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Darapiosite

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About DarapiositeHide

Formula:
K(Na,◻,K)2(Li,Zn,Fe)3(Mn,Zr,Y)2[Si12O30]
Colour:
colourless, white, brownish, bluish, pale violet
Hardness:
5
Crystal System:
Hexagonal
Member of:
Name:
Acording to the type locality - Darai-Pioz massif.
Osumilite Group. The Li-dominant analogue of dusmatovite, which is chemically similar. Also the Mn analogue of sugilite. Chemically somewhat similar to manganoneptunite and watatsumiite.

Structural characteristics: (1) dominance of Li at the T2 site; (2) dominance of Na at the B site.




Classification of DarapiositeHide

Approved
8/E.22-130
9.CM.05

9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si6O18]12- 6-membered double rings (sechser-Doppelringe)
63.2.1a.3

63 : CYCLOSILICATES Condensed Rings
2 : Condensed Rings (Milarite - Osumilite group)
14.10.29

14 : Silicates not Containing Aluminum
10 : Silicates of Zr or Hf

Physical Properties of DarapiositeHide

Transparency:
Transparent
Colour:
colourless, white, brownish, bluish, pale violet
Comment:
semitransparent
Hardness:

Optical Data of DarapiositeHide

Type:
Uniaxial (-)
RI values:
nω = 1.580 nε = 1.575
Max Birefringence:
δ = 0.005
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemical Properties of DarapiositeHide

Formula:
K(Na,◻,K)2(Li,Zn,Fe)3(Mn,Zr,Y)2[Si12O30]
IMA Formula:
KNa2Mn2(Li2ZnSi12)O30
Idealised Formula:
KNa2(Zn2Li)Mn2[Si12O30]
Common Impurities:
TR,Fe,Nb,Ca

Crystallography of DarapiositeHide

Crystal System:
Hexagonal
Class (H-M):
6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal
Space Group:
P6/mcc
Cell Parameters:
a = 10.32 Å, c = 14.39 Å
Ratio:
a:c = 1 : 1.394
Unit Cell V:
1,327.24 ų (Calculated from Unit Cell)
Comment:
parameters from the crystal structure determination: a=10.262, c=14.3198, V=1271.1

Type Occurrence of DarapiositeHide

Other Language Names for DarapiositeHide

Relationship of Darapiosite to other SpeciesHide

Member of:
Other Members of this group:
Agakhanovite-(Y)(YCa)□2KBe3Si12O30Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
AlmaruditeK(□,Na)2(Mn2+,Fe2+,Mg)2(Be,Al)3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
ArmeniteBaCa2Al6Si9O30 · 2H2OOrth. mmm (2/m 2/m 2/m) : Pnna
BerezanskiteK□2Li3(Ti,Zr,Sn)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Brannockite(K,Na)□2Li3(Sn,Zr,Ti)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
DusmatoviteK(Na,□)2(Zn,Li)3(Mn2+,Y,Zr)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
EifeliteKNa3Mg4Si12O30Hex.
FriedrichbeckeiteK(□0.5Na0.5)2Mg2Be3Si12O30Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Klöchite(□Na)KFe2+2Zn3(Si12O30)Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
Merrihueite(K,Na)2(Fe,Mg)5Si12O30Hex.
MilariteK2Ca4Al2Be4Si24O60 · H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mcc
OftedaliteK(Sc,Ca,Mn2+)22[(Be,Al)3Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Osumilite(K,Na)(Fe2+,Mg)2(Al,Fe3+)3(Si,Al)12O30Hex.
Osumilite-(Mg)KMg2Al3(Al2Si10)O30 Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
PoudretteiteKNa2B3Si12O30Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Roedderite(Na,K)2(Mg,Fe)5Si12O30Hex. 6 m2 : P62c
ShibkoviteK(□,K,Na)2Zn3Ca2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
SogdianiteK(□,Na)2Li3(Zr,Fe,Ti)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
SugiliteK(Na,□)2Li3(Fe,Mn,Al,Zr)2[Si12O30]Hex.
Trattnerite□(Fe3+,Mg,Fe2+)2(Mg,Fe2+,Fe3+)3(Si12O30)Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
UM1990-73-SiO:KMnNaZn(K,Na)2Zn3Mn1.5Si12O30Hex.
Yagiite(Na,K)3Mg4(Al,Mg)6(Si,Al)24O60Hex. 6/mmm (6/m 2/m 2/m)

Related Minerals - Nickel-Strunz GroupingHide

9.CM.05ArmeniteBaCa2Al6Si9O30 · 2H2OOrth. mmm (2/m 2/m 2/m) : Pnna
9.CM.05Brannockite(K,Na)□2Li3(Sn,Zr,Ti)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05ChayesiteK(Mg,Fe)4FeSi12O30Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05EifeliteKNa3Mg4Si12O30Hex.
9.CM.05Merrihueite(K,Na)2(Fe,Mg)5Si12O30Hex.
9.CM.05MilariteK2Ca4Al2Be4Si24O60 · H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05Osumilite-(Mg)KMg2Al3(Al2Si10)O30 Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05Osumilite(K,Na)(Fe2+,Mg)2(Al,Fe3+)3(Si,Al)12O30Hex.
9.CM.05PoudretteiteKNa2B3Si12O30Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05Roedderite(Na,K)2(Mg,Fe)5Si12O30Hex. 6 m2 : P62c
9.CM.05SogdianiteK(□,Na)2Li3(Zr,Fe,Ti)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05SugiliteK(Na,□)2Li3(Fe,Mn,Al,Zr)2[Si12O30]Hex.
9.CM.05Yagiite(Na,K)3Mg4(Al,Mg)6(Si,Al)24O60Hex. 6/mmm (6/m 2/m 2/m)
9.CM.05BerezanskiteK□2Li3(Ti,Zr,Sn)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05DusmatoviteK(Na,□)2(Zn,Li)3(Mn2+,Y,Zr)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05ShibkoviteK(□,K,Na)2Zn3Ca2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05AlmaruditeK(□,Na)2(Mn2+,Fe2+,Mg)2(Be,Al)3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
9.CM.05Trattnerite□(Fe3+,Mg,Fe2+)2(Mg,Fe2+,Fe3+)3(Si12O30)Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05OftedaliteK(Sc,Ca,Mn2+)22[(Be,Al)3Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.10FaizieviteK2Na(Ca6Na)Ti4Li6[F2|Si24O66]Tric. 1 : P1

Related Minerals - Dana Grouping (8th Ed.)Hide

63.2.1a.1Brannockite(K,Na)□2Li3(Sn,Zr,Ti)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
63.2.1a.2ChayesiteK(Mg,Fe)4FeSi12O30Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
63.2.1a.4EifeliteKNa3Mg4Si12O30Hex.
63.2.1a.5Merrihueite(K,Na)2(Fe,Mg)5Si12O30Hex.
63.2.1a.6Osumilite(K,Na)(Fe2+,Mg)2(Al,Fe3+)3(Si,Al)12O30Hex.
63.2.1a.8PoudretteiteKNa2B3Si12O30Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
63.2.1a.9SugiliteK(Na,□)2Li3(Fe,Mn,Al,Zr)2[Si12O30]Hex.
63.2.1a.10Yagiite(Na,K)3Mg4(Al,Mg)6(Si,Al)24O60Hex. 6/mmm (6/m 2/m 2/m)
63.2.1a.11DusmatoviteK(Na,□)2(Zn,Li)3(Mn2+,Y,Zr)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
63.2.1a.12MilariteK2Ca4Al2Be4Si24O60 · H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mcc
63.2.1a.13SogdianiteK(□,Na)2Li3(Zr,Fe,Ti)2[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
63.2.1a.14Roedderite(Na,K)2(Mg,Fe)5Si12O30Hex. 6 m2 : P62c

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

14.10.1ZirconZr(SiO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
14.10.2HafnonHfSiO4Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
14.10.3ZektzeriteLiNaZrSi6O15Orth.
14.10.4ParakeldyshiteNa2ZrSi2O7Tric.
14.10.5VlasoviteNa2ZrSi4O11Mon. 2/m : B2/b
14.10.6Keldyshite(Na,H)2ZrSi2O7Tric. 1 : P1
14.10.7GaidonnayiteNa2Zr(Si3O9) · 2H2OOrth. mmm (2/m 2/m 2/m) : Pmna
14.10.8TerskiteNa4ZrSi6O16 · 2H2OOrth.
14.10.9ElpiditeNa2ZrSi6O15 · 3H2OOrth.
14.10.10HilairiteNa2Zr[SiO3]3 · 3H2OTrig.
14.10.11PetarasiteNa5Zr2(Si6O18)(Cl,OH) · 2H2OMon. 2/m : P21/m
14.10.12KhibinskiteK2ZrSi2O7Mon.
14.10.13WadeiteK2Zr(Si3O9)Hex.
14.10.14DalyiteK2ZrSi6O15Tric.
14.10.15KostyleviteK2Zr(Si3O9) · H2OMon.
14.10.16UmbiteK2(Zr,Ti)Si3O9 · H2OOrth.
14.10.17ParaumbiteK3Zr2H(Si3O9)2 · nH2OOrth.
14.10.18GeorgechaoiteNaKZr[Si3O9] · 2H2OOrth. mm2
14.10.19GittinsiteCaZrSi2O7Mon.
14.10.20CalciocatapleiiteCaZr(Si3O9) · 2H2O
14.10.21CalciohilairiteCaZr[SiO3]3 · 3H2OTrig.
14.10.22ArmstrongiteCaZr[Si6O15] · 3H2OMon.
14.10.23Lemoynite(Na,K)2CaZr2Si10O26 · 5H2OMon. 2/m : B2/b
14.10.24CatapleiiteNa2Zr(Si3O9) · 2H2OMon.
14.10.25BaghdaditeCa3(Zr,Ti)(Si2O7)O2Mon.
14.10.26LovozeriteNa2Ca(Zr,Ti)(Si6O12)[(OH)4O2] · H2OMon.
14.10.27Låvenite(Na,Ca)2(Mn2+,Fe2+)(Zr,Ti)(Si2O7)(O,OH,F)2Mon. 2/m : P21/b
14.10.28PenkvilksiteNa4Ti2Si8O22 · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbcn
14.10.30BaziriteBaZr(Si3O9)Hex.
14.10.31KomkoviteBaZr[Si3O9] · 3H2OTrig.
14.10.32ZirsinaliteNa6(Ca,Mn2+,Fe2+)Zr(Si6O18)Trig.
14.10.33Tranquillityite(Fe2+,Ca)8(Zr,Y)2Ti3(SiO4)3O12Hex.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for DarapiositeHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
American Mineralogist: 61: 1053-1054.
Ferraris, G., Prencipe, M., Pautov, L.A. & Sokolova, E.V. (1999): The crystal structure of darapiosite and a comparison with Li and Zn-bearing minerals of the milarite group. Canadian Mineralogist, 37, 769-774.

Internet Links for DarapiositeHide

Localities for DarapiositeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Tajikistan (TL)
 
  • Region of Republican Subordination
    • Tien Shan Mtn
      • Alai Range (Alayskiy)
http://www.koeln.netsurf.de/~w.steffens/dara.htm; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
Mineral and/or Locality  
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