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Kempite

Formula:
Mn
2+
2
[(OH)
 
3
|Cl]
System:OrthorhombicColour:Emerald-green
Hardness:
Name:
After James Furman Kemp (1859-1926), mining geologist, and Professor of Geology, Columbia University.
This page provides mineralogical data about Kempite.

Classification of Kempite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:3/D.01-20
Nickel-Strunz 10th (pending) edition ID:3.DA.10a

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
A : With Cu, etc., without Pb
Dana 8th edition ID:10.1.4.1

10 : OXYHALIDES AND HYDROXYHALIDES
1 : A2(O,OH)3Xq
Hey's CIM Ref.:8.10.2

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
10 : Halides of Mn
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Type Occurrence of Kempite

Type Locality:Alum Rock Park, San Jose, Santa Clara Co., California, USA
Year of Discovery:1924
Geological Setting of type material:Erratic boulder
Associated Minerals at type locality:
RhodochrositePyrochroiteHausmannite

Physical Properties of Kempite

Diaphaneity (Transparency):Translucent
Colour:Emerald-green
Hardness (Mohs):
Density (measured):2.94 g/cm3
Density (calculated):2.96 g/cm3

Crystallography of Kempite

Crystal System:Orthorhombic
Class (H-M):mmm (2/m 2/m 2/m) - Dipyramidal
Cell Parameters:a = 6.49Å, b = 9.52Å, c = 7.12Å
Ratio:a:b:c = 0.682 : 1 : 0.748
Unit Cell Volume:V 439.91 ų (Calculated from Unit Cell)
Z:4
Morphology:Crystals prismatic [001]. {100} and {010} are usually absent or inconspicuous.

Optical Data of Kempite

Type:Biaxial (-)
RI values: nα = 1.684 nβ = 1.695 nγ = 1.698
2V:Calculated: 54°
Maximum Birefringence:δ = 0.014

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r > v

Chemical Properties of Kempite

Formula:
Mn
2+
2
[(OH)
 
3
|Cl]
Essential elements:Cl, H, Mn, O
All elements listed in formula:Cl, H, Mn, O

Relationship of Kempite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
3.DA.05Melanothallite
Cu
 
2
[O|Cl
 
2
]
3.DA.10aAtacamite
Cu
 
2
[(OH)
 
3
|Cl]
3.DA.10bBotallackite
Cu
 
2
[(OH)
 
3
|Cl]
3.DA.10bClinoatacamite
Cu
 
2
[(OH)
 
3
|Cl]
3.DA.10aHibbingite
Fe
2+
2
[(OH)
 
3
|Cl]
3.DA.10cParatacamite
Cu
 
3
(Cu,Zn)[(OH)
 
3
|Cl]
 
2
3.DA.10bBelloite
Cu[OH|Cl]
3.DA.10cHerbertsmithite
Cu
 
3
Zn[(OH)
 
3
|Cl]
 
2
3.DA.10cKapellasite
Cu
 
3
Zn[(OH)
 
3
|Cl]
 
2
3.DA.10cGillardite
Cu
 
3
NiCl
 
2
(OH)
 
6
3.DA.10cHaydeeite
Cu
 
3
Mg(OH)
 
6
Cl
 
2
3.DA.10dIMA2009-042
Cu
 
2
Cl(OH)
 
3
3.DA.15Claringbullite
Cu
 
4
[(OH)
 
7
|Cl] · nH
 
2
O
3.DA.20Simonkolleite
Zn
 
5
[(OH)
 
8
|Cl
 
2
] · H
 
2
O
3.DA.25Buttgenbachite
Cu
 
19
[(OH)
 
32
|(NO
 
3
)
 
2
|Cl
 
4
] · 2H
 
2
O
3.DA.25Connellite
Cu
 
19
[(OH)
 
32
|SO
 
4
|Cl
 
4
] · 3H
 
2
O
3.DA.30Abhurite
Sn
 
21
Cl
 
16
(OH)
 
14
O
 
6
3.DA.35Ponomarevite
K
 
4
Cu
 
4
[O|Cl
 
10
]
3.DA.40Anthonyite
Cu(OH,Cl)
 
2
· 3H
 
2
O
3.DA.40Calumetite
Cu(OH,Cl)
 
2
· 2H
 
2
O
3.DA.45Khaidarkanite
Na
 
0.34
Cu
 
4
Al
 
3
(OH)
 
14
F
 
3
·2H
 
2
O
3.DA.50Bobkingite
Cu
 
5
[(OH)
 
8
|Cl
 
2
] · 2H
 
2
O
3.DA.55Avdoninite
K
 
2
Cu
 
5
[(OH)
 
4
|Cl
 
8
] · H
 
2
O
3.DA.60Droninoite
Ni
 
3
Fe
3+
 
Cl(OH)
 
8
·2H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
8.10.1Scacchite
MnCl
 
2
8.10.3Chlormanganokalite
K
 
4
[MnCl
 
6
]

Other Names for Kempite

Other Languages:
German:Kempit
Russian:Кемпит
Spanish:Kempita

Other Information

Other Information:Soluble in dilute acid.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Kempite

Reference List:Rogers (1924) American Journal of Science: 8: 145.

Rogers (1949) Bulletin of the Geological Society of America: 60, no. 12, part 2: 1944.

Palache, Charles, Harry Berman & Clifford Frondel (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Seventh edition, Volume II: 73-74.

Internet Links for Kempite

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  • Raman and XRD data at RRUFF project
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    Localities for Kempite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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