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Khinite

A valid IMA mineral species
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About KhiniteHide

Formula:
Pb2+Cu2+3[Te6+O6](OH)2
Colour:
Dark green to bottle green
Lustre:
Vitreous
Hardness:
3
Specific Gravity:
6.5 - 7.0
Crystal System:
Orthorhombic
Name:
Named in honor of BaSaw Khin (b. 1931, Burma), a mineralogist with Phelps Dodge Corporation, USA. He found the first specimens of parakhinite.
Two polytypes are known, khinite-4O (orthorhombic) and khinite-3T (trigonal). The two polytypes have different stackings of otherwise identical layers of composition [Cu3(TeO6)(OH)2]2-, with Pb2+ cations between the layers.


Unique IdentifiersHide

Mindat ID:
2199
Long-form identifier:
mindat:1:1:2199:5
GUID
(UUID V4):
342ad99e-867c-4570-b98c-87c0e7263412

IMA Classification of KhiniteHide

Approved
IMA Formula:
Cu2+3PbTe6+O6(OH)2
Approval year:
1978
First published:
1978

Classification of KhiniteHide

4.FD.30

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
D : Hydroxides with OH, without H2O; chains of edge-sharing octahedra
Dana 7th ed.:
33.1.3.1
33.1.3.1

33 : SELENATES AND TELLURATES
1 : (AB)m(XO4)pZq
28.4.8

28 : Selenites, Selenates, Tellurites, and Tellurates
4 : Tellurates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KhnIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KhiniteHide

Vitreous
Transparency:
Translucent
Colour:
Dark green to bottle green
Streak:
Vivid green
Hardness:
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
On {001}
Density:
6.5 - 7.0 g/cm3 (Measured)    6.29 g/cm3 (Calculated)
Comment:
Thoulet's method

Optical Data of KhiniteHide

Type:
Biaxial (+)
RI values:
nα = 2.110 nβ = 2.112 nγ = 2.165
2V:
Measured: 20° , Calculated: 24°
Max Birefringence:
δ = 0.055
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
strong
Pleochroism:
Visible
Comments:
Rich yellowish green (Y,Z), vivid emerald green (X)
Z = Y > X

Chemistry of KhiniteHide

Mindat Formula:
Pb2+Cu2+3[Te6+O6](OH)2

Crystallography of KhiniteHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Khinite-3TKhinite-4O
Pb2+Cu2+3Te6+O6(OH)2 
Trigonal Orthorhombic 
3 - Pyramidalmm2 - Pyramidal
P32Fdd2
  
a = 5.765(2) Å, c = 18.001(9) Å
a = 5.7491(10) Å, b = 10.0176(14) Å, c = 24.022(3) Å
a:c = 1 : 3.122a:b:c = 0.574 : 1 : 2.398
V 518 ųV 1383.6 ų
38

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005428KhiniteBurns P C, Cooper M A, Hawthorne F C (1995) Parakhinite, Cu3PbTeO6(OH)2: Crystal structure and revision of chemical formula formerly known as parakhinite The Canadian Mineralogist 33 33-4019950293
0014583KhiniteCooper M A, Hawthorne F C, Back M E (2008) The crystal structure of khinite and polytypism in khinite and parakhinite Mineralogical Magazine 72 763-7702008the Empire mine, Tombstone, Arizona, USA0293
0014584KhiniteCooper M A, Hawthorne F C, Back M E (2008) The crystal structure of khinite and polytypism in khinite and parakhinite Mineralogical Magazine 72 763-7702008the Empire mine, Tombstone, Arizona, USA0293
CIF Raw Data - click here to close

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47e : [Vanadates, chromates, manganates]

Type Occurrence of KhiniteHide

General Appearance of Type Material:
Deeply etched curved or barrel shaped bipyramids.
Place of Conservation of Type Material:
The Natural History Museum, London, England, numbers 1980,541 and 1980,543.
National Museum of Natural History, Washington, D.C., USA, numbers 164352.
Geological Setting of Type Material:
Tellurium-bearing dumps.
Associated Minerals at Type Locality:
Reference:
Williams, S.A. (1978) Khinite, parakhinite, and dugganite, three new tellurates from Tombstone, AZ. American Mineralogist: 63: 1016-1019.

Synonyms of KhiniteHide

Other Language Names for KhiniteHide

German:Khinit
Spanish:Khinita

Common AssociatesHide

Associated Minerals Based on Photo Data:
31 photos of Khinite associated with TimroseitePb2Cu5(TeO6)2(OH)2
30 photos of Khinite associated with GoldAu
30 photos of Khinite associated with QuartzSiO2
24 photos of Khinite associated with ThorneitePb6(Te6+2O10)(CO3)Cl2(H2O)
10 photos of Khinite associated with ChlorargyriteAgCl
8 photos of Khinite associated with CerussitePbCO3
6 photos of Khinite associated with WulfenitePb(MoO4)
5 photos of Khinite associated with HousleyitePb6CuTe6+4O18(OH)2
4 photos of Khinite associated with Goethiteα-Fe3+O(OH)
4 photos of Khinite associated with Eckhardite(Ca,Pb)Cu2+Te6+O5(H2O)

Related Minerals - Strunz-mindat GroupingHide

4.FD.05SpertiniiteCu(OH)2Orth. mm2 : Cmc21
4.FD.10BracewelliteCrO(OH)Orth. mmm (2/m 2/m 2/m)
4.FD.10DiasporeAlO(OH)Orth. mmm (2/m 2/m 2/m)
4.FD.10GroutiteMn3+O(OH)Orth. mmm (2/m 2/m 2/m) : Pnma
4.FD.10GuyanaiteCrO(OH)Orth. mmm (2/m 2/m 2/m)
4.FD.10Montroseite(V3+,Fe3+)O(OH)Orth. mmm (2/m 2/m 2/m)
4.FD.10TsumgalliteGaO(OH)Orth. mmm (2/m 2/m 2/m)
4.FD.15ManganiteMn3+O(OH)Mon. 2/m : P21/b
4.FD.20Yttrotungstite-(Y)YW2O6(OH)3Mon. 2/m : P21/m
4.FD.20Yttrotungstite-(Ce)(Ce,Nd,Y)W2O6(OH)3Mon. 2 : P21
4.FD.25FrankhawthorneiteCu2Te6+O4(OH)2Mon. 2/m
4.FD.30Khinite-3TPb2+Cu2+3Te6+O6(OH)2Trig. 3 : P32
4.FD.30HousleyitePb6CuTe6+4O18(OH)2Mon. 2/m : P21/m

Fluorescence of KhiniteHide

Other InformationHide

Notes:
Quickly dissolves in even mildly alkaline water.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KhiniteHide

References for KhiniteHide

Localities for KhiniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Mexico
 
  • Sonora
    • Moctezuma Municipality
Lapis 2001 (1)
Maggie Wilson
USA
 
  • Arizona
    • Cochise County
      • Carr Canyon
"The Accidental Pocket" talk presented ...
Williams (1978) +1 other reference
Brent Thorne
Mike Scott S102329 from Cureton ex S. ...
        • Silver Plume Mine
Marek Chorazewicz (2023)
        • Tombstone
Williams (1978) +1 other reference
  • California
    • San Bernardino County
      • Silver Lake Mining District
        • Soda Mountains
          • Baker
Kampf et al. (2010)
EDS and XRD confirmed. +1 other reference
Marek Chorazewicz (2019)
Joe Marty specimens. Kampf et al. (2010)
Collected by and in the collection of ...
King (n.d.) +1 other reference
Collected by and in the collection of ... +1 other reference
Collected by and in the collection of ...
Collected by and in the collection of ...
          • Zzyzx
Collected by and in the collections of ...
Collected by and in the collection of ...
  • Nevada
    • Lincoln County
      • Delamar Mining District
        • Delamar Mine
Kampf et al. (2022)
  • Utah
    • Juab County
      • Detroit Mining District
Miyawaki et al. (2019) +1 other reference
Coolbaugh et al. (2020)
    • Utah County
      • East Tintic Mining District
SEM-EDS analyzed by Dr. Rob Bowell.
 
Mineral and/or Locality  
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