Clinoferrosilite
A valid IMA mineral species - grandfathered
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About Clinoferrosilite
Formula:
Fe2+2Si2O6
Simplified: FeSiO3.
Colour:
Brown, colourless, green
Hardness:
5 - 6
Specific Gravity:
4.068 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
Named for being the monoclinic polymorph of ferrosilite.
Type Locality:
Polymorph of:
Isostructural with:
Pyroxene Group - Clinopyroxene Subgroup
Note: in some previous texts the name ferrosilite was used for what is now called clinoferrosilite, whereas the equivalent orthorhombic dimorph was called orthoferrosilite, so be careful when reading older texts.
Note: in some previous texts the name ferrosilite was used for what is now called clinoferrosilite, whereas the equivalent orthorhombic dimorph was called orthoferrosilite, so be careful when reading older texts.
Unique Identifiers
Mindat ID:
1073
Long-form identifier:
mindat:1:1:1073:9
GUID
(UUID V4):
(UUID V4):
74596705-1367-4b97-94c7-170f1c2457ac
Classification of Clinoferrosilite
Clinoferrosilite and its relation to other pyroxenes
Previous petrological nomenclature of clinopyroxenes from basaltic magmas, note described here as 'ferrosilite' (after Poldervaart & Hess, 1951)
IMA Classification of Clinoferrosilite
Approved, 'Grandfathered' (first described prior to 1959)
9.DA.10
9 : SILICATES (Germanates)
D : Inosilicates
A : Inosilicates with 2-periodic single chains, Si2O6; pyroxene family
9 : SILICATES (Germanates)
D : Inosilicates
A : Inosilicates with 2-periodic single chains, Si2O6; pyroxene family
65.1.1.2
65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
1 : Single-Width Unbranched Chains, W=1 with chains P=2
65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
1 : Single-Width Unbranched Chains, W=1 with chains P=2
14.21.4
14 : Silicates not Containing Aluminum
21 : Silicates of Fe and Mg
14 : Silicates not Containing Aluminum
21 : Silicates of Fe and Mg
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Cfs | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Cfs | Kretz (1983) | Kretz, R. (1983) Symbols of rock-forming minerals. American Mineralogist, 68, 277–279. |
Cfs | Siivolam & Schmid (2007) | Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download |
Cfs | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Pronunciation of Clinoferrosilite
Pronunciation:
Play | Recorded by | Country |
---|---|---|
Jolyon Ralph | United Kingdom |
Physical Properties of Clinoferrosilite
Transparency:
Transparent, Translucent
Colour:
Brown, colourless, green
Streak:
White
Hardness:
5 - 6 on Mohs scale
Cleavage:
Distinct/Good
Density:
4.068 g/cm3 (Calculated)
Optical Data of Clinoferrosilite
Type:
Biaxial (+)
RI values:
nα = 1.764 nβ = 1.767 nγ = 1.792
2V:
Measured: 25° , Calculated: 40°
Max Birefringence:
δ = 0.028
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
very strong
Optical Extinction:
Z ∧ c = 31°.
Chemistry of Clinoferrosilite
Mindat Formula:
Fe2+2Si2O6
Simplified: FeSiO3.
Simplified: FeSiO3.
Elements listed:
Crystallography of Clinoferrosilite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 9.7085 Å, b = 9.0872 Å, c = 5.2284 Å
β = 108.432°
β = 108.432°
Ratio:
a:b:c = 1.068 : 1 : 0.575
Unit Cell V:
437.60 ų (Calculated from Unit Cell)
Z:
4
Comment:
Synthetic sample (pure Fe2Si2O6). Mg-bearing sample has 9.53, 9.21, 5.15 Å, 107.63°.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000459 | Clinoferrosilite | Ohashi Y, Burnham C W, Finger L W (1975) The effect of Ca-Fe substitution on the clinopyroxene crystal structure Fs80Wo20 American Mineralogist 60 423-434 | 1975 | 0 | 293 | ||
0000460 | Clinoferrosilite | Ohashi Y, Burnham C W, Finger L W (1975) The effect of Ca-Fe substitution on the clinopyroxene crystal structure Fs85Wo15 American Mineralogist 60 423-434 | 1975 | 0 | 293 | ||
0000936 | Clinoferrosilite | Sueno S, Kimata M, Prewitt C T (1984) The crystal structure of high clinoferrosilicate American Mineralogist 69 264-269 | 1984 | 0 | 1323 | ||
0001679 | Clinoferrosilite | Hugh-Jones D A, Woodland A B, Angel R J (1994) The structure of high-pressure C2/c ferrosilite and crystal chemistry of high-pressure C2/c pyroxenes American Mineralogist 79 1032-1041 | 1994 | 0 | 293 | ||
0001680 | Clinoferrosilite | Hugh-Jones D A, Woodland A B, Angel R J (1994) The structure of high-pressure C2/c ferrosilite and crystal chemistry of high-pressure C2/c pyroxenes American Mineralogist 79 1032-1041 | 1994 | 1.87 | 293 | ||
0001681 | Clinoferrosilite | Hugh-Jones D A, Woodland A B, Angel R J (1994) The structure of high-pressure C2/c ferrosilite and crystal chemistry of high-pressure C2/c pyroxenes American Mineralogist 79 1032-1041 | 1994 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.035 Å | (100) |
2.603 Å | (63) |
2.909 Å | (55) |
2.408 Å | (53) |
2.161 Å | (51) |
4.605 Å | (49) |
3.234 Å | (40) |
Comments:
Synthetic.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 4a: Earth’s earliest continental crust | >4.4-3.0 |
20 : Acidic volcanic rocks |
Type Occurrence of Clinoferrosilite
General Appearance of Type Material:
Needles about 0.05 x 0.005 mm in size.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, number 102793.
Geological Setting of Type Material:
Lithophysae of obsidian.
Other Language Names for Clinoferrosilite
Relationship of Clinoferrosilite to other Species
Member of:
Other Members of this group:
Aegirine | NaFe3+Si2O6 | Mon. 2/m : B2/b |
Aegirine-augite | (NaaCabFe2+cMgd)(Fe3+eAlfFe2+gMgh)Si2O6 | Mon. 2/m : B2/b |
Augite | (CaxMgyFez)(Mgy1Fez1)Si2O6 | Mon. 2/m : B2/b |
Burnettite | CaVAlSiO6 | Mon. 2/m : B2/b |
Clinoenstatite | MgSiO3 | Mon. 2/m : P21/b |
Colomeraite | NaTi3+Si2O6 | Mon. 2/m : B2/b |
Davisite | CaScAlSiO6 | Mon. 2/m : B2/b |
Diopside | CaMgSi2O6 | Mon. 2/m : B2/b |
Esseneite | CaFe3+[AlSiO6] | Mon. 2/m : B2/b |
Grossmanite | CaTi3+ AlSiO6 | Mon. 2/m : B2/b |
Hedenbergite | CaFe2+Si2O6 | Mon. 2/m : B2/b |
Jadeite | Na(Al,Fe3+)Si2O6 | Mon. 2/m : B2/b |
Jervisite | NaSc3+Si2O6 | Mon. 2/m : B2/b |
Johannsenite | CaMn2+Si2O6 | Mon. 2/m : B2/b |
Kanoite | Mn2+(Mg,Mn2+)Si2O6 | Mon. 2/m : P21/b |
Kosmochlor | NaCrSi2O6 | Mon. 2/m : B2/b |
Kushiroite | CaAl[AlSiO6] | Mon. 2/m : B2/b |
Namansilite | NaMn3+Si2O6 | Mon. 2/m : B2/b |
Natalyite | NaV3+Si2O6 | Mon. 2/m : B2/b |
Omphacite | (NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6 | Mon. 2/m |
Petedunnite | Ca(Zn,Mn2+,Mg,Fe2+)Si2O6 | Mon. 2/m : B2/b |
Pigeonite | (CaxMgyFez)(Mgy1Fez1)Si2O6 | Mon. 2/m : P21/b |
Ryabchikovite | CuMgSi2O6 | Mon. 2/m : P21/b |
Spodumene | LiAlSi2O6 | Mon. 2/m : B2/b |
Tissintite | (Ca,Na,◻)AlSi2O6 | Mon. 2/m : B2/b |
UM2001-19-SiO:AlCaMgNa | (Na,Mg,Ca)(Mg,Al)Si2O6 | Mon. 2/m : B2/b |
UM2003-36-SiO:CaNa | NaCrSi2O6 - CaMgSi2O6 | Mon. 2/m : B2/b |
Common Associates
Associated Minerals Based on Photo Data:
7 photos of Clinoferrosilite associated with Amethyst | SiO2 |
5 photos of Clinoferrosilite associated with Sanidine | K(AlSi3O8) |
1 photo of Clinoferrosilite associated with Diopside | CaMgSi2O6 |
1 photo of Clinoferrosilite associated with Quartz | SiO2 |
1 photo of Clinoferrosilite associated with Hemleyite | (Fe2+0.48Mg0.37Ca0.04Na0.04Mn2+0.03Al0.03Cr3+0.01)sum=1.00Si1.00O3 |
1 photo of Clinoferrosilite associated with Clinoenstatite | MgSiO3 |
1 photo of Clinoferrosilite associated with Fayalite-Forsterite Series | |
1 photo of Clinoferrosilite associated with Maskelynite | |
1 photo of Clinoferrosilite associated with Taenite | (Fe,Ni) |
Related Minerals - Strunz-mindat Grouping
9.DA. | Protoenstatite | Mg2Si2O6 |
9.DA. | Ryabchikovite | CuMgSi2O6 |
9.DA. | Colomeraite | NaTi3+Si2O6 |
9.DA.05 | Donpeacorite | (Mn,Mg)MgSi2O6 |
9.DA.05 | Enstatite | Mg2Si2O6 |
9.DA.05 | Ferrosilite | Fe2+2Si2O6 |
9.DA.10 | Clinoenstatite | MgSiO3 |
9.DA.10 | Kanoite | Mn2+(Mg,Mn2+)Si2O6 |
9.DA.10 | Pigeonite | (CaxMgyFez)(Mgy1Fez1)Si2O6 |
9.DA.15 | Augite | (CaxMgyFez)(Mgy1Fez1)Si2O6 |
9.DA.15 | Diopside | CaMgSi2O6 |
9.DA.15 | Esseneite | CaFe3+[AlSiO6] |
9.DA.15 | Hedenbergite | CaFe2+Si2O6 |
9.DA.15 va | Jeffersonite | Ca(Mn,Zn,Fe)Si2O6 |
9.DA.15 | Johannsenite | CaMn2+Si2O6 |
9.DA.15 | Petedunnite | Ca(Zn,Mn2+,Mg,Fe2+)Si2O6 |
9.DA.15 | Davisite | CaScAlSiO6 |
9.DA.15 | Kushiroite | CaAl[AlSiO6] |
9.DA.15 | Grossmanite | CaTi3+ AlSiO6 |
9.DA.20 | Aegirine-augite | (NaaCabFe2+cMgd)(Fe3+eAlfFe2+gMgh)Si2O6 |
9.DA.20 | Omphacite | (NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6 |
9.DA.25 | Aegirine | NaFe3+Si2O6 |
9.DA.25 | Jadeite | Na(Al,Fe3+)Si2O6 |
9.DA.25 | Jervisite | NaSc3+Si2O6 |
9.DA.25 | Kosmochlor | NaCrSi2O6 |
9.DA.25 | Namansilite | NaMn3+Si2O6 |
9.DA.25 | Natalyite | NaV3+Si2O6 |
9.DA.25 | Tissintite | (Ca,Na,◻)AlSi2O6 |
9.DA.30 | Spodumene | LiAlSi2O6 |
9.DA.35 | Hiroseite | FeSiO3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Clinoferrosilite
mindat.org URL:
https://www.mindat.org/min-1073.html
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References for Clinoferrosilite
Reference List:
Localities for Clinoferrosilite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Birch (1999) |
Brazil | |
| Jour. of South American Earth Sci. ... |
China | |
| Dongyang Zhang et al. (2010) |
Finland | |
| Kallio et al. (2021) |
Germany | |
| BLAß et al. (1995) |
| Blass |
India | |
| Bhattacharjee et al. (2012) |
Italy | |
| Marzio Mamberti find & collection |
Japan | |
| Matsueda (1980) |
Kenya | |
| Bowen N L (1935) |
Rocky Mountain (53rd) | |
Mongolia | |
| Savina et al. (2020) |
| Peretyazhko et al. (2018) |
Peretyazhko et al. (2017) | |
Russia | |
| Safina et al. (2015) |
| Sharygin et al. (2010) |
[World of Stones 12:49] | |
South Africa | |
| Cairncross et al. (1995) |
| Excalibur Minerals photo ID 140072 |
| Fosso-Kankeu et al. (2015, November) |
Tajikistan | |
| Sharygin et al. (2009) |
USA | |
| ... |
| Bowen (1935) +2 other references |
Bowen (1935) +2 other references | |
| Gunnar Färber - Mineralienliste 3-2017. |
| Amer.J.Sci. (1935) |
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Merensky Reef, Bojanala Platinum District Municipality, North West, South Africa