m
2.EB.15aLöllingiteFeAs2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.15aNisbiteNiSb2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.15aOmeiite(Os,Ru)As2Orth.
2.EB.15cPaxiteCuAs2Mon. 2/m : P21/b
2.EB.15aRammelsbergiteNiAs2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.15aSafflorite(Co,Ni,Fe)As2Orth. mmm (2/m 2/m 2/m) : Pnnm
2.EB.15bSeinÀjokite(Fe,Ni)(Sb,As)2Orth.
2.EB.20ArsenopyriteFeAsSMon. 2/m : P21/b
2.EB.20GudmunditeFeSbSMon. 2/m : P21/b
2.EB.20Osarsite(Os,Ru)AsSMon.
2.EB.20Ruarsite(Ru,Os)AsSMon.
2.EB.25 vaAntimony-bearing GersdorffiteNi(As,Sb)S
2.EB.25CobaltiteCoAsSOrth. mm2 : Pca21
2.EB.25GersdorffiteNiAsSIso. m3 (2/m 3) : Pa3
2.EB.25Hollingworthite(Rh,Pt,Pd)AsSIso. m3 (2/m 3) : Pa3
2.EB.25Irarsite(Ir,Ru,Rh,Pt)AsSIso. m3 (2/m 3) : Pa3
2.EB.25JolliffeiteNiAsSeIso. m3 (2/m 3) : Pa3
2.EB.25KrutoviteNiAs2Iso. 2 3 : P21 3
2.EB.25MaslovitePtBiTeIso. 2 3 : P21 3
2.EB.25MicheneritePdBiTeIso. 2 3 : P21 3
2.EB.25PadmaitePdBiSeIso. 4 3 2
2.EB.25PlatarsitePt(As,S)2Iso. m3 (2/m 3) : Pa3
2.EB.25TestibiopalladitePdSbTeIso.
2.EB.25TolovkiteIrSbSIso.
2.EB.25UllmanniteNiSbSIso. 2 3 : P21 3
2.EB.25WillyamiteCoSbS
2.EB.25ChangchengiteIrBiSIso. 2 3 : P21 3
2.EB.25MayingiteIrBiTeIso. m3 (2/m 3) : Pa3
2.EB.25KalungaitePdAsSeIso. m3 (2/m 3) : Pa3
2.EB.25MilotaitePdSbSeIso. 2 3 : P21 3
2.EB.25ParagersdorffiteNi(As,S)2Iso. m3 (2/m 3) : Pa3
2.EB.25OrthogersdorffiteNiAsSOrth. mm2 : Pca21
2.EB.30UrvantsevitePd(Bi,Pb)2Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
2.EB.35RheniiteReS2Tric. 1 : P1

Other InformationHide

Thermal Behaviour:
Heated in a closed tube, it gives a dark-red sublimate and the characteristic selenium odor.
Notes:
On heating becomes magnetic.
Dissolved by HNO3, only slightly by HCl and H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FerroseliteHide

References for FerroseliteHide

Reference List:

Localities for FerroseliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • La Rioja Province
    • Capital Department
      • Puerto Alegre
    • General Lamadrid Department
      • Villa Castelli
        • Sierra de Cacho
  • Mendoza Province
    • LujĂĄn de Cuyo department
      • Cacheuta District
          • Cerro de Cacheuta
Brazil
 
  • GoiĂĄs
    • Cavalcante
China
 
  • Gansu
    • Gannan
      • Luqu Co.
  • Guizhou
    • Guiyang
      • Kaiyang County
  • Inner Mongolia
    • Alxa League (Alashan Prefecture)
      • Alxa Right Banner (Alashan Youqi)
  • Xinjiang
    • Yili Hasake Autonomous Prefecture (Ili Kazakh Autonomous Prefecture)
      • Chabucha'er Xibo Co. (Qapqal Xibe Co.; Chapchal Shibe Co.)
Czech Republic
 
  • Central Bohemian Region
      • HĂĄje
  • Plzeƈ Region
    • Klatovy District
      • NalĆŸovskĂ© Hory
        • Ústaleč
    • Tachov District
      • ZadnĂ­ Chodov
  • South Bohemian Region
    • PĂ­sek District
      • Kováƙov
        • Pƙedboƙice
  • Vysočina Region
    • ĆœÄĂĄr nad SĂĄzavou District
      • NovĂ© Město na Moravě
      • RoĆŸnĂĄ
        • RoĆŸnĂĄ deposit
Finland
 
  • Lapland
    • Savukoski
      • Tulppio
        • Sokli carbonatite complex
  • North Ostrobothnia
Germany
 
  • Bavaria
    • Upper Palatinate
  • Lower Saxony
    • Goslar District
      • Braunlage
        • St Andreasberg
      • Harz (Landkreis Goslar)
  • Saxony-Anhalt
    • Mansfeld-SĂŒdharz
      • Mansfeld
  • Saxony
    • Erzgebirgskreis
      • Aue-Bad Schlema
        • Alberoda
          • Shaft 366
    • Görlitz District
      • Quitzdorf am See
        • Horscha
India
 
  • Meghalaya
    • South West Khasi Hills District
Kazakhstan
 
  • Almaty Region
    • Middle Ili River
      • Dzharkenskaya Depression
Russia
 
  • Kemerovo Oblast
  • Tuva
    • Turan District
Sweden
 
  • Östergötland County
    • Valdemarsvik
USA
 
  • Colorado
    • Montrose County
        • Paradox Valley
    • San Juan County
    • San Miguel County
      • Slick Rock Mining District
        • King Mine
  • New Mexico
    • McKinley County
      • Ambrosia Lake subdistrict
      • Nose Rock
  • Utah
    • Emery County
    • Grand County
      • Thompsons Mining District
        • The Poison Strip
        • Yellow Cat Mesa
    • San Juan County
      • Montezuma Canyon Mining District
  • Wyoming
    • Carbon County
    • Converse County
      • Southern Powder River Basin Mining District
 
Mineral and/or Locality  
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