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Holbrook Mine (Holbrook shaft), Copper Queen Mine (Halero Mine), Queen Hill, Bisbee, Cochise County, Arizona, USAi
Regional Level Types
Holbrook Mine (Holbrook shaft)Mine
Copper Queen Mine (Halero Mine)Mine
Queen HillHill
BisbeeTown
Cochise CountyCounty
ArizonaState
USACountry

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Key
Latitude & Longitude (WGS84):
31° 26' 3'' North , 109° 54' 33'' West
Latitude & Longitude (decimal):
Locality type:
Nearest Settlements:
PlacePopulationDistance
Bisbee5,208 (2017)2.4km
Naco1,046 (2011)11.6km
Naco6,064 (2018)12.4km
Palominas212 (2011)20.7km
Miracle Valley644 (2011)24.0km


A former medium output underground Cu-Pb-Zn-Au-Ag occurrence/mine located in the North-central sec. 16, T23S, R24E, G&SRM, approximately 1 mile NW of Lowell, on private property. The Holbrook Mine is a shaft of the Copper Queen Branch of the Phelps Dodge Corporation. Owned by the Phelps Dodge Corporation.

Mineralization is slightly oxidized and enriched copper and minor lead and zinc sulfides in highly irregular replacement bodies in contact breccia and in Devonian Martin Limestone along the edge of the porphyry stock. The ore bodies are large, with the exception of one, all occurred above the fourth level. Ore control was nearby dikes and sills, and faulting and associated brecciation. Ore concentration was bornite replacing pyrite. Alteration was gossan with Mn and Fe oxides induced by hydrothermal metamorphism. An associated rock unit is the Sacramento Hill Stock.

Local structures include pre-mineralization faulting and tilting. Main fault directions are N10W to N40E and S30W to N50W.

Workings include underground openings located 1,100 feet SSW of the Czar shaft, and give direct access to five levels and are comprised of a major shaft to a depth of 137.16 meters.

Production was several hundred thousand tons of ore as part of the Phelps Dodge total production.

Note on the chalcoalumite from Bisbee: According to Richard Graeme, all the chalcoalumite came from the Holbrook Mine and later the Holbrook Extension of the Lavender Pit, which removed the material from the former Holbrook Mine. Copper Queen listings may be from the access to the Holbrook, which was later through the Copper Queen entrance. No other area of Bisbee had the chemistry necessary to form chalcoalumite but the Holbrook.

Select Mineral List Type

Standard Detailed Strunz Dana Chemical Elements

Commodity List

This is a list of exploitable or exploited mineral commodities recorded from this region.


Mineral List

Mineral list contains entries from the region specified including sub-localities

26 valid minerals. 1 (TL) - type locality of valid minerals.

Detailed Mineral List:

Anglesite
Formula: PbSO4
Reference: MRDS database Dep. ID file #10046241, MRDS ID #M241106.
Antlerite
Formula: Cu3(SO4)(OH)4
Description: Occurs on the west side of the pit.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 115, 154; Graeme, R. (1993), Bisbee revisited, Min.Rec.: 24: 421-436.
Aurichalcite
Formula: (Zn,Cu)5(CO3)2(OH)6
Reference: Dana 6:1093.
Azurite
Formula: Cu3(CO3)2(OH)2
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 154, 320; Graeme, R. (1993), Bisbee revisited, Min.Rec.: 24: 421-436; Dana 6:1093.
Bornite
Formula: Cu5FeS4
Reference: MRDS database Dep. ID file #10046241, MRDS ID #M241106.
Calcite
Formula: CaCO3
Reference: Dana 6:1093.
Carbonatecyanotrichite
Formula: Cu4Al2(CO3,SO4)(OH)12 · 2H2O
Description: Occurs as fibrous, radiating needles in tiny spherules on silicified shaly limestones.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 154; Graeme, R. (1993), Bisbee revisited, Min.Rec.: 24: 421-436.
Chalcoalumite (TL)
Formula: CuAl4(SO4)(OH)12 · 3H2O
Type Locality:
Reference: Richard Graeme personal communications
Chalcocite
Formula: Cu2S
Reference: MRDS database Dep. ID file #10046241, MRDS ID #M241106.; Ransome, F.L. (1904a), The geology and ore deposits of the Bisbee quadrangle, Arizona: U.S. Geological Survey Professional Paper 21, 168 p., 3 sheets, scales 1:12,000 and 1:62,500: 119.
Chalcopyrite
Formula: CuFeS2
Reference: MRDS database Dep. ID file #10046241, MRDS ID #M241106.; Ransome, F.L. (1904a), The geology and ore deposits of the Bisbee quadrangle, Arizona: U.S. Geological Survey Professional Paper 21, 168 p., 3 sheets, scales 1:12,000 and 1:62,500: 119.
Chrysocolla
Formula: Cu2-xAlx(H2-xSi2O5)(OH)4 · nH2O
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 177; Dana 6:1093.
'Clinochrysotile'
Description: Scaly, micaceous intergrowths with stevensite.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 177.
Copper
Formula: Cu
Reference: Ransome, F.L. (1904a), The geology and ore deposits of the Bisbee quadrangle, Arizona: U.S. Geological Survey Professional Paper 21, 168 p., 3 sheets, scales 1:12,000 and 1:62,500: 119.
Cuprite
Formula: Cu2O
Reference: The Resources of Arizona - A Manual of Reliable Information Concerning the Territory, compiled by Patrick Hamilton (1881), Scottsdale, AZ: 41; Dana 6:1093.; Ransome, F.L. (1904a), The geology and ore deposits of the Bisbee quadrangle, Arizona: U.S. Geological Survey Professional Paper 21, 168 p., 3 sheets, scales 1:12,000 and 1:62,500: 119.
Felsőbányaite
Formula: Al4(SO4)(OH)10 · 4H2O
Colour: White
Description: Earthy masses with other aluminum sulphates encrusting silicified limestones and as micro-crystals.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 129.
'Halloysite'
Formula: Al2(Si2O5)(OH)4
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 372; Schwartz, G.M. & C.F. Park, Jr. (1932), A microscopic study of ores from the Campbell Mine, Bisbee, AZ, Econ.Geol.: 27: 39-51.
Hydrobasaluminite
Formula: Al4(SO4)(OH)10 · 12-36H2O
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 129.
'Limonite'
Formula: (Fe,O,OH,H2O)
Reference: Rolf Luetcke
Malachite
Formula: Cu2(CO3)(OH)2
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 320; Dana 6:1093.
Meionite
Formula: Ca4Al6Si6O24CO3
Description: Occurs on the 500 level in Abrigo Limestone.
Reference: Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 6.
Paramelaconite
Formula: Cu1+2Cu2+2O3
Reference: Dana 6:1093.
Paratacamite
Formula: Cu3(Cu,Zn)(OH)6Cl2
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 320.
Pyrite
Formula: FeS2
Reference: MRDS database Dep. ID file #10046241, MRDS ID #M241106.; Ransome, F.L. (1904a), The geology and ore deposits of the Bisbee quadrangle, Arizona: U.S. Geological Survey Professional Paper 21, 168 p., 3 sheets, scales 1:12,000 and 1:62,500: 119.
Rosasite
Formula: (Cu,Zn)2(CO3)(OH)2
Reference: Evan Jones
Silver
Formula: Ag
Description: Occurs in a few places.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 372; Schwartz, G.M. & C.F. Park, Jr. (1932), A microscopic study of ores from the Campbell Mine, Bisbee, AZ, Econ.Geol.: 27: 39-51.
Stevensite
Formula: (Ca,Na)xMg3-x(Si4O10)(OH)2
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 166.
Tenorite
Formula: CuO
Reference: Dana 6:1093.
Tremolite
Formula: ☐{Ca2}{Mg5}(Si8O22)(OH)2
Description: Occurs on the 500 level in Abrigo Limestone.
Reference: Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 6.
Wollastonite
Formula: CaSiO3
Description: Occurs on the 500 level in Abrigo Limestone.
Reference: Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 6.

List of minerals arranged by Strunz 10th Edition classification

Group 1 - Elements
Copper1.AA.05Cu
Silver1.AA.05Ag
Group 2 - Sulphides and Sulfosalts
Bornite2.BA.15Cu5FeS4
Chalcocite2.BA.05Cu2S
Chalcopyrite2.CB.10aCuFeS2
Pyrite2.EB.05aFeS2
Group 3 - Halides
Paratacamite3.DA.10cCu3(Cu,Zn)(OH)6Cl2
Group 4 - Oxides and Hydroxides
Cuprite4.AA.10Cu2O
Paramelaconite4.AA.15Cu1+2Cu2+2O3
Tenorite4.AB.10CuO
Group 5 - Nitrates and Carbonates
Aurichalcite5.BA.15(Zn,Cu)5(CO3)2(OH)6
Azurite5.BA.05Cu3(CO3)2(OH)2
Calcite5.AB.05CaCO3
Malachite5.BA.10Cu2(CO3)(OH)2
Rosasite5.BA.10(Cu,Zn)2(CO3)(OH)2
Group 7 - Sulphates, Chromates, Molybdates and Tungstates
Anglesite7.AD.35PbSO4
Antlerite7.BB.15Cu3(SO4)(OH)4
Carbonatecyanotrichite7.DE.10Cu4Al2(CO3,SO4)(OH)12 · 2H2O
Chalcoalumite (TL)7.DD.75CuAl4(SO4)(OH)12 · 3H2O
Felsőbányaite7.DD.05Al4(SO4)(OH)10 · 4H2O
Hydrobasaluminite7.DE.60Al4(SO4)(OH)10 · 12-36H2O
Group 9 - Silicates
Chrysocolla9.ED.20Cu2-xAlx(H2-xSi2O5)(OH)4 · nH2O
'Clinochrysotile'9.ED.
'Halloysite'9.ED.10Al2(Si2O5)(OH)4
Meionite9.FB.15Ca4Al6Si6O24CO3
Stevensite9.EC.45(Ca,Na)xMg3-x(Si4O10)(OH)2
Tremolite9.DE.10☐{Ca2}{Mg5}(Si8O22)(OH)2
Wollastonite9.DG.05CaSiO3
Unclassified Minerals, Rocks, etc.
'Limonite'-(Fe,O,OH,H2O)

List of minerals arranged by Dana 8th Edition classification

Group 1 - NATIVE ELEMENTS AND ALLOYS
Metals, other than the Platinum Group
Copper1.1.1.3Cu
Silver1.1.1.2Ag
Group 2 - SULFIDES
AmBnXp, with (m+n):p = 2:1
Chalcocite2.4.7.1Cu2S
AmBnXp, with (m+n):p = 3:2
Bornite2.5.2.1Cu5FeS4
AmBnXp, with (m+n):p = 1:1
Chalcopyrite2.9.1.1CuFeS2
AmBnXp, with (m+n):p = 1:2
Pyrite2.12.1.1FeS2
Group 4 - SIMPLE OXIDES
A2X
Cuprite4.1.1.1Cu2O
AX
Tenorite4.2.3.1CuO
Miscellaneous
Paramelaconite4.6.4.1Cu1+2Cu2+2O3
Group 10 - OXYHALIDES AND HYDROXYHALIDES
A2(O,OH)3Xq
Paratacamite10.1.2.1Cu3(Cu,Zn)(OH)6Cl2
Group 14 - ANHYDROUS NORMAL CARBONATES
A(XO3)
Calcite14.1.1.1CaCO3
Group 16a - ANHYDROUS CARBONATES CONTAINING HYDROXYL OR HALOGEN
Azurite16a.2.1.1Cu3(CO3)2(OH)2
Malachite16a.3.1.1Cu2(CO3)(OH)2
Rosasite16a.3.1.2(Cu,Zn)2(CO3)(OH)2
Aurichalcite16a.4.2.1(Zn,Cu)5(CO3)2(OH)6
Group 16b - HYDRATED CARBONATES CONTAINING HYDROXYL OR HALOGEN
Carbonatecyanotrichite16b.7.7.1Cu4Al2(CO3,SO4)(OH)12 · 2H2O
Group 28 - ANHYDROUS ACID AND NORMAL SULFATES
AXO4
Anglesite28.3.1.3PbSO4
Group 30 - ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
(AB)m(XO4)pZq, where m:p>2:1
Antlerite30.1.12.1Cu3(SO4)(OH)4
Group 31 - HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
(AB)5(XO4)Zq·xH2O
Chalcoalumite (TL)31.3.1.1CuAl4(SO4)(OH)12 · 3H2O
(AB)4(XO4)Zq·xH2O
Felsőbányaite31.4.4.1Al4(SO4)(OH)10 · 4H2O
Hydrobasaluminite31.4.6.1Al4(SO4)(OH)10 · 12-36H2O
Group 65 - INOSILICATES Single-Width,Unbranched Chains,(W=1)
Single-Width Unbranched Chains, W=1 with chains P=3
Wollastonite65.2.1.1cCaSiO3
Group 66 - INOSILICATES Double-Width,Unbranched Chains,(W=2)
Amphiboles - Mg-Fe-Mn-Li subgroup
Tremolite66.1.3a.1☐{Ca2}{Mg5}(Si8O22)(OH)2
Group 71 - PHYLLOSILICATES Sheets of Six-Membered Rings
Sheets of 6-membered rings with 1:1 layers
'Clinochrysotile'71.1.2d.1
'Halloysite'71.1.1.4Al2(Si2O5)(OH)4
Sheets of 6-membered rings with 2:1 clays
Stevensite71.3.1b.6(Ca,Na)xMg3-x(Si4O10)(OH)2
Group 74 - PHYLLOSILICATES Modulated Layers
Modulated Layers with joined strips
Chrysocolla74.3.2.1Cu2-xAlx(H2-xSi2O5)(OH)4 · nH2O
Unclassified Minerals, Mixtures, etc.
'Limonite'-(Fe,O,OH,H2O)
Meionite-Ca4Al6Si6O24CO3

List of minerals for each chemical element

HHydrogen
H ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
H AzuriteCu3(CO3)2(OH)2
H MalachiteCu2(CO3)(OH)2
H ChrysocollaCu2-xAlx(H2-xSi2O5)(OH)4 · nH2O
H Aurichalcite(Zn,Cu)5(CO3)2(OH)6
H CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
H AntleriteCu3(SO4)(OH)4
H FelsőbányaiteAl4(SO4)(OH)10 · 4H2O
H Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2
H ParatacamiteCu3(Cu,Zn)(OH)6Cl2
H HalloysiteAl2(Si2O5)(OH)4
H HydrobasaluminiteAl4(SO4)(OH)10 · 12-36H2O
H Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2
H Rosasite(Cu,Zn)2(CO3)(OH)2
H Limonite(Fe,O,OH,H2O)
CCarbon
C AzuriteCu3(CO3)2(OH)2
C MalachiteCu2(CO3)(OH)2
C CalciteCaCO3
C Aurichalcite(Zn,Cu)5(CO3)2(OH)6
C CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
C MeioniteCa4Al6Si6O24CO3
C Rosasite(Cu,Zn)2(CO3)(OH)2
OOxygen
O ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
O AzuriteCu3(CO3)2(OH)2
O MalachiteCu2(CO3)(OH)2
O CupriteCu2O
O ChrysocollaCu2-xAlx(H2-xSi2O5)(OH)4 · nH2O
O TenoriteCuO
O ParamelaconiteCu21+Cu22+O3
O CalciteCaCO3
O Aurichalcite(Zn,Cu)5(CO3)2(OH)6
O CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
O AntleriteCu3(SO4)(OH)4
O FelsőbányaiteAl4(SO4)(OH)10 · 4H2O
O Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2
O ParatacamiteCu3(Cu,Zn)(OH)6Cl2
O HalloysiteAl2(Si2O5)(OH)4
O HydrobasaluminiteAl4(SO4)(OH)10 · 12-36H2O
O AnglesitePbSO4
O MeioniteCa4Al6Si6O24CO3
O Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2
O WollastoniteCaSiO3
O Rosasite(Cu,Zn)2(CO3)(OH)2
O Limonite(Fe,O,OH,H2O)
NaSodium
Na Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2
Na MeioniteCa4Al6Si6O24CO3
MgMagnesium
Mg Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2
Mg Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2
AlAluminium
Al ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
Al ChrysocollaCu2-xAlx(H2-xSi2O5)(OH)4 · nH2O
Al CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
Al FelsőbányaiteAl4(SO4)(OH)10 · 4H2O
Al HalloysiteAl2(Si2O5)(OH)4
Al HydrobasaluminiteAl4(SO4)(OH)10 · 12-36H2O
Al MeioniteCa4Al6Si6O24CO3
SiSilicon
Si ChrysocollaCu2-xAlx(H2-xSi2O5)(OH)4 · nH2O
Si Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2
Si HalloysiteAl2(Si2O5)(OH)4
Si MeioniteCa4Al6Si6O24CO3
Si Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2
Si WollastoniteCaSiO3
SSulfur
S ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
S CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
S AntleriteCu3(SO4)(OH)4
S FelsőbányaiteAl4(SO4)(OH)10 · 4H2O
S HydrobasaluminiteAl4(SO4)(OH)10 · 12-36H2O
S AnglesitePbSO4
S BorniteCu5FeS4
S ChalcociteCu2S
S ChalcopyriteCuFeS2
S PyriteFeS2
S MeioniteCa4Al6Si6O24CO3
ClChlorine
Cl ParatacamiteCu3(Cu,Zn)(OH)6Cl2
Cl MeioniteCa4Al6Si6O24CO3
CaCalcium
Ca CalciteCaCO3
Ca Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2
Ca MeioniteCa4Al6Si6O24CO3
Ca Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2
Ca WollastoniteCaSiO3
FeIron
Fe BorniteCu5FeS4
Fe ChalcopyriteCuFeS2
Fe PyriteFeS2
Fe Limonite(Fe,O,OH,H2O)
CuCopper
Cu ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
Cu AzuriteCu3(CO3)2(OH)2
Cu MalachiteCu2(CO3)(OH)2
Cu CupriteCu2O
Cu ChrysocollaCu2-xAlx(H2-xSi2O5)(OH)4 · nH2O
Cu TenoriteCuO
Cu ParamelaconiteCu21+Cu22+O3
Cu Aurichalcite(Zn,Cu)5(CO3)2(OH)6
Cu CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
Cu AntleriteCu3(SO4)(OH)4
Cu ParatacamiteCu3(Cu,Zn)(OH)6Cl2
Cu BorniteCu5FeS4
Cu ChalcociteCu2S
Cu ChalcopyriteCuFeS2
Cu Rosasite(Cu,Zn)2(CO3)(OH)2
Cu CopperCu
ZnZinc
Zn Aurichalcite(Zn,Cu)5(CO3)2(OH)6
Zn ParatacamiteCu3(Cu,Zn)(OH)6Cl2
Zn Rosasite(Cu,Zn)2(CO3)(OH)2
AgSilver
Ag SilverAg
PbLead
Pb AnglesitePbSO4

References

Sort by

Year (asc) Year (desc) Author (A-Z) Author (Z-A)
The Resources of Arizona - A Manual of Reliable Information Concerning the Territory, compiled by Patrick Hamilton (1881), Scottsdale, Arizona: 41.
Dana, E.S. (1892) System of Mineralogy, 6th. Edition, New York: 1093.
Ransome, F.L. (1904 a), The geology and ore deposits of the Bisbee quadrangle, Arizona: USGS Professional Paper 21, 168 p., 3 sheets, scales 1:12,000 and 1:62,500: 111.
Bonillas, Y.S., Tenny, and Feuchere (1917), Geology of the Warren mining district: A.I.M.E. Transactions: 55: 325, 328, 337.
Schwartz, G.M. & C.F. Park, Jr. (1932), A microscopic study of ores from the Campbell Mine, Bisbee, Arizona, Economic Geology: 27: 39-51.
Keith, Stanton B. (1973), Arizona Bureau of Mines Bull. 187, Index of Mining Properties in Cochise County, Arizona: 87 (Table 4).
Graeme, R. (1993), Bisbee revisited, Mineralogical Record: 24: 421-436.
Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 115, 129, 154, 177, 320, 372.
U.S. Bureau of Mines (1995), Minerals Availability System/Mineral Industry Location System (MAS/MILS), U.S. Bureau of Mines, file ID #0040030627.
USGS (2005), Mineral Resources Data System (MRDS): U.S. Geological Survey, Reston, Virginia, loc. file ID #10046241 & 10112776.
Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 6.
USGS MRDS ID #M241106.

USGS MRDS Record:10046241

Mindat Articles

Bisbee Arizona Chalcoalumite Story by Rolf Luetcke


Localities in this Region

  • Arizona
    • Cochise County
      • Bisbee
        • Queen Hill
          • Copper Queen Mine (Halero Mine)

Other Regions, Features and Areas containg this locality

North America
North America PlateTectonic Plate

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