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Nantokite

A valid IMA mineral species - grandfathered

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Photos of Nantokite (58)

Nantokite Gallery Search Photos of Nantokite

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Nantokite, etc.

Baratti slag locality, Piombino, Livorno Province, Tuscany, Italy

Nantokite, etc.

Baratti slag locality, Piombino, Livorno Province, Tuscany, Italy

Nantokite, etc.

Baratti slag locality, Piombino, Livorno Province, Tuscany, Italy

Nantokite, etc.

Baratti slag locality, Piombino, Livorno Province, Tuscany, Italy

Nantokite, etc.

Baratti slag locality, Piombino, Livorno Province, Tuscany, Italy

Nantokite, etc.

Baratti slag locality, Piombino, Livorno Province, Tuscany, Italy

Nantokite, etc.

Baratti slag locality, Piombino, Livorno Province, Tuscany, Italy

Nantokite, etc.

Baratti slag locality, Piombino, Livorno Province, Tuscany, Italy

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About NantokiteHide

Formula:

CuCl

Colour:

Colourless, white to greyish, greenish

Lustre:

Adamantine

Hardness:

2 - 2½

Specific Gravity:

3.93 - 4.3

Crystal System:

Isometric

Member of:

Chlorargyrite Group

Name:

For the locality at Nantoko, Copiapó, Chile.

Type Locality:

ⓘ Carmen Bajo Mine, Candelaria Copper mining complex, Tierra Amarilla, Copiapó Province, Atacama, Chile

Chlorargyrite Group.

A rare anhydrous copper chloride, known only from arid environments and slags (as tetrahedral crystals). Colourless and transparent when fresh. Alters superficially to paratacamite (or rather clinoatacamite?) when exposed to air.

Unique IdentifiersHide

Mindat ID:

2840

Long-form identifier:

mindat:1:1:2840:6

GUID
(UUID V4):

917e4cad-8ddb-49d2-b606-48cfebfa8736

IMA Classification of NantokiteHide

IMA status:

Approved, 'Grandfathered' (first described prior to 1959)

First published:

1868

Type description reference:

Breithaupt, J.F.A. (1868) Nantokit, ein neues Mineral. Berg- und Hüttenmännische Zeitung: 27: 3-3.

Classification of NantokiteHide

Strunz-mindat (2024):

3.AA.05

3 : HALIDES
A : Simple halides, without H₂O
A : M:X = 1:1, 2:3, 3:5, etc.

Dana 8th ed.:

9.1.7.1

9 : NORMAL HALIDES
1 : AX

Hey's CIM Ref.:

8.2.1

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
2 : Halides of Cu

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Ntk	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NantokiteHide

Lustre:

Adamantine

Transparency:

Transparent

Colour:

Colourless, white to greyish, greenish

Streak:

White

Hardness:

2 - 2½ on Mohs scale

Tenacity:

Sectile

Cleavage:

Distinct/Good
On {011}.

Fracture:

Conchoidal

Density:

3.93 - 4.3 g/cm³ (Measured) 4.22 g/cm³ (Calculated)

Optical Data of NantokiteHide

Type:

Isotropic

RI values:

n = 1.930(5)

Birefringence:

Anomalously anisotropic

Surface Relief:

Very High

Comments:

On synthetic material.

Chemistry of NantokiteHide

Mindat Formula:

CuCl

Elements listed:

Cl, Cu - search for minerals with similar chemistry

Crystallography of NantokiteHide

Crystal System:

Isometric

Class (H-M):

4 3m - Hextetrahedral

Space Group:

F4 3m

Cell Parameters:

a = 5.407 Å

Unit Cell V:

158.08 Å³ (Calculated from Unit Cell)

Morphology:

Massive, granular; small white tetrahedra.

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Year	Temp (K)
0011520	Nantokite	Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-237	1963	293
0017906	Nantokite	Wyckoff R, Posnjak E (1922) The Crystal Structures of the Cuprous Halides _cod_database_code 1010991 Journal of the American Chemical Society 44 30-36	1922	293
0015185	Nantokite	Hull S, Keen D A (1994) High-pressure polymorphism of the copper(I) halides: A neutron-diffraction study to ~10 GPa Physical Review B50 5868-5885	1994	293
0015186	Nantokite	Hull S, Keen D A (1994) High-pressure polymorphism of the copper(I) halides: A neutron-diffraction study to ~10 GPa Physical Review B50 5868-5885	1994	293
0015187	Nantokite	Hull S, Keen D A (1994) High-pressure polymorphism of the copper(I) halides: A neutron-diffraction study to ~10 GPa Physical Review B50 5868-5885	1994	293
0015188	Nantokite	Hull S, Keen D A (1994) High-pressure polymorphism of the copper(I) halides: A neutron-diffraction study to ~10 GPa Physical Review B50 5868-5885	1994	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Nantokite'
loop_
_publ_author_name
'Wyckoff R W G'
_journal_name_full 'Crystal Structures'
_journal_volume 1 
_journal_year 1963
_journal_page_first 85
_journal_page_last 237
_publ_section_title
;
 Second edition. Interscience Publishers, New York, New York
 Note: ZnS structure, sphalerite structure
;
_database_code_amcsd 0011520
_chemical_formula_sum 'Cu Cl'
_cell_length_a 5.4057
_cell_length_b 5.4057
_cell_length_c 5.4057
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 157.963
_exptl_crystal_density_diffrn      4.163
_symmetry_space_group_name_H-M 'F -4 3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
  '1/2+x,y,1/2+z'
  '1/2+x,1/2+y,z'
  '-z,x,-y'
  '-z,1/2+x,1/2-y'
  '1/2-z,x,1/2-y'
  '1/2-z,1/2+x,-y'
  '-y,z,-x'
  '-y,1/2+z,1/2-x'
  '1/2-y,z,1/2-x'
  '1/2-y,1/2+z,-x'
  '-x,y,-z'
  '-x,1/2+y,1/2-z'
  '1/2-x,y,1/2-z'
  '1/2-x,1/2+y,-z'
  'x,-z,-y'
  'x,1/2-z,1/2-y'
  '1/2+x,-z,1/2-y'
  '1/2+x,1/2-z,-y'
  'z,-y,-x'
  'z,1/2-y,1/2-x'
  '1/2+z,-y,1/2-x'
  '1/2+z,1/2-y,-x'
  'y,-x,-z'
  'y,1/2-x,1/2-z'
  '1/2+y,-x,1/2-z'
  '1/2+y,1/2-x,-z'
  'x,z,y'
  'x,1/2+z,1/2+y'
  '1/2+x,z,1/2+y'
  '1/2+x,1/2+z,y'
  'z,y,x'
  'z,1/2+y,1/2+x'
  '1/2+z,y,1/2+x'
  '1/2+z,1/2+y,x'
  'y,x,z'
  'y,1/2+x,1/2+z'
  '1/2+y,x,1/2+z'
  '1/2+y,1/2+x,z'
  '-z,-x,y'
  '-z,1/2-x,1/2+y'
  '1/2-z,-x,1/2+y'
  '1/2-z,1/2-x,y'
  '-y,-z,x'
  '-y,1/2-z,1/2+x'
  '1/2-y,-z,1/2+x'
  '1/2-y,1/2-z,x'
  '-x,-y,z'
  '-x,1/2-y,1/2+z'
  '1/2-x,-y,1/2+z'
  '1/2-x,1/2-y,z'
  'z,-x,-y'
  'z,1/2-x,1/2-y'
  '1/2+z,-x,1/2-y'
  '1/2+z,1/2-x,-y'
  'y,-z,-x'
  'y,1/2-z,1/2-x'
  '1/2+y,-z,1/2-x'
  '1/2+y,1/2-z,-x'
  'x,-y,-z'
  'x,1/2-y,1/2-z'
  '1/2+x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  '-x,z,-y'
  '-x,1/2+z,1/2-y'
  '1/2-x,z,1/2-y'
  '1/2-x,1/2+z,-y'
  '-z,y,-x'
  '-z,1/2+y,1/2-x'
  '1/2-z,y,1/2-x'
  '1/2-z,1/2+y,-x'
  '-y,x,-z'
  '-y,1/2+x,1/2-z'
  '1/2-y,x,1/2-z'
  '1/2-y,1/2+x,-z'
  '-x,-z,y'
  '-x,1/2-z,1/2+y'
  '1/2-x,-z,1/2+y'
  '1/2-x,1/2-z,y'
  '-z,-y,x'
  '-z,1/2-y,1/2+x'
  '1/2-z,-y,1/2+x'
  '1/2-z,1/2-y,x'
  '-y,-x,z'
  '-y,1/2-x,1/2+z'
  '1/2-y,-x,1/2+z'
  '1/2-y,1/2-x,z'
  'z,x,y'
  'z,1/2+x,1/2+y'
  '1/2+z,x,1/2+y'
  '1/2+z,1/2+x,y'
  'y,z,x'
  'y,1/2+z,1/2+x'
  '1/2+y,z,1/2+x'
  '1/2+y,1/2+z,x'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Cu   0.00000   0.00000   0.00000
Cl   0.25000   0.25000   0.25000

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
3.127 Å	(100)
1.915 Å	(55)
1.633 Å	(30)
1.243 Å	(10)
2.710 Å	(8)
1.1054 Å	(8)
1.354 Å	(6)

Comments:

Synthetic

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
45b : [Other oxidized fumarolic minerals]
47g : [Halogen-bearing surface weathering minerals]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere	<0.6
50 : Coal and/or oil shale minerals	<0.36
Stage 10b: Anthropogenic minerals	<10 Ka
54 : Coal and other mine fire minerals (see also #51 and #56)
56 : Slag and smelter minerals (see also #51 and #55)

Type Occurrence of NantokiteHide

Type Locality:

ⓘ Carmen Bajo Mine, Candelaria Copper mining complex, Tierra Amarilla, Copiapó Province, Atacama, Chile

Place of Conservation of Type Material:

Mining Academy, Freiberg, Germany, 12012.

Reference:

Breithaupt, J.F.A. (1868) Nantokit, ein neues Mineral. Berg- und Hüttenmännische Zeitung: 27: 3-3.

Download:

https://rruff.info/rruff_1.0/uploads/Berg_und_huttenmannische_Zeitung_27_1868_3.pdf

Synonyms of NantokiteHide

Kupferchlorür

Other Language Names for NantokiteHide

German:Nantokit

Russian:Нантокит

Spanish:Nantokita
Nantoquita

Relationship of Nantokite to other SpeciesHide

Member of:

Chlorargyrite Group

Other Members of this group:

Bromargyrite	AgBr	Iso. m3m (4/m 3 2/m) : Fm3m
Chlorargyrite	AgCl	Iso. m3m (4/m 3 2/m) : Fm3m
Marshite	CuI	Iso. 4 3m : F4 3m
Miersite	(Ag,Cu)I	Iso. 4 3m : F4 3m

Common AssociatesHide

Associated Minerals Based on Photo Data:

8 photos of Nantokite associated with Cuprite	Cu₂O
7 photos of Nantokite associated with Copper	Cu
5 photos of Nantokite associated with Atacamite	Cu₂(OH)₃Cl
5 photos of Nantokite associated with Paratacamite	Cu₃(Cu,Zn)(OH)₆Cl₂
2 photos of Nantokite associated with Limonite
1 photo of Nantokite associated with Malachite	Cu₂(CO₃)(OH)₂
1 photo of Nantokite associated with Gypsum	CaSO₄ · 2H₂O
1 photo of Nantokite associated with Brochantite	Cu₄(SO₄)(OH)₆
1 photo of Nantokite associated with Goethite	α-Fe³⁺O(OH)

Related Minerals - Strunz-mindat Grouping Hide

3.AA.	Brontesite	(NH₄)₃PbCl₅	Orth. mmm (2/m 2/m 2/m) : Pnma
3.AA.05	Marshite	CuI	Iso. 4 3m : F4 3m
3.AA.05	Miersite	(Ag,Cu)I	Iso. 4 3m : F4 3m
3.AA.05	UM1999-11:I:CuS	Cu(I,S)
3.AA.10	Iodargyrite	AgI	Hex. 6mm : P6mm
3.AA.10	Tocornalite	(Ag,Hg)I	Hex.
3.AA.15	Bromargyrite	AgBr	Iso. m3m (4/m 3 2/m) : Fm3m
3.AA.15	Chlorargyrite	AgCl	Iso. m3m (4/m 3 2/m) : Fm3m
3.AA.20	Carobbiite	KF	Iso. m3m (4/m 3 2/m) : Fm3m
3.AA.20	Griceite	LiF	Iso. m3m (4/m 3 2/m) : Fm3m
3.AA.20	Halite	NaCl	Iso. m3m (4/m 3 2/m) : Fm3m
3.AA.20	Sylvite	KCl	Iso. m3m (4/m 3 2/m) : Fm3m
3.AA.20	Villiaumite	NaF	Iso. m3m (4/m 3 2/m) : Fd3m
3.AA.25	Salammoniac	NH₄Cl	Iso. m3m (4/m 3 2/m)
3.AA.25	UM1998-03-Cl:Tl	TlCl
3.AA.25	Lafossaite	Tl(Cl,Br)	Iso. m3m (4/m 3 2/m) : Pm3m
3.AA.25	Nataliyamalikite	TlI	Orth. mmm (2/m 2/m 2/m) : Cmcm
3.AA.30	Calomel	[Hg₂]²⁺Cl₂	Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
3.AA.30	Kuzminite	[Hg₂]²⁺(Br,Cl)₂	Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
3.AA.30	Moschelite	[Hg₂]²⁺I₂	Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
3.AA.35	Neighborite	NaMgF₃	Orth. mmm (2/m 2/m 2/m)
3.AA.35	Parascandolaite	KMgF₃	Iso. m3m (4/m 3 2/m) : Pm3m
3.AA.40	Chlorocalcite	KCaCl₃	Orth. mmm (2/m 2/m 2/m) : Pnma
3.AA.40	Javorieite	KFeCl₃	Orth. mmm (2/m 2/m 2/m) : Pnma
3.AA.45	Kolarite	PbTeCl₂	Orth.
3.AA.50	Radhakrishnaite	PbTe₃(Cl,S)₂	Tet.
3.AA.55	Challacolloite	KPb₂Cl₅	Mon. 2/m : P2₁/b
3.AA.60	Hephaistosite	TlPb₂Cl₅	Mon. 2/m : P2₁/b
3.AA.90	Pseudocotunnite	K₂PbCl₄	Orth.

Other InformationHide

Special Storage/
Display Requirements:

Unstable in humid air, and transforms slowly into greenish secondary Cu-hydroxchlorides. Alters to "paratacamite" on exposure.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for NantokiteHide

mindat.org URL:

https://www.mindat.org/min-2840.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for NantokiteHide

Reference List:

Breithaupt, J.F.A. (1868) Nantokit, ein neues Mineral. Berg- und Hüttenmännische Zeitung: 27: 3-3.

Breithaupt, J.F.A. (1872) Mineralogische Notizen. Nantokit. Neues Jahrbuch für Mineralogie, Geologie und Paläontologie: 1872: 814-820.

Armstrong and Carmichael (1894) Proceedings of the Royal Society of New South Wales: 28: 96.

Wyckoff and Posnjak (1922) Journal of the American Chemical Society: 44: 30.

Barth and Lunde (1925) Norsk Geol. Tidsskr.: 8: 281.

Palache, C., Berman, H., Frondel, C. (1951) The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Seventh edition, Volume II: 18-19.

Pfitzner, A., Lutz, H.D. (1993) The systems CuCl-MIICl2 (M=Mn, Cd) - crystal structures of Cu2MnCl4 and γ-CuCl. Zeitschrift für Kristallographie: 205: 165-175.

(2023) Nantokite. Handbook of Mineralogy. Mineralogical Society of America

Localities for NantokiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Atlantic Ocean
Mid-Atlantic Ridge complex ⓘ Snake Pit hydrothermal field	Fouquet et al. (1993)

Australia
New South Wales Yancowinna Co. Broken Hill district ⓘ Broken Hill	Mineralogical Society of America - ...
ⓘ Broken Hill South Mine (BHS Mine; South Mine)	Mineralogical Magazine 1894 10 : 326-327
Queensland Cloncurry Shire Cloncurry ⓘ Great Australia Mine	Mineralogical Society of America - ... +1 other reference
ⓘ Magpie prospect (Magpie Mine)	Australian Journal of Mineralogy Volume ...
Selwyn District ⓘ Wewak Mine	Mineralogical Society of America - ...
Western Australia Exmouth Shire ⓘ Rapid shipwreck	MacLeod (1991)

Chile (TL)
Atacama Copiapó Province Tierra Amarilla Candelaria Copper mining complex ⓘ Carmen Bajo Mine (TL)	Dana 6 (1892) +1 other reference

China
Qinghai Haixi Mongol and Tibetan Autonomous Prefecture Golmud City (Ge'ermu Co.) ⓘ Ka'erqueka Cu-polymetallic deposit	Yi et al. (2017)

Czech Republic
Ústí nad Labem Region Teplice District Krupka Steinknochen area ⓘ Nový Martin adit	Sejkora (1998)

Germany
Saxony-Anhalt Mansfeld-Südharz Mansfeld ⓘ Lichtloch 25 (of the Schlüssel-Stollen)	Mineralien Welt 15 Jg.Heft 2 ...
ⓘ Lichtloch 26 S (of the Schlüssel-Stollen) ?	Ko Jansen +2 other references

Greece
South Aegean Milos Serifos Island Avissalos ⓘ Slag locality	Fritz Schreiber collection (analysed by U. Kolitsch)

India
Madhya Pradesh Jabalpur Division Balaghat District Baihar Tehsil Malanjkand ⓘ Malanjkhand Mine	Singer et al. (2008)

Italy
Aosta Valley Brusson ⓘ Brusson Mine ?	· Maletto et al. (2016)
Campania Naples ⓘ Somma-Vesuvius Complex	AA. VV.
Liguria Genoa Genoa Varenna Valley ⓘ Carpenara slag locality	Rivista Mineralogica Italiana (Avril/Juin)
Tuscany Grosseto Province Massa Marittima Valpiana - Castello della Marsiliana area slag sites ⓘ Bottricoli slag locality	"Lithothek der Münchener Micromounter" ...
ⓘ Marsiliana slag locality	Ko Jansen +2 other references
Livorno Province Campiglia Marittima ⓘ Madonna di Fucinaia (Madonna della Fucinaia) slag heaps	C.Boutry
ⓘ Capattoli Valley slag locality	www.comune.pisa.it (2000)
Piombino ⓘ Baratti slag locality	Franzini et al. (1992) +3 other references
Sassetta Canina Valley ⓘ Podere del Cancellino (Podere dei Cancellini) slag locality	Jansen et al. (1998)
Suvereto ⓘ Suvereto slag locality	Luigi Chiappino data

Kazakhstan
Karaganda Region ⓘ Dzhezkazgan mining district	Mineralogical Society of America - ... +1 other reference

Mexico
Durango Mapimí Municipality Mapimí ⓘ Ojuela Mine	Rocks & Min.: 56:247.
Tamaulipas Villagrán Municipality San José ⓘ Priedra Mine (La Piedra Iman Mine)	Panczner (1987)

Morocco
Drâa-Tafilalet Region Zagora Province Agdz Cercle Bou Skour mining district ⓘ Agoulzi slag locality	Georges Favreau collection

Pakistan
Khyber Pakhtunkhwa Province Charsadda District ⓘ Sakhakot-Quila complex	Ahmed (1991)

Poland
Lesser Poland Voivodeship Chrzanów County Gmina Trzebinia ⓘ Trzebionka mine	Coppola et al. (2009)
ⓘ Matylda Mine	Coppola et al. (2009)
Silesian Voivodeship ⓘ Bytom	Coppola et al. (2009)

Russia
Chelyabinsk Oblast ⓘ Chelyabinsk coal basin	Cesnokov et al. (1998)

Spain
Andalusia Almería Huércal-Overa Cuesta Alta Cerro Minado Mines ⓘ La Cena del Depósito concession	in Spanish version (Revista de Minerales) +1 other reference

UK
England Cornwall St Just Trewellard ⓘ Levant Mine	Golley et al. (1995)

USA
Arizona Cochise County Bisbee ⓘ Campbell Mine	Graeme (1993) +1 other reference
Hendricks Gulch ⓘ Southwest Mine	Graeme (1993) +2 other references
Colorado San Juan County Eureka Mining District Gladstone Bonita Peak ⓘ Sunnyside Mine group	PXRD by John Attard
Connecticut Fairfield County Stamford ⓘ Dyke Park	Henderson et al. (1967)
Michigan Ontonagon County Mass City ⓘ Algomah Mine	Williams (1962) +1 other reference
New Mexico Grant County ⓘ Steeple Rock Mining District	Mineralogical Society of America - ...
Socorro County Magdalena Mining District ⓘ Kelly Mine	Collection of Patrick Haynes. Found in ...
New York St. Lawrence County Balmat-Edwards Zinc Mining District ⓘ Balmat	Rocks & Minerals (2008)

Nantokite

About NantokiteHide

Unique IdentifiersHide

IMA Classification of NantokiteHide

Classification of NantokiteHide

Mineral SymbolsHide

Physical Properties of NantokiteHide

Optical Data of NantokiteHide

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X-Ray Powder DiffractionHide

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Common AssociatesHide

Related Minerals - Strunz-mindat GroupingHide

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Related Minerals - Strunz-mindat Grouping Hide