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Huemulite

A valid IMA mineral species

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Photos of Huemulite (22)

Huemulite Gallery Search Photos of Huemulite

Edit Add Synonym Edit CIF structures Clear Cache

Huemulite

Liebenbergite slag dump, Lavrion slag localities, Lavreotiki, East Attica, Attica, Greece

Huemulite

Little Eva Mine, Yellow Cat Mesa, Thompsons Mining District, Grand County, Utah, USA

Huemulite

Saint Jude Mine, Slick Rock Mining District, San Miguel County, Colorado, USA

Huemulite

Liebenbergite slag dump, Lavrion slag localities, Lavreotiki, East Attica, Attica, Greece

Huemulite

Little Eva Mine, Yellow Cat Mesa, Thompsons Mining District, Grand County, Utah, USA

Huemulite

Saint Jude Mine, Slick Rock Mining District, San Miguel County, Colorado, USA

Huemulite

Liebenbergite slag dump, Lavrion slag localities, Lavreotiki, East Attica, Attica, Greece

Huemulite

Little Eva Mine, Yellow Cat Mesa, Thompsons Mining District, Grand County, Utah, USA

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About HuemuliteHide

View of "Huemul" Uranium Mine abandoned.

Huemul Mine, Pampa Amarilla mining district, Malargüe Department, Mendoza Province, Argentina

Formula:

Na₄Mg(V₁₀O₂₈) · 24H₂O

Colour:

Yellowish orange to orange

Lustre:

Adamantine, Sub-Adamantine, Vitreous, Sub-Vitreous, Dull

Hardness:

2½ - 3

Specific Gravity:

2.39

Crystal System:

Triclinic

Member of:

Pascoite Group > Pascoite Family Group

Name:

Named in 1966 by C. E. Gordillo, E. Linares, R. O. Toubes, and Horace Winchell for one of the type localities: Huemul Mine, Mendoza Province, Argentina.

Type Locality:

ⓘ Huemul Mine, Pampa Amarilla mining district, Malargüe Department, Mendoza Province, Argentina

Easily soluble in water.

Unique IdentifiersHide

Mindat ID:

1941

Long-form identifier:

mindat:1:1:1941:1

GUID
(UUID V4):

28dd21e0-67ed-481e-a944-123dd5e2899c

IMA Classification of HuemuliteHide

IMA status:

Approved

IMA Formula:

Na₄MgV⁵⁺₁₀O₂₈ · 24H₂O

First published:

1966

Type description reference:

Gordillo, C.E., Linares, E., Toubes, R.O., Winchell, H. (1966) Huemulite, Na4MgV10O28·24H2O, a new hydrous sodium a magnesium vanadate from Huemul mine, Mendoza province, Argentina. American Mineralogist: 51: 1-13.

Classification of HuemuliteHide

Strunz-mindat (2024):

4.HG.10

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
H : V[5,6] Vanadates
G : Unclassified V oxides

Dana 8th ed.:

47.2.3.1

47 : VANADIUM OXYSALTS
2 : Anhydrous Vanadium Oxysalts Containing Hydroxyl or Halogen

Hey's CIM Ref.:

21.1.6

21 : Vanadates (and vanadates with arsenate or phosphate)
1 : Vanadates of the alkalis and Cu

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Hml	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HuemuliteHide

Lustre:

Adamantine, Sub-Adamantine, Vitreous, Sub-Vitreous, Dull

Transparency:

Transparent, Translucent

Comment:

Natural fine-grained material is dull

Colour:

Yellowish orange to orange

Streak:

Yellow

Hardness:

2½ - 3 on Mohs scale

Tenacity:

Brittle

Cleavage:

Perfect
{001} perfect; {010} good

Density:

2.39(5) g/cm³ (Measured) 2.404 g/cm³ (Calculated)

Optical Data of HuemuliteHide

Type:

Biaxial (-)

RI values:

n_α = 1.679(3) n_β = 1.734(3) n_γ = 1.742(2)

2V:

Measured: 20° to 25°, Calculated: 40°

Birefringence:

0.063

Max Birefringence:

δ = 0.063

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

High

Dispersion:

r > v strong

Pleochroism:

Visible

Comments:

X= light yellow
Y= golden yellow
Z= yellowish orange

Chemistry of HuemuliteHide

Mindat Formula:

Na₄Mg(V₁₀O₂₈) · 24H₂O

Elements listed:

H, Mg, Na, O, V - search for minerals with similar chemistry

Crystallography of HuemuliteHide

Crystal System:

Triclinic

Cell Parameters:

a = 11.770 Å, b = 11.838 Å, c = 9.018(9) Å
α = 107.2°, β = 112.2°, γ = 101.5°

Ratio:

a:b:c = 0.994 : 1 : 0.762

Unit Cell V:

1,040.32 Å³ (Calculated from Unit Cell)

Morphology:

Synthetic crystals are pseudohexagonal elongated along [100].

Comment:

Point Group: 1 or 1; Space Group: P1 or P1.

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0018460	Huemulite	Colombo F, Baggio R, Kampf A R (2011) The crystal structure of the elusive huemulite The Canadian Mineralogist 49 849-864		2011	synthetic	0	293
0018461	Huemulite	Colombo F, Baggio R, Kampf A R (2011) The crystal structure of the elusive huemulite The Canadian Mineralogist 49 849-864		2011	West Sunday mine, Utah, USA	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Huemulite'
loop_
_publ_author_name
'Colombo F'
'Baggio R'
'Kampf A R'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 49 
_journal_year 2011
_journal_page_first 849
_journal_page_last 864
_publ_section_title
;
 The crystal structure of the elusive huemulite
;
_database_code_amcsd 0018460
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Na4 Mg V10 O51.82 H47.64'
_cell_length_a 9.0425
_cell_length_b 11.3303
_cell_length_c 11.7353
_cell_angle_alpha 105.222
_cell_angle_beta 97.377
_cell_angle_gamma 100.791
_cell_volume 1119.459
_exptl_crystal_density_diffrn      2.229
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Na1   0.50000   0.50000   0.50000   1.00000   0.04080
Na2   0.28638   0.40537   0.70452   1.00000   0.04280
Na3   0.50000   0.50000   0.00000   1.00000   0.03350
Mg1   0.50000   0.00000   0.50000   1.00000   0.02630
V1   0.83596   0.74497   0.75465   1.00000   0.02424
V2   0.18295   0.84113   0.79384   1.00000   0.02460
V3   0.03857   0.76811   0.99849   1.00000   0.01924
V4   0.81256   0.94733   0.97807   1.00000   0.01611
V5   0.97200   0.02589   0.77571   1.00000   0.01931
O1   0.70360   0.63652   0.66035   1.00000   0.03970
O2   0.70196   0.82217   0.86861   1.00000   0.02360
O3   0.82631   0.88103   0.69383   1.00000   0.02520
O4   0.01290   0.72617   0.69917   1.00000   0.02970
O5   0.88645   0.67025   0.87581   1.00000   0.02390
O6   0.83030   0.06848   0.89225   1.00000   0.01870
O7   0.13044   0.96593   0.72610   1.00000   0.02480
O8   0.18995   0.75544   0.90835   1.00000   0.02570
O9   0.89011   0.85207   0.07876   1.00000   0.01690
O10   0.94441   0.11931   0.69616   1.00000   0.02910
O11   0.32200   0.80842   0.72721   1.00000   0.03740
O12   0.06696   0.67647   0.07938   1.00000   0.03040
O13   0.00329   0.90959   0.90089   1.00000   0.01700
O14   0.30389   0.99325   0.93135   1.00000   0.02350
OW1   0.51340   0.37056   0.63290   1.00000   0.04480
H1A   0.52100   0.29680   0.60300   1.00000   0.05400
H1B   0.57800   0.39700   0.69760   1.00000   0.05400
OW2   0.30090   0.55030   0.59170   1.00000   0.05530
H2A   0.21900   0.53500   0.53900   1.00000   0.06600
H2B   0.30600   0.62000   0.64300   1.00000   0.06600
OW3   0.14310   0.21150   0.55469   1.00000   0.04370
H3A   0.12000   0.19300   0.47910   1.00000   0.05200
H3B   0.06400   0.18200   0.57900   1.00000   0.05200
OW4   0.06450   0.45930   0.76860   1.00000   0.05770
H4A   0.02300   0.41900   0.81200   1.00000   0.06900
H4B   0.05200   0.53240   0.79700   1.00000   0.06900
OW5   0.42970   0.61851   0.86666   1.00000   0.03680
H5A   0.36500   0.66100   0.88400   1.00000   0.04400
H5B   0.50500   0.67400   0.86600   1.00000   0.04400
OW6   0.33930   0.30988   0.85774   1.00000   0.03490
H6A   0.26700   0.26400   0.87500   1.00000   0.04200
H6B   0.39900   0.26200   0.84800   1.00000   0.04200
OW7   0.68970   0.45484   0.87850   1.00000   0.04150
H7A   0.74800   0.52330   0.88300   1.00000   0.05000
H7B   0.74700   0.41500   0.90700   1.00000   0.05000
OW8   0.63470   0.14362   0.64575   1.00000   0.04040
H8A   0.60500   0.14400   0.71170   1.00000   0.04800
H8B   0.72970   0.15500   0.64500   1.00000   0.04800
OW9   0.31200   0.03070   0.57329   1.00000   0.04280
H9A   0.26700   0.00300   0.62300   1.00000   0.05100
H9B   0.27400   0.09300   0.57600   1.00000   0.05100
OW10   0.46470   0.13222   0.41227   1.00000   0.03390
H10A   0.52300   0.14200   0.36400   1.00000   0.04100
H10B   0.37530   0.12300   0.37600   1.00000   0.04100
OW11   0.54280   0.14010   0.86016   1.00000   0.04010
H11A   0.47300   0.09000   0.87700   1.00000   0.04800
H11B   0.62300   0.13200   0.89800   1.00000   0.04800
Wat12A   0.87750   0.34730   0.53850   0.26000   0.10200
Wat12B   0.96430   0.43800   0.52290   0.65000   0.09000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Na1 0.03580 0.04730 0.02750 0.00370 0.00420 -0.00740
Na2 0.04940 0.04710 0.04010 0.01870 0.01800 0.01570
Na3 0.03220 0.03300 0.03580 0.01290 0.00610 0.00520
Mg1 0.02460 0.02930 0.03120 0.01450 0.01090 0.00930
V1 0.02800 0.01904 0.01970 0.00230 0.00178 -0.00240
V2 0.02820 0.02150 0.02830 0.00740 0.01661 0.00811
V3 0.02220 0.01564 0.02300 0.00847 0.00724 0.00569
V4 0.01277 0.01633 0.02017 0.00745 0.00407 0.00198
V5 0.02280 0.01971 0.01627 0.00785 0.00428 0.00284
O1 0.04480 0.02890 0.03040 0.00020 -0.00270 -0.00900
O2 0.01830 0.02240 0.02740 0.00860 0.00150 -0.00160
O3 0.02780 0.02480 0.01820 0.00610 -0.00090 -0.00180
O4 0.03990 0.02200 0.02450 0.00140 0.01370 0.00340
O5 0.02840 0.01590 0.02640 0.00590 0.00750 0.00160
O6 0.01490 0.02030 0.02280 0.01080 0.00290 0.00310
O7 0.03050 0.02440 0.02300 0.00950 0.01300 0.00600
O8 0.02640 0.02200 0.03610 0.01210 0.01610 0.01140
O9 0.01620 0.01590 0.01990 0.00740 0.00520 0.00240
O10 0.03200 0.03130 0.02790 0.01700 0.00540 0.00490
O11 0.04080 0.03410 0.04660 0.01350 0.02970 0.01430
O12 0.03490 0.02670 0.03950 0.01960 0.01210 0.01300
O13 0.01650 0.01620 0.01900 0.00640 0.00520 0.00290
O14 0.01850 0.02410 0.03140 0.01080 0.01040 0.00560
OW1 0.04760 0.03160 0.05550 0.01040 0.01560 0.00910
OW2 0.07790 0.04470 0.04980 0.01170 0.02690 0.02260
OW3 0.05030 0.05290 0.03120 0.01530 0.01610 0.00960
OW4 0.07550 0.04650 0.07350 0.02910 0.04910 0.02830
OW5 0.03430 0.03500 0.04590 0.01640 0.01090 0.01110
OW6 0.03080 0.03120 0.04640 0.01840 0.01300 0.00260
OW7 0.03010 0.03180 0.07040 0.02550 0.01440 0.00740
OW8 0.03360 0.04310 0.04430 0.01070 0.00760 0.01150
OW9 0.04320 0.05650 0.05270 0.03610 0.03130 0.02590
OW10 0.02760 0.04680 0.04000 0.02750 0.01320 0.01350
OW11 0.02440 0.05180 0.05070 0.02940 0.00470 0.00600
Wat12A 0.08200 0.14600 0.08700 0.03100 0.00900 0.05900
Wat12B 0.07300 0.08700 0.09300 -0.00100 -0.00900 0.03100

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
10.59 Å	(90)
10.20 Å	(55)
9.12 Å	(60)
8.22 Å	(35)
7.62 Å	(100)
6.07 Å	(15)
5.26 Å	(25)
3.956 Å	(20)
3.795 Å	(25)
3.054 Å	(30)
2.833 Å	(35)

Comments:

Gordillo, et al. (1966).

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
47a : [Near-surface hydration of prior minerals]
47e : [Vanadates, chromates, manganates]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere	<0.6
50 : Coal and/or oil shale minerals	<0.36
Stage 10b: Anthropogenic minerals	<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of HuemuliteHide

Type Locality:

ⓘ Huemul Mine, Pampa Amarilla mining district, Malargüe Department, Mendoza Province, Argentina

General Appearance of Type Material:

Fibrous crusts and films, also fine-grained granular.

Place of Conservation of Type Material:

National Museum of Natural History, Washington, D.C., USA, 120076.

Geological Setting of Type Material:

A post-mining mineral derived from Cu-U sandstone/conglomerate deposits.

Associated Minerals at Type Locality:

Thénardite	Rossite	Quartz	Hummerite	Gypsum
Epsomite

Reference:

Download:

http://rruff.info/rruff_1.0/uploads/AM51_1.pdf

Synonyms of HuemuliteHide

IMA1965-012

Other Language Names for HuemuliteHide

German:Huemulit

Spanish:Huemulita

Relationship of Huemulite to other SpeciesHide

Member of:

Pascoite Group > Pascoite Family Group

Other Members of this group:

Hummerite	K₂Mg₂(V₁₀O₂₈) · 16H₂O	Tric. 1 : P1
Lasalite	Na₂Mg₂(V₁₀O₂₈) · 20H₂O	Mon. 2/m : B2/b
Magnesiopascoite	Ca₂Mg(V₁₀O₂₈) · 16H₂O	Mon. 2/m : B2/m
Pascoite	Ca₂Ca(V₁₀O₂₈) · 17H₂O	Mon. 2 : B2
Rakovanite	(NH₄)₃Na₃(V₁₀O₂₈) · 12H₂O	Mon. 2/m

Common AssociatesHide

Associated Minerals Based on Photo Data:

8 photos of Huemulite associated with Pascoite	Ca₂Ca(V₁₀O₂₈) · 17H₂O
1 photo of Huemulite associated with Slag
1 photo of Huemulite associated with Rossite	Ca(VO₃)₂ · 4H2O
1 photo of Huemulite associated with Corvusite	(Na,K,Ca,Mg)₂(V⁵⁺,V⁴⁺,Fe²⁺)₈O₂₀ · 6-10H₂O
1 photo of Huemulite associated with Montroseite	(V³⁺,Fe³⁺)O(OH)

Related Minerals - Strunz-mindat Grouping Hide

4.HG.	Calciodelrioite	Ca(VO₃)₂ · 4H₂O	Mon. 2/m : B2/b
4.HG.	Trebiskyite	Na₃Mg₂[TiV₉O₂₈] · 22H₂O	Mon. 2/m : P2₁/b
4.HG.05	Fervanite	Fe³⁺₄V⁵⁺₄O₁₆ · 5H₂O	Mon.
4.HG.15	Vanalite	NaAl₈V₁₀O₃₈ · 30H₂O	Mon.
4.HG.20	Simplotite	CaV⁴⁺₄O₉ · 5H₂O	Mon.
4.HG.25	Vanoxite	V⁴⁺₄V⁵⁺₂O₁₃ · 8H₂O
4.HG.30	Navajoite	Fe³⁺V⁵⁺₉O₂₄ · 12H₂O	Mon. 2/m : B2/m
4.HG.35	Delrioite	CaSr(V₂O₆)(OH)₂ · 3H₂O	Mon.
4.HG.40	Metadelrioite	CaSr(V₂O₆)(OH)₂	Tric.
4.HG.45	Barnesite	(Na,Ca)V₆O₁₆ · 3H₂O	Mon. 2/m : P2/m
4.HG.50	Hendersonite	(Ca,Sr)_1.3V₆O₁₆ · 6H₂O	Orth.
4.HG.55	Grantsite	(Na,Ca)_2+x(V⁵⁺,V⁴⁺)₆O₁₆ · 4H₂O	Mon. 2/m : P2₁/m
4.HG.60	Lenoblite	V⁴⁺₂O₄ · 2H₂O	Orth. 2 2 2 : P2₁ 2₁ 2₁
4.HG.65	Satpaevite	Al₁₂V⁴⁺₂V⁵⁺₆O₃₇ · 30H₂O	Orth.
4.HG.70	Pandoraite-Ba	BaV⁴⁺₅V⁵⁺₂O₁₆ · 3H₂O	Mon. 2 : P2
4.HG.70	Pandoraite-Ca	CaV⁴⁺₅V⁵⁺₂O₁₆ · 3H₂O	Mon. 2 : P2

Fluorescence of HuemuliteHide

In UV light:

Not fluorescent in UV.

Other InformationHide

Thermal Behaviour:

Melts at 500 °C.

Notes:

Soluble in water. Most properties measured on recrystallized material.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HuemuliteHide

mindat.org URL:

https://www.mindat.org/min-1941.html
Please feel free to link to this page.

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External Links:

Look for Huemulite on Webmineral

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for HuemuliteHide

Reference List:

Fleischer, M. (1969) New mineral names. American Mineralogist: 54: 326-330.

Frost, R.L., Erickson, K.L., Weier, M.L. (2004) Hydrogen bonding in selected vanadates: a Raman and infrared spectroscopy study. Spectrochimica Acta Part A: 60: 2419.

Colombo, B., Baggio, R., Kampf, A.R. (2011) The crystal structure of the elusive huemulite. Canadian Mineralogist: 49: 849-864.

(2023) Huemulite. Handbook of Mineralogy. Mineralogical Society of America

Localities for HuemuliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Argentina
Mendoza Province Malargüe Department Pampa Amarilla mining district ⓘ Agua Botada	Gordillo et al. (1966)
ⓘ Agua Botada Mine	Anthony et al. (1997)
ⓘ Agua Botada Sur Mine	Anthony et al. (1997)
ⓘ Huemul Mine (TL)	Gordillo et al. (1966)

Czech Republic
Central Bohemian Region ⓘ Příbram District	Josef Vajdak (2008)
Dubno ⓘ Uranium Mine No. 21	Lapis 7-8/2003

Greece
Attica East Attica Lavreotiki Lavrion slag localities ⓘ Liebenbergite slag dump	Färber (n.d.) +2 other references

Spain
Catalonia Lleida El Pallars Jussà La Vall Fosca La Torre de Cabdella Castell-estaó ⓘ Eureka mine	Joy Desor analysis by Raman spectroscopy and SEM-EDS: Desor (2018)

UK
England Devon East Devon Budleigh Salterton ⓘ Littleham Bay	Brian Craik-Smith collection (NHM London XRD ID)

USA
Colorado Montrose County Bull Canyon Mining District ⓘ Blue Streak Mine	Kampf et al. (2012) +1 other reference
San Miguel County Slick Rock Mining District ⓘ Burro Mine	Kampf et al. (2019)
ⓘ Saint Jude Mine	Collected by and in the collection of ...
ⓘ Suncup No. 2 Mine	Collected by and in the collection of ...
ⓘ West Sunday Mine	Kampf et al. (2012)
Nevada Eureka County Fish Creek Mining District ⓘ Bisoni prospect (McCulloughs Butte prospect)	Castor et al. (2004)
Gibellini Mining District Fish Creek Range ⓘ Gibellini Vanadium Project	Rocks & Minerals
ⓘ Gibellini mine (Niganz mine; Black Iron mine)	Castor et al. (2004)
ⓘ The Fish	Frost et al. (5)
Utah Grand County Thompsons Mining District D-Day Mine group ⓘ D-Day No. 4 Mine ?	Pavel M. Kartashov analytical data 2015
Yellow Cat Mesa ⓘ Little Eva Mine	Kasatkin et al. (2014) +1 other reference

Huemulite

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