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Masutomilite

A valid IMA mineral species
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About MasutomiliteHide

03610220014947046822821.jpg
Dr. Kazunosuke Masutomi
Formula:
(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2
Colour:
Pale purplish-pink
Hardness:
Specific Gravity:
2.90 - 2.94
Crystal System:
Monoclinic
Name:
Named in 1977 by Kazuo Harada, Mariko Honda, Kozo Nagashima and Satoshi Kanisawa in honor of Dr. Kazunosuke Masutomi, pharmacist and amateur mineralogist, for his contribution to minerals from Japan.

Unique IdentifiersHide

Mindat ID:
2588
Long-form identifier:
mindat:1:1:2588:7
GUID
(UUID V4):
d98e55b2-9fc6-4a72-8567-8a1afcc808b4

IMA Classification of MasutomiliteHide

Classification of MasutomiliteHide

9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.2.2b.12

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
2 : Sheets of 6-membered rings with 2:1 layers
16.16.11

16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
MsuIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
MsuWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of MasutomiliteHide

Transparency:
Transparent, Translucent
Colour:
Pale purplish-pink
Hardness:
2½ on Mohs scale
Tenacity:
Flexible
Cleavage:
Perfect
{001}
Density:
2.90 - 2.94 g/cm3 (Measured)    2.96 g/cm3 (Calculated)

Optical Data of MasutomiliteHide

Type:
Biaxial (-)
RI values:
nα = 1.534 - 1.536 nβ = 1.569 - 1.570 nγ = 1.570 - 1.574
2V:
Measured: 28° to 35°, Calculated: 18°
Max Birefringence:
δ = 0.036 - 0.038
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
r > v, very weak.
Optical Extinction:
Y = b; Z ∧ a = 2°-4°.
Pleochroism:
Visible
Comments:
X = Z = colorless to pale pink, Y = purple.
Comments:
Absorption: Y > Z > X.

Chemistry of MasutomiliteHide

Mindat Formula:
(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2
Common Impurities:
Ti,Fe,Na,Rb,H2O

Crystallography of MasutomiliteHide

Crystal System:
Monoclinic
Class (H-M):
2 - Sphenoidal
Space Group:
B2
Setting:
C2
Cell Parameters:
a = 5.262(2) Å, b = 9.102(3) Å, c = 10.094(3) Å
β = 100.83(2)°
Ratio:
a:b:c = 0.578 : 1 : 1.109
Unit Cell V:
474.84 ų (Calculated from Unit Cell)
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0004418MasutomiliteBrigatti M F, Mottana A, Malferrari D, Cibin G (2007) Crystal structure and chemical composition of Li-, Fe-, and Mn-rich micas American Mineralogist 92 1395-14002007Sawtooth Mountains, Boise county, Idaho, USA0293
0014426MasutomiliteMizota T, Kato T, Harada K (1986) The crystal structure of masutomilite, Mn analogue of zinnwaldite Mineralogical Journal 13 13-211986Tanakamiyama, Ohtsu, Japan0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.10 Å(72)
3.64 Å(43)
3.32 Å(100)
3.09 Å(58)
2.903 Å(35)
2.89 Å(17)
1.989 Å(46)
1.653 Å(23)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of MasutomiliteHide

General Appearance of Type Material:
Zoned mica crystal 10 cm across and 1 cm thick
Place of Conservation of Type Material:
Department of Earth Science, Kanazawa Universitya; Tohoku University, Kawauchi, Japan.
Geological Setting of Type Material:
Granite pegmatite
Associated Minerals at Type Locality:
Reference:
Harada, K., Honda, M., Nagashima, K., Kanisawa, S. (1976) Masutomilite, manganese analog of zinnwaldite, with special reference to masutomilite-lepidolite-zinnwaldite series. Mineralogical Journal (Japan): 8(2): 95-109.

Other Language Names for MasutomiliteHide

Relationship of Masutomilite to other SpeciesHide

Other Members of this group:
AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
BalestraiteKLi2V5+Si4O12Mon. 2 : B2
BiotiteK(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2
EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
GarmiteCsLiMg2(Si4O10)F2Mon.
HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
LepidoliteA Li-rich mica in, or close to, the so-called Polylithionite-Trilithionite series.Mon.
NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
SokolovaiteCsLi2Al(Si4O10)F2Mon.
Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
ZinnwalditeMica Group.

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Masutomilite associated with SpessartineMn2+3Al2(SiO4)3
4 photos of Masutomilite associated with Zinnwaldite
3 photos of Masutomilite associated with Lepidolite
1 photo of Masutomilite associated with CleavelanditeNa(AlSi3O8)
1 photo of Masutomilite associated with PyromorphitePb5(PO4)3Cl
1 photo of Masutomilite associated with ApatiteCa5(PO4)3(Cl/F/OH)
1 photo of Masutomilite associated with GearksutiteCa[Al(F,OH)5(H2O)]
1 photo of Masutomilite associated with Smoky QuartzSiO2
1 photo of Masutomilite associated with ProsopiteCaAl2F4[(OH)4-xFx]
1 photo of Masutomilite associated with AlbiteNa(AlSi3O8)

Related Minerals - Strunz-mindat GroupingHide

9.EC.BalestraiteKLi2V5+Si4O12Mon. 2 : B2
9.EC.MeifuiteKFe6(Si7Al)O19(OH)4Cl2Tric. 1 : P1
9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.9.EC.VoloshiniteRb(LiAl1.50.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon. 2/m
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.
9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.
9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15Tobelite(NH4,K)Al2(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 : B2
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15UM1988-22-SiO:AlCaFFeHKLiMgKLiMgAl2Si3O10F2Mon.
9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2Mon. 2/m : B2/m
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
9.EC.20ShirozuliteKMn2+3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.20Chloroferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.22PimeliteNi3Si4O10(OH)2 · 4H2OHex.
9.EC.30Chlorophaeite(Ca,Mg,Fe)2Fe2Si4O13 · 10H2O
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.35BityiteCaLiAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35ClintoniteCaAlMg2(SiAl3O10)(OH)2Mon. 2/m : B2/m
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon. 2/m : B2/m
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon. 2/m : B2/m
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m : B2/m
9.EC.45ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45HanjiangiteBa2CaV3+Al(H2AlSi3O12)(CO3)2FMon. 2 : B2
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.52Tarasovitenear NaKAl11Si13O40(OH)9 · 3H2O
9.EC.55Baileychlore(Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8Tric. 1
9.EC.55Chamosite(Fe2+)5Al(Si,Al)4O10(OH,O)8Mon. 2/m : B2/m
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8Mon. 2/m : B2/m
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55SudoiteMg2Al3(Si3Al)O10)(OH)8Mon. 2/m : B2/m
9.EC.55DonbassiteAl4.33(Si3Al)O10(OH)8Mon. 2 : B2
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon. 2/m : B2/m
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m (3 2/m) : P3 1m
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon. 2 : P21
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MasutomiliteHide

References for MasutomiliteHide

Reference List:

Localities for MasutomiliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Algeria
 
  • In Guezzam Province
    • In Guezzam District
Czech Republic
 
  • South Moravian Region
    • Znojmo District
      • Ctidružice
Scarlett Urbanová (2021)
  • Vysočina Region
    • Třebíč District
      • Stařeč
Škoda +2 other references
    • Žďár nad Sázavou District
      • Strážek (Straschkau)
Scarlett Urbanová (2021)
Japan
 
  • Gifu Prefecture
    • Nakatsugawa City
Am.Min. 62:594 (1977) +1 other reference
Harada (1976)
  • Ibaraki Prefecture
    • Hitachiota City
www.mindat.org (n.d.)
  • Iwate Prefecture
    • Ofunato City
Yohei Shirose (2017)
  • Shiga Prefecture
    • Otsu City
Nagashima (1975) +2 other references
Russia
 
  • Chelyabinsk Oblast
    • Kyshtym
Old data. Confirmed by V.Popov
  • Sverdlovsk Oblast
    • Prigorodny District
      • Yuzhakovo
        • Alabashka pegmatite field
Pavel.M. Kartashov (n.d.)
    • Rezhevsky District
      • Lipovsk pegmatite field
Igor.V. Pekov (2008)
USA
 
  • Connecticut
    • Middlesex County
      • Portland
        • Collins Hill
          • Strickland pegmatite
Schooner (circa 1985)
  • Idaho
Rocks & Min. 70:246 +8 other references
  • Virginia
    • Amelia County
      • Winterham
O’Neill et al. (1996)
 
Mineral and/or Locality  
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