 | Roper, A. J., Leverett, P., Murphy, T. D., Williams, P. A., Hibbs, D. E. (2015) Klebelsbergite, Sb4O4SO4(OH)2: Stability relationships, formation in Nature, and refinement of its structure. American Mineralogist, 100 (2) 602-607 doi:10.2138/am-2015-4953 | Journal (article/letter/editorial) | | Mineralogist, Volume 100, pages 602–607, 2015 Klebelsbergite, Sb4O4SO4(OH)2: Stability relationships, formation...to be fully understood. Stability studies of klebelsbergite have been undertaken to better understand its...and the data obtained used to derive ∆Gfθ (klebelsbergite, s, 298.15 K) = –2056.4 ± 5.0 kJ/mol. Solubility...single-crystal X‑ray structure of synthetic klebelsbergite has been determined 293 K and is essentially...125(5)°, respectively. Keywords: Klebelsbergite, antimony, antimony sulfate, solubility, stability, structure |  | | Journal (issue) | | .... 5 by C. S. Stolburg Minerals of the Pereta mine, Tuscany, Italy ..................................and M. Tazzini Alteration minerals of the Cetine mine, Tuscany, It a ly ................................ Sabelli and G. Brizzi Siegenite from the Buick mine, Bixby, Missouri .................................years he was Resident Geologist at the Copper Queen mine until Phelps Dodge Cor poration closed all the...transferred to Ajo as Mine Planning Engineer and later promoted to General Mine Foreman. He left Ajo in |  | Roper, Adam J., Leverett, Peter, Murphy, Timothy D., Williams, Peter A. (2014) The stability of onoratoite, Sb8O11Cl2, in the supergene environment. Mineralogical Magazine, 78 (7) 1671-1675 doi:10.1180/minmag.2014.078.7.10 | Journal (article/letter/editorial) | | Calculations involving sénarmontite, Sb2O3, klebelsbergite, Sb4O4SO4(OH)2 and schafarzikite, FeSb2O4,...supergene environment. K EY WORDS : onoratoite, antimony oxychloride, solubility, stability, chemical mineralogy...simple sulfates coquandite, Sb6O8SO4 ·H2O and klebelsbergite, Sb4O4SO4(OH)2, do occur in a small number...deposits, but are rare. Stability data for klebelsbergite have been reported recently (Roper et al.,...Valentinite Tripuhyite Schafarzikite Onoratoite Klebelsbergite SO24 (aq) H2O(l) Fe2+(aq) Fe3+(aq) Cl (aq) |  | Sabelli, C., Orlandi, P., Vezzalini, G. (1992) Coquandite, Sb6O8(SO4)H2O, a new mineral from Pereta, Tuscany, Italy, and two other localities. Mineralogical Magazine, 56 (385) 599-603 doi:10.1180/minmag.1992.056.385.16 | Journal (article/letter/editorial) | | 41100 Modena, Italy Abstract Coaquandite, a new antimony oxy-sulphate hydrate, occurs as spheroidal knobs...stibnite at the Pereta mine, Tuscany, Italy; it is associated with klebelsbergite, peretaite, valentinite...been found at the Cetine mine, Tuscany, Italy, and at the Lucky Knock mine, Tonasket, Okanogan County...Pereta stibnite mine, Tuscany, Italy. Two other antimony-bearing species, klebelsbergite (Cipriani et al...were also found in this mine. Coquandite is the third naturally occurring antimony oxy-sulphate known, |  | | Report (issue) | | Sb3+ 4 O4 (SO4 )(OH)2 Klebelsbergite c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic...Occurrence: An alteration product of stibnite in antimony deposits. Association: Stibnite, valentinite...in Tuscany, at the Cetine mine, 20 km southwest of Siena; in the Pereta mine, Scansano; and at Micciano...583. (2) Nakai, I. and D.E. Appleman (1980) Klebelsbergite, Sb4 O4 (OH)2 SO4 : redefinition and synthesis...Menchetti, and C. Sabelli (1980) Klebelsbergite and another antimony mineral from Pereta, Tuscany, Italy |  | | Journal (article/letter/editorial) | | 50121 Firenze,Italy Abstract Klebelsbergiteis an antimony sulfate found at Felscibdnia,Hungary, and recently...semiempirical method proposedby North et al- (1968). Klebelsbergite from Felsobdnia, Hungary, was first describedby...Appleman (1980). A secondoccurrenceof klebelsbergite, at Pereta mine (Tuscany,Italy), is reported by Cipriani...0003-004x/80/09 931 MENCHETTI AND SABELLI: KLEBELSBERGITE Table l. Klebelsbergite:fractional atomic...' Discussion The basic structural units of klebelsbergite are the Sb3*-O polyhedra and the SOotetrahedron |  | | Journal (article/letter/editorial) | | Mineralogist, Volume 65, pages 499-505, 1980 Klebelsbergite, Sb.O4(OH)2SO4: redefinition and synthesis...diffraction strongestlines given as 6.19(100), Klebelsbergite was first described by Zsivny in chart with...physical and chemical propmula, tially a basic antimony sulfate, containing a little klebelsbergite.This...Klebelsbergiteoccurs as aggregatesof very small antimony by X-ray fluorescenceanalysis and more platy or...0003-004x/80/0506-0499$02.00 499 500 NAKAI AND APPLEMAN: KLEBELSBERGITE Fig. l. SEM photograph of natural klebelsbergitefrom |  | | Journal (article/letter/editorial) | | de/chemer Secondary antimony minerals: Phases that control the dispersion of antimony in the supergene zone...October 2011 Accepted 8 January 2012 Keywords: Antimony Oxidation Secondary minerals Supergene environment...Oxide zone Pollution a b s t r a c t Secondary antimony minerals play an important role in buffering the...particularly in the supergene zones of Sb-rich ores, mine wastes and other situations where appreciable amounts...1. Introduction Because of the perception that antimony is a toxic element, a significant number of researchers |  | Cipriani, Nicola, Menchetti, Silvio, Orlandi, Paolo, Sabelli, Cesare (1980) Peretaite, CaSb4O4(OH)2(SO4)2·2H2O, a new mineral from Pereta, Tuscany, Italy. American Mineralogist, 65 (9-10) 936-939 | Journal (article/letter/editorial) | | calcium and antimony sulfate mineral, occursas aggregatesof colorless tabular crystalsin the antimony-bearingvein...Introduction In a paper dealing with a new find of klebelsbergite (Cipriani et al., 1980),some of us pointed...is present among the accessory minerals of the antimony-bearing vein at Pereta, Tuscany, ttaly. Further...red from incrustations of valentinite. Unlike klebelsbergite, which was found rather abundantly in the fissuresof...boundary with limestones.The mineral, as well as klebelsbergite,has apparentlybeenformed by the action of sulfuric |  | Damian, , Buzatu, , Apopei, , Szakács, , Denuț, , Iepure, , Bârgăoanu, (2020) Valentinite and Colloform Sphalerite in Epithermal Deposits from Baia Mare Area, Eastern Carpathians. Minerals, 10 (2) 121 doi:10.3390/min10020121 | Journal (article/letter/editorial) | | the Baia Mare area. The Baia Mare metallogenic district of Neogene age occurs in the northwestern part...Me2 O3 and contains small amounts of tin as an antimony substituent. Colloform sphalerite was identified...deposits deposits from from Baia Baia Mare mining district are internationally recognized for the minerals...minerals that were first described Mare mining district are internationally recognized for the minerals that...felsöbanyite felsöbanyite [4], [4], klebelsbergite klebelsbergite [5], [5], dietrichite dietrichite [6] |  | | Journal (article/letter/editorial) | | structure of thick short prisms. W. F. Fossr.c Klebelsbergite Vrcron ZsrvNv: Klebelsbergit, ein neues Mineral...Mineral von Felsiibd.nya (Klebelsbergite a new mineral from Felsiibd,nya). Mor. Term|szeltud. Ertesild...summary. Cmv-rcar, Pnopnnttns: A basic sulfate of antimony with water. Fusible. Dissolves in strong hydrochloric...bastna6siteet d'un min6ral nouveau,Ia lessingite,dansle district minier de Kychtl'rn (Oural). (On the occurrence...bastnaesiteand a new mineral, lessingite,in the district of Kychtym (Urals)). Compt.Renil.Aco.d.Sci. URS |  | | Journal (article/letter/editorial) | | given. Introduction Peretaiteis a new sulfateof antimony and calcium found at Pereta,Tuscany,Italy. Its...quartz, pyrite, calcite, sulfur, gypsum, and other antimony minerals, stibnite, valentinite, kermesite,and...crystal-chemicalrelationshipswith the structuresof klebelsbergite(Menchetti and Sabelli, 1980)and of other synthetic...coordinates,the heavy atoms (mainly the 40 -|> antimony atoms) contribute, in the structure-factor calculation...the sym- the summation of a formula unit of klebelsbergite MENCHETTI AND SABELLI: PERETAITE ATOMIC ARRANGEMENT |  | | Report (issue) | | = n.d. β =∼ 110◦ X-ray Powder Pattern: Cetine mine, Italy. 3.190 (100), 2.677 (60), 3.041 (50), 2.822...(2) 87.54 12.46 Total 100.00 100.00 (1) Cetine mine, Italy; by TGA. (2) Sb8 O11 Cl2 . Occurrence: evaporites...evaporites. An oxidation product of stibnite in an antimony deposit in highly silicified Association: Stibnite...cetineite, peretaite, klebelsbergite, quartz. Distribution: In the Cetine mine, 20 km southwest of Siena...Fornaseri, and M. Nicoletti (1968) Onoratoite, a new antimony oxychloride from Cetine di Cotorniano, Rosia (Siena |  | Bittarello, Erica, Cámara, Fernando, Ciriotti, Marco E., Marengo, Alessandra (2015) Ottensite, brizziite and mopungite from Pereta mine (Tuscany, Italy): new occurrences and crystal structure refinement of mopungite. Mineralogy and Petrology, 109 (4) 431-442 doi:10.1007/s00710-015-0375-5 | Journal (article/letter/editorial) | | Ottensite, brizziite and mopungite from Pereta mine (Tuscany, Italy): new occurrences and crystal structure...specimens from the antimony mine of Pereta (Grosseto, Tuscany, Italy). Ottensite from Pereta mine occurs as brilliant...samples (collected about 25 years ago) from Pereta mine (Tuscany, Italy) (Fig. 1). Botryoidal and stalactitic...mopungite, NaSb(OH)6 (Williams 1985). The antimoniferous mine of Pereta (42°38′37″N; 11°21′ 28″E) is located about...Italy) bordering on the sulphur-cinnabar Zolfiere mine (Fig. 1). Relevant historical, geological and mineralogical |  | | Report (issue) | | c = 11.314–11.337 X-ray Powder Pattern: Pereta mine, Italy. 3.092 (100), 3.304 (93), 6.81 (67), 14.84...Pereta mine, Italy; by electron microprobe, average of 10 analyses on three grains. (2) Cetine mine, Italy;...of four analyses on two grains. (3) Lucky Knock mine, Washington, USA; by electron microprobe, average...silicified limestone (Pereta mine, Italy). Association: Klebelsbergite, peretaite, valentinite, sénarmontite...Distribution: From the Cetine mine, 20 km southwest of Siena, and the Pereta mine, Scansano, Tuscany, Italy |  | | Report (issue) | | 6006(9) c = 10.185(1) X-ray Powder Pattern: Pereta mine, Italy; shows some preferred orientation due to...68.33 6.57 6.33 Total 99.15 100.00 (1) Pereta mine, Italy; CaO by AA, H2 O by TGA; corresponds to Ca1...oxidized zone of a limestone-hosted hydrothermal antimony-bearing deposit. Association: Stibnite, pyrite...kermesite, sulfur, valentinite, onoratoite, klebelsbergite, gypsum, calcite, quartz. Distribution: In...Tuscany. Name: For its occurrence at the Pereta mine, Italy. Type Material: University of Florence, |  | Bindi, L., Biagioni, C., Ceccantini, L., Batoni, M., Menchetti, S. (2014) Coquandite, Sb6+xO8+x(SO4)(OH)x·(H2O)1–x (x = 0.3), from the Cetine mine, Tuscany, Italy: crystal structure and revision of the chemical formula. Mineralogical Magazine, 78 (4) 871-888 doi:10.1180/minmag.2014.078.4.08 | Journal (article/letter/editorial) | | Sb6+xO8+x(SO4)(OH)x·(H2O)1 x (x = 0.3), from the Cetine mine, Tuscany, Italy: crystal structure and revision...intensity data collected from a crystal from the Cetine mine, Tuscany, Italy. This study revealed that the structure...structure solution, crystal-structure refinement, Cetine mine. Introduction COQUANDITE, Sb6O8(SO4)·H2O (with...collected in the 1970s in the abandoned Pereta stibnite mine, Tuscany, Italy. Those authors supplied a detailed..., 1980a; Menchetti and Sabelli, 1980a) and klebelsbergite, Sb4O4(OH)2(SO4) (Cipriani et al., 1980b; Menchetti |  | | Journal (article/letter/editorial) | | Received: October 28, 1986 Richelsdorfite I Antimony I Arsenate I Crystal structure Abstract. Richelsdorfite...Richelsdorfite, a hydrated arsenate of calcium, copper and antimony, is monoclinic, C2/m, with a = 14.079(5), b =...chemical composition [CazCusCI(As04)4t . Pentavalent antimony, octahedrally coordinated by six hydroxyl groups...further occurrence has been reported from the Clara Mine in the Black Forest(Walenta, 1985). The crystal...analysis alone, since neither the valence state of antimony nor the OR - /RzO relation was known. Crystal |  | | | | Received: October 28, 1986 Richelsdorfite I Antimony I Arsenate I Crystal structure Abstract. Richelsdorfite...Richelsdorfite, a hydrated arsenate of calcium, copper and antimony, is monoclinic, C2/m, with a = 14.079(5), b =...chemical composition [CazCusCI(As04)4t . Pentavalent antimony, octahedrally coordinated by six hydroxyl groups...further occurrence has been reported from the Clara Mine in the Black Forest(Walenta, 1985). The crystal...analysis alone, since neither the valence state of antimony nor the OR - /RzO relation was known. Crystal |  | | Journal (article/letter/editorial) | | cassiterite and quartz from near Arandis, Swakopmund district, South-West Africa. Named from the locality. [M...lth List). Named from the locality, Khakassky district in Siberia. Kilbreckanite. R. Griffith, Catalogue...Kilbreckan lead mine, near Quin, Co. Clare, Ireland. A synonym of Geoeronite. Klebelsbergite. V. Zsivny,...vol. 46, p. 19 (Klebelsbergit). Hydrous basic antimony sulphate, as monoclinic needles on stibnite from...monoclinic prisms in the borate deposits of the Kramer district, Kern Co., California. Named flom the locality |  | | Catalog/List | | Nice. 75x50x31 010 ALUMINOCOPIAPITE - Champion Mine, California, USA. A pure yellow botryodal mass....24xl8x8 complete50 ,00 terminated 45, 00 016 ANTIMONY- Montril, Granada, Spain. Extremely rich: bright...matrix. 6lx47xl8 22,00 017 APACHEITE - Christmas Mine, Gila Co., USA. Pale blue patches in matrix. Moderately...xl 13xl0x8 8,00 )!. .. 022 AXINITE xx - Obira Mine, Japan. A large terminated xl, 47x27, forming the...BRUSHITE - CALCIOFERRITE - ARAGONITE - Rocabruna Mine, Brugues Gaba, Barcelona, Spain. Very rich whitish |  | Topa, Dan, Kolitsch, Uwe, Makovicky, Emil, Stanley, Chris (2017) Écrinsite, AgTl3Pb4As11Sb9S36, a new thallium-rich homeotype of baumhauerite from the Jas Roux sulphosalt deposit, Parc national des Écrins, Hautes-Alpes, France. European Journal of Mineralogy, 29 (4) 689-700 doi:10.1127/ejm/2017/0029-2639 | Journal (article/letter/editorial) | | Naturhistorisches Museum, Burgring 7, 1010 Wien, Austria *Corresponding author, e-mail: dan.topa@nhm-wien...Universität Wien, Althanstraße 14, 1090 Wien, Austria Department of Geoscience and Resource Management...localities. Among the latter are Moosegg mine, Salzburg, Austria (Graeser et al., 1986; Topa & Makovicky...2013b), Monte Arsiccio mine, Tuscany, Italy (Orlandi et al., 2012), and Pollone mine, Tuscany, Italy (Biagioni...collection of the Naturhistorisches Museum, Wien, Austria, with catalogue number N 9870. 2. Occurrence |  | | Journal (article/letter/editorial) | | proton promoted dissolution of the main natural antimony oxide phases, namely stibiconite (idealized composition...ionic strength I = 0.01 mol l1. The rates of antimony release by stibiconite were r = (2.2 ± 0.2) ...correspond to the dissolution rate minima. I.e.p. of antimony oxides have not yet been documented in the literature...geochemical implications for the weathering of antimony oxide minerals and stibnite, with particular reference...to the mobilization of antimony in the context of an abandoned antimony mine (Goesdorf, Luxembourg), |  | | Journal (article/letter/editorial) | | homepage: http://www.elsevier.com/locate/apgeochem Antimony mobility during the early stages of stibnite weathering...speciation and mineralogy of antimony (Sb) in waters and tailings at Beaver Brook antimony de posit have been... Keywords: Secondary antimony minerals Stibnite weathering Tailings Antimony speciation Arsenic speciation...quality of resulting mine drainage. Not only acid rock drainage (ARD) is problematic; mine drainage with neutral... (2016) characterized the Sb(III) sulfates klebelsbergite (Sb4O4(OH)2(SO4)) and peretaite (CaSb4O4(OH)2(SO4)2⋅H2O) |  | | Journal (article/letter/editorial) | | analysesplotted) compared with those from the Quairading district of WesternAustralia (Davidson, 1969).Superimposedis...metamorphosediron formations of the Quairading district, Westem Australia. NeuesJahrb. Mineral. Monatsh...amorphous semiconductors and glasses containing antimony, tin and iron: a review. Mbssbauet Efect Methodology...50121 Firenze,Italy Abstract Klebelsbergiteis an antimony sulfate found at Felscibdnia,Hungary, and recently...semiempirical method proposedby North et al- (1968). Klebelsbergite from Felsobdnia, Hungary, was first describedby |
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