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Stilleite

A valid IMA mineral species - grandfathered

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Photos of Stilleite (2)

Search Photos of Stilleite

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Stilleite

Shinkolobwe Mine, Shinkolobwe, Kambove Territory, Haut-Katanga, DR Congo

Stilleite, etc.

Santa Brígida mine, Sañogasta, Chilecito department, La Rioja Province, Argentina

Stilleite

Shinkolobwe Mine, Shinkolobwe, Kambove Territory, Haut-Katanga, DR Congo

Stilleite, etc.

Santa Brígida mine, Sañogasta, Chilecito department, La Rioja Province, Argentina

Stilleite

Shinkolobwe Mine, Shinkolobwe, Kambove Territory, Haut-Katanga, DR Congo

Stilleite, etc.

Santa Brígida mine, Sañogasta, Chilecito department, La Rioja Province, Argentina

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About StilleiteHide

Hans Wilhelm Stille

Formula:

ZnSe

Colour:

Gray

Lustre:

Metallic

Hardness:

Specific Gravity:

5.42

Crystal System:

Isometric

Member of:

Sphalerite Group

Name:

Named after Hans Wilhelm Stille (October 8, 1876 – December 26, 1966) Hanover, Germany, German geologist in the field of tectonics.

Type Locality:

ⓘ Shinkolobwe Mine, Shinkolobwe, Kambove Territory, Haut-Katanga, DR Congo

Sphalerite Group.

Unique IdentifiersHide

Mindat ID:

3786

Long-form identifier:

mindat:1:1:3786:6

GUID
(UUID V4):

39d4ba98-aa6e-4fae-81f0-0805b2d962e3

IMA Classification of StilleiteHide

IMA status:

Approved, 'Grandfathered' (first described prior to 1959)

First published:

1956

Type description reference:

Ramdohr, P. (1956) Stilleit, ein neues Mineral, natürliches Zinkselenid, von Shinkolobwe. Zeitschrift der Deutschen Geologischen Gesellschaft: 1: 481-483.

Classification of StilleiteHide

Strunz-mindat (2024):

2.CB.05a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.

Dana 8th ed.:

2.8.2.2

2 : SULFIDES
8 : A_mX_p, with m:p = 1:1

Hey's CIM Ref.:

3.4.6

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
4 : Sulphides etc. of Group II metals other than Hg (Mg, Ca, Zn, Cd)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol	Source	Reference
Sll	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Sll	The Canadian Mineralogist (2019)	The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of StilleiteHide

Lustre:

Metallic

Transparency:

Translucent, Opaque

Colour:

Gray

Hardness:

5 on Mohs scale

Density:

5.42 g/cm³ (Measured) 5.267 g/cm³ (Calculated)

Optical Data of StilleiteHide

Type:

Isotropic

RI values:

n = 2.5

Birefringence:

Isotropic minerals have no birefringence

Surface Relief:

Very High

Colour in reflected light:

Gray

Comments:

resembles tetrahedrite without the olive-brown or greenish blue hues.

Chemistry of StilleiteHide

Mindat Formula:

ZnSe

Elements listed:

Se, Zn - search for minerals with similar chemistry

Common Impurities:

Crystallography of StilleiteHide

Crystal System:

Isometric

Class (H-M):

4 3m - Hextetrahedral

Space Group:

F4 3m

Cell Parameters:

a = 5.667 Å

Unit Cell V:

182.00 Å³ (Calculated from Unit Cell)

Twinning:

Twin lamellae noted in polished section.

Comment:

Synthetic

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0011535	Stilleite	Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237		1963		0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Stilleite'
loop_
_publ_author_name
'Wyckoff R W G'
_journal_name_full 'Crystal Structures'
_journal_volume 1 
_journal_year 1963
_journal_page_first 85
_journal_page_last 237
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
 Note: ZnS structure, sphalerite structure
;
_database_code_amcsd 0011535
_chemical_formula_sum 'Zn Se'
_cell_length_a 5.6676
_cell_length_b 5.6676
_cell_length_c 5.6676
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 182.053
_exptl_crystal_density_diffrn      5.267
_symmetry_space_group_name_H-M 'F -4 3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
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  '-z,x,-y'
  '-z,1/2+x,1/2-y'
  '1/2-z,x,1/2-y'
  '1/2-z,1/2+x,-y'
  '-y,z,-x'
  '-y,1/2+z,1/2-x'
  '1/2-y,z,1/2-x'
  '1/2-y,1/2+z,-x'
  '-x,y,-z'
  '-x,1/2+y,1/2-z'
  '1/2-x,y,1/2-z'
  '1/2-x,1/2+y,-z'
  'x,-z,-y'
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  '1/2+z,-y,1/2-x'
  '1/2+z,1/2-y,-x'
  'y,-x,-z'
  'y,1/2-x,1/2-z'
  '1/2+y,-x,1/2-z'
  '1/2+y,1/2-x,-z'
  'x,z,y'
  'x,1/2+z,1/2+y'
  '1/2+x,z,1/2+y'
  '1/2+x,1/2+z,y'
  'z,y,x'
  'z,1/2+y,1/2+x'
  '1/2+z,y,1/2+x'
  '1/2+z,1/2+y,x'
  'y,x,z'
  'y,1/2+x,1/2+z'
  '1/2+y,x,1/2+z'
  '1/2+y,1/2+x,z'
  '-z,-x,y'
  '-z,1/2-x,1/2+y'
  '1/2-z,-x,1/2+y'
  '1/2-z,1/2-x,y'
  '-y,-z,x'
  '-y,1/2-z,1/2+x'
  '1/2-y,-z,1/2+x'
  '1/2-y,1/2-z,x'
  '-x,-y,z'
  '-x,1/2-y,1/2+z'
  '1/2-x,-y,1/2+z'
  '1/2-x,1/2-y,z'
  'z,-x,-y'
  'z,1/2-x,1/2-y'
  '1/2+z,-x,1/2-y'
  '1/2+z,1/2-x,-y'
  'y,-z,-x'
  'y,1/2-z,1/2-x'
  '1/2+y,-z,1/2-x'
  '1/2+y,1/2-z,-x'
  'x,-y,-z'
  'x,1/2-y,1/2-z'
  '1/2+x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  '-x,z,-y'
  '-x,1/2+z,1/2-y'
  '1/2-x,z,1/2-y'
  '1/2-x,1/2+z,-y'
  '-z,y,-x'
  '-z,1/2+y,1/2-x'
  '1/2-z,y,1/2-x'
  '1/2-z,1/2+y,-x'
  '-y,x,-z'
  '-y,1/2+x,1/2-z'
  '1/2-y,x,1/2-z'
  '1/2-y,1/2+x,-z'
  '-x,-z,y'
  '-x,1/2-z,1/2+y'
  '1/2-x,-z,1/2+y'
  '1/2-x,1/2-z,y'
  '-z,-y,x'
  '-z,1/2-y,1/2+x'
  '1/2-z,-y,1/2+x'
  '1/2-z,1/2-y,x'
  '-y,-x,z'
  '-y,1/2-x,1/2+z'
  '1/2-y,-x,1/2+z'
  '1/2-y,1/2-x,z'
  'z,x,y'
  'z,1/2+x,1/2+y'
  '1/2+z,x,1/2+y'
  '1/2+z,1/2+x,y'
  'y,z,x'
  'y,1/2+z,1/2+x'
  '1/2+y,z,1/2+x'
  '1/2+y,1/2+z,x'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Zn   0.00000   0.00000   0.00000
Se   0.25000   0.25000   0.25000

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
3.273 Å	(100)
2.003 Å	(70)
1.707 Å	(44)
1.1561 Å	(15)
1.299 Å	(13)
1.416 Å	(9)
1.0901 Å	(8)

Comments:

Synthetic

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of StilleiteHide

Type Locality:

ⓘ Shinkolobwe Mine, Shinkolobwe, Kambove Territory, Haut-Katanga, DR Congo

General Appearance of Type Material:

Microscopic angular inclusions.

Place of Conservation of Type Material:

No designated type material.

Associated Minerals at Type Locality:

Vaesite	Pyrite	Molybdenite	Linnaeite	Dolomite
Clausthalite

Reference:

Ramdohr, P. (1956) Stilleit, ein neues Mineral, natürliches Zinkselenid, von Shinkolobwe. Zeitschrift der Deutschen Geologischen Gesellschaft: 1: 481-483.

Download:

https://rruff.info/rruff_1.0/uploads/ZDGG1_481.pdf

Other Language Names for StilleiteHide

German:Stilleit

Russian:Штиллеит

Spanish:Stilleita

Relationship of Stilleite to other SpeciesHide

Member of:

Sphalerite Group

Other Members of this group:

Browneite	MnS	Iso. 4 3m : F4 3m
Coloradoite	HgTe	Iso. 4 3m : F4 3m
Hawleyite	CdS	Iso. 4 3m : F4 3m
Ishiharaite	(Cu,Ga,Fe,In,Zn)S	Iso. 4 3m : F4 3m
Metacinnabar	HgS	Iso. 4 3m : F4 3m
Rudashevskyite	(Fe,Zn)S	Iso. 4 3m : F4 3m
Sphalerite	ZnS	Iso. 4 3m : F4 3m
Tiemannite	HgSe	Iso. 4 3m : F4 3m

Common AssociatesHide

Associated Minerals Based on Photo Data:

1 photo of Stilleite associated with Klockmannite	CuSe
1 photo of Stilleite associated with Umangite	Cu₃Se₂

Related Minerals - Strunz-mindat Grouping Hide

2.CB.	Agmantinite	Ag₂MnSnS₄	Orth.
2.CB.	Richardsite	Zn₂CuGaS₄	Tet. 4 2m : I4 2m
2.CB.	Gachingite	Au(Te_1-xSe_x)	Orth. mmm (2/m 2/m 2/m)
2.CB.	Tolstykhite	Au₃S₄Te₆	Tric. 1 : P1
2.CB.	Hanswilkeite	KFeS₂	Mon. 2/m : B2/b
2.CB.	Auroselenide	AuSe	Mon. 2/m : B2/m
2.CB.	Ruizhongite	(Ag₂◻)Pb₃Ge₂S₈	Iso. 4 3m : I4 3d
2.CB.	Okruginite	Cu₂SnSe₃	Mon. m : Bb
2.CB.05a	Coloradoite	HgTe	Iso. 4 3m : F4 3m
2.CB.05a	Hawleyite	CdS	Iso. 4 3m : F4 3m
2.CB.05a	Metacinnabar	HgS	Iso. 4 3m : F4 3m
2.CB.05c	Polhemusite	(Zn,Hg)S	Tet.
2.CB.05b	Sakuraiite	(Cu,Zn,Fe)₃(In,Sn)S₄	Iso.
2.CB.05a	Sphalerite	ZnS	Iso. 4 3m : F4 3m
2.CB.05a	Tiemannite	HgSe	Iso. 4 3m : F4 3m
2.CB.05	UM1998-15-S:CuFeZn	Cu₂Fe₃Zn₅S₁₀
2.CB.05a	Rudashevskyite	(Fe,Zn)S	Iso. 4 3m : F4 3m
2.CB.05a	Ishiharaite	(Cu,Ga,Fe,In,Zn)S	Iso. 4 3m : F4 3m
2.CB.07a	Shenzhuangite	NiFeS₂	Tet. 4 2m : I4 2d
2.CB.07a	Unnamed (Cu-Mn-Sn Sulpide)	Cu₂MnSnS₄
2.CB.10a	Chalcopyrite	CuFeS₂	Tet. 4 2m : I4 2d
2.CB.10a	Eskebornite	CuFeSe₂	Tet. 4 2m : P4 2c
2.CB.10a	Gallite	CuGaS₂	Tet. 4 2m : I4 2d
2.CB.10b	Haycockite	Cu₄Fe₅S₈	Orth. 2 2 2
2.CB.10a	Lenaite	AgFeS₂	Tet. 4 2m : I4 2d
2.CB.10b	Mooihoekite	Cu₉Fe₉S₁₆	Tet. 4 2m : P4 2m
2.CB.10b	Putoranite	Cu_1.1Fe_1.2S₂	Iso. m3m (4/m 3 2/m) : Pn3m
2.CB.10a	Roquesite	CuInS₂	Tet. 4 2m : I4 2d
2.CB.10b	Talnakhite	Cu₉(Fe,Ni)₈S₁₆	Iso. 4 3m : I4 3m
2.CB.10a	Laforêtite	AgInS₂	Tet. 4 2m : I4 2d
2.CB.10a	Unnamed (Cu-Zn-In Sulphide)	CuZn₂InS₄
2.CB.10a	UM1984-30-S:CuFeSn	Cu₂Fe₂Sn₃S₇
2.CB.10c	Omariniite	Cu₈Fe₂ZnGe₂S₁₂	Orth. 2 2 2 : I2 2 2
2.CB.15a	Černýite	Cu₂(Cd,Zn,Fe)SnS₄	Tet. 4 2m : I4 2m
2.CB.15a	Ferrokësterite	Cu₂FeSnS₄	Tet. 4 : I4
2.CB.15a	Hocartite	Ag₂(Fe²⁺,Zn)SnS₄	Tet. 4 2m : I4 2m
2.CB.15a	Idaite	Cu₅FeS₆	Hex.
2.CB.15a	Kësterite	Cu₂ZnSnS₄	Tet. 4 : I4
2.CB.15a	Kuramite	Cu₃SnS₄	Tet. 4 2m : I4 2m
2.CB.15b	Mohite	Cu₂SnS₃	Mon.
2.CB.15a	Pirquitasite	Ag₂ZnSnS₄	Tet. 4 : I4
2.CB.15a	Stannite	Cu₂FeSnS₄	Tet. 4 2m : I4 2m
2.CB.15c	Stannoidite	Cu⁺₆Cu²⁺₂(Fe²⁺,Zn)₃Sn₂S₁₂	Orth. 2 2 2 : I2 2 2
2.CB.15a	Velikite	Cu₂HgSnS₄	Tet. 4 : I4
2.CB.15c	UM2006-11-S:CuFeGeZn	Cu₈(Fe,Zn)₃Ge₂S₁₂ (?)
2.CB.17a v	Arsenic-bearing Renierite	Cu₁₁GeAsFe₄S₁₆
2.CB.20	Chatkalite	Cu₆FeSn₂S₈	Tet. 4 2m : P4m2
2.CB.20	Mawsonite	Cu₆Fe₂SnS₈	Tet. 4 2m : P4m2
2.CB.30	Argyropyrite	near Ag₂Fe₇S₁₁
2.CB.30	Colusite	Cu₁₃VAs₃S₁₆	Iso. 4 3m : P4 3n
2.CB.30	Germanite	Cu₁₃Fe₂Ge₂S₁₆	Iso. 4 3m : P4 3n
2.CB.30	Germanocolusite	Cu₂₆V₂(Ge,As)₆S₃₂	Iso. 4 3m : P4 3m
2.CB.30	Nekrasovite	Cu₂₆V₂(Sn,As,Sb)₆S₃₂	Iso. 4 3m : P4 3n
2.CB.30	Stibiocolusite	Cu₁₃V(Sb,Sn,As)₃S₁₆	Iso. 4 3m : P4 3m
2.CB.30	Ovamboite	Cu₂₀(Fe,Cu,Zn)₆W₂Ge₆S₃₂	Iso. 4 3m : P4 3n
2.CB.30	Maikainite	Cu₂₀(Fe,Cu)₆Mo₂Ge₆S₃₂	Iso. m3m (4/m 3 2/m)
2.CB.30	Frieseite	Ag₂Fe₅S₈ (?)
2.CB.35a	Hemusite	Cu₆SnMoS₈	Iso.
2.CB.35a	Kiddcreekite	Cu₆SnWS₈	Iso. 4 3m : F4 3m
2.CB.35a	Polkovicite	(Fe,Pb)₃(Ge,Fe)_1-xS₄	Iso.
2.CB.35a	Renierite	(Cu¹⁺,Zn)₁₁Fe₄(Ge⁴⁺,As⁵⁺)₂S₁₆	Tet. 4 2m : P4 2c
2.CB.35a	Vinciennite	Cu⁺₇Cu²⁺₃Fe²⁺₂Fe³⁺₂Sn(As,Sb)S₁₆	Tet.
2.CB.35a	Morozeviczite	(Pb,Fe)₃Ge_1-xS₄	Iso.
2.CB.35b	Catamarcaite	Cu₆GeWS₈	Hex. 6mm : P6₃mc
2.CB.40	Lautite	CuAsS	Orth. mmm (2/m 2/m 2/m) : Pnma
2.CB.42	Lingbaoite	AgTe₃	Trig. 3m : R3m
2.CB.45	Cadmoselite	CdSe	Hex. 6mm : P6₃mc
2.CB.45	Greenockite	CdS	Hex. 6mm : P6₃mc
2.CB.45	Wurtzite	(Zn,Fe)S	Hex. 6mm : P6₃mc
2.CB.45	Rambergite	MnS	Hex. 6mm : P6₃mc
2.CB.45	Buseckite	(Fe,Zn,Mn)S	Hex. 6mm : P6₃mc
2.CB.45	Maletoyvayamite	Au₃Se₄Te₆	Tric. 1 : P1
2.CB.47	Murchisite	Cr₅S₆	Trig. 3m (3 2/m) : P3 1c
2.CB.50	Zincselenide	ZnSe
2.CB.50	Wassonite	TiS	Trig. 3m (3 2/m) : R3m
2.CB.52	Dzhezkazganite	ReMoCu₂PbS₆ ?	Trig. 3m : R3m
2.CB.55a	Cubanite	CuFe₂S₃	Orth. mmm (2/m 2/m 2/m)
2.CB.55b	Isocubanite	CuFe₂S₃	Iso. m3m (4/m 3 2/m) : Fm3m
2.CB.60	Picotpaulite	TlFe₂S₃	Orth. mmm (2/m 2/m 2/m) : Cmcm
2.CB.60	Raguinite	TlFeS₂	Orth.
2.CB.65	Argentopyrite	AgFe₂S₃	Mon. 2/m
2.CB.65	Sternbergite	AgFe₂S₃	Orth. mmm (2/m 2/m 2/m)
2.CB.70	Sulvanite	Cu₃VS₄	Iso. 4 3m : P4 3m
2.CB.75	Vulcanite	CuTe	Orth. mmm (2/m 2/m 2/m)
2.CB.80	Empressite	AgTe	Orth. mmm (2/m 2/m 2/m)
2.CB.85	Muthmannite	AuAgTe₂	Mon. 2/m : P2/m

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for StilleiteHide

mindat.org URL:

https://www.mindat.org/min-3786.html
Please feel free to link to this page.

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External Links:

Look for Stilleite on Webmineral

Look for Stilleite on Wikipedia

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for StilleiteHide

Reference List:

Ramdohr, P. (1956) Stilleit, ein neues Mineral, natürliches Zinkselenid, von Shinkolobwe. Geotektonisches Symposium zu Ehren von Hans Stille: 481–483. (in German)

Ramdohr, P. (1956) Stilleit, ein neues Mineral, natürliches Zinkselenid, von Shinkolobwe. Zeitschrift der Deutschen Geologischen Gesellschaft: 1: 481-483.

Fleischer, M. (1957) New mineral names. American Mineralogist, 42 (7-8) 580-586

DeMontreuil, L.A. (1974) Occurrence of mercurian stilleite. Boletín de la Sociedad Geológica del Perú: 44: 28–41. (in Spanish)

McIntyre, G.J., Moss, G., Barnea, Z. (1980) Anharmonic temperature factors of zinc selenide determined by X-ray diffraction from an extended-face crystal. Acta Crystallographica: A36: 482–490.

(2023) Stilleite. Handbook of Mineralogy. Mineralogical Society of America

Localities for StilleiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Argentina
La Rioja Province Chilecito department Sañogasta ⓘ Santa Brígida mine	Anthony et al. (1990)
General Lamadrid Department Villa Castelli ⓘ Sierra de Cacho	Economic Geology (1997)
ⓘ ~~Sierra de Umango~~	Economic Geology (1997)
ⓘ Los Llantenes mining district	Recursos Minerales de la Republica ... +3 other references

Canada
Manitoba Wellburns Creek ⓘ Drill hole M-5-00	Bamburak et al. (parts of NTS 62N1, 16, 63C1) +1 other reference

DR Congo (TL)
Haut-Katanga Kambove Territory Shinkolobwe ⓘ Shinkolobwe Mine (TL)	Ramdohr (1956) +2 other references

Germany
Lower Saxony Goslar District Braunlage St Andreasberg ⓘ Roter Bär Mine	Weiß (1990)
Saxony-Anhalt Mansfeld-Südharz Mansfeld ⓘ Tilkerode mining district	Wittern (2001)

Jordan
Amman Governorate Transjordan Plateau Daba-Siwaqa complex Hashem region Lisdan-Siwaga Fault ⓘ Jordan Areva Resources	Fleurance et al. (2013)

Stilleite

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