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Bismutoferrite

Formula:
Fe
3+
2
Bi[OH|(SiO
 
4
)
 
2
]
System:MonoclinicHardness:6


The bismuth analogue of Chapmanite, with which it is easily confused.

Classification of Bismutoferrite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/B.06-20
Nickel-Strunz 10th (pending) edition ID:9.ED.25

9 : SILICATES (Germanates)
E : Phyllosilicates
D : Phyllosilicates with kaolinite layers composed of tetrahedral and octahedral nets
Dana 8th edition ID:71.1.3.1

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
1 : Sheets of 6-membered rings with 1:1 layers
Hey's CIM Ref.:14.14.8

14 : Silicates not Containing Aluminum
14 : Silicates of V and Bi
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Type Occurrence of Bismutoferrite

Type Locality:Schneeberg District, Erzgebirge, Saxony, Germany
Year of Discovery:1871

Physical Properties of Bismutoferrite

Hardness (Mohs):6

Crystallography of Bismutoferrite

Crystal System:Monoclinic
Cell Parameters:a = 5.21Å, b = 9.02Å, c = 7.74Å
β = 100.67°
Ratio:a:b:c = 0.578 : 1 : 0.858
Unit Cell Volume:V 357.45 ų (Calculated from Unit Cell)

Optical Data of Bismutoferrite

Type:Biaxial
RI values: nα = 1.930 nβ = 1.970 nγ = 2.010
Maximum Birefringence:δ = 0.080

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:r > v strong

Chemical Properties of Bismutoferrite

Formula:
Fe
3+
2
Bi[OH|(SiO
 
4
)
 
2
]
Essential elements:Bi, Fe, H, O, Si
All elements listed in formula:Bi, Fe, H, O, Si
Common Impurities:Al,As

Relationship of Bismutoferrite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
9.ED.05Dickite
Al
 
2
Si
 
2
O
 
5
(OH)
 
4
9.ED.05Kaolinite
Al
 
2
Si
 
2
O
 
5
(OH)
 
4
9.ED.05Nacrite
Al
 
2
Si
 
2
O
 
5
(OH)
 
4
9.ED.05Odinite
(Fe,Mg,Al,Fe,Ti,Mn)
 
2.4
(Si,Al)
 
2
O
 
5
(OH)
 
4
9.ED.10Halloysite
Al
 
2
Si
 
2
O
 
5
(OH)
 
4
9.ED.10Hisingerite
Fe
3+
2
Si
 
2
O
 
5
(OH)
 
4
·2H
 
2
O
9.ED.10Halloysite-7Å
Al
 
2
Si
 
2
O
 
5
(OH)
 
4
9.ED.15Amesite
Mg
 
2
Al[(OH)
 
4
|AlSiO
 
5
]
9.ED.15Antigorite
(Mg,Fe
2+
 
)
 
3
[(OH)
 
4
|Si
 
2
O
 
5
]
9.ED.15Berthierine
(Fe,Fe,Mg)
 
2-3
(Si,Al)
 
2
O
 
5
(OH)
 
4
9.ED.15Brindleyite
(Ni,Mg,Fe)
 
2
Al(Si,Al)O
 
5
(OH)
 
4
9.ED.15Caryopilite
(Mn,Mg)
 
3
Si
 
2
O
 
5
(OH)
 
4
9.ED.15Chrysotile
Mg
 
3
Si
 
2
O
 
5
(OH)
 
4
9.ED.15Cronstedtite
Fe
2+
2
Fe
3+
 
[(Si,Fe
3+
 
)
 
2
O
 
5
](OH)
 
4
9.ED.15Fraipontite
(Zn,Al)
 
3
[(OH)
 
4
|(Si,Al)
 
2
O
 
5
]
9.ED.15Greenalite
Fe
 
2-3
Si
 
2
O
 
5
(OH)
 
4
9.ED.15Kellyite
Mn
2+
2
Al[(OH)
 
4
|AlSiO
 
5
]
9.ED.15Lizardite
Mg
 
3
[(OH)
 
4
|Si
 
2
O
 
5
]
9.ED.15Manandonite
LiAl
 
4
Si
 
3
BO
 
10
(OH)
 
6
9.ED.15Népouite
(Ni,Mg)
 
3
Si
 
2
O
 
5
(OH)
 
4
9.ED.15Pecoraite
Ni
 
3
[(OH)
 
4
|Si
 
2
O
 
5
]
9.ED.20Allophane
(Al
 
2
O
 
3
)(SiO
 
2
)
 
1.3-2
·2.5-3H
 
2
O
9.ED.20Chrysocolla
(Cu,Al)
 
2
H
 
2
Si
 
2
O
 
5
(OH)
 
4
·nH
 
2
O
9.ED.20Imogolite
Al
 
2
SiO
 
3
(OH)
 
4
9.ED.20Neotocite
(Mn,Fe,Mg)SiO
 
3
·H
 
2
O
9.ED.25Chapmanite
Fe
3+
2
Sb
3+
 
[OH|(SiO
 
4
)
 
2
]
Related Minerals - Hey's Index Grouping:

- +
14.14.1Cavansite
Ca(VO)Si
 
4
O
 
10
·4H
 
2
O
14.14.2Pentagonite
Ca(VO)Si
 
4
O
 
10
·4H
 
2
O
14.14.3Goldmanite
Ca
 
3
(V
3+
 
,Al,Fe
3+
 
)
 
2
[SiO
 
4
]
 
3
14.14.4Haradaite
SrVSi
 
2
O
 
7
14.14.5Saneroite
Na
 
2
(Mn,Mn)
 
10
Si
 
11
VO
 
34
(OH)
 
4
14.14.6Erlianite
(Fe,Mg)
 
4
(Fe,V)
 
2
Si
 
6
O
 
15
(OH,O)
 
8
14.14.7Eulytine
Bi
 
4
[SiO
 
4
]
 
3

Other Names for Bismutoferrite

Other Languages:
German:Bismutoferrit
Russian:Бисмутоферрит
Spanish:Bismutoferrita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Bismutoferrite

Reference List:American Mineralogist: 43: 656-670.

Soviet Physics – Crystallography: 22: 419-423.

Internet Links for Bismutoferrite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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    Localities for Bismutoferrite

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