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Hydrocerussite

Formula:
Pb
 
3
(CO
 
3
)
 
2
(OH)
 
2
System:TrigonalColour:White or grey; ...
Hardness:
Name:In allusion to the composition, being a HYDRated lead carbonate, similar to cerussite.


Hydrocerussite is a secondary mineral usually found in oxidized lead ore deposits.

A closely related mineral is Plumbonacrite.

Classification of Hydrocerussite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:5/C.08-10
Nickel-Strunz 10th (pending) edition ID:5.BE.10

5 : CARBONATES (NITRATES)
B : Carbonates with additional anions, without H2O
E : With Pb, Bi
Dana 8th edition ID:16a.2.2.1

16a : ANHYDROUS CARBONATES CONTAINING HYDROXYL OR HALOGEN
2 : (AB)3(XO3)2Zq
Hey's CIM Ref.:11.9.2

11 : Carbonates
9 : Carbonates of Pb, Zr and Th
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Type Occurrence of Hydrocerussite

Type Locality:Långban, Filipstad, Värmland, Sweden
Geological Setting of type material:Metamorphosed Mn-Fe deposit.
Associated Minerals at type locality:
Lead

Physical Properties of Hydrocerussite

Lustre:Adamantine, Pearly
Diaphaneity (Transparency):Transparent, Translucent
Colour:White or grey; colourless in transmitted light
Streak:White
Hardness (Mohs):
Tenacity:Brittle
Cleavage:Perfect
On {0001}.
Density (measured):6.8 g/cm3
Density (calculated):6.94 g/cm3

Crystallography of Hydrocerussite

Crystal System:Trigonal
Morphology:Crystals steep pyramidal {h0h1} with {0001} very small at times. Thin scales with a hexagonal presentation and flattened {0001}; also thick tabular {0001}.

Optical Data of Hydrocerussite

Type:Uniaxial (-)
RI values: nω = 2.090 nε = 1.940
Maximum Birefringence:δ = 0.150

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High

Chemical Properties of Hydrocerussite

Formula:
Pb
 
3
(CO
 
3
)
 
2
(OH)
 
2
Essential elements:C, H, O, Pb
All elements listed in formula:C, H, O, Pb

Relationship of Hydrocerussite to other Species

Common Associates:
ParalaurioniteMendipiteMatlockiteLeadhilliteCerussite
Related Minerals - Nickel-Strunz Grouping):

- +
5.BE.05Shannonite
Pb
 
2
[O|CO
 
3
]
5.BE.15Plumbonacrite
Pb
 
5
O(OH)
 
2
(CO
 
3
)
 
3
5.BE.20Phosgenite
Pb
 
2
[Cl
 
2
|CO
 
3
]
5.BE.25Bismutite
(BiO)
 
2
CO
 
3
5.BE.30Kettnerite
(BiO)Ca[F|CO
 
3
]
5.BE.35Beyerite
Ca(BiO)
 
2
(CO
 
3
)
 
2
Related Minerals - Hey's Index Grouping:

- +
11.9.1Cerussite
PbCO
 
3
11.9.3Dundasite
PbAl
 
2
[(OH)
 
2
|CO
 
3
]
 
2
· H
 
2
O
11.9.4Gysinite-(Nd)
Pb(Nd,La)[OH|(CO
 
3
)
 
2
] · H
 
2
O
11.9.5Schuilingite-(Nd)
PbCu(Nd,Gd,Sm,Y)(CO
 
3
)
 
3
(OH)·1.5H
 
2
O
11.9.6Tuliokite
Na
 
6
BaTh(CO
 
3
)
 
6
·6H
 
2
O
11.9.7Weloganite
Sr
 
3
Na
 
2
Zr(CO
 
3
)
 
6
·3H
 
2
O
11.9.8Sabinaite
Na
 
4
Zr
 
2
TiO
 
4
(CO
 
3
)
 
4

Other Names for Hydrocerussite

Synonyms:
Hydrocerusite
Other Languages:
German:Hydrocerussit
Russian:Гидроцеруссит
Spanish:Hydrocerussita

Other Information

Other Information:Soluble in acids with effervescence.
Health Warning:Contains lead - always wash hands after handling. Do not lick.

References for Hydrocerussite

Reference List:Nordenskild (1877) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 3: 381.

Heddle (1889) Mineralogical Magazine: 8: 201 (as Plumbonacrite).

Flink (1901) Bull. Geol. Inst. Upsala: 5: 94.

Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 202.

Spencer (1925) Mineralogical Magazine: 20: 80.

Aminoff (1926) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 48: 44.

Kokkoros, P. and Vassiliadis, K. (1953). Röntgenkristallographie von Hydrocerussit. Tschermaks Mineral. Petrogr. Mitt. 3, 298-304.

Voronova, A. A. and Vainshtein, B. K. (1964): An electron-diffraction study of the crystal structure of PbCO3PbO(H2O)2. Kristallografiya 9, 197-203. (in Russian).

Keller, P. (1977): Hydrocerussit von Tsumeb/Südwestafrika. Der Aufschluss, 28, 413-415.

Flemming, N. J.; Lopata, V. J.; Sanipelli, B. L.; Taylor, P. (1984): Thermal decomposition of basic lead carbonates: a comparison of hydrocerussite and plumbonacrite. Thermochim. Acta 81, 1-8.

Taylor, P. & Lopata, V. J. (1984): Stability and solubility relationships between some solids in the system lead oxide-carbon dioxide-water. Can. J. Chem. 62, 395-402.

Martinetto, P., M. Anne, E. Dooryhée, P. Walter and G. Tsoucaris (2002): Synthetic hydrocerussite, 2PbCO3•Pb(OH)2, by X-ray powder diffraction. Acta Cryst. C58, i82-i84. [possibly incorrect structure/space group; comment by Uwe Kolitsch]

Internet Links for Hydrocerussite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Hydrocerussite in the Natural History Museum (London) online catalogue
  • Hydrocerussite details from Handbook of Mineralogy (PDF)
  • Mineral Dealers:
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    Localities for Hydrocerussite

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