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Ferro-barroisite

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Formula:
☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2
The barroisite group minerals are sodium-calcium amphiboles defined with A(Na+K+2Ca)< 0.5 apfu and 1.5 apfu < C(Al+Fe3++2Ti).

Ferro-barroisite is defined with

C2+ position: Fe dominant
C3+ position: Al dominant
W position: (OH) dominant
Colour:
Bluish-green to green.
Lustre:
Vitreous
Hardness:
5 - 6
Crystal System:
Monoclinic
Name:
For its relationship to barroisite, which was named in 1922 by Murgoci with no mention of etymology
Ferro-barroisite is defined as a barroisite-group member with Fe2+>Mg and Al>Fe3+ in the C position. Barroisite has been redefined in the 2012 Amphibole nomenclature in that:


1) The formula is changed from ☐(NaCa)(Fe2+3AlFe3+)(AlSi7O22)(OH)3 to ☐(NaCa)(Fe2+3Al2)(AlSi7O22)(OH)3. Consequently all pre-2012 literature references to ferro-barroisite should be checked to verify that Al>Fe3+ in the C position. If Fe3+>Al in the C position the material will be ferro-ferri-barroisite.

2) The barroisite group is in the 2012 nomenclature defined with C(Al+Fe3++2Ti)>1,5 apfu, whereas the pre-2012 definition was defined with 6,5 < Si < 7,5 apfu. This redefinition does not change the formula, but some amphiboles qualifying as barroisite pre-2012 will now be ferro-winchite or ferro-ferri-winchite. Since the content of the C3+ position was not part of the pre-2012 definition, it was often omitted in the presentation of data.


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Classification of Ferro-barroisiteHide

Notes:
Unnamed (probably valid)
Approval History:
Unnamed, but probably valid.
8/F.09-120
9.DE.20

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
16.24.9

16 : Silicates Containing Aluminum and other Metals
24 : Aluminosilicates of Fe, Mg, Ca and alkalis

Physical Properties of Ferro-barroisiteHide

Vitreous
Transparency:
Transparent
Colour:
Bluish-green to green.
Streak:
White
Hardness:
5 - 6 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
Perfect on {110}

Chemical Properties of Ferro-barroisiteHide

Formula:
☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2

The barroisite group minerals are sodium-calcium amphiboles defined with A(Na+K+2Ca)< 0.5 apfu and 1.5 apfu < C(Al+Fe3++2Ti).

Ferro-barroisite is defined with

C2+ position: Fe dominant
C3+ position: Al dominant
W position: (OH) dominant
Common Impurities:
Ti,Mn,K

Crystallography of Ferro-barroisiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m

Synonyms of Ferro-barroisiteHide

Other Language Names for Ferro-barroisiteHide

Relationship of Ferro-barroisite to other SpeciesHide

Other Members of this group:
Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
Ferri-barroisite☐(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
Ferri-fluoro-barroisite☐{CaNa}{Mg3Fe3+2}(AlSi7O22)F2
Ferro-ferri-barroisite☐(CaNa)(Fe2+3Fe3+2)(AlSi7O22)(OH)2
Ferro-ferri-fluoro-barroisite☐{CaNa}{Fe2+3Fe3+2}(AlSi7O22)F2
Ferro-fluoro-barroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)F2
Fluoro-barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)F2
Forms a series with:

Related Minerals - Nickel-Strunz GroupingHide

9.DE.05Anthophyllite☐{Mg2}{Mg5}(Si8O22)(OH)2Orth. mmm (2/m 2/m 2/m) : Pnma
9.DE.05Cummingtonite☐{Mg2}{Mg5}(Si8O22)(OH)2Mon.
9.DE.05Clino-holmquistite Root Name☐{Li2}{Z2+3Z3+2}(Si8O22)(OH,F,Cl)2Mon.
9.DE.05Grunerite☐{Fe2+2}{Fe2+5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Manganocummingtonite☐{Mn2+2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Manganogrunerite☐{Mn2+2}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.05Permanganogrunerite☐{Mn2+2}{Mn2+5}(Si8O22)(OH)2Mon.
9.DE.05Ferro-fluoro-pedrizite{Na}{Li2}{Fe2Al2Li}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.05Ferri-fluoro-leakeite{Na}{Na2}{Mg2Fe3+2Li}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Actinolite☐{Ca2}{Mg4.5-2.5Fe0.5-2.5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Ferri-tschermakite☐{Ca2}{Mg3Fe3+2}(Al2Si6O22)(OH)2Mon.
9.DE.10Ferro-actinolite☐{Ca2}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.10Ferro-hornblende☐{Ca2}{Fe2+4Al}(AlSi7O22)(OH)2Mon.
9.DE.10Ferro-tschermakite☐{Ca2}{Fe2+3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10Joesmithite{Pb}{Ca2}{Mg3Fe3+2}(Be2Si6O22)(OH)2Mon.
9.DE.10Magnesio-hornblende☐{Ca2}{Mg4Al}(AlSi7O22)(OH)2Mon.
9.DE.10Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Tschermakite☐(Ca2)(Mg3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10CannilloiteCa(Ca2)(Mg4Al)(Al3Si5O22)(OH)2Mon.
9.DE.10Fluoro-cannilloite{Ca}{Ca2}{Mg4Al}(Al3Si5O22)(F,OH)2Mon.
9.DE.10Parvo-manganotremolite☐{CaMn2+}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Fluoro-tremolite☐{Ca2}{Mg5}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Potassic-fluoro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.15Edenite{Na}{Ca2}{Mg5}(AlSi7O22)(OH)2Mon.
9.DE.15Ferro-edenite{Na}{Ca2}{Fe2+5}(AlSi7O22)(OH)2Mon.
9.DE.15Ferro-kaersutite{Na}{Ca2}{Fe2+3AlTi}(Al2Si6O22)O2Mon.
9.DE.15Ferro-pargasite{Na}{Ca2}{Fe2+4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Hastingsite{Na}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(OH)2Mon.
9.DE.15Kaersutite{Na}{Ca2}{Mg3AlTi}(Al2Si6O22)O2 Mon.
9.DE.15Magnesio-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon.
9.DE.15Pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Sadanagaite{Na}{Ca2}{Mg3Al2}(Si5Al3O22)(OH)2Mon.
9.DE.15Fluoro-edenite{Na}{Ca2}{Mg5}(AlSi7O22)(F,OH)2Mon. 2/m : P2/m
9.DE.15Potassic-ferro-ferri-sadanagaite{K}{Ca2}{Fe2+3Fe3+2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-sadanagaite{K}{Ca2}{Mg3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2Mon.
9.DE.15Potassic-ferro-sadanagaite{K}{Ca2}{Fe2+3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Magnesio-fluoro-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.15Potassic-fluoro-hastingsite{K}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(F,OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-hastingsite{K}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(Cl,OH)2Mon. 2/m : B2/m
9.DE.15Fluoro-pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(F,OH)2Mon. 2/m : B2/m
9.DE.15Parvo-mangano-edenite{Na}{CaMn2+}{Mg5}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(Cl,OH)2
9.DE.15Potassic-ferro-chloro-edenite{K}{Ca2}{Fe2+5}(AlSi7O22)(Cl,OH)2
9.DE.15Potassic-magnesio-hastingsite{K}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-ferro-pargasite{K}{Ca2}{Fe2+4Al}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Chromio-pargasite{Na}{Ca2}{Mg4Cr3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-taramiteNa(CaNa)(Fe2+3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
9.DE.20Ferro-ferri-barroisite☐(CaNa)(Fe2+3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-winchite☐[CaNa][Fe2+4(Fe3+,Al)]Si8O22(OH)2
9.DE.20Ferri-barroisite☐(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-taramiteNa(CaNa)(Fe2+3Fe3+2)(Al2Si6O22)(OH)2
9.DE.20Ferro-ferri-katophoriteNa(NaCa)(Fe2+4Fe3+)(Si7Al)O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-richterite{Na}{CaNa}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.20Ferro-winchite ☐{CaNa}{Fe2+4Al}(Si8O22)(OH)2Mon.
9.DE.20Ferro-katophorite{Na}{CaNa}{Fe2+4Al}[(AlSi7)O22](OH)2
9.DE.20Ferri-taramiteNa(CaNa)(Mg3Fe3+2)(Al2Si6O22)(OH)2Mon.
9.DE.20Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2Mon.
9.DE.20Richterite{Na}{NaCa}{Mg5}(Si8O22)(OH)2Mon.
9.DE.20Winchite☐{CaNa}{Mg4Al}(Si8O22)(OH)2Mon.
9.DE.20Taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-richterite{Na}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon. 2/m
9.DE.20Katophorite{Na}{CaNa}{Mg4Al}[(AlSi7)O22](OH)2Mon. 2/m : B2/m
9.DE.20Potassic-fluoro-richterite{K}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon.
9.DE.20Potassic-richteriteK[CaNa][Mg5]Si8O22(OH)2Mon.
9.DE.20Ferri-ghoseite☐[Mn2+Na][Mg4Fe3+]Si8O22(OH)2Mon. 2/m
9.DE.20Ferri-winchite☐[CaNa][Mg4(Fe3+,Al)]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.25Arfvedsonite[Na][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25EckermanniteNaNa2(Mg4Al}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-eckermanniteNaNa2(Fe2+4Al)Si8O22(OH)2Mon.
9.DE.25Ferro-glaucophane◻[Na2][Fe2+3Al2]Si8O22(OH)2Mon.
9.DE.25Glaucophane◻[Na2][Mg3Al2]Si8O22(OH)2Mon.
9.DE.25Potassic-mangani-leakeite[(Na,K)][Na2][Mg2Mn3+2Li]Si8O22(OH)2Mon.
9.DE.25Mangano-ferri-eckermannite[Na][Na2][Mn2+4(Fe3+)]Si8O22(OH)2Mon.
9.DE.25Ferri-leakeite[Na][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Magnesio-riebeckite◻{Na2}{Mg3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-arfvedsonite{Na}{Na2}{Mg4Fe3+}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25NybøiteNaNa2(Mg3Al2)(AlSi7O22)(OH)2Mon.
9.DE.25Riebeckite◻[Na2][Fe2+3Fe3+2]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangano-mangani-ungarettiiteNaNa2(Mn2+2Mn3+3)(Si8O22)O2Mon.
9.DE.25Ferro-ferri-nybøiteNaNa2[(Fe2+3,Mg)Fe3+2](AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.25Clino-ferro-ferri-holmquistite◻{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferri-nybøiteNaNa2(Mg3Fe3+2](AlSi7O22)(OH)2Mon.
9.DE.25Ferro-ferri-leakeite[Na][Na2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Ferro-ferri-fluoro-leakeiteNa(Na2)(Fe2+2Fe3+2Li)(Si8O22)(F)2Mon.
9.DE.25Sodic-ferri-clinoferroholmquistiteNa0.5{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-fluoro-arfvedsonite[Na][Na2][Mg4Fe3+][Si8O22](F,OH)2Mon.
9.DE.25Ferri-pedrizite[Na][Li2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Potassic-ferri-leakeite[K][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Fluoro-nybøiteNaNa2(Mg3Al2)(AlSi7O22)(F,OH)2Mon. 2/m : B2/m
9.DE.25Mangani-dellaventuraite{Na}{Na2}{MgMn3+2LiTi4+}Si8O22O2Mon. 2/m : B2/m
9.DE.25Fluoro-pedriziteNaLi2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Potassic-arfvedsonite[(K,Na)][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangani-obertiiteNa(Na2)(Mg3Mn3+Ti)(Si8O22)O2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-fluoro-arfvedsonite[(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]
9.DE.25Ferro-ferri-pedrizite[Na][Li2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-arfvedsonite[K][Na2][Mg4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25PedriziteNaLi2(LiMg2Al2)(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-pedriziteNaLi2(Fe2+2Al2Li)Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Fluoro-leakeiteNaNa2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Ferro-ferri-obertiiteNaNa2(Fe2+3Fe3+Ti)Si8O22O2Mon. 2/m : B2/m

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

16.24.1Aegirine-augite(NaaCabFe2+cMgd)(Fe3+eAlfFe2+gMgh)Si2O6Mon. 2/m : B2/b
16.24.2Omphacite(NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6Mon. 2/m
16.24.4Ferri-katophoriteNa(CaNa)(Mg4Fe3+)(AlSi7O22)(OH)2Mon.
16.24.5Ferro-ferri-katophoriteNa(NaCa)(Fe2+4Fe3+)(Si7Al)O22(OH)2Mon. 2/m : B2/m
16.24.6Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
16.24.7Ferri-barroisite☐(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
16.24.8Alumino-ferrobarroisite☐{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2
16.24.10Ferro-ferri-barroisite☐(CaNa)(Fe2+3Fe3+2)(AlSi7O22)(OH)2
16.24.11Hastingsite{Na}{Ca2}{Fe2+4Fe3+}(Al2Si6O22)(OH)2Mon.
16.24.12Magnesio-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2Mon.
16.24.13Taramite Root NameA(CaNa)(Z2+3Z3+2)(Al2Si6O22)(OH,F,Cl)2
16.24.14Ferri-taramiteNa(CaNa)(Mg3Fe3+2)(Al2Si6O22)(OH)2Mon.
16.24.15Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2Mon.
16.24.16Osumilite-(Mg)KMg2Al3(Al2Si10)O30 Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
16.24.16Osumilite(K,Na)(Fe2+,Mg)2(Al,Fe3+)3(Si,Al)12O30Hex.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferro-barroisiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Leake, B.E (1978) Nomenclature of amphiboles. The Canadian Mineralogist: 16: 501–520.
Leake, B.E., Woolley, A.R., Arps, C.E.S., Birch, W.D., Gilbert, M.C., Grice, J.D., Hawthorne, F.C., Kato, A., Kisch, H.J., Krivovichev, V.G., Linthout, K., Laird, J., Mandarino, J.A., Maresch, W.V., Nickel, E.H., Rock, N.M.S., Schumacher, J.C., Smith, D.C., Stephenson, N.C.N., Ungaretti, L., Whittaker, E.J.W., Guo, Y. (1997) Nomenclature of amphiboles: Report of the subcommittee on amphiboles of the International Mineralogical Association, Commission on New Minerals and Mineral Names. The Canadian Mineralogist: 35: 219–246.
Mandarino, J.A. (1998) The Second List of Additions and Corrections to the Glossary of Mineral Species (1995). The Amphibole Group. Mineralogical Record: 29: 169-174.
Hawthorne, F.C., Oberti, R. (2006) On the classification of amphiboles. The Canadian Mineralogist: 44: 1-21.
Hawthorne, F.C., Oberti, R., Harlow, G.E., Maresch, W.V., Martin, R.F., Schumacher, J.C., Welch, M.D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist: 97: 2031-2048.

Internet Links for Ferro-barroisiteHide

Localities for Ferro-barroisiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Canada
 
  • Ontario
    • Thunder Bay District
Mitchell et al. (1993)
France
 
  • Corsica
    • Corse-du-Sud
Handbook of Mineralogy
Niger
 
  • Agadez Department
    • Aïr Region
Handbook of Mineralogy
USA
 
  • Hawaii
    • Hawaii Co. (Hawaii Island)
Erik Vercammen collection
  • Washington
    • Skagit Co.
      • Rockport
Erik Vercammen collection (obtained from Bart Cannon, Seattle, with identification)
Mineral and/or Locality  
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