Zavaritskite
A valid IMA mineral species
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About Zavaritskite
Formula:
(BiO)F
Colour:
Grey
Lustre:
Greasy, Sub-Metallic
Hardness:
2 - 2½
Specific Gravity:
7.88 - 8.34
Crystal System:
Tetragonal
Member of:
Name:
Named after Aleksandr Nikolaevich Zavaritskii (Александр Николаевич Заварицкий) (2(14) March 1884, Ufa, Russian Empire — 23 July 1952, Moscow, USSR), academician, Academy of Sciences (Russia), a specialist in the petrology of ore deposits. He founded the field of petrochemistry.
Unique Identifiers
Mindat ID:
4389
Long-form identifier:
mindat:1:1:4389:8
GUID
(UUID V4):
(UUID V4):
2cf5d1f6-068c-48b3-acdd-49a1f4785460
IMA Classification of Zavaritskite
Approved
IMA Formula:
BiOF
First published:
1962
Classification of Zavaritskite
3.DC.25
3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
C : With Pb (As,Sb,Bi), without Cu
3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
C : With Pb (As,Sb,Bi), without Cu
10.2.1.1
10 : OXYHALIDES AND HYDROXYHALIDES
2 : A(O,OH)Xq
10 : OXYHALIDES AND HYDROXYHALIDES
2 : A(O,OH)Xq
8.9.4
8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
9 : Halides of Sb and Bi
8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
9 : Halides of Sb and Bi
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Zav | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Zavaritskite
Greasy, Sub-Metallic
Transparency:
Translucent, Opaque
Colour:
Grey
Hardness:
2 - 2½ on Mohs scale
Density:
7.88 - 8.34 g/cm3 (Measured) 9.21 g/cm3 (Calculated)
Comment:
Low measured values due to fined grained nature of the sample
Optical Data of Zavaritskite
Type:
Uniaxial (+/-)
RI values:
nα = 2.210 nβ = 2.213
Birefringence:
Weak
Max Birefringence:
δ = 2.210
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Chemistry of Zavaritskite
Mindat Formula:
(BiO)F
Elements listed:
Crystallography of Zavaritskite
Crystal System:
Tetragonal
Class (H-M):
4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:
P4/nmm
Setting:
P4/nmm
Cell Parameters:
a = 3.75(1) Å, c = 6.23(1) Å
Ratio:
a:c = 1 : 1.661
Unit Cell V:
87.61 ų (Calculated from Unit Cell)
Z:
2
Crystal Structure
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2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0011842 | Zavaritskite | Wyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 294-296 | 1963 | 0 | 293 | ||
0015507 | Zavaritskite | Soubeyroux J L, Matar S F, Reau J M, Hagenmuller P (1984) Etude des proprietes structurales et electriques de la solution solide Pb1-xBixOxF2-x Solid State Ionics 14 337-345 | 1984 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.18 Å | (80) |
3.09 Å | (50) |
2.63 Å | (50) |
2.01 Å | (60) |
1.614 Å | (80 broad diffuse) |
1.478 Å | (50) |
1.438 Å | (70) |
1.305 Å | (70) |
1.248 Å | (60) |
1.223 Å | (80 broad) |
1.185 Å | (70) |
1.141 Å | (90) |
1.126 Å | (80) |
1.108 Å | (90) |
1.070 Å | (70) |
1.037 Å | (90) |
1.028 Å | (100 broad doublet) |
1.025 Å | (100 broad doublet) |
0.998 Å | (100) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47c : [Carbonates, phosphates, borates, nitrates] | |
47g : [Halogen-bearing surface weathering minerals] | |
47h : [Near-surface oxidized, dehydrated minerals] |
Type Occurrence of Zavaritskite
General Appearance of Type Material:
Pseudomorphs, with bismutite, after bismuthinite.
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia.
Geological Setting of Type Material:
Quartz-topaz-siderophyllite greisens.
Associated Minerals at Type Locality:
Reference:
Dolomanova, E.I., Senderova, V.M., Yanchenko, M.T. (1962) Zavaritskite (BiOF), a new mineral of the oxyfluoride group. Doklady Akademii Nauk SSSR: 146: 680-682.
Synonyms of Zavaritskite
Other Language Names for Zavaritskite
Relationship of Zavaritskite to other Species
Member of:
Other Members of this group:
Bismoclite | BiOCl | Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm |
Daubréeite | BiO(OH) | Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm |
Laurionite | PbCl(OH) | Orth. mmm (2/m 2/m 2/m) |
Matlockite | PbFCl | Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm |
Paralaurionite | PbCl(OH) | Mon. 2/m : B2/m |
Rorisite | CaFCl | Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm |
Common Associates
Associated Minerals Based on Photo Data:
6 photos of Zavaritskite associated with Russellite | Bi2WO6 |
5 photos of Zavaritskite associated with Bismuth | Bi |
3 photos of Zavaritskite associated with Quartz | SiO2 |
2 photos of Zavaritskite associated with Preisingerite | Bi3(AsO4)2O(OH) |
2 photos of Zavaritskite associated with Rose Quartz | SiO2 |
2 photos of Zavaritskite associated with Zinnwaldite | |
1 photo of Zavaritskite associated with Koechlinite | Bi2MoO6 |
1 photo of Zavaritskite associated with Bismutite | (BiO)2CO3 |
1 photo of Zavaritskite associated with Ferberite | FeWO4 |
Related Minerals - Strunz-mindat Grouping
3.DC. | Lucabindiite | (K,NH4)As4O6(Cl,Br) |
3.DC. | Torrecillasite | Na(As,Sb)3+4O6Cl |
3.DC. | Gajardoite | KCa0.5As3+4O6Cl2 · 5H2O |
3.DC. | Cuatrocapaite-(NH₄) | (NH4)3(NaMg◻)(As2O3)6Cl6 · 16H2O |
3.DC. | Cuatrocapaite-(K) | K3(NaMg◻)(As2O3)6Cl6 · 16H2O |
3.DC. | Napoliite | Pb2OFCl |
3.DC.05 | Laurionite | PbCl(OH) |
3.DC.05 | Paralaurionite | PbCl(OH) |
3.DC.05 | Russoite | (NH4)ClAs2O3(H2O)0.5 |
3.DC.05 | Mauriziodiniite | (NH4)(As2O3)2I |
3.DC.10 | Fiedlerite | Pb3FCl4(OH) · H2O |
3.DC.15 | Penfieldite | Pb2Cl3(OH) |
3.DC.15 | Telluroperite | Pb3TeO4Cl2 |
3.DC.20 | Laurelite | Pb7F12Cl2 |
3.DC.25 | Bismoclite | BiOCl |
3.DC.25 | Matlockite | PbFCl |
3.DC.25 | Rorisite | CaFCl |
3.DC.25 | Zhangpeishanite | BaFCl |
3.DC.30 | Nadorite | PbSbClO2 |
3.DC.30 | Perite | PbBiClO2 |
3.DC.40 | Thorikosite | Pb3Cl2(OH)(SbO3,AsO3) |
3.DC.45 | Mereheadite | Pb47Cl25(OH)13O24(CO3)(BO3)2 |
3.DC.50 | Blixite | Pb8O5(OH)2Cl4 |
3.DC.52 | Rumseyite | Pb2OClF |
3.DC.55 | Pinalite | Pb3WO5Cl2 |
3.DC.55 | Vladkrivovichevite | [Pb32O18][Pb4Mn2O]Cl14(BO3)8 · 2H2O |
3.DC.57 | Yeomanite | Pb2O(OH)Cl |
3.DC.60 | Lorettoite | Pb7O6Cl2 |
3.DC.60 | Symesite | Pb10(SO4)O7Cl4 · H2O |
3.DC.62 | Sarawakite (of Frenzel) | Sb, O, Cl (?) |
3.DC.65 | Ecdemite | Pb6Cl4(As2O7) |
3.DC.70 | Mendipite | Pb3Cl2O2 |
3.DC.75 | Damaraite | Pb3Cl(OH)O2 |
3.DC.80 | Onoratoite | Sb8Cl2O11 |
3.DC.95 | Barstowite | Pb4Cl6(CO3) · H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Zavaritskite
mindat.org URL:
https://www.mindat.org/min-4389.html
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References for Zavaritskite
Reference List:
Localities for Zavaritskite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
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Elsmore, Gough Co., New South Wales, Australia