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Grand View Mine (Last Chance Mine; Canyon Copper Mine; Grand Canyon Mine), Horseshoe Mesa, Grand View Mining District, Grand Canyon, Coconino County, Arizona, USAi
Regional Level Types
Grand View Mine (Last Chance Mine; Canyon Copper Mine; Grand Canyon Mine)Mine
Horseshoe MesaMesa
Grand View Mining DistrictMining District
Grand CanyonCanyon
Coconino CountyCounty
ArizonaState
USACountry

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Key
Latitude & Longitude (WGS84):
36° 1' 1'' North , 111° 58' 36'' West
Latitude & Longitude (decimal):
Locality type:
Nearest Settlements:
PlacePopulationDistance
Tusayan567 (2017)14.3km
Grand Canyon1,460 (2018)15.2km
Grand Canyon Village1,550 (2006)16.3km
Valle832 (2011)43.0km
Other/historical names associated with this locality:
No. 1 Pat claim 3591; No. 5 Pat claim 3592a; No. 4 Pat claim 3592a


A former Cu-U occurrence/mine located in the NE¼ sec. 5, T30N, R4E, G&SRM, 0.8 km (0.5 mile) SSE of Horseshoe Mesa (coordinates of record) (Vishnu Temple 15 minute topo map), N of Grandview Point, South rim, Grand Canyon, on National Park Service land (Grand Canyon National Park). The Grand View Mine and (this) Last Chance Mine are the same (Mineralogy of Arizona, 3rd. ed.). Discovered 1890. First production was 1893 and the last was 1916. Operated by the Canyon Copper Company from 1901 to 1908. William Randolph Hearst purchased the below-rim property in 1913. The ore was hauled by mule to the top of the canyon. The USGS MRDS database stated accuracy for this locality is 100 meters.

The Grandview Mine officially closed in 1907 but went through a series of owners until William Randolph Hearst acquired the Grandview Mine. Hearst sold the property to the United States National Park Service in 1940 and it is now part of the Grand Canyon National Park. The Grandview Mine is now a roost for protected bat species including Townsend’s Big-eared Bat (Corynorthinus townsendii).

Mineralization is a Cu-U deposit secondary Cu minerals with gangue species in a breccia zone along a monocline flexure in Shea basalt hosted in the Navajo sandstone. Controls for ore emplacement included a breccia zone along a monocline flexure. Local alteration involves the Redwall limestone which is bleached, brecciated and marbleized. The Grandview monocline lies along the WNW-trending Cremation fault. The presence of kaolinite and fully hydrated zeunerite suggest formation temperature under 70°C. Local rocks include Mississippian, Devonian, and Cambrian sedimentary rocks.

The ore body is a pipe-like body hosted in the upper Redwall Limestone and the basal Supai Formation. U minerals are associated with limonite, copper carbonates, silicates and sulfate minerals, also minor pyrite and other sulfides along brecciated, bleached and marbleized Redwall Limestone. Metazeunerite/zeunerite are found in limonitic, gossan-type ore. Radiation is 20,000 counts per second.

Local geologic structures include the Grandview Monocline that lies along the WNW-trending Cremation Fault.

Analysis test results: 2.764% e U3O8; 1.892% U3O8.

Production statistics for the period 1893 to 1900 are unknown. Production during the period 1901 to 1908 was 907,402 pounds of Cu, 14,1103 (14,110 ??) pounds of Ag, and 1,628 tons ___??.

Select Mineral List Type

Standard Detailed Gallery Strunz Dana Chemical Elements

Commodity List

This is a list of exploitable or exploited mineral commodities recorded at this locality.


Mineral List


32 valid minerals. 1 (TL) - type locality of valid minerals. 1 erroneous literature entry.

Detailed Mineral List:

Adamite
Formula: Zn2(AsO4)(OH)
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 102; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Anglesite
Formula: PbSO4
Reference: Michael Cline collection
Aurichalcite
Formula: (Zn,Cu)5(CO3)2(OH)6
Description: Occurs in a fault zone in Redwall Limestone.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 123, 127; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Azurite
Formula: Cu3(CO3)2(OH)2
Habit: Short prismatic
Description: Occurs on clay & in vugs in sandstone
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 125; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Baryte
Formula: BaSO4
Description: Occurs in a fault zone in Redwall Limestone.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 127; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
'Bisbeeite'
Formula: (Cu,Mg)SiO3·nH2O
Habit: Rogers (1922): minute imperfect spherulites of acicular crystals
Description: Gordon (1923) corrects Rogers' (1922) "Bisbeeite" to "Cyanotrichite".
Reference: Rogers, A.F. (1922) The optical properties and morphology of bisbeeite. American Mineralogist 7, 153-154.; Gordon, S.G. (1923) Recently described 'bisbeeite' from the Grand Canyon is cyanotrichite. American Mineralogist 8, 92-93.
Brochantite
Formula: Cu4(SO4)(OH)6
Habit: Acicular crystals in radiating groups & shorter, prismatic crystals
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 146, 162; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Carbonatecyanotrichite
Formula: Cu4Al2(CO3,SO4)(OH)12 · 2H2O
Reference: Colchester, D. M., Klish, D. R., Leverett, P. & Williams, P. A. (2008): Grandviewite, Cu3Al9(SO4)2(OH)29, a new mineral from the Grandview Mine, Arizona, USA. Australian Journal of Mineralogy, 14, 51-54.
Cerussite
Formula: PbCO3
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 157.
Chalcanthite
Formula: CuSO4 · 5H2O
Description: Occurs as cross-fiber veinlets associated with clay.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 160; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Chalcoalumite
Formula: CuAl4(SO4)(OH)12 · 3H2O
Colour: Sky-blue to greenish
Description: Occurs as botryoidal crusts on limonite.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 162; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Chalcocite
Formula: Cu2S
Reference: Rogers, A.F. (1922) The optical properties and morphology of bisbeeite. American Mineralogist: 7: 153-154.; Leicht, W.C. (1971) Minerals of the Grandview Mine. Mineralogical Record: 2: 214-221.; Anthony, J.W., et al. (1995) Mineralogy of Arizona, 3rd. ed.: 162.
Chalcophyllite
Formula: Cu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
Reference: Michael Cline collection, confirmed via Raman spectroscopy at the University of Arizona 03/2010
Covellite
Formula: CuS
Habit: Hexagonal Plates
Colour: Blue, Purple, Irridescent
Description: Single specimen, found on mine floor. Sharp, Irridescent, Hexagonal plates to about 1mm, both interlocking and isolated. Associated with unknown green species.
Reference: Michael Cline Collection
Cyanotrichite
Formula: Cu4Al2(SO4)(OH)12 · 2H2O
Habit: Radiating crystals
Description: Crystals; also occurs as massive nodules & veins closely associated with brochantite.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 146, 198; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221; Rogers, A.F. (1922), The optical properties and morphology of bisbeeite, Am.Min.: 7: 153-154; Gordon, S.G. (1923), Recently described 'bisbeeite' from the Grand Canyon is cyanotrichite, Am.Min.: 8: 92-93; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 65.
Devilline
Formula: CaCu4(SO4)2(OH)6 · 3H2O
Habit: Lath-like
Colour: Bluish-green
Description: Crusts.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 201-202; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Dickite
Formula: Al2(Si2O5)(OH)4
Reference: Michael Cline collection
Grandviewite (TL)
Formula: Cu3Al9(SO4)2(OH)29
Type Locality:
Reference: Australian J. Mineralogy 14(2),51-54(2008)
Gypsum
Formula: CaSO4 · 2H2O
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 201-202; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Hemimorphite
Formula: Zn4Si2O7(OH)2 · H2O
Reference: Dr Marcus Origlieri
Kaolinite
Formula: Al2(Si2O5)(OH)4
Reference: Leicht, W.C. (1971), Minerals of the Grandview Mine, Min.Rec.: 2(5): 214-221.
Langite
Formula: Cu4(SO4)(OH)6 · 2H2O
Colour: Greenish
Description: As silky crusts lining cavities.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 271; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
'Limonite'
Formula: (Fe,O,OH,H2O)
Reference: Leicht, W.C. (1971), Minerals of the Grandview Mine, Min.Rec.: 2(5): 214-221.
Malachite
Formula: Cu2(CO3)(OH)2
Description: Botryoidal crusts coating limestone & in fissures in clay.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 125, 285; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Metazeunerite
Formula: Cu(UO2)2(AsO4)2 · 8H2O
Habit: Tabular
Colour: Leek-green
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 297, 365; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Olivenite
Formula: Cu2(AsO4)(OH)
Habit: Short prismatic; acicular groups
Colour: Olive-green; lighter olive-green
Description: Occurs on altered metazeunerite.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 162, 297, 316, 365; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Osarizawaite
Formula: Pb(Al2Cu2+)(SO4)2(OH)6
Reference: Michael Cline collection
Parnauite
Formula: Cu9(AsO4)2(SO4)(OH)10 · 7H2O
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 322.
Pharmacosiderite
Formula: KFe3+4(AsO4)3(OH)4 · 6-7H2O
Reference: Michael Cline collection; Michael Cline collection, confirmed via Raman spectroscopy at the University of Arizona 03/2010
Philipsbornite
Formula: PbAl3(AsO4)(AsO3OH)(OH)6
Reference: Michael Cline collection
Scorodite
Formula: Fe3+AsO4 · 2H2O
Colour: Light brown to gray
Description: Occurs as mammillary masses with radiating internal structure.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 102, 162, 297, 365; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Smithsonite
Formula: ZnCO3
Description: Occurs in small amounts lining vugs in clay in limestone.
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 374; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.
Spangolite
Formula: Cu6Al(SO4)(OH)12Cl · 3H2O
Reference: Dr Marcus Origlieri
'UM1971-01-AsO:CuFeS'
Formula: Cu-Fe-As-S-O
Reference: Leicht, W.C. (1971): Minerals of the Grandview Mine. Mineral. Rec.: 2: 214-221; in: Fleischer, M. (1972): New mineral names. American Mineralogist: 57: 1003-1006
Zeunerite
Formula: Cu(UO2)2(AsO4)2 · 12H2O
Habit: Exceptional crystals to ¼ inch on edge (0.8 cm)
Reference: Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd. ed.: 102, 162, 297, 429; Leicht, W.C. (1971), Minerals of the Grandview mine, Min.Rec.: 2: 214-221.

Gallery:

List of minerals arranged by Strunz 10th Edition classification

Group 2 - Sulphides and Sulfosalts
Chalcocite2.BA.05Cu2S
Covellite2.CA.05aCuS
Group 5 - Nitrates and Carbonates
Aurichalcite5.BA.15(Zn,Cu)5(CO3)2(OH)6
Azurite5.BA.05Cu3(CO3)2(OH)2
Cerussite5.AB.15PbCO3
Malachite5.BA.10Cu2(CO3)(OH)2
Smithsonite5.AB.05ZnCO3
Group 7 - Sulphates, Chromates, Molybdates and Tungstates
Anglesite7.AD.35PbSO4
Baryte7.AD.35BaSO4
Brochantite7.BB.25Cu4(SO4)(OH)6
Carbonatecyanotrichite7.DE.10Cu4Al2(CO3,SO4)(OH)12 · 2H2O
Chalcanthite7.CB.20CuSO4 · 5H2O
Chalcoalumite7.DD.75CuAl4(SO4)(OH)12 · 3H2O
Cyanotrichite7.DE.10Cu4Al2(SO4)(OH)12 · 2H2O
Devilline7.DD.30CaCu4(SO4)2(OH)6 · 3H2O
Grandviewite (TL)7.BB.60Cu3Al9(SO4)2(OH)29
Gypsum7.CD.40CaSO4 · 2H2O
Langite7.DD.10Cu4(SO4)(OH)6 · 2H2O
Osarizawaite7.BC.10Pb(Al2Cu2+)(SO4)2(OH)6
Spangolite7.DD.15Cu6Al(SO4)(OH)12Cl · 3H2O
Group 8 - Phosphates, Arsenates and Vanadates
Adamite8.BB.30Zn2(AsO4)(OH)
Chalcophyllite8.DF.30Cu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
Metazeunerite8.EB.10Cu(UO2)2(AsO4)2 · 8H2O
Olivenite8.BB.30Cu2(AsO4)(OH)
Parnauite8.DF.35Cu9(AsO4)2(SO4)(OH)10 · 7H2O
Pharmacosiderite8.DK.10KFe3+4(AsO4)3(OH)4 · 6-7H2O
Philipsbornite8.BL.10PbAl3(AsO4)(AsO3OH)(OH)6
Scorodite8.CD.10Fe3+AsO4 · 2H2O
Zeunerite8.EB.05Cu(UO2)2(AsO4)2 · 12H2O
Group 9 - Silicates
Dickite9.ED.05Al2(Si2O5)(OH)4
Hemimorphite9.BD.10Zn4Si2O7(OH)2 · H2O
Kaolinite9.ED.05Al2(Si2O5)(OH)4
Unclassified Minerals, Rocks, etc.
'Bisbeeite' ?-(Cu,Mg)SiO3·nH2O
'Limonite'-(Fe,O,OH,H2O)
'UM1971-01-AsO:CuFeS'-Cu-Fe-As-S-O

List of minerals arranged by Dana 8th Edition classification

Group 2 - SULFIDES
AmBnXp, with (m+n):p = 2:1
Chalcocite2.4.7.1Cu2S
AmXp, with m:p = 1:1
Covellite2.8.12.1CuS
Group 14 - ANHYDROUS NORMAL CARBONATES
A(XO3)
Cerussite14.1.3.4PbCO3
Smithsonite14.1.1.6ZnCO3
Group 16a - ANHYDROUS CARBONATES CONTAINING HYDROXYL OR HALOGEN
Azurite16a.2.1.1Cu3(CO3)2(OH)2
Malachite16a.3.1.1Cu2(CO3)(OH)2
Aurichalcite16a.4.2.1(Zn,Cu)5(CO3)2(OH)6
Group 16b - HYDRATED CARBONATES CONTAINING HYDROXYL OR HALOGEN
Carbonatecyanotrichite16b.7.7.1Cu4Al2(CO3,SO4)(OH)12 · 2H2O
Group 28 - ANHYDROUS ACID AND NORMAL SULFATES
AXO4
Anglesite28.3.1.3PbSO4
Baryte28.3.1.1BaSO4
Group 29 - HYDRATED ACID AND NORMAL SULFATES
AXO4·xH2O
Chalcanthite29.6.7.1CuSO4 · 5H2O
Gypsum29.6.3.1CaSO4 · 2H2O
Group 30 - ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
(AB)m(XO4)pZq, where m:p>2:1
Brochantite30.1.3.1Cu4(SO4)(OH)6
Grandviewite (TL)30.1.19.Cu3Al9(SO4)2(OH)29
(AB)2(XO4)Zq
Osarizawaite30.2.4.4Pb(Al2Cu2+)(SO4)2(OH)6
Group 31 - HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
(AB)m(XO4)pZq·xH2O, where m:p > 6:1
Spangolite31.1.5.1Cu6Al(SO4)(OH)12Cl · 3H2O
(AB)6(XO4)Zq·xH2O
Cyanotrichite31.2.1.1Cu4Al2(SO4)(OH)12 · 2H2O
(AB)5(XO4)Zq·xH2O
Chalcoalumite31.3.1.1CuAl4(SO4)(OH)12 · 3H2O
(AB)4(XO4)Zq·xH2O
Langite31.4.3.1Cu4(SO4)(OH)6 · 2H2O
(AB)5(XO4)2Zq·xH2O
Devilline31.6.1.1CaCu4(SO4)2(OH)6 · 3H2O
Group 40 - HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
AB2(XO4)2·xH2O, containing (UO2)2+
Metazeunerite40.2a.14.2Cu(UO2)2(AsO4)2 · 8H2O
Zeunerite40.2a.14.1Cu(UO2)2(AsO4)2 · 12H2O
(AB)5(XO4)2·xH2O
Scorodite40.4.1.3Fe3+AsO4 · 2H2O
Group 41 - ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
A2(XO4)Zq
Adamite41.6.6.3Zn2(AsO4)(OH)
Olivenite41.6.6.1Cu2(AsO4)(OH)
Group 42 - HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
(AB)2(XO4)Zq·xH2O
Philipsbornite42.7.4.2PbAl3(AsO4)(AsO3OH)(OH)6
(AB)5(XO4)3Zq·xH2O
Pharmacosiderite42.8.1a.1KFe3+4(AsO4)3(OH)4 · 6-7H2O
Group 43 - COMPOUND PHOSPHATES, ETC.
Hydrated Compound Phosphates, etc·, Containing Hydroxyl or Halogen
Chalcophyllite43.5.14.1Cu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
Parnauite43.5.13.1Cu9(AsO4)2(SO4)(OH)10 · 7H2O
Group 56 - SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
Si2O7 Groups and O, OH, F, and H2O with cations in [4] coordination
Hemimorphite56.1.2.1Zn4Si2O7(OH)2 · H2O
Group 71 - PHYLLOSILICATES Sheets of Six-Membered Rings
Sheets of 6-membered rings with 1:1 layers
Dickite71.1.1.1Al2(Si2O5)(OH)4
Unclassified Minerals, Mixtures, etc.
'Bisbeeite' ?-(Cu,Mg)SiO3·nH2O
Kaolinite-Al2(Si2O5)(OH)4
'Limonite'-(Fe,O,OH,H2O)
'UM1971-01-AsO:CuFeS'-Cu-Fe-As-S-O

List of minerals for each chemical element

HHydrogen
H GrandviewiteCu3Al9(SO4)2(OH)29
H AdamiteZn2(AsO4)(OH)
H ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
H CyanotrichiteCu4Al2(SO4)(OH)12 · 2H2O
H ZeuneriteCu(UO2)2(AsO4)2 · 12H2O
H KaoliniteAl2(Si2O5)(OH)4
H Limonite(Fe,O,OH,H2O)
H BrochantiteCu4(SO4)(OH)6
H ScoroditeFe3+AsO4 · 2H2O
H OliveniteCu2(AsO4)(OH)
H MetazeuneriteCu(UO2)2(AsO4)2 · 8H2O
H GypsumCaSO4 · 2H2O
H DevillineCaCu4(SO4)2(OH)6 · 3H2O
H LangiteCu4(SO4)(OH)6 · 2H2O
H ParnauiteCu9(AsO4)2(SO4)(OH)10 · 7H2O
H AzuriteCu3(CO3)2(OH)2
H MalachiteCu2(CO3)(OH)2
H Aurichalcite(Zn,Cu)5(CO3)2(OH)6
H ChalcanthiteCuSO4 · 5H2O
H CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
H PharmacosideriteKFe43+(AsO4)3(OH)4 · 6-7H2O
H OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6
H PhilipsbornitePbAl3(AsO4)(AsO3OH)(OH)6
H DickiteAl2(Si2O5)(OH)4
H ChalcophylliteCu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
H SpangoliteCu6Al(SO4)(OH)12Cl · 3H2O
H HemimorphiteZn4Si2O7(OH)2 · H2O
H Bisbeeite(Cu,Mg)SiO3·nH2O
CCarbon
C SmithsoniteZnCO3
C AzuriteCu3(CO3)2(OH)2
C MalachiteCu2(CO3)(OH)2
C Aurichalcite(Zn,Cu)5(CO3)2(OH)6
C CerussitePbCO3
C CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
OOxygen
O GrandviewiteCu3Al9(SO4)2(OH)29
O AdamiteZn2(AsO4)(OH)
O ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
O CyanotrichiteCu4Al2(SO4)(OH)12 · 2H2O
O ZeuneriteCu(UO2)2(AsO4)2 · 12H2O
O KaoliniteAl2(Si2O5)(OH)4
O Limonite(Fe,O,OH,H2O)
O BrochantiteCu4(SO4)(OH)6
O ScoroditeFe3+AsO4 · 2H2O
O OliveniteCu2(AsO4)(OH)
O MetazeuneriteCu(UO2)2(AsO4)2 · 8H2O
O GypsumCaSO4 · 2H2O
O DevillineCaCu4(SO4)2(OH)6 · 3H2O
O LangiteCu4(SO4)(OH)6 · 2H2O
O ParnauiteCu9(AsO4)2(SO4)(OH)10 · 7H2O
O SmithsoniteZnCO3
O AzuriteCu3(CO3)2(OH)2
O MalachiteCu2(CO3)(OH)2
O Aurichalcite(Zn,Cu)5(CO3)2(OH)6
O BaryteBaSO4
O CerussitePbCO3
O ChalcanthiteCuSO4 · 5H2O
O CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
O PharmacosideriteKFe43+(AsO4)3(OH)4 · 6-7H2O
O OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6
O AnglesitePbSO4
O PhilipsbornitePbAl3(AsO4)(AsO3OH)(OH)6
O DickiteAl2(Si2O5)(OH)4
O ChalcophylliteCu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
O SpangoliteCu6Al(SO4)(OH)12Cl · 3H2O
O HemimorphiteZn4Si2O7(OH)2 · H2O
O UM1971-01-AsO:CuFeSCu-Fe-As-S-O
O Bisbeeite(Cu,Mg)SiO3·nH2O
MgMagnesium
Mg Bisbeeite(Cu,Mg)SiO3·nH2O
AlAluminium
Al GrandviewiteCu3Al9(SO4)2(OH)29
Al ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
Al CyanotrichiteCu4Al2(SO4)(OH)12 · 2H2O
Al KaoliniteAl2(Si2O5)(OH)4
Al CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
Al OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6
Al PhilipsbornitePbAl3(AsO4)(AsO3OH)(OH)6
Al DickiteAl2(Si2O5)(OH)4
Al ChalcophylliteCu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
Al SpangoliteCu6Al(SO4)(OH)12Cl · 3H2O
SiSilicon
Si KaoliniteAl2(Si2O5)(OH)4
Si DickiteAl2(Si2O5)(OH)4
Si HemimorphiteZn4Si2O7(OH)2 · H2O
Si Bisbeeite(Cu,Mg)SiO3·nH2O
SSulfur
S GrandviewiteCu3Al9(SO4)2(OH)29
S CovelliteCuS
S ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
S CyanotrichiteCu4Al2(SO4)(OH)12 · 2H2O
S BrochantiteCu4(SO4)(OH)6
S ChalcociteCu2S
S GypsumCaSO4 · 2H2O
S DevillineCaCu4(SO4)2(OH)6 · 3H2O
S LangiteCu4(SO4)(OH)6 · 2H2O
S ParnauiteCu9(AsO4)2(SO4)(OH)10 · 7H2O
S BaryteBaSO4
S ChalcanthiteCuSO4 · 5H2O
S CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
S OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6
S AnglesitePbSO4
S ChalcophylliteCu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
S SpangoliteCu6Al(SO4)(OH)12Cl · 3H2O
S UM1971-01-AsO:CuFeSCu-Fe-As-S-O
ClChlorine
Cl SpangoliteCu6Al(SO4)(OH)12Cl · 3H2O
KPotassium
K PharmacosideriteKFe43+(AsO4)3(OH)4 · 6-7H2O
CaCalcium
Ca GypsumCaSO4 · 2H2O
Ca DevillineCaCu4(SO4)2(OH)6 · 3H2O
FeIron
Fe Limonite(Fe,O,OH,H2O)
Fe ScoroditeFe3+AsO4 · 2H2O
Fe PharmacosideriteKFe43+(AsO4)3(OH)4 · 6-7H2O
Fe UM1971-01-AsO:CuFeSCu-Fe-As-S-O
CuCopper
Cu GrandviewiteCu3Al9(SO4)2(OH)29
Cu CovelliteCuS
Cu ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2O
Cu CyanotrichiteCu4Al2(SO4)(OH)12 · 2H2O
Cu ZeuneriteCu(UO2)2(AsO4)2 · 12H2O
Cu BrochantiteCu4(SO4)(OH)6
Cu OliveniteCu2(AsO4)(OH)
Cu ChalcociteCu2S
Cu MetazeuneriteCu(UO2)2(AsO4)2 · 8H2O
Cu DevillineCaCu4(SO4)2(OH)6 · 3H2O
Cu LangiteCu4(SO4)(OH)6 · 2H2O
Cu ParnauiteCu9(AsO4)2(SO4)(OH)10 · 7H2O
Cu AzuriteCu3(CO3)2(OH)2
Cu MalachiteCu2(CO3)(OH)2
Cu Aurichalcite(Zn,Cu)5(CO3)2(OH)6
Cu ChalcanthiteCuSO4 · 5H2O
Cu CarbonatecyanotrichiteCu4Al2(CO3,SO4)(OH)12 · 2H2O
Cu OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6
Cu ChalcophylliteCu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
Cu SpangoliteCu6Al(SO4)(OH)12Cl · 3H2O
Cu UM1971-01-AsO:CuFeSCu-Fe-As-S-O
Cu Bisbeeite(Cu,Mg)SiO3·nH2O
ZnZinc
Zn AdamiteZn2(AsO4)(OH)
Zn SmithsoniteZnCO3
Zn Aurichalcite(Zn,Cu)5(CO3)2(OH)6
Zn HemimorphiteZn4Si2O7(OH)2 · H2O
AsArsenic
As AdamiteZn2(AsO4)(OH)
As ZeuneriteCu(UO2)2(AsO4)2 · 12H2O
As ScoroditeFe3+AsO4 · 2H2O
As OliveniteCu2(AsO4)(OH)
As MetazeuneriteCu(UO2)2(AsO4)2 · 8H2O
As ParnauiteCu9(AsO4)2(SO4)(OH)10 · 7H2O
As PharmacosideriteKFe43+(AsO4)3(OH)4 · 6-7H2O
As PhilipsbornitePbAl3(AsO4)(AsO3OH)(OH)6
As ChalcophylliteCu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
As UM1971-01-AsO:CuFeSCu-Fe-As-S-O
BaBarium
Ba BaryteBaSO4
PbLead
Pb CerussitePbCO3
Pb OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6
Pb AnglesitePbSO4
Pb PhilipsbornitePbAl3(AsO4)(AsO3OH)(OH)6
UUranium
U ZeuneriteCu(UO2)2(AsO4)2 · 12H2O
U MetazeuneriteCu(UO2)2(AsO4)2 · 8H2O

References

Sort by

Year (asc) Year (desc) Author (A-Z) Author (Z-A) In-text Citation No.
Emmons, S.F. (1905), Contributions to Economic Geology, USGS Bulletin 260: 221-232.
Rogers, A.F. (1922) The optical properties and morphology of bisbeeite. American Mineralogist: 7: 153-154.
Gordon, S.G. (1923) Recently described 'bisbeeite' from the Grand Canyon is cyanotrichite. American Mineralogist: 8: 92-93.
Galbraith, F.W. and Brennan, D.J. (1959) Minerals of Arizona: 65.
Moore, R.T. and Roseveare, G.H. (1969) Mineral and water resources of Arizona: U.S. 90th Congress, 2nd Session, Senate Committee on Interior and Insular Affairs. Arizona Bureau of Mines Bulletin 180: 257, 259.
Roseveare, G.H. (1969) in USGS & Arizona Bureau of Mines, and U.S. Bureau Of Reclamation, Mineral and water resources of Arizona, Arizona Bureau of Mines Bulletin: 180.
Roseveare, G.H. (1969), in USGS, Arizona Bureau of Mines, and US Bureau of Reclamation 1969, Mineral and water resources of Arizona, Arizona Bureau of Mines Bulletin 180.
Leicht, W.C. (1971) Minerals of the Grandview Mine. Mineralogical Record: 2: 214-221.
Breed, W.J. and Roat, Ed (1974) Geology of the Grand Canyon: 172, 174.
Scarborough, Robert B. (1981), Radioactive occurrences and uranium production in Arizona, Arizona Bureau of Geology and Mineral Technology Report for U.S. Department of Energy (Atomic Energy Commission), GJBX-143. RME-2071: 150.
Blair, Gerry (1992), The Rockhound's Guide to Arizona: Helena, MT, Falcon Press.
Niemuth, N.J. and Phillips, K.A. (1992) Copper Oxide Resources. Arizona Department of Mines & Mineral Resources Open File Report 92-10: 6 (Table 1).
Wenrich, Karen J., et al. (1992) USGS Bulletin 1683-D: D2.
Anthony, J.W., et al. (1995) Mineralogy of Arizona, 3rd. ed.: 102, 123, 125, 127, 146, 157, 160, 162, 198, 201-202, 271, 285, 297, 316, 322, 365, 374, 429.
U.S. Bureau of Mines (1995), Minerals Availability System/Mineral Industry Location System (MAS/MILS), U.S. Bureau of Mines, file ID #0040050159.
USGS (2005), Mineral Resources Data System (MRDS): U.S. Geological Survey, Reston, Virginia, deposit ID #10102468 & 10161170.
Unknown Author (2009) Grandview and Last Chance Mines – Bat gating project.
Arizona Department of Mineral Resources, Last Chance Mine file.
Bureau of Land Management Mining District sheet No. 102.
U.S. Atomic Energy Commission, USAEC Preliminary Report 172-479: 57.
USGS MRDS ID #M002801.
USGS Minerals Yearbooks 1902-1967.
USGS Vishnu Temple, Arizona, quadrangle topo map.
USGS crib #W016025.

Other Databases

Link to USGS MRDS:10161170

External Links

Minegates.com

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