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Silica

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Not really a true synonym, silica can mean many things, but in mineralogy it is the suite of species comprised of SiO2 (e.g. see chalcedony, opal etc.).

Classification of Silica

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Other Names for Silica

Varieties:
Float-stone

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Silica

Reference List:

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Sosman, R.B. (1927) The Properties of Silica. 856 pp., New York.

Rogers, Austin Flint (1928), Natural history of the silica minerals: American Mineralogist: 13: 73-92;

Cartz, L. (1964) An X-ray diffraction study of the structure of silica glass. Zeitschrift für Kristallographie: 120: 241-260.

Robinson, H.A. (1965) On the structure of vitreous SiO2. I. A new pentagonal dodecahedral model. Journal Phys. Chem. Solids: 26: 209-222.

Henninger, E.H., Buschert, R.C., and Heaton, L. (1967) Atomic structure and correlation in vitreous silica by x-ray and neutron diffraction. Journal Phys. Chem. Solids: 28: 423-432.

Hicks, J.F.G. (1967) Structure of silica glass. Scence: 155: 459-461.

Kushiro, I. (1969), The system forsterite-diopside-silica with and without water at high pressures: American Journal of Science: 267: 269-294.

Mozzi, R.L. and Warren, B.E (1969) The structure of vitreous silica. Journalm of Applied Crystallography: 2: 164-172.

Bell, R.J. and Dean, P. (1972) The structure of vitreous silica: validity of the random network theory. Phil. Magazine: 25: 1381-1398.

Konnert, J.H. and Karle, J. (1972) Tridymite-like structure in silica glass. Nature Phys. Sci.: 236: 92-94.

Narten, A.H. (1972) Diffraction pattern and structure of non-crystalline BeF2 and SiO2 at 25°C. Journal Chem. Phys.: 56: 1905-1909.

Konnert, J.H. and Karle, J. (1973a) Crystalline ordering in silica and germania glasses. Science: 179: 177-179.

Konnert, J.H., Ferguson, G.A., and Karle, J. (1974) Structure of silica glass: rebuttal. Science: 184: 93.

Da Silva, J.R.G.D., Pinatti, D.G., Anderson, C.E., and Rudee, M.L. (1975) A refinement of the structure of vitreous silica. Phil. Magazine: 31: 713-717.

Yip, K.L. and Fowler, W.B. (1975) Electronic structure of E1' centers in SiO2. Physics Review B: B11: 2327-2338.

Gaskell, P.H. and Tarrant, I.D. (1980) Refinement of a random network model for vitreous silicon dioxide. Phil. Magazine: B42: 265-286.

Herms, G. and Steil, H. (1980) The pentagonal dodecahedral model of vitreous silica and its compatibility with diffraction experiments. Krist. Tech.-Cryst. Res. Tech.: 15: 879-884.

Konnert, J.H., D'Antonio, P., and Karle, J. (1982) Comparison of radial distribution function for silica glass with those for various bonding topologies: use of correlation function. Journal of Non-Crystalline Solids 53: 135-141.

Richet, P., Bottinga, Y., Deniélou, L., Petitet, J.P., and Téqui, C. (1982) Thermodynamic properties of quartz, cristobalite, and amorphous SiO2: drop calorimetry measurements between 1000 and 1800 K and a review from 0 to 2000 K. Geochimica et Cosmochmica Acta: 46: 2639-2658.

Jani, M.G., Bossoli, R.B., and Halliburton, L.E. (1983) Further characterization of the E1' center in crystalline SiO2. Physics Review: B 27: 2285-2293.

Johnson, P.A.V., Wright, A.C., and Sinclair, R.N. (1983) Neutron scattering from vitreous silica. II. Twin-axis diffraction experiments. Journal of Non-Crystalline Solids: 58: 109-130.

Smith, J.V. and Blackwell, C.S. (1983) Nuclear magnetic resonance of silica polymorphs. Nature: 303: 223-225.

Dupree, E. and Pettifer, R.F. (1984) Determination of the Si-O-Si angle distribution in vitreous silica by magic angle spinning NMR. Nature: 308: 523-525.

Coombs, P.G., De Natale, J.F., Hood, P.J., McElfresh, D.K., Wortman, R.S., and Shackelford, J.F. (1985) The nature of the Si-O-Si bond angle distribution in vitreous silica. Phil. Magazine: B51: L39-L42.

Gupta, R.P. (1985) Electronic structure of crystalline and amorphous silicon dioxide. Physical Review: B32: 8278-8292.

Galeener, F.L. and Wright, A.C. (1986) The J.C. Phillips model for vitreous SiO2: a critical appraisal. Solid State Commun.: 57: 677-682.

Gerber, T. and Himmel, B. (1986) The structure of silica glass. Journal of Non-Crystalline Solids: 83: 324-334.

Goodman, C.H.L. (1986) The structure of silica glass and its surface. Phys. Chem. Glasses: 27: 27-31.

Kusabiraki, K. (1987) Infrared and Raman spectra of vitreous silica and sodium silicates containing titanium. Journal of Non-Crystalline Solids: 95-96: 411-418.

Galeener, F.L. (1988) Current models for amorphous SiO2. In: The Physics and Technology of Amorphous SiO* (R.A.B. Devine, ed.) Plenum Press, New York, NY.

Griscom, D.L. (1989) Self-trapped holes in amorphous silicon dioxide. Physics review: B 40: 4224-4228.

Gladden, L.F. (1990b) Medium-range order in v-SiO2. Journal of Non-Crystalline Solids: 119: 318-330.

Guttman, L. (1990) Ring structure of the crystalline and amorphous forms of silicon dioxide. Journal of Non-Crystalline Solids: 116: 154-147.

Marians, C.S. and Burdett, J.K. (1990) Geometric constraints: a refined model for the structure of silica glass. Journal of Non-Crystalline Solids: 124: 1-21.

Marians, C.S. and Hobbs, L.W. (1990) Local structure of silica glasses. Journal of Non-Crystalline Solids: 119: 269-282.

Young-nian, X. and Ching, W.Y. (1991) Electronic and optical properties of all polymorphic forms of silicon dioxide. Physical review: B44: 11048-11059.

Leko, V.K. (1993) The structure of vitreous silica. Glass Phys. Chem.: 19: 351-374.

Li, D., Bancroft, G.M., Kasrai, M., Fleet, M.E., Secco, R.A., Feng,X.H., Tan, K.H., and Yang, B.X. (1994): X-ray absorption spectroscopy of silicon dioxide (SiO2) polymorphs: the structural characterization of opal. American Mineralogist: 79: 622-632.

Wright, A.C. (1994) Neutron scatterng from vitreous silica. V. The structure of vitreous silica: what have we learned from 60 years of diffraction studies? Journal of Non-Crystalline Solids: 179: 84-115.

Di Pomponio, A., Continenza, Lozzi, A.A., Passacantando, L., Santucci, M., and Picozzi, P. (1995) Electronic properties of crystalline and amorphous SiO2 investigated via all-electron calculations and photoemission spectroscopy. Solid State Communications: 95: 313-317.

LeBail, A. (1995) Modelling the silica glass structure by the Rietveld method. Journal of Non-Crystalline Solids: 183: 39-42.

Gaskell, P.H. and Wallis, D.J. (1996) Medum-range order in silica, the canonical network glass. Phys. Rev. Lett.: 76: 66-69.

MAuri, F., Pasquarello, A., Pfrommr, BG., Yoon, Y.-G., and Louie, S.G. (2000) Si-O-Si bond-angle distribution in vitreous silica from first principles 29Si NMR analysis. Phys. Rev.: B62: R4786-R4789.

Nakamura, M., Arai, M., Otomo, T., Inamura, Y., and Bennington, S.M. (2001) Dispersive excitation in different forms of SiO2 Journal of Non-Crystalline Solids: 293-295: 377-382.

Nakamura, M., Arai, M., Inamura, Y., and Otomo, T. (2003) Dynamical properties of vitreous silica around the first sharp diffraction peak. Phys. Rev.: B67: 064204.

Clark, T.M., Grandinetti, P.J., Florian, P., and Stebbins, J.F. (2004) Correlated structural distributions in silica glass. Phys. Rev.: B70: 064202.

Tucker, M.G., Keen, D.A., Dove, M.T., and Trachenko, K. (2005) Refinement of the Si-O-Si angle distribution in vitreous silica. Journal Phys. Condens. Matter: 17: S67-S75.

Uchino, T., Harrop, J.D., Taraskin, S.N., and Elliott, S.R. (2005) Real and reciprocal space structural correlations contributing to the first sharp diffraction peak in silica glass. Phys. Rev.: B71: 014202.

Internet Links for Silica

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