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Crawfordite

A valid IMA mineral species
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About CrawforditeHide

Formula:
Na3Sr(CO3)(PO4)
Colour:
Colourless
Lustre:
Sub-Vitreous
Hardness:
3
Specific Gravity:
3.05
Crystal System:
Monoclinic
Name:
Named in 1994 by Alexander Petrovich Khomyakov, L. I. Polezhaeva, and E. V. Sokolova in honor of Sir Adair Crawford [1748 Crumlin, County Antrim, Northern Ireland, United Kingdom - July 29, 1795 Lymington, England, United Kingdom] professor of chemistry at the Royal Military Academy, London, England as well as a staff physician at St. Thomas Hospital, also in London. He researched and made many contributions to calorimetry and specific heats. He was co-discoverer of strontium.
Found in hyperagpaitic pegmatites


Unique IdentifiersHide

Mindat ID:
1148
Long-form identifier:
mindat:1:1:1148:4
GUID
(UUID V4):
f724da17-b3a4-49e6-a87c-43d38196d739

IMA Classification of CrawforditeHide

Classification of CrawforditeHide

5.BF.10

5 : CARBONATES (NITRATES)
B : Carbonates with additional anions, without H2O
F : With (Cl), SO4, PO4, TeO3
43.2.1.4

43 : COMPOUND PHOSPHATES, ETC.
2 : Anhydrous Normal Compound Phosphates, etc·

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
CfdIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of CrawforditeHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of CrawforditeHide

Sub-Vitreous
Transparency:
Transparent, Translucent
Colour:
Colourless
Streak:
White
Hardness:
Fracture:
Conchoidal
Density:
3.05 g/cm3 (Measured)    3.08 g/cm3 (Calculated)

Optical Data of CrawforditeHide

Type:
Biaxial (-)
RI values:
nα = 1.520 nβ = 1.564 nγ = 1.565
2V:
Measured: 20° (1), Calculated: 16°
Max Birefringence:
δ = 0.045
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
not discernible
Comments:
X ≈ γ, Y ≈ α, Z ≈ β

Chemistry of CrawforditeHide

Mindat Formula:
Na3Sr(CO3)(PO4)

Crystallography of CrawforditeHide

Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
P21
Setting:
P21
Cell Parameters:
a = 9.18 Å, b = 6.7 Å, c = 5.27 Å
β = 89.98°
Ratio:
a:b:c = 1.37 : 1 : 0.787
Unit Cell V:
324.14 ų (Calculated from Unit Cell)
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012486CrawforditeSokolova E V, Khomyakov A P (1992) Crystal structure of a new mineral Na3SePO4CO3 from bredleyite group Doklady Akademii Nauk SSSR 322 531-53519920293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.708 Å(100)
2.648 Å(90)
2.172 Å(100)
1.891 Å(90)
1.415 Å(70)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
36 : Carbonatites, kimberlites, and related igneous rocks
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36

Type Occurrence of CrawforditeHide

General Appearance of Type Material:
Irregular grains to 1 mm in diameter.
Place of Conservation of Type Material:
A. E. Fersman Mineralogical Museum, Moscow, Russia.
Associated Minerals at Type Locality:
Reference:
Khomjakov, A.P., Polezhaeva, L.I., Sokolova, E.V. (1994) Crawfordite Na3Sr(PO4)(CO3) - a new mineral from the bradleyite family. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 123(3): 107-111.

Synonyms of CrawforditeHide

Other Language Names for CrawforditeHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Crawfordite associated with AegirineNaFe3+Si2O6
1 photo of Crawfordite associated with NephelineNa3K(Al4Si4O16)

Related Minerals - Strunz-mindat GroupingHide

5.BF.05FerrotychiteNa6(Fe,Mn,Mg)2(CO3)4(SO4)Iso. m3 (2/m 3) : Fd3
5.BF.05ManganotychiteNa6Mn2(CO3)4(SO4)Iso. m3 (2/m 3) : Fd3
5.BF.05NorthupiteNa3Mg(CO3)2ClIso. m3 (2/m 3) : Fd3
5.BF.05TychiteNa6Mg2(CO3)4(SO4)Iso. m3 (2/m 3) : Fd3
5.BF.10BonshtedtiteNa3Fe2+(CO3)(PO4)Mon. 2/m : P21/m
5.BF.10BradleyiteNa3Mg(CO3)(PO4)Mon. 2/m : P21/m
5.BF.10SidorenkiteNa3Mn2+(CO3)(PO4)Mon.
5.BF.15Daqingshanite-(Ce)(Sr,Ca,Ba)3(Ce,La)(CO3)3-x(PO4)(OH,F)2xTrig.
5.BF.20Reederite-(Y)(Na,Mn)15Y2(CO3)9(FSO3)ClHex. 6 : P6
5.BF.25Mineevite-(Y)Na25Ba(Y,Gd,Dy)2(CO3)11(HCO3)4(SO4)2F2ClHex. 6/m : P63/m
5.BF.30BrianyoungiteZn3(CO3,SO4)(OH)4Mon. 2/m : P21/m
5.BF.35PhilolithitePb12Mn2+(Mg,Mn2+)2(Mn2+,Mg)4(CO3)4(SO4)O6(OH)12Cl4Tet. 4/mmm (4/m 2/m 2/m)
5.BF.40LeadhillitePb4(CO3)2(SO4)(OH)2Mon. 2/m : P21/b
5.BF.40MacphersonitePb4(CO3)2(SO4)(OH)2Orth. mmm (2/m 2/m 2/m)
5.BF.40SusannitePb4(CO3)2(SO4)(OH)2Trig. 3 : P3
5.BF.45Peatite-(Y)Li4Na12Y12(PO4)12(CO3)4(F,OH)8Orth. 2 2 2 : P2 2 2
5.BF.50Ramikite-(Y)Li4(Na,Ca)12Y6Zr6(PO4)12(CO3)4O4[(OH),F]4Tric. 1 : P1

Fluorescence of CrawforditeHide

Bright greenish yellow

Other InformationHide

IR Spectrum:
Absorption bands at 1445, 1055, and 575 cm-1.
Notes:
Readily soluble in 10% HCl and in citric acid at room temperature
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CrawforditeHide

References for CrawforditeHide

Localities for CrawforditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Murmansk Oblast
    • Khibiny Massif
      • Koashva Mt
Mandarino (1996) +1 other reference
 
Mineral and/or Locality  
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