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Hejtmanite

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About HejtmaniteHide

Formula:
Ba2(Mn2+,Fe2+)4Ti2(Si2O7)2O2(OH)2F2
Colour:
Brownish to golden yellow
Lustre:
Vitreous
Hardness:
Crystal System:
Triclinic
Name:
Named in honour of Prof. RNDr. Bohuslav Hejtman (12 August 1911 Stranná u Kamenice nad Lipou - 18 September 2000 Praha), professor of petrology at Charles University in Prague, Czech Republic.
The Mn analogue of bafertisite (redefined as so basing on the Mbolve Hill material).

Previously reported to be monoclinic, which was proved wrong.

Chemistry is somewhat similar to that of perraultite. Compare UM1989-33-SiO:BaHMnTi.

Hejtmanite belongs to a group of titanosilicates built of TS (titanosilicate) and I (intermediate) blocks. In this group the TS block consists of HOH sheets, with H standing for heteropolyhedral sheets (penta- and hexacoordinated), and O for central octahedral (trioctahedral) sheet (Sokolova, 2010).
Hejtmanite is a Group-II TS-block mineral, which indicates that the (Ti+Nb) to (Si2O7) ratio is 2:2. In hejtmanite the O sheet consists of five hexacoordinated MO sites occupied mainly by Mn, surrounded by O or OH. The H sheet has (1) two hexacoordinated MH sites (mainly Ti, surrounded by O or F), and (2) four tetrahedral silicon sites. The I block comprises a layer of [12]Ba atoms, that reside within two AP(1,2) sites. Ba is surrounded by O or F. Four (XO) sites equal to two (XO M) and two (XO A) sites, corresponding to O2(OH)2 (Sokolova et al., 2016).


Classification of HejtmaniteHide

Approved
Approval Year:
1989
9.BE.55

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
56.2.6b.2

56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
14.9.18

14 : Silicates not Containing Aluminum
9 : Silicates of Ti

Physical Properties of HejtmaniteHide

Vitreous
Colour:
Brownish to golden yellow
Streak:
Yellow, brown
Hardness:
4½ on Mohs scale

Optical Data of HejtmaniteHide

Type:
Biaxial (-)
RI values:
nα = 1.814 nβ = 1.846 nγ = 1.867
2V:
Measured: 76° to 76.8°, Calculated: 76°
Max Birefringence:
δ = 0.053
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
r > v

Chemical Properties of HejtmaniteHide

Formula:
Ba2(Mn2+,Fe2+)4Ti2(Si2O7)2O2(OH)2F2
IMA Formula:
Ba2Mn2+4Ti2(Si2O7)2O2(OH)2F2
Common Impurities:
Fe,Nb,K,(Al,Mg,Na,Cl,Sr,Zr)

Crystallography of HejtmaniteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Cell Parameters:
a = 10.716(2) Å, b = 13.795(3) Å, c = 11.778(2) Å
α = 90.07(3)°, β = 112.24(3)°, γ = 90.03(3)°
Ratio:
a:b:c = 0.777 : 1 : 0.854
Unit Cell V:
1612 ų
Comment:
Space group setting is C-1

Type Occurrence of HejtmaniteHide

Synonyms of HejtmaniteHide

Other Language Names for HejtmaniteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
Rhodonite3 photos of Hejtmanite associated with Rhodonite on mindat.org.
Quartz3 photos of Hejtmanite associated with Quartz on mindat.org.
Aegirine2 photos of Hejtmanite associated with Aegirine on mindat.org.
Zektzerite2 photos of Hejtmanite associated with Zektzerite on mindat.org.
Alabandite1 photo of Hejtmanite associated with Alabandite on mindat.org.
Tephroite1 photo of Hejtmanite associated with Tephroite on mindat.org.
Khristovite-(Ce)1 photo of Hejtmanite associated with Khristovite-(Ce) on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

9.BE.02Wadsleyite(Mg,Fe2+)2(SiO4)Orth.
9.BE.05HennomartiniteSrMn3+2(Si2O7)(OH)2 · H2OOrth.
9.BE.05LawsoniteCaAl2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
9.BE.05NoelbensoniteBaMn3+2(Si2O7)(OH)2 · H2OOrth.
9.BE.05ItoigawaiteSrAl2(Si2O7)(OH)2 · H2OOrth.
9.BE.07IlvaiteCaFe3+Fe2+2(Si2O7)O(OH)Orth. mmm (2/m 2/m 2/m)
9.BE.07ManganilvaiteCaFe2+Fe3+Mn2+(Si2O7)O(OH)Mon. 2/m : P21/b
9.BE.10SuoluniteCa2(H2Si2O7) · H2OOrth.
9.BE.12JaffeiteCa6(Si2O7)(OH)6Trig. 3 : P3
9.BE.15FresnoiteBa2Ti(Si2O7)OTet.
9.BE.17BaghdaditeCa3(Zr,Ti)(Si2O7)O2Mon.
9.BE.17BurpaliteNa2CaZr(Si2O7)F2Mon.
9.BE.17CuspidineCa4(Si2O7)(F,OH)2Mon. 2/m : P21/b
9.BE.17Hiortdahlite(Na,Ca)2Ca4Zr(Mn,Ti,Fe)(Si2O7)2(F,O)4 Tric.
9.BE.17Janhaugite(Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2Mon. 2/m : P21/m
9.BE.17Låvenite(Na,Ca)2(Mn2+,Fe2+)(Zr,Ti)(Si2O7)(O,OH,F)2Mon. 2/m : P21/b
9.BE.17Niocalite(Ca,Nb)4(Si2O7)(O,OH,F)2Mon.
9.BE.17NormanditeNaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OFMon. 2/m : P21/b
9.BE.17WöhleriteNaCa2(Zr,Nb)(Si2O7)(O,OH,F)2Mon. 2 : P21
9.BE.17Hiortdahlite INa4Ca8Zr2(Nb,Mn,Ti,Fe,Mg,Al)2(Si2O7)4O3F5
9.BE.17MarianoiteNa2Ca4(Nb,Zr)2(Si2O7)2(O,F)4Mon. 2 : P21
9.BE.20Mosandrite-(Ce)(Ca3REE)[(H2O)2Ca0.50.5]Ti(Si2O7)2(OH)2(H2O)2Mon. 2/m : P21/b
9.BE.20Nacareniobsite-(Ce)NbNa3Ca3(Ce,REE )(Si2O7)2OF3Mon.
9.BE.22GötzeniteNaCa6Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22Hainite-(Y)Na2Ca4(Y,REE)Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22RosenbuschiteNa6Ca6Zr3Ti(Si2O7)4O2F6Tric. 1 : P1
9.BE.22KochiteNa3Ca2MnZrTi(Si2O7)2OF3Tric. 1 : P1
9.BE.23DovyreniteCa6Zr(Si2O7)2(OH)4Orth. mmm (2/m 2/m 2/m) : Pnnm
9.BE.25Barytolamprophyllite(Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)Mon.
9.BE.25EricssoniteBaMn2+2Fe3+(Si2O7)O(OH)Mon. 2/m : B2/m
9.BE.25Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2Mon.
9.BE.25Ericssonite-2OBaMn2+2Fe3+(Si2O7)O(OH)Orth.
9.BE.25SeidozeriteNa4MnZr2Ti(Si2O7)2O2F2Mon.
9.BE.25NabalamprophylliteNa3(Ba,Na)2Ti3(Si2O7)2O2(OH,F)2Mon. 2/m
9.BE.25GrenmariteNa4MnZr3(Si2O7)2O2F2Mon. 2/m : P2/b
9.BE.25SchülleriteBa2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4Tric. 1 : P1
9.BE.25LileyiteBa2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.27MurmaniteNa2Ti2(Si2O7)O2 · 2H2OTric.
9.BE.30EpistoliteNa2(Nb,Ti)2(Si2O7)O2 · nH2OTric.
9.BE.32LomonosoviteNa5Ti2(Si2O7)(PO4)O2Tric.
9.BE.35VuonnemiteNa11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)Tric.
9.BE.37SoboleviteNa13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3Mon. m : Pb
9.BE.40InneliteNa2CaBa4Ti3(Si2O7)2(SO4)2O4Tric. 1 : P1
9.BE.40PhosphoinneliteNa3Ba4Ti3(Si2O7)2(PO4,SO4)2O2FTric.
9.BE.42YoshimuraiteBa2Mn2Ti(Si2O7)(PO4)O(OH)Tric. 1 : P1
9.BE.45QuadruphiteNa14Ca2Ti4(Si2O7)2(PO4)2O2FTric.
9.BE.47PolyphiteNa5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2Tric. 1 : P1
9.BE.50BornemaniteNa6BaTi2Nb(Si2O7)2(PO4)O2(OH)F Tric. 1 : P1
9.BE.50ShkatulkaliteNa5(Nb1−xTix)2(Ti1−yMn2+y)[Si2O7]2O2(OH)2·nH2O (x + y = 0.5; n ≤ 10)Mon.
9.BE.55BafertisiteBa2Fe2+4Ti2(Si2O7)2O2(OH)2F2Tric.
9.BE.55Bykovaite(Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2OMon. 2/m
9.BE.55Nechelyustovite(Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2OMon. 2/m : B2/m
9.BE.60Delindeite(Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2OMon.
9.BE.65BusseniteNa2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3FTric. 1 : P1
9.BE.67JinshajiangiteBaNaFe2+4Ti2(Si2O7)2O2(OH)2FMon. 2/m
9.BE.67PerraultiteBaNaMn2+4Ti2(Si2O7)2O2(OH)2FMon. 2/m : B2/m
9.BE.67SurkhobiteNaCaBa2Mn8Ti4(Si2O7)4O5F5
9.BE.70Karnasurtite-(Ce)(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2O
9.BE.70Perrierite-(Ce)Ce4MgFe3+2Ti2(Si2O7)2O8
9.BE.70Strontiochevkinite(Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8Mon.
9.BE.70Chevkinite-(Ce)(Ce,La,Ca,Th)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8Mon.
9.BE.70Polyakovite-(Ce)(Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70RengeiteSr4ZrTi4(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70MatsubaraiteSr4Ti5(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Dingdaohengite-(Ce)(Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe2+)2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Maoniupingite-(Ce)(Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70Perrierite-(La)(La,Ce,Ca)4(Fe,Mn2+,Mg)Fe3+2(Ti,Fe3+)2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70UKI-2008-(SiO:SrTiZr)Sr4ZrTi4(Si2O7)2O8Orth. mmm (2/m 2/m 2/m) : Pbca
9.BE.70Hezuolinite(Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.72FersmaniteCa4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3Tric.
9.BE.75BelkoviteBa3(Nb,Ti)6(Si2O7)2O12Hex.
9.BE.77NasonitePb6Ca4(Si2O7)3Cl2Hex.
9.BE.80KentrolitePb2Mn3+2(Si2O7)O2Orth. mmm (2/m 2/m 2/m) : Pbcm
9.BE.80MelanotekitePb2Fe3+2(Si2O7)O2Orth.
9.BE.82TilleyiteCa5(Si2O7)(CO3)2Mon.
9.BE.85KillalaiteCa6.4(H0.6Si2O7)2(OH)2Mon.
9.BE.87Stavelotite-(La)(La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30Trig. 3 : P31
9.BE.90Biraite-(Ce)Ce2Fe2+(Si2O7)(CO3)Mon. 2/m : P21/b
9.BE.92Cervandonite-(Ce)(Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH)Trig. 3m : R3m
9.BE.95BatisiviteBaV3+8Ti6(Si2O7)O22Tric. 1 : P1

Related Minerals - Dana Grouping (8th Ed.)Hide

56.2.6b.1BafertisiteBa2Fe2+4Ti2(Si2O7)2O2(OH)2F2Tric.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

14.9.1NatisiteNa2Ti(SiO4)OTet.
14.9.2LorenzeniteNa2Ti2(Si2O6)O3Orth. mmm (2/m 2/m 2/m) : Pbcn
14.9.3LintisiteLiNa3Ti2(Si2O6)2O2 · 2H2OMon.
14.9.4DavaniteK2TiSi6O15Tric.
14.9.5KazakoviteNa6Mn2+Ti(Si6O18)Trig.
14.9.6TitaniteCaTi(SiO4)OMon. 2/m : P21/b
14.9.7OhmiliteSr3(Ti,Fe3+)(Si4O12)(O,OH) · 2-3H2OMon.
14.9.8Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2Mon.
14.9.9BenitoiteBaTi(Si3O9)Hex. 6 m2 : P62c
14.9.10BatisiteBaNaNaTi2(Si4O12)O2Orth.
14.9.11FresnoiteBa2Ti(Si2O7)OTet.
14.9.12Joaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2OMon. 2 : B2
14.9.13Orthojoaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2O
14.9.14StrontiojoaquiniteSr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2OMon.
14.9.15Bario-orthojoaquinite(Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2OOrth.
14.9.16Strontio-orthojoaquinite(Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2OOrth.
14.9.17BafertisiteBa2Fe2+4Ti2(Si2O7)2O2(OH)2F2Tric.
14.9.19Delindeite(Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2OMon.
14.9.20Barytolamprophyllite(Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)Mon.
14.9.21Trimounsite-(Y)Y2Ti2(SiO4)O5Mon.
14.9.22Perrierite-(Ce)Ce4MgFe3+2Ti2(Si2O7)2O8
14.9.23Chevkinite(Ce,Ca,Th)4(Fe,Mn)2(Ti,Fe)3[Si2O7]2O8
14.9.24Strontiochevkinite(Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8Mon.
14.9.25TisinaliteNa3H3(Mn,Ca,Fe)TiSi6(O,OH)18 · 2H2OTrig.
14.9.26NeptuniteNa2KLiFe2+2Ti2Si8O24Mon. m : Bb
14.9.27ManganoneptuniteNa2KLiMn2+2Ti2Si8O24Mon.
14.9.28Kupletskite(K,Na)3(Mn,Fe)7Ti2Si8O26(OH)4FTric.
14.9.29AstrophylliteK2NaFe2+7Ti2Si8O28(OH)4FTric. 1 : P1
14.9.30Hydroastrophyllite(H3O,K,Ca)3(Fe,Mn)5-65Ti2Si8(O,OH)31Tric.
14.9.31LobanoviteK2Na(Fe2+4Mg2Na)Ti2(Si4O12)2O2(OH)4Mon. 2/m : B2/m
14.9.32BaratoviteKCa7(Ti,Zr)2Li3Si12O36F2Mon. 2/m : B2/b
14.9.34AenigmatiteNa4[Fe2+10Ti2]O4[Si12O36]Tric. 1 : P1
14.9.35SchorlomiteCa3(Ti,Fe3+)2((Si,Fe3+)O4)3Iso.
14.9.36TinaksiteK2Na(Ca,Mn2+)2Ti[O|Si7O18(OH)]Tric.
14.9.37Janhaugite(Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2Mon. 2/m : P21/m
14.9.38KoashviteNa6(Ca,Mn)(Ti,Fe)Si6O18 · H2OOrth.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for HejtmaniteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Vrana, S., Rieder, M. & Gunter, M. E. (1992): Hejtmanite, a manganese-dominant analogue of bafertisite, a new mineral. European Journal of Mineralogist: 4, 35-43.
American Mineralogist: 77: 1306.
Sokolova, E. (2010): Predictive crystal-chemical relations in Ti-silicates based on the TS block. Geology of Ore Deposits: 52(5): 410-427.
Sokolova, E., Cámara, F., Hawthorne, F.C., Pautov, L.A. (2016): From structure topology to chemical composition. XX. Titanium silicates: the crystal structure of hejtmanite, Ba2Mn4Ti2(Si2O7)2O2(OH)2F2, a Group-II TS-block mineral. MIneralogical Magazine: 80 (in press); http://forum.amiminerals.it/viewtopic.php?f=5&t=12499 (2016)

Internet Links for HejtmaniteHide

Localities for HejtmaniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
France
 
  • Occitanie
    • Aveyron
Kruszewski, Ł., Gatel, P., Thiéry, V., Moszumańska, I., and Kusy, D. (2018) Crystallochemical Behavior of Slag Minerals and the Occurrence of Potentially New Mineral Species from Lapanouse-de-Sévérac, France. In: Stracher, G.B. (Ed.) Coal and Peat Fires: A Global Perspective, Vol. 5: Case Studies - Advances in Field and Laboratory Research, xx-xx (in press; publication date: November 2018).
Japan
 
  • Honshu Island
    • Chubu Region
      • Aichi Prefecture
        • Kita-Shidara-gun
          • Shidara-cho
Yamada collection (Crystal World, Japan)
    • Tohoku Region
      • Iwate Prefecture
        • Shimohei-gun
          • Fudai-mura
Alfredo Petrov collection
Kyrgyzstan
 
  • Issyk-Kul Oblast (Ysyk-Köl Oblast)
    • Inyl'chek Range
      • Muzeinyi Valley
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
Russia
 
  • Eastern-Siberian Region
    • Prebaikalia (Pribaikal'e)
      • Buriatia (Buryatia)
        • Mama River Basin
          • Maigunda River
Ganzeev A.A., e.a. Geochemistry, 1968, N3, p.335.
    • Transbaikalia (Zabaykalye)
      • Chitinskaya Oblast'
Sharygin, V. V., & Vladykin, N. V. (2014). Mineralogy of cryolite rocks from the Katugin massif, Transbaikalia, Russia. Abstract Book of 30th International Conference on “Ore Potential of Alkaline, Kimberlite and Carbonatite Magmatism,” Antalya, Turkey, 166-168.
  • Northern Region
    • Murmanskaya Oblast'
Lykova, I. S., Pekov, I. V., Kononkova, N. N., & Shpachenko, A. K. Bafertisite and jinshajiangite from the Gremyakha-Vyrmes alkaline complex, Kola Peninsula.
South Africa
 
  • North West Province
    • Bojanala Platinum District
      • Western Bushveld Complex
R. Liferovich - L. Horváth p.c. (2004)
Tajikistan
 
  • Region of Republican Subordination
    • Tien Shan Mtn
      • Alai Range (Alayskiy)
http://www.koeln.netsurf.de/~w.steffens/dara.htm
Ukraine
 
  • Donetsk (Donets'k) Oblast'
    • Azov Sea Region
      • Oktyabr'skii Massif (Mariupol'skii)
Victor V. Sharygin analytycal data (2013)
Zambia (TL)
 
  • Central Province
    • Mkushi District
      • Mkushi
        • Mkushi River area
European Journal of Mineralogy(1992) 4, 35-43
Mineral and/or Locality  
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