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Coesite

Formula:
SiO
 
2
System:MonoclinicColour:Colourless
Lustre:VitreousHardness:7½ - 8
Name:For Loring Coes Jr. (1915-1978), American chemist who first synthesized it.
Polymorph of:Cristobalite, Quartz, Stishovite, Tridymite
This page provides mineralogical data about Coesite.

Classification of Coesite

IMA status:Approved
Strunz 8th edition ID:4/D.01-50
Nickel-Strunz 10th (pending) edition ID:4.DA.35

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
A : With small cations: Silica family
Dana 8th edition ID:75.1.4.1

75 : TECTOSILICATES Si Tetrahedral Frameworks
1 : Si Tetrahedral Frameworks - SiO2 with [4] coordinated Si
Hey's CIM Ref.:7.8.2

7 : Oxides and Hydroxides
8 : Oxides of Si
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Type Occurrence of Coesite

Type Locality:Meteor Crater (Barringer Crater), Winslow, Coconino Co., Arizona, USA
Year of Discovery:1954

Occurrences of Coesite

Geological Setting:Formed at pressures > 20 kbar. Impact craters, kimberlites, eclogites.

Physical Properties of Coesite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:Colourless
Hardness (Mohs):7½ - 8
Cleavage:Poor/Indistinct
Suspected on {010}{012}
Fracture:Sub-Conchoidal
Density (calculated):2.92 g/cm3

Crystallography of Coesite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/b {B1 1 2/b} {C2/c} {C1 2/c 1}
Cell Parameters:a = 7.143(2) Å, b = 12.383(3) Å, c = 7.143(2) Å
β = 120°
Ratio:a:b:c = 0.577 : 1 : 0.577
Unit Cell Volume:V 547.16 ų (Calculated from Unit Cell)
Z:16
Morphology:Irregular to rectangular grains.

Optical Data of Coesite

Type:Biaxial (+)
RI values: nα = 1.593 - 1.599 nγ = 1.597 - 1.604
2V:Measured: 54° to 64°
Maximum Birefringence:δ = 0.004 - 0.005

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r < v weak
Comments:On synthetic material

Chemical Properties of Coesite

Formula:
SiO
 
2
Essential elements:O, Si
All elements listed in formula:O, Si
Common Impurities:Al,Fe,Na

Relationship of Coesite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
4.DA.05Quartz
SiO
 
2
4.DA.10Opal
SiO
 
2
·nH
 
2
O
4.DA.10Tridymite
SiO
 
2
4.DA.15Cristobalite
SiO
 
2
4.DA.20Mogánite
SiO
 
2
4.DA.25Melanophlogite
46SiO
 
2
·6(N
 
2
,CO
 
2
)·2(CH
 
4
,N
 
2
)
4.DA.30Lechatelierite
SiO
 
2
4.DA.40Stishovite
SiO
 
2
4.DA.45Keatite
4.DA.50Seifertite
SiO
 
2
Related Minerals - Hey's Index Grouping:

- +
7.8.1Quartz
SiO
 
2
7.8.3Tridymite
SiO
 
2
7.8.4Stishovite
SiO
 
2
7.8.5Cristobalite
SiO
 
2
7.8.6Lechatelierite
SiO
 
2
7.8.7Silhydrite
3SiO
 
2
·H
 
2
O
7.8.8Opal
SiO
 
2
·nH
 
2
O
7.8.9Mogánite
SiO
 
2

Other Names for Coesite

Other Languages:
German:Coesit
Russian:Коэсит
Spanish:Coesita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Coesite

Reference List:Chao, E.C.T., et al (1960), First natural occurrence of coesite, Science: 132: 220-222.

American Mineralogist (1960): 45: 1313.

American Mineralogist (1962): 47: 1292-1302.

Fahey, J.J. (1964), Recovery of coesite and stishovite from Coconino Sandstone of Meteor Crater, AZ, American Mineralogist: 49: 1643-1647.

Bohn, E. & W. Stöber (1966), Coesit und Stishovit als isolierte natürliche Mineralien, Neues Jahrb. Min.: 89-96.

Zeitschrift für Kristallographie: 145: 108-123.

Bohlen, S.R. and Boettcher, A.L. (1982) The quartz-coesite transformation: a precise determination and the effects of other components. Journal of Geophysical Research: 87(B8): 7073-7078.

Zhang, J., Li, B., Utsumi, W., and Liebermann, R.C. (1996) In situ X-ray observations of the coesite-stishovite transition: reversed phase boundary and kinetics. Physics and Chemistry of Minerals: 23: 1-10.

Gibbs, G.V., M.B. Boisen, Jr., .M. Rosso, D.M. Teter, & M..T. Bukowinski (2000), Model structures and electron density distribution for the silica polymorph coesite at pressure: An assessment of OO bonded interactions: Journal of Physical Chemistry: B: 104: 10534-10542.

Mosenfelder, J.L. (2000) Pressure dependence of hydroxyl solubility in coesite. Physics and Chemistry of Minerals 27(9): 610-617.

Internet Links for Coesite

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    Localities for Coesite

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