Zaherite
A valid IMA mineral species
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About Zaherite
Formula:
Al12(SO4)5(OH)26 · 20H2O
Colour:
White to blue-green
Lustre:
Pearly, Earthy
Hardness:
3½
Specific Gravity:
2.007
Crystal System:
Triclinic
Name:
Named in 1977 by A. P. Ruotsala and L. L. Babcock in honour of Mohammed Abduz Zaher (1932, Bancharampur, Bangladesh - 27 August 2017, Dhaka, Bangladesh), geologist and director general of the Geological Survey of Bangladesh. He discovered the mineral in the course of his master's thesis.
Type Locality:
Dehydrates reversibly at room temperature.
Unique Identifiers
Mindat ID:
4381
Long-form identifier:
mindat:1:1:4381:2
GUID
(UUID V4):
(UUID V4):
809c3704-0287-4105-aa34-df0415e8eef3
IMA Classification of Zaherite
Approved
Approval year:
1977
First published:
1977
Classification of Zaherite
7.DE.65
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
31.10.3.1
31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
10 : Miscellaneous
31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
10 : Miscellaneous
25.6.11
25 : Sulphates
6 : Sulphates of Al and Tl
25 : Sulphates
6 : Sulphates of Al and Tl
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Zah | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Zaherite
Pearly, Earthy
Transparency:
Translucent
Colour:
White to blue-green
Hardness:
3½ on Mohs scale
Comment:
Aggregate hardness
Cleavage:
Very Good
In one direction
In one direction
Density:
2.007 g/cm3 (Measured)
Comment:
Measured with a gas pycnometer
Optical Data of Zaherite
Type:
Biaxial (+)
RI values:
nα = 1.498 nβ = 1.498 nγ = 1.499
2V:
Calculated: 38°
Birefringence:
Extremely low
Max Birefringence:
δ = 0.001
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
very weak
Chemistry of Zaherite
Mindat Formula:
Al12(SO4)5(OH)26 · 20H2O
Elements listed:
Crystallography of Zaherite
Crystal System:
Triclinic
Cell Parameters:
a = 18.47 Å, b = 19.45 Å, c = 3.77 Å
α = 95.24°, β = 91.48°, γ = 80.24°
α = 95.24°, β = 91.48°, γ = 80.24°
Ratio:
a:b:c = 0.95 : 1 : 0.194
Unit Cell V:
1,329.09 ų (Calculated from Unit Cell)
Comment:
Space group P1 or P-1.
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
17.9 Å | (100) |
9.5 Å | (5) |
4.82 Å | (5) |
4.61 Å | (7) |
4.58 Å | (7) |
4.56 Å | (7) |
3.55 Å | (6) |
3.22 Å | (8) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
46 : Near-surface hydrothermal alteration of minerals (see also #22) | |
47a : [Near-surface hydration of prior minerals] | |
47b : [Sulfates and sulfites] |
Type Occurrence of Zaherite
General Appearance of Type Material:
Veinlets (up to 1 cm across) that cut massive kaolinite-boehmite rock. Densely packed aggregates of extremely small grains.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, number 143793.
Geological Setting of Type Material:
Kaolinite-boehmite rock.
Associated Minerals at Type Locality:
Reference:
Ruotsala, A.P., Babcock, L.L. (1977) Zaherite, a new hydrated aluminum sulfate. American Mineralogist: 62: 1125-1128.
Synonyms of Zaherite
Other Language Names for Zaherite
Common Associates
Associated Minerals Based on Photo Data:
1 photo of Zaherite associated with Sillimanite | Al2(SiO4)O |
Related Minerals - Strunz-mindat Grouping
7.DE. | Cossaite | (Mg0.5,◻)Al6(SO4)6(HSO4)F6 · 36H2O |
7.DE. | Magnesioalterite | Mg2Fe3+4(SO4)4(C2O4)2(OH)4 · 17H2O |
7.DE. | Liangjunite | K2(Mo2O5)(SO4)2 · 3H2O |
7.DE. | Fabritzite | Zn9(SO4)2(OH)12Cl2 · 6H2O |
7.DE. | Downsite | K2(MoO3)3(SO4) · 4H2O |
7.DE.05 | Mangazeite | Al2(SO4)(OH)4 · 3H2O |
7.DE.10 | Carbonatecyanotrichite | Cu4Al2(CO3,SO4)(OH)12 · 2H2O |
7.DE.10 | Cyanotrichite | Cu4Al2(SO4)(OH)12 · 2H2O |
7.DE.10 | UKI-1975-(SO:AlCu) | (Cu, Al, SO4, H2O) |
7.DE.15 | Schwertmannite | Fe3+16(OH,SO4)12-13O16 · 10-12H2O |
7.DE.20 | Tlalocite | Cu10Zn6(Te6+O4)2(Te4+O3)(OH)25Cl · 27H2O |
7.DE.25 | Utahite | MgCu4Zn2Te6+3O14(OH)4 · 6H2O |
7.DE.35 | Coquandite | Sb6+xO8+x(SO4)(OH)x(H2O)1- x (x = 0.3) |
7.DE.40 | Osakaite | Zn4(SO4)(OH)6 · 5H2O |
7.DE.42 | Alterite | Zn2Fe3+4(SO4)4(C2O4)2(OH)4 · 17H2O |
7.DE.45 | Wilcoxite | MgAl(SO4)2F · 17H2O |
7.DE.45 | Barrotite | Cu9Al(HSiO4)2[(SO4)(HAsO4)0.5](OH)12 · 8H2O |
7.DE.47 | Tiberiobardiite | {Cu9Al[SiO3(OH)]2(OH)12(H2O)6}(SO4)1.5 · 10H2O |
7.DE.50 | Stanleyite | (V4+O)(SO4) · 6H2O |
7.DE.50 | Bouškaite | (MoO2)2O(SO3OH)2(H2O)4 |
7.DE.57 | Khangalasite | Fe(SO4)(OH) · 2H2O |
7.DE.60 | Hydrobasaluminite | Al4(SO4)(OH)10 · 12-36H2O |
7.DE.62 | Volaschioite | Fe4(SO4)O2(OH)6 · 2H2O |
7.DE.75 | Camérolaite | Cu6Al3(OH)18(H2O)2[Sb(OH)6](SO4) |
Other Information
Thermal Behaviour:
Hydrates and dehydrates reversibly at room temperature.
200 C = loss of hydrated water; 360 C = loss of hydroxyl; 855 C, 890 C = loss of SO2.
200 C = loss of hydrated water; 360 C = loss of hydroxyl; 855 C, 890 C = loss of SO2.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Zaherite
mindat.org URL:
https://www.mindat.org/min-4381.html
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References for Zaherite
Reference List:
Beukes, G. J., Schoch, A. E., de Bruiyn, H., Van der Westhuizen, W. A., Bok, L. D. C. (1984) A new occurrence of the hydrated aluminium sulphate zaherite, from Pofadder, South Africa. Mineralogical Magazine, 48 (346) 131-135 doi:10.1180/minmag.1984.048.346.18
De Bruiyn, H., Schoch, A. E., Beukes, G. J., Bok, L. D. C., Van Der Westhuizen, W. A. (1985) Note on cell parameters of zaherite. Mineralogical Magazine, 49 (350) 145-146 doi:10.1180/minmag.1985.049.350.26
Localities for Zaherite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Harris et al. (2003) |
Italy | |
| P.Forti (1994) |
Pakistan (TL) | |
| The Mineralogical Record: 9: 115. +1 other reference |
Romania | |
| Januszewska et al. (2023) |
South Africa | |
| Beukes et al. (1984) +1 other reference |
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Salt Range, Punjab Province, Pakistan