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Ferro-ferri-barroisite

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Formula:
☐(CaNa)(Fe2+3Fe3+2)(AlSi7O22)(OH)2
The barroisite group minerals are sodium-calcium amphiboles defined with A(Na+K+2Ca)< 0.5 apfu and 1.5 apfu < C(Al+Fe3++2Ti).

Barroisite is defined with

C2+ position: Fe dominant
C3+ position: Fe dominant
W position: (OH) dominant
The barroisite group is in the 2012 nomenclature defined with C(Al+Fe3++2Ti)>1,5 apfu, whereas the pre-2012 definition was defined with 6,5 < Si < 7,5 apfu. This redefinition does not change the formula, but some amphiboles qualifying as ferro-ferri-barroisite pre-2012 may now be ferro-ferri-winchite. Since the content of the C3+ position was not part of the pre-2012 definition, it was often omitted in the presentation of data


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Classification of Ferro-ferri-barroisiteHide

Notes:
Unnamed (probably valid)
Approval History:
Unnamed, but probably valid.
9.DE.20

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
16.24.10

16 : Silicates Containing Aluminum and other Metals
24 : Aluminosilicates of Fe, Mg, Ca and alkalis

Chemical Properties of Ferro-ferri-barroisiteHide

Formula:
☐(CaNa)(Fe2+3Fe3+2)(AlSi7O22)(OH)2

The barroisite group minerals are sodium-calcium amphiboles defined with A(Na+K+2Ca)< 0.5 apfu and 1.5 apfu < C(Al+Fe3++2Ti).

Barroisite is defined with

C2+ position: Fe dominant
C3+ position: Fe dominant
W position: (OH) dominant

Synonyms of Ferro-ferri-barroisiteHide

Relationship of Ferro-ferri-barroisite to other SpeciesHide

Other Members of this group:
Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
Ferri-barroisite☐(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
Ferri-fluoro-barroisite☐{CaNa}{Mg3Fe3+2}(AlSi7O22)F2
Ferro-barroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2Mon. 2/m : B2/m
Ferro-ferri-fluoro-barroisite☐{CaNa}{Fe2+3Fe3+2}(AlSi7O22)F2
Ferro-fluoro-barroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)F2
Fluoro-barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)F2

Related Minerals - Nickel-Strunz GroupingHide

9.DE.Clino-suenoite□{Mn2+2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Anthophyllite☐{Mg2}{Mg5}(Si8O22)(OH)2Orth. mmm (2/m 2/m 2/m) : Pnma
9.DE.05Cummingtonite☐{Mg2}{Mg5}(Si8O22)(OH)2Mon.
9.DE.05Clino-holmquistite Root Name☐{Li2}{Z2+3Z3+2}(Si8O22)(OH,F,Cl)2Mon.
9.DE.05Grunerite☐{Fe2+2}{Fe2+5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Permanganogrunerite☐{Mn2+2}{Mn2+5}(Si8O22)(OH)2Mon.
9.DE.05Ferro-fluoro-pedrizite{Na}{Li2}{Fe2Al2Li}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.05Ferri-fluoro-leakeite{Na}{Na2}{Mg2Fe3+2Li}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Actinolite☐{Ca2}{Mg4.5-2.5Fe0.5-2.5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Ferri-tschermakite☐{Ca2}{Mg3Fe3+2}(Al2Si6O22)(OH)2Mon.
9.DE.10Ferro-actinolite☐{Ca2}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.10Ferro-hornblende☐{Ca2}{Fe2+4Al}(AlSi7O22)(OH)2Mon.
9.DE.10Ferro-tschermakite☐{Ca2}{Fe2+3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10Joesmithite{Pb}{Ca2}{Mg3Fe3+2}(Be2Si6O22)(OH)2Mon.
9.DE.10Magnesio-hornblende☐{Ca2}{Mg4Al}(AlSi7O22)(OH)2Mon.
9.DE.10Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Tschermakite☐(Ca2)(Mg3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10CannilloiteCa(Ca2)(Mg4Al)(Al3Si5O22)(OH)2Mon.
9.DE.10Fluoro-cannilloite{Ca}{Ca2}{Mg4Al}(Al3Si5O22)(F,OH)2Mon.
9.DE.10Parvo-manganotremolite☐{CaMn2+}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Fluoro-tremolite☐{Ca2}{Mg5}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Potassic-fluoro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.15Edenite{Na}{Ca2}{Mg5}(AlSi7O22)(OH)2Mon.
9.DE.15Ferro-edenite{Na}{Ca2}{Fe2+5}(AlSi7O22)(OH)2Mon.
9.DE.15Ferro-kaersutite{Na}{Ca2}{Fe2+3AlTi}(Al2Si6O22)O2Mon.
9.DE.15Ferro-pargasite{Na}{Ca2}{Fe2+4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Hastingsite{Na}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(OH)2Mon.
9.DE.15Kaersutite{Na}{Ca2}{Mg3AlTi}(Al2Si6O22)O2 Mon.
9.DE.15Magnesio-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon.
9.DE.15Pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Sadanagaite{Na}{Ca2}{Mg3Al2}(Si5Al3O22)(OH)2Mon.
9.DE.15Fluoro-edenite{Na}{Ca2}{Mg5}(AlSi7O22)(F,OH)2Mon. 2/m : P2/m
9.DE.15Potassic-ferro-ferri-sadanagaite{K}{Ca2}{Fe2+3Fe3+2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-sadanagaite{K}{Ca2}{Mg3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Potassic-ferro-sadanagaite{K}{Ca2}{Fe2+3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Magnesio-fluoro-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.15Potassic-fluoro-hastingsite{K}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(F,OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-hastingsite{K}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(Cl,OH)2Mon. 2/m : B2/m
9.DE.15Fluoro-pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(F,OH)2Mon. 2/m : B2/m
9.DE.15Parvo-mangano-edenite{Na}{CaMn2+}{Mg5}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(Cl,OH)2
9.DE.15Potassic-ferro-chloro-edenite{K}{Ca2}{Fe2+5}(AlSi7O22)(Cl,OH)2
9.DE.15Potassic-magnesio-hastingsite{K}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-ferro-pargasite{K}{Ca2}{Fe2+4Al}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Chromio-pargasite{Na}{Ca2}{Mg4Cr3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-taramiteNa(CaNa)(Fe2+3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
9.DE.20Ferro-ferri-winchite☐[CaNa][Fe2+4(Fe3+,Al)]Si8O22(OH)2
9.DE.20Ferri-barroisite☐(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-taramiteNa(CaNa)(Fe2+3Fe3+2)(Al2Si6O22)(OH)2
9.DE.20Ferro-ferri-katophoriteNa(NaCa)(Fe2+4Fe3+)(Si7Al)O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-barroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-richterite{Na}{CaNa}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.20Ferro-winchite ☐{CaNa}{Fe2+4Al}(Si8O22)(OH)2Mon.
9.DE.20Ferro-katophorite{Na}{CaNa}{Fe2+4Al}[(AlSi7)O22](OH)2
9.DE.20Ferri-taramiteNa(CaNa)(Mg3Fe3+2)(Al2Si6O22)(OH)2Mon.
9.DE.20Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2Mon.
9.DE.20Richterite{Na}{NaCa}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.20Winchite☐{CaNa}{Mg4Al}(Si8O22)(OH)2Mon. 2/m
9.DE.20Taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-richterite{Na}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon. 2/m
9.DE.20Katophorite{Na}{CaNa}{Mg4Al}[(AlSi7)O22](OH)2Mon. 2/m : B2/m
9.DE.20Potassic-fluoro-richterite{K}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon.
9.DE.20Potassic-richterite{K}{CaNa}{Mg5}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferri-ghoseite☐[Mn2+Na][Mg4Fe3+]Si8O22(OH)2Mon. 2/m
9.DE.20Ferri-winchite☐[CaNa][Mg4(Fe3+,Al)]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.25Arfvedsonite[Na][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25EckermanniteNaNa2(Mg4Al}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-eckermanniteNaNa2(Fe2+4Al)Si8O22(OH)2Mon.
9.DE.25Ferro-glaucophane◻[Na2][Fe2+3Al2]Si8O22(OH)2Mon.
9.DE.25Glaucophane◻[Na2][Mg3Al2]Si8O22(OH)2Mon.
9.DE.25Potassic-mangani-leakeite[(Na,K)][Na2][Mg2Mn3+2Li]Si8O22(OH)2Mon.
9.DE.25Mangano-ferri-eckermannite{Na}{Na2}{Mn2+4Fe3+}Si8O22(OH)2Mon.
9.DE.25Ferri-leakeite[Na][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Magnesio-riebeckite◻{Na2}{Mg3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-arfvedsonite{Na}{Na2}{Mg4Fe3+}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25NybøiteNaNa2(Mg3Al2)(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.25Riebeckite◻[Na2][Fe2+3Fe3+2]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangano-mangani-ungarettiiteNaNa2(Mn2+2Mn3+3)(Si8O22)O2Mon.
9.DE.25Ferro-ferri-nybøiteNaNa2[(Fe2+3,Mg)Fe3+2](AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.25Clino-ferro-ferri-holmquistite◻{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferri-nybøiteNaNa2(Mg3Fe3+2](AlSi7O22)(OH)2Mon.
9.DE.25Ferro-ferri-leakeite[Na][Na2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Ferro-ferri-fluoro-leakeiteNa(Na2)(Fe2+2Fe3+2Li)(Si8O22)(F)2Mon.
9.DE.25Sodic-ferri-clinoferroholmquistiteNa0.5{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-fluoro-arfvedsonite[Na][Na2][Mg4Fe3+][Si8O22](F,OH)2Mon.
9.DE.25Ferri-pedrizite[Na][Li2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Potassic-ferri-leakeite[K][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Fluoro-nybøiteNaNa2(Mg3Al2)(AlSi7O22)(F,OH)2Mon. 2/m : B2/m
9.DE.25Mangani-dellaventuraite{Na}{Na2}{MgMn3+2LiTi4+}Si8O22O2Mon. 2/m : B2/m
9.DE.25Fluoro-pedriziteNaLi2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Potassic-arfvedsonite[(K,Na)][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangani-obertiiteNa(Na2)(Mg3Mn3+Ti)(Si8O22)O2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-fluoro-arfvedsonite[(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]
9.DE.25Ferro-ferri-pedrizite[Na][Li2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-arfvedsonite[K][Na2][Mg4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25PedriziteNaLi2(LiMg2Al2)(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-pedriziteNaLi2(Fe2+2Al2Li)Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Fluoro-leakeiteNaNa2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Ferro-ferri-obertiiteNaNa2(Fe2+3Fe3+Ti)Si8O22O2Mon. 2/m : B2/m

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

16.24.1Aegirine-augite(NaaCabFe2+cMgd)(Fe3+eAlfFe2+gMgh)Si2O6Mon. 2/m : B2/b
16.24.2Omphacite(NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6Mon. 2/m
16.24.4Ferri-katophoriteNa(CaNa)(Mg4Fe3+)(AlSi7O22)(OH)2Mon.
16.24.5Ferro-ferri-katophoriteNa(NaCa)(Fe2+4Fe3+)(Si7Al)O22(OH)2Mon. 2/m : B2/m
16.24.6Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
16.24.7Ferri-barroisite☐(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
16.24.8Alumino-ferrobarroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2
16.24.9Ferro-barroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2Mon. 2/m : B2/m
16.24.11Hastingsite{Na}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(OH)2Mon.
16.24.12Magnesio-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon.
16.24.13Taramite Root NameA(CaNa)(Z2+3Z3+2)(Al2Si6O22)(OH,F,Cl)2
16.24.14Ferri-taramiteNa(CaNa)(Mg3Fe3+2)(Al2Si6O22)(OH)2Mon.
16.24.15Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2Mon.
16.24.16Osumilite-(Mg)KMg2Al3(Al2Si10)O30 Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
16.24.16Osumilite(K,Na)(Fe2+,Mg)2(Al,Fe3+)3(Si,Al)12O30Hex.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferro-ferri-barroisiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Hawthorne, F.C., Oberti, R. (2006) On the classification of amphiboles. The Canadian Mineralogist: 44: 1-21.
Hawthorne, F.C., Oberti, R., Harlow, G.E., Maresch, W.V., Martin, R.F., Schumacher, J.C., Welch, M.D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist: 97: 2031-2048.

Internet Links for Ferro-ferri-barroisiteHide

Localities for Ferro-ferri-barroisiteHide

ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
China
 
  • Hebei Province
    • Qinhuangdao Prefecture
      • Funing Co.
Lingdi Zhou, Deren Li, Zhenhua Zhao, and Yangchuan Wang (1989): Acta Mineralogica Sinica 9(3)
Mineral and/or Locality  
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