Zeolite Group.

According to Galli et.al., "Terranovaite .... was found in only one of the Ferrar dolerite samples collected. The specimen is from the SW crest, just under the summit of Mt. Adamson (Lat. 73° 56'S, Long. 162° 56'E)."

Terranovaite, tabular, transparent and bluish, was closely associated with heulandite.

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Unique IdentifiersHide

Mindat ID:

7332

Long-form identifier:

mindat:1:1:7332:1

GUID
(UUID V4):

b20098f7-5171-4786-8b1d-e477cd15c509

IMA Classification of TerranovaiteHide

IMA status:

Approved

IMA Formula:

NaCaAl₃Si₁₇O₄₀ · ~8H₂O

Approval year:

1995

First published:

1997

Type description reference:

Galli, Ermanno, Quartieri, Simona, Vezzalini, Giovanna, Alberti, Alberto, Franzini, Marco (1997) Terranovaite from Antarctica; a new "pentasil" zeolite. American Mineralogist, 82 (3) 423-429 doi:10.2138/am-1997-3-420

Classification of TerranovaiteHide

Strunz-mindat (2024):

9.GF.05

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H₂O; zeolite family
F : Other Rare Zeolites

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Tnv	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TerranovaiteHide

Lustre:

Vitreous

Transparency:

Transparent

Colour:

Bluish

Streak:

White

Hardness Data:

Could not be measured

Comment:

Could not be measured due to the small crystal size.

Tenacity:

Brittle

Cleavage:

Perfect
{010}

Parting:

Distinct {001}

Fracture:

Irregular/Uneven

Density:

2.13(2) g/cm³ (Measured)

Optical Data of TerranovaiteHide

Type:

Biaxial (+)

RI values:

n_α = 1.476(2) n_β = 1.478(2) n_γ = 1.483(3)

2V:

Measured: 65° (5), Calculated: 65°

Max Birefringence:

δ = 0.007

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

Moderate

Dispersion:

r < v moderate

Optical Extinction:

X = c; Y = a; Z = b.

Chemistry of TerranovaiteHide

Mindat Formula:

(Na,Ca)₈(Si₆₈Al₁₂)O₁₆₀ · 29H₂O

Elements listed:

Al, Ca, H, Na, O, Si - search for minerals with similar chemistry

Crystallography of TerranovaiteHide

Crystal System:

Orthorhombic

Cell Parameters:

a = 9.747(1) Å, b = 23.880(2) Å, c = 20.068(2) Å

Ratio:

a:b:c = 0.408 : 1 : 0.84

Unit Cell V:

4,670.99 Å³ (Calculated from Unit Cell)

Comment:

Cmcm space group, even though the real symmetry is probably C2cm

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0001886	Terranovaite	Galli E, Quartieri S, Vezzalini G, Alberti A, Franzini M (1997) Terranovaite from Antarctica: A new 'pentasil' zeolite American Mineralogist 82 423-429		1997		0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Terranovaite'
loop_
_publ_author_name
'Galli E'
'Quartieri S'
'Vezzalini G'
'Alberti A'
'Franzini M'
_journal_name_full 'American Mineralogist'
_journal_volume 82 
_journal_year 1997
_journal_page_first 423
_journal_page_last 429
_publ_section_title
;
 Terranovaite from Antarctica: A new 'pentasil' zeolite
;
_database_code_amcsd 0001886
_chemical_formula_sum '(Si17 Al3) O50.72 Na1.48 Ca1.48 H21.44'
_cell_length_a 9.747
_cell_length_b 23.880
_cell_length_c 20.068
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 4670.995
_exptl_crystal_density_diffrn      2.111
_symmetry_space_group_name_H-M 'C m c m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,y,z'
  '1/2-x,1/2+y,z'
  'x,-y,-z'
  '1/2+x,1/2-y,-z'
  'x,y,1/2-z'
  '1/2+x,1/2+y,1/2-z'
  '-x,-y,1/2+z'
  '1/2-x,1/2-y,1/2+z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Si1   0.00000   0.45240   0.32810   0.85000   0.01279
Al1   0.00000   0.45240   0.32810   0.15000   0.01279
Si2   0.00000   0.54400   0.43960   0.85000   0.01494
Al2   0.00000   0.54400   0.43960   0.15000   0.01494
Si3   0.79190   0.36040   0.37280   0.85000   0.01621
Al3   0.79190   0.36040   0.37280   0.15000   0.01621
Si4   0.79170   0.63920   0.46940   0.85000   0.01431
Al4   0.79170   0.63920   0.46940   0.15000   0.01431
Si5   0.00000   0.18060   0.44140   0.85000   0.01355
Al5   0.00000   0.18060   0.44140   0.15000   0.01355
Si6   0.00000   0.73210   0.43650   0.85000   0.01279
Al6   0.00000   0.73210   0.43650   0.15000   0.01279
Si7   0.00000   0.26970   0.32720   0.85000   0.01456
Al7   0.00000   0.26970   0.32720   0.15000   0.01456
Si8   0.00000   0.82520   0.32890   0.85000   0.01292
Al8   0.00000   0.82520   0.32890   0.15000   0.01292
O1   0.00000   0.46920   0.25000   1.00000   0.04319
O2   0.00000   0.51130   0.36790   1.00000   0.05028
O3   0.13670   0.41600   0.34530   1.00000   0.04737
O4   0.00000   0.50000   0.50000   1.00000   0.07168
O5   0.86300   0.58360   0.44150   1.00000   0.05028
O6   0.19580   0.36830   0.45120   1.00000   0.06383
O7   0.63250   0.36230   0.34880   1.00000   0.04002
O8   0.86610   0.30570   0.34150   1.00000   0.04395
O9   0.36630   0.63740   0.44530   1.00000   0.02964
O10   0.86550   0.69320   0.43770   1.00000   0.03838
O11   0.00000   0.21240   0.36850   1.00000   0.03711
O12   0.00000   0.77510   0.49700   1.00000   0.03914
O13   0.00000   0.76480   0.36560   1.00000   0.03027
O14   0.00000   0.25150   0.25000   1.00000   0.04154
O15   0.00000   0.81230   0.25000   1.00000   0.05079
Na1   0.00000   0.04580   0.44420   0.05000   0.00887
Ca1   0.00000   0.04580   0.44420   0.05000   0.00887
Wat1   0.00000   0.04580   0.44420   0.37000   0.00887
Na2   0.00000   0.04030   0.25000   0.08000   0.02026
Ca2   0.00000   0.04030   0.25000   0.08000   0.02026
Wat2   0.00000   0.04030   0.25000   0.56000   0.02026
Na3   0.35780   0.46030   0.25000   0.11000   0.11652
Ca3   0.35780   0.46030   0.25000   0.11000   0.11652
Wat3   0.35780   0.46030   0.25000   0.76000   0.11652
Na4   0.14570   0.03990   0.34950   0.08000   0.12032
Ca4   0.14570   0.03990   0.34950   0.08000   0.12032
Wat4   0.14570   0.03990   0.34950   0.58000   0.12032
Na5   0.00000   0.69820   0.25000   0.06000   0.12032
Ca5   0.00000   0.69820   0.25000   0.06000   0.12032
Wat5   0.00000   0.69820   0.25000   0.44000   0.12032
Na6   0.00000   0.95090   0.44050   0.06000   0.12032
Ca6   0.00000   0.95090   0.44050   0.06000   0.12032
Wat6   0.00000   0.95090   0.44050   0.44000   0.12032
Na7   0.90890   0.12880   0.25000   0.06000   0.12032
Ca7   0.90890   0.12880   0.25000   0.06000   0.12032
Wat7   0.90890   0.12880   0.25000   0.44000   0.12032
Na8   0.35190   0.48040   0.45980   0.04000   0.10385
Ca8   0.35190   0.48040   0.45980   0.04000   0.10385
Wat8   0.35190   0.48040   0.45980   0.29000   0.10385
Na9   0.00000   0.96510   0.35470   0.03000   0.05193
Ca9   0.00000   0.96510   0.35470   0.03000   0.05193
Wat9   0.00000   0.96510   0.35470   0.20000   0.05193
Na10   0.00000   0.59720   0.25000   0.06000   0.14945
Ca10   0.00000   0.59720   0.25000   0.06000   0.14945
Wat10   0.00000   0.59720   0.25000   0.44000   0.14945
Na11   0.30560   0.19830   0.25000   0.05000   0.12032
Ca11   0.30560   0.19830   0.25000   0.05000   0.12032
Wat11   0.30560   0.19830   0.25000   0.37000   0.12032
Na12   0.19010   0.08150   0.19070   0.02000   0.11019
Ca12   0.19010   0.08150   0.19070   0.02000   0.11019
Wat12   0.19010   0.08150   0.19070   0.16000   0.11019

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
11.94 Å	(40)
10.16 Å	(65)
9.04 Å	(33)
3.79 Å	(100)
3.61 Å	(40)
3.03 Å	(27)
2.504 Å	(14)

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust	>4.50
10 : Basalt-hosted zeolite minerals

Type Occurrence of TerranovaiteHide

Type Locality:

ⓘ Mount Adamson, Victoria Land, Eastern Antarctica, Antarctica

General Appearance of Type Material:

Globular masses that flake off in transparent lamellae.

Place of Conservation of Type Material:

Museo di Storia Naturale e del Territorio, University of Pisa, Italy (catalog no. 15520).

Geological Setting of Type Material:

Cavities in dolerite.

Associated Minerals at Type Locality:

Tschernichite

Smectite Group

Heulandite Subgroup

Reference:

Galli, E., Quartieri, S., Vezzalini, G., Alberti, A., Franzini, M. (1997) Terranovaite from Antarctica: A new ‘pentasil’ zeolite. American Mineralogist, 82(3-4), 423-429.

Synonyms of TerranovaiteHide

IMA1995-026

Other Language Names for TerranovaiteHide

German:Terranovait

Russian:Террановаит

Spanish:Terranovaita

Relationship of Terranovaite to other SpeciesHide

Member of:

Zeolite Group

Other Members of this group:

Alflarsenite	NaCa₂Be₃Si₄O₁₃(OH) · 2H₂O	Mon. 2 : P2₁
Amicite	K₂Na₂Al₄Si₄O₁₆ · 5H₂O	Mon. 2
Ammonioleucite	(NH₄)(AlSi₂O₆)	Tet. 4/m : I4₁/a
Analcime	Na(AlSi₂O₆) · H₂O	Tric. 1 : P1
Bellbergite	(K,Ba,Sr)₂Sr₂Ca₂(Ca,Na)₄[Al₃Si₃O₁₂]₆ · 30H₂O	Hex.
Bikitaite	LiAlSi₂O₆ · H₂O	Tric. 1 : P1
Boggsite	Ca₈Na₃(Si,Al)₉₆O₁₉₂ · 70H₂O	Orth. mmm (2/m 2/m 2/m) : Imma
Brewsterite Subgroup	Zeolite Group.
Chabazite-Levyne Subgroup	M[Al₂Si₄O₁₂] · 6H₂O
Chiavennite	CaMnBe₂Si₅O₁₃(OH)₂ · 2H₂O	Mon. 2/m : P2₁/b
Clinoptilolite Subgroup	M_3-6(Si₃₀Al₆)O₇₂ · 20H₂O
Cowlesite	CaAl₂Si₃O₁₀ · 6H₂O	Orth. mmm (2/m 2/m 2/m)
Dachiardite Subgroup	Zeolite Group.
Direnzoite	NaK₆MgCa₂(Al₁₃Si₄₇O₁₂₀) · 36H₂O	Orth. mmm (2/m 2/m 2/m) : Pmmn
Edingtonite	Ba[Al₂Si₃O₁₀] · 4H₂O	Orth. 2 2 2 : P2₁ 2₁ 2₁
Epistilbite	CaAl₂Si₆O₁₆ · 5H₂O	Mon.
Erionite Subgroup	M₂[Al₄Si₁₄O₃₆] · 15H₂O
Faujasite Subgroup	M_3.5[Al₇Si₁₇O₄₈] · 32H₂O
Ferrierite Subgroup	Zeolite Group.
Ferrochiavennite	Ca_1-2Fe[(Si,Al,Be)₅Be₂O₁₃(OH)₂] · 2H₂O	Mon. 2/m : P2₁/b
Flörkeite	(K₃Ca₂Na)[Al₈Si₈O₃₂] · 12H₂O	Tric. 1 : P1
Garronite Subgroup
Gaultite	Na₄Zn₂Si₇O₁₈ · 5H₂O	Orth. mm2 : Fdd2
Gismondine Subgroup	Zeolite Group.
Gmelinite Subgroup	In 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
Gobbinsite	Na₅(Si₁₁Al₅)O₃₂ · 11H₂O	Orth. mmm (2/m 2/m 2/m) : Pnma
Goosecreekite	Ca[Al₂Si₆O₁₆] · 5H₂O	Mon. 2 : P2₁
Gottardiite	Na₃Mg₃Ca₅Al₁₉Si₁₁₇O₂₇₂ · 93H₂O	Orth. mmm (2/m 2/m 2/m) : Cmca
Heulandite Subgroup	(Na/Ca/K)_5-6[Al_8-9 Si_27-28 O₇₂] · nH₂O
Hsianghualite	Ca₃Li₂(Be₃Si₃O₁₂)F₂	Iso. 4 3 2 : I4₁ 3 2
Kirchhoffite	Cs(BSi₂O₆)	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/acd
Laumontite	CaAl₂Si₄O₁₂ · 4H₂O	Mon. 2/m : B2/m
Loomisite	Ba[Be₂P₂O₈] · H₂O	Mon. m
Lovdarite	K₂Na₆Be₄Si₁₄O₃₆ · 9H₂O	Orth. mm2
Maricopaite	Pb₇Ca₂(Si,Al)₄₈O₁₀₀ · 32H₂O	Orth.
Martinandresite	Ba₂(Al₄Si₁₂O₃₂) · 10H₂O	Orth. mmm (2/m 2/m 2/m) : Pmmn
Mazzite Subgroup	Zeolite Group.
Merlinoite	(K,Na)₅(Ca,Ba)₂Al₉Si₂₃O₆₄ · 23H₂O	Orth. mmm (2/m 2/m 2/m) : Immm
Montesommaite	(K,Na)₉Al₉Si₂₃O₆₄ · 10H₂O	Orth. mm2 : Fdd2
Mordenite	(Na₂,Ca,K₂)₄(Al₈Si₄₀)O₉₆ · 28H₂O	Orth.
Mutinaite	Na₃Ca₄Si₈₅Al₁₁O₁₉₂ · 60H₂O	Orth. mmm (2/m 2/m 2/m) : Pnma
Nabesite	Na₂BeSi₄O₁₀ · 4H₂O	Orth. 2 2 2 : P2₁ 2₁ 2₁
Natrolite Subgroup	A subgroup of the Zeolite Group.
Offretite	KCaMg(Si₁₃Al₅)O₃₆ · 15H₂O	Hex. 6 m2 : P6m2
Pahasapaite	Li₈(Ca,Li,K)_10.5Be₂₄(PO₄)₂₄ · 38H₂O	Iso. 2 3 : I2 3
Parthéite	Ca₂(Si₄Al₄) O₁₅ (OH)₂ · 4H₂O	Mon. 2/m : B2/b
Paulingite Subgroup	Paulingite was originally described in 1960.
Perlialite	K₉Na(Ca,Sr)[Al₂Si₄O₁₂]₆ · 15H₂O	Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
Phillipsite Subgroup	Zeolite Group.
Pollucite	(Cs,Na)₂(Al₂Si₄O₁₂) · 2H₂O	Iso. m3m (4/m 3 2/m) : Ia3d
Roggianite	Ca₂Be(OH)₂Al₂Si₄O₁₃ · 2.5H₂O	Tet. 4/mmm (4/m 2/m 2/m) : I4/mcm
Stilbite Subgroup	M_6-7[Al_8-9Si_27-28O₇₂] · nH₂O
Thomsonite Subgroup	The large majority of "thomsonite" is thomsonite-Ca.
Tschernichite	(Ca,Na₂)[Al₂Si₄O₁₂] · 4-8H₂O	Tet. 4/mmm (4/m 2/m 2/m) : P4/mmm
Tschörtnerite	Ca₄(Ca,Sr,K,Ba)₃Cu₃[Al₃Si₃O₁₂]₄(OH)₈ · nH₂O	Iso. m3m (4/m 3 2/m) : Fm3m
UM1996-38-SiO:AlCaHNa	Na-Ca-Al-Si-O-H
UM1999-33-SiO:AlHKNa	K₇Na₅Al₁₂Si₂₀O₆₄ · 24H₂O
UM2002-40-SiO:AlCaHKMgNa	(Mg,Ca,Na,K)_7.5(Al_12.8Si_51.2)O₁₂₈ · 65H₂O	Tet. 4 2 2 : P4₁ 2 2
Unnamed (Ca analogue of Merlinoite)	(Ca,K,Na)₅(Ca,Ba)₂Al₉Si₂₃O₆₄ · 23H₂O ?
Wairakite	Ca(Al₂Si₄O₁₂) · 2H₂O	Mon. 2/m : B2/m
Weinebeneite	CaBe₃(PO₄)₂(OH)₂ · 4H₂O	Mon. m : Bb
Wenkite	(Ba,K)₄(Ca,Na)₆[(Si,Al)₂₀O₃₉(OH)₂](SO₄)₃ · 0.5H₂O	Hex. 6 m2 : P6₂m
Willhendersonite	KCa[Al₃Si₃O₁₂] · 5H₂O	Tric. 1 : P1
Yugawaralite	CaAl₂Si₆O₁₆ · 4H₂O	Mon. m : Pb

Related Minerals - Strunz-mindat Grouping Hide

9.GF.10	Gottardiite	Na₃Mg₃Ca₅Al₁₉Si₁₁₇O₂₇₂ · 93H₂O	Orth. mmm (2/m 2/m 2/m) : Cmca
9.GF.15	Lovdarite	K₂Na₆Be₄Si₁₄O₃₆ · 9H₂O	Orth. mm2
9.GF.20	Gaultite	Na₄Zn₂Si₇O₁₈ · 5H₂O	Orth. mm2 : Fdd2
9.GF.25	Chiavennite	CaMnBe₂Si₅O₁₃(OH)₂ · 2H₂O	Mon. 2/m : P2₁/b
9.GF.25	Ferrochiavennite	Ca_1-2Fe[(Si,Al,Be)₅Be₂O₁₃(OH)₂] · 2H₂O	Mon. 2/m : P2₁/b
9.GF.30	Tschernichite	(Ca,Na₂)[Al₂Si₄O₁₂] · 4-8H₂O	Tet. 4/mmm (4/m 2/m 2/m) : P4/mmm
9.GF.35	Mutinaite	Na₃Ca₄Si₈₅Al₁₁O₁₉₂ · 60H₂O	Orth. mmm (2/m 2/m 2/m) : Pnma
9.GF.40	Tschörtnerite	Ca₄(Ca,Sr,K,Ba)₃Cu₃[Al₃Si₃O₁₂]₄(OH)₈ · nH₂O	Iso. m3m (4/m 3 2/m) : Fm3m
9.GF.50	Thornasite	(Na,K)₁₂Th₃[Si₈O₁₉]₄ · 18H₂O	Trig. 3m : R3m
9.GF.55	Direnzoite	NaK₆MgCa₂(Al₁₃Si₄₇O₁₂₀) · 36H₂O	Orth. mmm (2/m 2/m 2/m) : Pmmn
9.GF.60	Meierite	Ba₄₄Si₆₆Al₃₀O₁₉₂Cl₂₅(OH)₃₃	Iso. m3m (4/m 3 2/m) : Im3m
9.GF.65	Rongibbsite	Pb₂(Si₄Al)O₁₁(OH)	Mon. 2/m : B2/m

Fluorescence of TerranovaiteHide

In UV light:

none

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TerranovaiteHide

mindat.org URL:

https://www.mindat.org/min-7332.html
Please feel free to link to this page.

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

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References for TerranovaiteHide

Reference List:

Vezzalini, G., Quartieri, S., Rossi, A., Alberti, A. (1994) Occurrence of zeolites from Northern Victoria Land, Antarctica. Terra Antarctica, 1. 96-99

Vezzalini, G., Alberti, A., Galli, E., Quartieri, S. (1995) A new zeolite topology: terranovaite from Antarctica. Plinius: 14: 170-172.

Coombs, Douglas S., Alberti, Alberto, Armbruster, Thomas, Artioli, Gilberto, Colella, Carmine, Galli, Ermanno, Grice, Joel D., Liebau, Friedrich, Mandarino, Joseph A., Minato, Hideo, Nickel, Ernest H., Passaglia, Elio, Peacor, Donald R., Quartieri, Simona, Rinaldi, Romano, Ross, Malcolm I., Sheppard, Richard A., Tillmanns, Ekkehart, Vezzalini, Giovanna (1997) Recommended nomenclature for zeolite minerals; report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. The Canadian Mineralogist, 35 (6) 1571-1606

Localities for TerranovaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Antarctica (TL)

Eastern Antarctica

Victoria Land

ⓘ Mount Adamson (TL)

Vezzalini et al. (1994) +2 other references

Terranovaite