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Ferroalluaudite

A valid IMA mineral species - grandfathered
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About FerroalluauditeHide

Formula:
(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3
Colour:
Straw-yellow to brownish yellow, green, greenish black; yellow to yellow-green in transmitted light.
Hardness:
5 - 5½
Specific Gravity:
3.4 - 3.5
Crystal System:
Monoclinic
Name:
In allusion to the composition, containing dominant iron (Latin = FERRum) and Alluaudite in allusion to its relationship to that species.
Alluaudite Group. Alluaudite-Ferroalluaudite Series.

A confusing change of nomenclature occurred regarding the species in this series. Ferroalluaudite was formerly Alluaudite and the present day Alluaudite was formerly Mangan-Alluaudite.

Occurs as an alteration product of Varulite and Arrojadite-(KFe).


Unique IdentifiersHide

Mindat ID:
1507
Long-form identifier:
mindat:1:1:1507:9
GUID
(UUID V4):
c70aacab-2de0-4f02-9d69-1b83d2e0ea54

IMA Classification of FerroalluauditeHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
NaFe2+Fe3+2(PO4)3

Classification of FerroalluauditeHide

8.AC.10

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 7th ed.:
38.2.5.1
38.2.3.5

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
19.12.29

19 : Phosphates
12 : Phosphates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
FaldIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
FalThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of FerroalluauditeHide

Transparency:
Opaque
Colour:
Straw-yellow to brownish yellow, green, greenish black; yellow to yellow-green in transmitted light.
Streak:
Straw-yellow
Hardness:
5 - 5½ on Mohs scale
Cleavage:
Distinct/Good
On {100} and {010}, good.
Density:
3.4 - 3.5 g/cm3 (Measured)    3.67 g/cm3 (Calculated)

Optical Data of FerroalluauditeHide

Type:
Biaxial (+)
RI values:
nα = 1.727 nγ = 1.738
Max Birefringence:
δ = 0.011
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
relatively strong
Pleochroism:
Strong
Comments:
X = dull green to pale blue; Y = Z = bright green with a bluish tinge.
Comments:
2V large

Chemistry of FerroalluauditeHide

Mindat Formula:
(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3

Crystallography of FerroalluauditeHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 11.898(2) Å, b = 12.541(2) Å, c = 6.434(1) Å
β = 114.1°
Ratio:
a:b:c = 0.949 : 1 : 0.513
Unit Cell V:
876.35 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Massive; compact granular; radiating fibrous or globular aggregates.
Comment:
space group by analogy to alluaudite

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012695FerroalluauditeCorbin D R, Whitney J F, Fultz W C, Stucky G D, Eddy M M, Cheetham A K (1986) Synthesis of open-framework transition-metal phosphates using organometallic precursors in acidic media. Preparation and structural characterization of Fe5P4O20H10 and NaFe3P3O12 Inorganic Chemistry 25 2279-228019860293
CIF Raw Data - click here to close

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of FerroalluauditeHide

Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 162558.

Synonyms of FerroalluauditeHide

Other Language Names for FerroalluauditeHide

Relationship of Ferroalluaudite to other SpeciesHide

Other Members of this group:
Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon. 2/m : B2/b
Alluaudite-Ca□◻4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
Alluaudite-Na□◻4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
ArseniopleiteNaCaMnMn2(AsO4)3Mon. 2/m
BadaloviteNa2Mg2Fe(AsO4)3Mon. 2/m : B2/b
BradaczekiteNaCu4(AsO4)3Mon. 2/m : B2/b
CalciohatertiteNaNaCa(CaFe3+)(AsO4)3Mon. 2/m : B2/b
CalciojohilleriteNaCaMg3(AsO4)3Mon. 2/m : B2/b
CamanchacaiteNaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
CanutiteNaMn3[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
ErikapohliteCu3(Zn,Cu,Mg)4Ca2(AsO4)6 ¡ 2H2O Mon. 2/m : B2/m
Ferroalluaudite-NaNaNa4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m : B2/m
FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.
GroatiteNaCaMn2(PO4)[PO3(OH)]2Mon. 2/m : B2/b
HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
Hagendorfite-NaNaNaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)Mon. 2/m : B2/b
HatertiteNa2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m : B2/b
JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
KeyiteCu2+3Zn4Cd2(AsO4)6 ¡ 2H2OMon. 2/m
KhrenoviteNa3Fe3+2(AsO4)3Mon. 2/m : B2/b
Maghagendorfite(Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3Mon. 2/m
MagnesiocanutiteNaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m : B2/b
Magnesiohatertite(Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m : B2/b
NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
O'DanieliteNa(Zn,Mg)3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
ParaberzeliiteNaCa2Mg2(AsO4)3Mon. 2/m : B2/b
Unnamed (Na-Mg Arsenate Hydroxyarsenate)NaMg3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
Unnamed (Na-Zn-H Arsenate Hydrxyarsenate)Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2Mon. 2/m : B2/b
VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
YazganiteNaFe3+2(Mg,Mn2+)(AsO4)3 ¡ H2OMon. 2/m : B2/b
ZhanghuifeniteNa3Mn4Mg2Al(PO4)6Mon. 2/m
ZincobradaczekiteNaZn2Cu2(AsO4)3Mon. 2/m : B2/b
Forms a series with:

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Ferroalluaudite associated with QuartzSiO2
3 photos of Ferroalluaudite associated with MitridatiteCa2Fe3+3(PO4)3O2 ¡ 3H2O
1 photo of Ferroalluaudite associated with FerrowodginiteFe2+Sn4+Ta2O8
1 photo of Ferroalluaudite associated with FluorapatiteCa5(PO4)3F
1 photo of Ferroalluaudite associated with AlmandineFe2+3Al2(SiO4)3

Related Minerals - Strunz-mindat GroupingHide

8.AC.AngarfiteNaFe3+5(PO4)4(OH)4 ¡ 4H2O Orth. 2 2 2 : C2 2 21
8.AC.WopmayiteCa6Na3◻Mn(PO4)3(PO3OH)4 Trig. 3m : R3c
8.AC.XDyrnaesite-(La)Na8Ce4+(La,REE)2(PO4)6Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.EdtolliteK2NaCu5Fe3+O2(AsO4)4Tric. 1 : P1
8.AC.AlumoedtolliteK2NaCu5AlO2(AsO4)4Tric. 1 : P1
8.AC.CrocobeloniteCaFe3+2O(PO4)2Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.ManganobadaloviteNaNaMn(MgFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.BeershevaiteCaFe3+3(PO4)3OMon. 2/m : P21/m
8.AC.CalciohatertiteNaNaCa(CaFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.KabaloviteFe2+3Fe3+4(PO4)6Tric. 1 : P1
8.AC.Nazarchukite Ca2NiFe3+2(PO4)4Orth. mmm (2/m 2/m 2/m) : Pbca
8.AC.Changesite–(Y)(Ca8Y)◻Fe2+(PO4)7Trig. 3m : R3c
8.AC.Crocobelonite-1MCaFe3+2O(PO4)2Mon. 2/m : P21/m
8.AC.Ebnerite(NH4)Zn(PO4)Hex. 6 : P63
8.AC.MagnesioqingheiiteNa2Mg(MgAl)(PO4)3Mon. 2/m
8.AC.Epiebnerite(NH4)Zn(PO4)Mon. 2 : P21
8.AC.02GrigorieviteCu3Fe3+2Al2(VO4)6Tric. 1 : P1
8.AC.02KoksharoviteCaMg2Fe3+4(VO4)6Tric. 1 : P1
8.AC.02ZiminaiteFe3+ 6 (VO4)6Tric. 1 : P1
8.AC.05CalciojohilleriteNaCaMg3(AsO4)3Mon. 2/m : B2/b
8.AC.05HowardevansiteNaCuFe2(VO4)3Tric. 1 : P1
8.AC.05O'DanieliteNa(Zn,Mg)3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05 vaAlluaudite-Na□◻4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
8.AC.05 vaAlluaudite-Ca□◻4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
8.AC.05 vaFerroalluaudite-NaNaNa4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m : B2/m
8.AC.05Hagendorfite-NaNaNaNaFe2+(Mn2+,Mn3+)(PO4)3 (?)Mon. 2/m : B2/b
8.AC.05ErikapohliteCu3(Zn,Cu,Mg)4Ca2(AsO4)6 ¡ 2H2O Mon. 2/m : B2/m
8.AC.05HatertiteNa2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m : B2/b
8.AC.05Unnamed (Na-Mg Arsenate Hydroxyarsenate)NaMg3(AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05Unnamed (Na-Zn-H Arsenate Hydrxyarsenate)Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2Mon. 2/m : B2/b
8.AC.05ZincobradaczekiteNaZn2Cu2(AsO4)3Mon. 2/m : B2/b
8.AC.05BadaloviteNa2Mg2Fe(AsO4)3Mon. 2/m : B2/b
8.AC.05MagnesiocanutiteNaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m : B2/b
8.AC.05Magnesiohatertite(Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m : B2/b
8.AC.05KhrenoviteNa3Fe3+2(AsO4)3Mon. 2/m : B2/b
8.AC.05ParaberzeliiteNaCa2Mg2(AsO4)3Mon. 2/m : B2/b
8.AC.05CamanchacaiteNaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
8.AC.05ManganohatertiteNaNaCa(MnFe3+)(AsO4)3Mon. 2/m : B2/b
8.AC.07ZhanghuifeniteNa3Mn4Mg2Al(PO4)6Mon. 2/m
8.AC.07FerrobobfergusoniteNa2Fe2+5Fe3+Al(PO4)6Mon.
8.AC.10Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon. 2/m : B2/b
8.AC.10ArseniopleiteNaCaMnMn2(AsO4)3Mon. 2/m
8.AC.10Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
8.AC.10HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
8.AC.10JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
8.AC.10Maghagendorfite(Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3Mon. 2/m
8.AC.10NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
8.AC.10VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
8.AC.10FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.
8.AC.10BradaczekiteNaCu4(AsO4)3Mon. 2/m : B2/b
8.AC.10GroatiteNaCaMn2(PO4)[PO3(OH)]2Mon. 2/m : B2/b
8.AC.15BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m : P2/b
8.AC.15Ferrowyllieite(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15QingheiiteNaNaMn2+(MgAl)(PO4)3Mon. 2/m : P21/b
8.AC.15Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15Wyllieite(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m
8.AC.15Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon. 2/m
8.AC.15FerroqingheiiteNaNaFe2+(MgAl)(PO4)3Mon. 2/m : P21/m
8.AC.17CzochralskiiteNa4Ca3Mg(PO4)4Orth. mmm (2/m 2/m 2/m) : Pnma
8.AC.18ManitobaiteNa16Mn2+ 25Al8(PO4)30Mon. m : Pb
8.AC.20MarićiteNaFe2+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
8.AC.25Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Manganberzeliite(NaCa2)Mn2+2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Palenzonaite(NaCa2)Mn2+2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Schäferite(NaCa2)Mg2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Hedegaardite(Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.25MatyhiteCa18(Ca,◻)2Fe2+2(PO4)14Trig. 3m : R3c
8.AC.30BrianiteNa2CaMg(PO4)2Mon. 2/m : P21/b
8.AC.35Vitusite-(Ce)Na3(Ce,La,Nd)(PO4)2Orth. mm2 : Pca21
8.AC.40Olgite(Sr,Ba)(Na,Sr,REE)2Na(PO4)2Trig. 3m (3 2/m) : P3m1
8.AC.40Bario-olgite(Ba,Sr)(Na,Sr,REE)2Na(PO4)2 ¡ Trig. 3 : P3
8.AC.45StrontiowhitlockiteSr9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45WhitlockiteCa9Mg(PO4)6(PO3OH)Trig. 3m : R3c
8.AC.45MerrilliteCa9NaMg(PO4)7Trig. 3m : R3m
8.AC.45TuiteCa3(PO4)2Trig. 3m (3 2/m) : R3m
8.AC.45FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m : R3c
8.AC.47IwateiteNa2BaMn(PO4)2Trig. 3 : P3
8.AC.47YurmariniteNa7(Fe3+,Mg,Cu)4(AsO4)6Trig. 3m (3 2/m) : R3c
8.AC.47OzerovaiteNa2KAl3(AsO4)4Orth. mmm (2/m 2/m 2/m) : Cmca
8.AC.47AnatolyiteNa6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6Trig. 3m (3 2/m) : R3c
8.AC.47PansneriteK3Na3(Fe3+,Al)6(AsO4)8Orth. mmm (2/m 2/m 2/m)
8.AC.50ChladniiteNa3CaMg11(PO4)9Trig. 3 : R3
8.AC.50FillowiteNa3CaMn2+11(PO4)9Trig. 3 : R3
8.AC.50JohnsomervilleiteNa3CaFe11(PO4)9Trig. 3 : R3
8.AC.50GalileiiteNa3Fe2+Fe2+11(PO4)9Trig. 3 : R3
8.AC.50XenophylliteNa4Fe2+7(PO4)6Tric. 1 : P1
8.AC.50UdinaiteNaMg4(VO4)3Tet. 4 2m : I4 2d
8.AC.50ArsenudinaiteNaMg4(AsO4)3Tet. 4 2m : I4 2d
8.AC.52Lasnierite(Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3Orth. mmm (2/m 2/m 2/m) : Pbcn
8.AC.55PharmazinciteKZnAsO4Hex. 6 : P63
8.AC.57ZubkovaiteCa3Cu3(AsO4)4Mon. 2 : B2
8.AC.60KosnariteKZr2(PO4)3Trig. 3m (3 2/m) : R3c
8.AC.65Panethite(Na,Ca)2(Mg,Fe2+)2(PO4)2Mon. 2/m : P21/b
8.AC.70StanfielditeCa4Mg5(PO4)6Mon.
8.AC.75RonneburgiteK2MnV4O12Mon. 2/m
8.AC.80TillmannsiteAg3Hg[(V,As)O4]Tet. 4 : I4
8.AC.85FilatoviteK(Al,Zn)2(As,Si)2O8Mon. 2/m

Other InformationHide

Notes:
Soluble in acids.

Alters to Heterosite and Purpurite.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FerroalluauditeHide

References for FerroalluauditeHide

Localities for FerroalluauditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Yukon
    • Dawson mining district
Robinson et al. (1992)
[Mineralogical Record Vol 23 No.4 ...
Czech Republic
 
  • Central Bohemian Region
    • KutnĂĄ Hora District
      • Vlkaneč
Povondra et al. (eds.) +1 other reference
Finland
 
  • Kanta-Häme
    • Tammela
Palache et al. (1951)
  • Southwest Finland
Ilkka Mikkola Collection XRD+ ...
      • KimitoĂśn Island
Pavel M. Kartashov analytical data 2019
France (TL)
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Bellac
        • Razès
Palache et al. (1951)
Germany
 
  • North Rhine-Westphalia
    • Arnsberg
      • Märkischer Kreis
        • Iserlohn
          • Letmathe
Blaß et al. (1994) +1 other reference
Morocco
 
  • Drâa-Tafilalet Region
    • Ouarzazate Province
      • Amerzgane Cercle
        • Ouisselsate CaĂŻdat
Pavel.M. Kartashov (n.d.) +1 other reference
Poland
 
  • Lower Silesian Voivodeship
    • Świdnica County
      • Gmina Świdnica
Łodziński M. & Sitarz M. 2008: Chemical and Spectroscopic Characterization of Some Phosphates Accessory Minerals from Pegmatites of the Sowie Mts (Owles Mts)
Rwanda
 
  • Western Province
Anthony et al. (2016)
Spain
 
  • Castile and Leon
    • Salamanca
      • PereĂąa de la Ribera
Roda-Robles et al. (2012)
  • Galicia
    • Pontevedra
      • Forcarei
Calvo Rebollar (2015)
Sweden
 
  • Stockholm County
    • Haninge
      • NorrĂś
Gustafson (1989) +1 other reference
    • Sigtuna
      • Arlanda
Swedish Museum of Natural History (Naturarv database)
Turkey
 
  • Muğla Province
    • Milâs District
Hikmet Kinaci et al. (2023)
 
Mineral and/or Locality  
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