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Bariopharmacosiderite

Formula:
BaFe
3+
4
[(OH)
 
5
|(AsO
 
4
)
 
3
] · 5H
 
2
O
System:TetragonalColour:Brown, yellow, reddish ...
Hardness:
Name:In allusion to its composition reflecting the dominant barium and its relationship to pharmacosiderite.


Pharmacosiderite Group.
The tetragonal-pseudocubic Ba-Fe-end member.

Originally called barium-pharmacosiderite; renamed in 2008 (Burke, 2008).

Classification of Bariopharmacosiderite

IMA status:Approved 1990
Strunz 8th edition ID:7/D.47-40
Nickel-Strunz 10th (pending) edition ID:8.DK.10

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
K : With large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1
Dana 8th edition ID:42.8.1.3

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
8 : (AB)5(XO4)3Zq·xH2O
Hey's CIM Ref.:20.2.22

20 : Arsenates (also arsenates with phosphate, but without other anions)
2 : Arsenates of Be, Mg, Ca or Ba
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Type Occurrence of Bariopharmacosiderite

Type Locality:Clara Mine, Rankach valley, Oberwolfach, Wolfach, Black Forest, Baden-Württemberg, Germany

Physical Properties of Bariopharmacosiderite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent, Translucent
Colour:Brown, yellow, reddish brown, green, bluish
Hardness (Mohs):
Hardness Data:Estimated
Cleavage:Distinct/Good
(100) and (001), both good
Fracture:Conchoidal
Density (measured):3.05 g/cm3
Density (calculated):3.07 g/cm3

Crystallography of Bariopharmacosiderite

Crystal System:Tetragonal
Class (H-M):4 2m - Scalenohedral
Space Group:P4 2m
Cell Parameters:a = 7.97Å, c = 8.1Å
Ratio:a:c = 1 : 1.016
Unit Cell Volume:V 514.52 ų (Calculated from Unit Cell)
Z:1
X-Ray Powder Diffraction:
d-spacingIntensity
8.06 (9)
4.65 (6)
4.04 (8)
3.28 (10)

Optical Data of Bariopharmacosiderite

Type:Uniaxial (+/-)
RI values: nω = 1.728 nε = 1.718
Maximum Birefringence:δ = 0.010

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High

Chemical Properties of Bariopharmacosiderite

Formula:
BaFe
3+
4
[(OH)
 
5
|(AsO
 
4
)
 
3
] · 5H
 
2
O
Essential elements:As, Ba, Fe, H, O
All elements listed in formula:As, Ba, Fe, H, O

Relationship of Bariopharmacosiderite to other Species

Member of Group:
Pharmacosiderite Group:
Related Minerals - Nickel-Strunz Grouping):

- +
8.DK.Richelsdorfite
Ca
 
2
Cu
 
5
Sb[Cl|(OH)
 
6
|(AsO
 
4
)
 
4
] · 6H
 
2
O
8.DK.10Alumopharmacosiderite
KAl
 
4
[(OH)
 
4
|(AsO
 
4
)
 
3
] · 6-7H
 
2
O
8.DK.10Barium-Alumopharmacosiderite
Ba(Al,Fe
3+
 
)
 
4
[(OH)
 
5
|(AsO
 
4
)
 
3
] · 7H
 
2
O (?)
8.DK.10Pharmacosiderite
KFe
3+
4
[(OH)
 
4
|(AsO
 
4
)
 
3
] · 6-7H
 
2
O
8.DK.10Natropharmacosiderite
(Na,K)Fe
3+
4
[(OH)
 
4
|(AsO
 
4
)
 
3
] · 6-7H
 
2
O
8.DK.10Barium-zinc-alumopharmacosiderite
(Ba,K)
 
0.5
(Zn,Cu)
 
0.5
(Al,Fe)
 
4
(AsO
 
4
)
 
3
·5H
 
2
O
8.DK.15Burangaite
(Na,Ca
 
0.5
)(Fe
2+
 
,Mg)Al
 
5
[(OH,O)
 
3
|(PO
 
4
)
 
2
]
 
2
· 2H
 
2
O
8.DK.15Dufrénite
Ca
 
0.5
Fe
2+
 
Fe
3+
5
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
· 2H
 
2
O
8.DK.15Natrodufrénite
NaFe
2+
 
(Fe
3+
 
,Al)
 
5
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
· 2H
 
2
O
8.DK.15Matioliite
NaMgAl
 
5
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
· 2H
 
2
O
8.DK.15IMA2008-056
NaMn
2+
 
Fe
3+
5
(PO
 
4
)
 
4
(OH)
 
6
·2H
 
2
O
8.DK.20Kidwellite
NaFe
3+
9
[(OH)
 
5
|(PO
 
4
)
 
3
]
 
2
· 5H
 
2
O
8.DK.25Bleasdaleite
(Ca,Fe
3+
 
)
 
2
Cu
 
5
(Bi,Cu)[(H
 
2
O,OH,Cl)
 
13
|(PO
 
4
)
 
4
]
8.DK.30Matulaite
CaAl
 
18
[(OH)
 
5
|(PO
 
4
)
 
3
]
 
4
· 28H
 
2
O
8.DK.35Krasnovite
Ba(Al,Mg)[(OH)
 
2
|(PO
 
4
,CO
 
3
)] · H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.2.1Bearsite
Be
 
2
[OH|AsO
 
4
] · 4H
 
2
O
20.2.2Brassite
MgHAsO
 
4
·4H
 
2
O
20.2.3Rösslerite
MgHAsO
 
4
·7H
 
2
O
20.2.4Hörnesite
Mg
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
20.2.5Weilite
CaHAsO
 
4
20.2.6Johnbaumite
Ca
 
5
[OH|(AsO
 
4
)
 
3
]
20.2.7Haidingerite
Ca[HAsO
 
4
] · H
 
2
O
20.2.8Pharmacolite
CaHAsO
 
4
·2H
 
2
O
20.2.9Sainfeldite
CaCa
 
2
Ca
 
2
(AsO
 
3
OH)
 
2
(AsO
 
4
)
 
2
·4H
 
2
O
20.2.10Vladimirite
Ca
 
5
[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 5H
 
2
O
20.2.11Guérinite
Ca
 
5
[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 9H
 
2
O
20.2.12Ferrarisite
Ca
 
5
[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 9H
 
2
O
20.2.13Rauenthalite
Ca
 
3
[AsO
 
4
]
 
2
· 10H
 
2
O
20.2.14Phaunouxite
Ca
 
3
[AsO
 
4
]
 
2
· 11H
 
2
O
20.2.15Mcnearite
NaCa
 
5
[(HAsO
 
4
)
 
4
|AsO
 
4
] · 4H
 
2
O
20.2.16Bergslagite
CaBe[OH|AsO
 
4
]
20.2.17Adelite
CaMg[AsO
 
4
](OH)
20.2.18Talmessite
Ca
 
2
Mg[AsO
 
4
]
 
2
· 2H
 
2
O
20.2.19Irhtemite
Ca
 
4
Mg[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 4H
 
2
O
20.2.20Camgasite
CaMg[OH|AsO
 
4
] · 5H
 
2
O
20.2.21Picropharmacolite
Ca
 
4
Mg[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 11H
 
2
O

Other Names for Bariopharmacosiderite

Synonyms:
Barium-Pharmacosiderite
Other Languages:
German:Barium-Pharmakosiderit
Bariumpharmocosiderit
Spanish:Bariumpharmocosiderita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Bariopharmacosiderite

Reference List:Peacor, D. R. and Dunn, P. J. (1985): Sodium-pharmacosiderite, a new analog of pharmacosiderite from Australia and new occurrences of barium-pharmacosiderite. Mineralogical Record, 16, 121-124.

Walenta, K. (1994): Über den Barium-Pharmakosiderit. Aufschluss 45, 73-81. (in German)

Burke, E. A. J. (2008): Tidying up Mineral Names: An IMA scheme for Suffixes, Hyphens and Diacritical Marks. Mineralogical Record, 39, 131-135.

Internet Links for Bariopharmacosiderite

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    Localities for Bariopharmacosiderite

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