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Afghanite

A valid IMA mineral species
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About AfghaniteHide

08760190014946708727324.jpg
Flag of Afghanistan
Formula:
(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6
Colour:
White, light blue, dark blue
Lustre:
Vitreous
Hardness:
5½ - 6
Specific Gravity:
2.55
Crystal System:
Trigonal
Name:
Named after the country of its discovery, Afghanistan.
Structurally related to UM2004-48-SiO:AlClCaNaS.




Unique IdentifiersHide

Mindat ID:
41
Long-form identifier:
mindat:1:1:41:9
GUID
(UUID V4):
6f9e1a00-d7ad-4dfc-a023-919dec36009c

IMA Classification of AfghaniteHide

Classification of AfghaniteHide

9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.1

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.10.12

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
AfgIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AfghaniteHide

Vitreous
Transparency:
Translucent
Colour:
White, light blue, dark blue
Comment:
Colourless in thin section
Streak:
White
Hardness:
5½ - 6 on Mohs scale
Hardness Data:
Measured
Cleavage:
Perfect
{1010}
Fracture:
Conchoidal
Density:
2.55 g/cm3 (Measured)    2.65 g/cm3 (Calculated)

Optical Data of AfghaniteHide

Type:
Uniaxial (+)
RI values:
nω = 1.523 nε = 1.529
Max Birefringence:
δ = 0.006
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemistry of AfghaniteHide

Mindat Formula:
(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6

Crystallography of AfghaniteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
P3 1c
Setting:
P3 1c
Cell Parameters:
a = 12.8013(7) Å, c = 21.4119(18) Å
Ratio:
a:c = 1 : 1.673
Unit Cell V:
3,038.74 ų (Calculated from Unit Cell)
Morphology:
As stout to slender, thin tabular laths and as rounded grains.
Comment:
Cell data from Ballirano et al. (1996). Previously assumed space group P63mc is incorrect.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018843AfghaniteBallirano P, Bosi F (2012) Thermal behavior of afghanite, an ABABACAC member of the cancrinite group American Mineralogist 97 630-6402012Case Collina, Latium, Italy0293
0006636AfghaniteBallirano P, Bonaccorsi E, Maras A, Merlino S (1997) Crystal structure of afghanite, the eight-layer member of the cancrinite-group: evidence for long-range Si,Al ordering European Journal of Mineralogy 9 21-3019970293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.688 Å(100)
3.298 Å(100)
4.82 Å(80)
3.997 Å(60)
2.865 Å(60)
2.130 Å(60)
1.792 Å(60)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Geological Setting:
In silicified limestone xenoliths in pumice (Pitigliano quarry, Italy).

Type Occurrence of AfghaniteHide

General Appearance of Type Material:
In thin veinlets cutting lazurite crystals.
Place of Conservation of Type Material:
Mineralogy-Crystallography Laboratory, University Pierre and Marie Curie, Paris;
National School of Mines, Paris, France;
The Natural History Museum, London, England, 1969,72.
Associated Minerals at Type Locality:
Reference:
Bariand,P., Cesbron, F., Giraud, R. (1968) Une nouvelle espèce minérale: l'afghanite de Sar-e-sang, Badakhshan, Afghanistan. Comparaison avec les minéraux du groupe de la cancrinite. Bulletin de la Société Francaise de Minéralogie et Christallographie: 91: 34-42.

Synonyms of AfghaniteHide

Other Language Names for AfghaniteHide

Dutch:Afghaniet
German:Afghanit
Italian:Afghanite
Latvian:Afganīts
Spanish:Afghanita

Relationship of Afghanite to other SpeciesHide

Other Members of this group:
Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
Tounkite(Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2OHex. 6 2 2 : P62 2 2
UM2004-48-SiO:AlClCaNaS(Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
UM2009-23-SiO:AlCCaClHKNaS(Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4 · 11H2OTrig. 3 : P3
Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63

Common AssociatesHide

Associated Minerals Based on Photo Data:
128 photos of Afghanite associated with CalciteCaCO3
73 photos of Afghanite associated with PyriteFeS2
45 photos of Afghanite associated with LazuriteNa7Ca(Al6Si6O24)(SO4)(S3) · H2O
16 photos of Afghanite associated with PhlogopiteKMg3(AlSi3O10)(OH)2
10 photos of Afghanite associated with MarialiteNa4Al3Si9O24Cl
8 photos of Afghanite associated with DiopsideCaMgSi2O6
8 photos of Afghanite associated with NephelineNa3K(Al4Si4O16)
6 photos of Afghanite associated with Marble
6 photos of Afghanite associated with Sodalite Group
6 photos of Afghanite associated with Thomsonite-CaNaCa2[Al5Si5O20] · 6H2O

Related Minerals - Strunz-mindat GroupingHide

9.FB.SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
9.FB.SapozhnikoviteNa8(Al6Si6O24)(HS)2Iso. 4 3m : P4 3n
9.FB.BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
9.FB.SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
9.FB.Bolotinaite(Na7◻)(Al6Si6O24)F · 4H2OIso. 4 3m : I4 3m
9.FB.Wenlanzhangite-(Y)Y2V3+2V4+2(SiO4)2O4(OH)4Tric. 1 : P1
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
9.FB.05Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
9.FB.05Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
9.FB.05Tounkite(Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2OHex. 6 2 2 : P62 2 2
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
9.FB.05SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10 vaHackmaniteNa8Al6Si6O24(Cl2,S)
9.FB.10HaüyneNa3Ca(Si3Al3)O12(SO4)Iso. 4 3m : P4 3n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10LazuriteNa7Ca(Al6Si6O24)(SO4)(S3) · H2OIso. 4 3m : P4 3n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
9.FB.10SodaliteNa4(Si3Al3)O12ClIso. 4 3m : P4 3n
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth. 2 2 2 : I2 2 2
9.FB.10TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
9.FB.10VladimirivanoviteNa6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2OOrth. mmm (2/m 2/m 2/m)
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AfghaniteHide

References for AfghaniteHide

Reference List:

Localities for AfghaniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Afghanistan
 
Hogarth (1979)
    • Kuran wa Munjan District
Dudley Blauwet priv. comm. (2008)
      • Sar-e-Sang
Bariand et al. (1968) +1 other reference
Moore et al. (2014)
Fernando Camara (2013)
Canada
 
  • Nunavut
    • Qikiqtaaluk Region
      • Baffin Island
Hogarth (1979)
Germany
 
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Vordereifel
        • Ettringen
Blass
Italy
 
  • Campania
    • Naples
      • Somma-Vesuvius Complex
... +5 other references
in the collection of Luigi Mattei
  • Lazio
    • Metropolitan City of Rome Capital
      • Magliano Romano
Stoppani et al. (1982)
Min Rec (1996)
Gresta et al. (2002)
    • Viterbo Province
Stoppani et al. (1982) +1 other reference
Di Domenico Dario
      • Gradoli
Signoretti et al. (2001)
      • Onano
Cresta et al. (2002)
      • Valentano
Burli et al. (2007)
      • Vetralla
Signoretti et al. (2004) +1 other reference
American Mineralogist
Carlini
      • Viterbo
Bill Henderson specimens
www.gminromano.it (2005) +1 other reference
Stoppani F.S (1982)
  • Tuscany
    • Grosseto Province
      • Pitigliano
Liotti L. (Grosseto)
Russia
 
  • Irkutsk Oblast
    • Lake Baikal area
      • Slyudyanka
        • Malaya Bystraya River Valley
Hogarth (1979) +1 other reference
Pavel.M. Kartashov (n.d.) +2 other references
Tajikistan
 
  • Gorno-Badakhshan
    • Shughnon
      • Shakhdara range
        • Badom-Dara
Hogarth (1979)
USA
 
  • New York
    • St. Lawrence County
      • Balmat-Edwards Zinc Mining District
        • Edwards
Hogarth (1979)
 
Mineral and/or Locality  
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