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Kingite

A valid IMA mineral species - grandfathered
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About KingiteHide

Formula:
Al3(PO4)2F2(OH) · 7H2O
Originally assumed to be Al3(PO4)2(OH)3.9H2O.
Colour:
White, colorless, greenish yellow
Lustre:
Vitreous, Dull
Specific Gravity:
2.21 - 2.30
Crystal System:
Triclinic
Name:
Named in 1957 by Keith Norrish, Lillian E.R. Rogers, and R.E. Shapter in honor of Donald King (3 June 1926, Adelaide, Australia - 3 August 1989, The Gap, Australia), exploration geologist and mining executive with a varied background. He made significant contributions to the coal industry in Queensland. He collected the first specimens of kingite while he was a geologist with the Department of Mines, Adelaide, South Australia.
This page provides mineralogical data about Kingite.


Unique IdentifiersHide

Mindat ID:
2210
Long-form identifier:
mindat:1:1:2210:7
GUID
(UUID V4):
e330a1ba-46e8-43a9-b28f-e6a8d2df9873

IMA Classification of KingiteHide

Classification of KingiteHide

8.DC.47

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
42.10.3.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
10 : A3(XO4)2Zq·xH2O
19.7.11

19 : Phosphates
7 : Phosphates of Al alone

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KgiIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KingiteHide

Vitreous, Dull
Transparency:
Translucent
Colour:
White, colorless, greenish yellow
Streak:
White
Density:
2.21 - 2.30 g/cm3 (Measured)    2.465 g/cm3 (Calculated)

Optical Data of KingiteHide

Type:
Biaxial
Dispersion:
strong

Chemistry of KingiteHide

Mindat Formula:
Al3(PO4)2F2(OH) · 7H2O

Originally assumed to be Al3(PO4)2(OH)3.9H2O.

Crystallography of KingiteHide

Crystal System:
Triclinic
Cell Parameters:
a = 9.15(1) Å, b = 10.00(1) Å, c = 7.24(2) Å
α = 98.6(1)°, β = 93.6(1)°, γ = 93.2(1)°
Ratio:
a:b:c = 0.915 : 1 : 0.724
Unit Cell V:
652.29 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Platelets or irregular fragments, to 1 ”m, aggregated in nodules; as crusts of intergrown spheroids resembling fish roe.
Comment:
Point Group: 1 or 1; Space Group: P1 or P1.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0002976KingiteWallwork K S, Pring A, Taylor M R, Hunter B A (2003) A model for the structure of the hydrated aluminum phosphate, kingite determined by ab initio powder diffraction methods American Mineralogist 88 235-23920030293
0005931KingiteWallwork K S, Pring A, Taylor M R, Hunter B A (2004) The network of hydrogen bonding in kingite, as revealed by a neutron-diffraction investigation of its deuterated analogue, Al3(PO4)2F3.7D2O The Canadian Mineralogist 42 135-14120040293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.1 Å(100)
3.45 Å(80)
3.48 Å(65)
5.28 Å(52)
3.17 Å(39)
3.108 Å(30)
5.34 Å(28)
Comments:
Fairview Quarry, South Australia, Australia. Data from the type description.

Geological EnvironmentHide

Type Occurrence of KingiteHide

General Appearance of Type Material:
White nodules to 5 cm in diameter.
Place of Conservation of Type Material:
Natural History Museum, Paris, France, 175.300.
Harvard University, Cambridge, Massachusetts, USA, 109441.
National Museum of Natural History, Washington, D.C., USA, 112693.
Geological Setting of Type Material:
Found in Cambrian and Upper Precambrian limestones. Probably of supergene origin. Thought to have been deposited by meteoric waters in fault zones and breccias during Tertiary times.
Associated Minerals at Type Locality:
Reference:
Norrish, K., Rogers, L.E.R., and Shapter, R.E. (1957) Kingite, a new hydrated aluminum phosphate mineral from Robertstown, South Australia. Mineralogical Magazine, vol. 31, n° 236, 351-357.

Other Language Names for KingiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
4 photos of Kingite associated with TyuyamuniteCa(UO2)2(VO4)2 · 5-8H2O
3 photos of Kingite associated with GypsumCaSO4 · 2H2O
1 photo of Kingite associated with VolborthiteCu3(V2O7)(OH)2 · 2H2O
1 photo of Kingite associated with FluelliteAl2(PO4)F2(OH) · 7H2O

Related Minerals - Strunz-mindat GroupingHide

8.DC.IanbruceiteZn2(AsO4)(OH) · 3H2OMon. 2/m : P21/b
8.DC.CésarferreiraiteFe2+ Fe3+2(AsO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.FerrivauxiteFe3+Al2(PO4)2(OH)3 · 5H2OTric. 1 : P1
8.DC.05NissoniteCu2Mg2(PO4)2(OH)2 · 5H2OMon. 2/m : B2/b
8.DC.07EuchroiteCu2(AsO4)(OH) · 3H2OOrth. 2 2 2 : P21 21 21
8.DC.10LegranditeZn2(AsO4)(OH) · H2OMon. 2/m : P21/b
8.DC.12StrashimiriteCu8(AsO4)4(OH)4 · 5H2OMon.
8.DC.15ArthuriteCuFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15EarlshannoniteMn2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15OjuelaiteZnFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15WhitmoreiteFe2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15Cobaltarthurite(Co,Mg)Fe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15BendadaiteFe2+Fe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15KunatiteCuFe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15UM2006-27-PO:FeHZnZnFe3+2(PO4)2(OH)2 · 4H2OMon.
8.DC.15UKI-2006-(PO:AlCuFeH)Fe2+Al3+2(PO4)2(OH)2 · 4H2O
8.DC.17KleemaniteZnAl2(PO4)2(OH)2 · 3H2OMon.
8.DC.20BermaniteMn2+Mn3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P2/b
8.DC.20CoralloiteMn2+Mn3+2(AsO4)2(OH)2 · 4H2OTric. 1 : P1
8.DC.20MagnesiobermaniteMgMn3+2(PO4)2(OH)2 · 4H2OMon. 2 : P21
8.DC.22KovdorskiteMg2(PO4)(OH) · 3H2OMon. 2/m : P21/b
8.DC.25FerristrunziteFe3+Fe3+2(PO4)2(OH)3 · 5H2OTric.
8.DC.25FerrostrunziteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric.
8.DC.25MetavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/b
8.DC.25MetavivianiteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.25StrunziteMn2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.25ZincostrunziteZnFe3+2(PO4)2(OH)2 · 6.5H2OTric. 1 : P1
8.DC.27BerauniteFe3+6(PO4)4O(OH)4 · 6H2OMon. m : Bb
8.DC.27TvrdĂœiteFe2+Fe3+2 Al3(PO4)4(OH)5(H2O)4 · 2H2OMon. 2/m : B2/b
8.DC.27ZincoberauniteZnFe3+5(PO4)4(OH)5 · 6H2OMon. 2/m : B2/b
8.DC.30GordoniteMgAl2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30LaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30MangangordoniteMn2+Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30ParavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30PseudolaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/b
8.DC.30SigloiteFe3+Al2(PO4)2(OH)3 · 7H2OTric. 1 : P1
8.DC.30StewartiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30UshkoviteMgFe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30FerrolaueiteFe2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30Kastningite(Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30MaghrebiteMgAl2(AsO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30NordgauiteMnAl2(PO4)2(F,OH)2 · 5H2OTric. 1 : P1
8.DC.30Kayrobertsonite[MnAl2(PO4)2(OH)2(H2O)4] · 2H2OTric. 1 : P1
8.DC.30KummeriteMn2+Fe3+Al(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.32TinticiteFe3+3(PO4)2(OH)3 · 3H2OTric. 1 : P1
8.DC.32KamarizaiteFe3+3(AsO4)2(OH)3 · 3H2OTric. 1 : P1
8.DC.35VauxiteFe2+Al2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.37VantasseliteAl4(PO4)3(OH)3 · 9H2OOrth.
8.DC.40CacoxeniteFe3+24AlO6(PO4)17(OH)12 · 75H2OHex. 6/m : P63/m
8.DC.45Gormanite(Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2OTric.
8.DC.45Souzalite(Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2OTric. 1
8.DC.50WavelliteAl3(PO4)2(OH,F)3 · 5H2OOrth. mmm (2/m 2/m 2/m)
8.DC.50AllanpringiteFe3+3(PO4)2(OH)3 · 5H2OMon. 2/m : P21/m
8.DC.50FluorwavelliteAl3(PO4)2(OH)2F · 5H2OOrth. mmm (2/m 2/m 2/m)
8.DC.52KribergiteAl5(PO4)3(SO4)(OH)4 · 4H2OTric. 1 : P1
8.DC.55MapimiteZn2Fe3+3(AsO4)3(OH)4 · 10H2OMon. m : Bm
8.DC.57OgdensburgiteCa2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2OOrth. mmm (2/m 2/m 2/m) : Cmmm
8.DC.60Nevadaite(Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2OOrth. mmm (2/m 2/m 2/m)
8.DC.60CloncurryiteCu0.5(VO)0.5Al2(PO4)2F2 · 5H2OMon. 2/m : P21/b
8.DC.62KenngottiteMn2+3Fe3+4(PO4)4(OH)6(H2O)2 Mon. 2/m : P2/b
8.DC.67MolinelloiteCu(H2O)(OH)V4+O(V5+O4)Tric. 1 : P1
8.DC.70WhitecapsiteH16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2OHex. 6/m : P63/m
8.DC.75HeimitePbCu2(AsO4)(OH)3 · 2H2OMon. 2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KingiteHide

References for KingiteHide

Localities for KingiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • South Australia
    • Mt Lofty Ranges
      • North Mt Lofty Ranges
        • Kapunda
Frost et al. (2004) +1 other reference
        • Robertstown
Norrish et al. (1957) +2 other references
    • Yorke Peninsula
      • Port Clinton
Norrish et al. (1957) +1 other reference
Norrish et al. (1957) +1 other reference
Germany
 
  • Thuringia
    • Greiz District
      • Kauern
T. Witzke & F. RĂŒger: Lapis 1998 (7/8)
      • Zeulenroda-Triebes
www.handbookofmineralogy.org (2012)
www.handbookofmineralogy.org (2012)
Hungary
 
  • Borsod-AbaĂșj-ZemplĂ©n County
    • Kazincbarcika District
      • DĂ©destapolcsĂĄny
Koch: Minerals of Hungary
    • NekĂ©zseny
SzakĂĄll et al. (1996)
Russia
 
  • Buryatia
    • Okinsky District
Damdinov et al. (2022)
Spain
 
  • Extremadura
    • CĂĄceres
      • Zarza la Mayor
Calvo Rebollar et al. (2022)
USA
 
  • Arkansas
    • Garland County
www.handbookofmineralogy.org (2012)
        • Union Carbide Mine
R&M 70:3 pp 154-170
Howard +1 other reference
  • Nevada
    • Eureka County
      • Carlin Trend
        • Maggie Creek Mining Subdistrict
Jensen et al. (1995) +1 other reference
      • Lynn Mining District
        • Elko
Jensen et al. (1995)
 
Mineral and/or Locality  
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