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Hillebrandite

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About HillebranditeHide

02131770014947005739252.jpg
William Francis Hillebrand
Formula:
Ca2(SiO3)(OH)2
Colour:
White, colorless, very pale greenish white.
Lustre:
Sub-Vitreous
Hardness:
5 - 5½
Specific Gravity:
2.66 - 2.69
Crystal System:
Orthorhombic
Name:
Named by Fred Eugene Wright in 1908 in honor of William Francis Hillebrand (12 December 1853, Honolulu, Hawaii, USA - 7 February 1925, Washington, D.C., USA). Hillebrand was regarded as one of the best wet analytical method chemists in the USA and was with the U.S. Geological Survey. He described 5 new minerals himself, and 11 others jointly.
White fibrous crystals typical. Compare 'UM1977-14-SiO:CaH'.


Classification of HillebranditeHide

Approved, 'Grandfathered' (first described prior to 1959)
First Published:
1908
8/F.18-100
9.DG.40

9 : SILICATES (Germanates)
D : Inosilicates
G : Inosilicates with 3-periodic single and multiple chains
65.2.3.1

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
2 : Single-Width Unbranched Chains, W=1 with chains P=3
14.5.14

14 : Silicates not Containing Aluminum
5 : Silicates of Ca

Physical Properties of HillebranditeHide

Sub-Vitreous
Transparency:
Translucent
Colour:
White, colorless, very pale greenish white.
Streak:
White
Hardness:
5 - 5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
{010}
Density:
2.66 - 2.69 g/cm3 (Measured)    2.69 g/cm3 (Calculated)

Optical Data of HillebranditeHide

Type:
Biaxial (-)
RI values:
nα = 1.598 - 1.607 nβ = 1.603 - 1.610 nγ = 1.603 - 1.614
2V:
Measured: 51° to 60°, Calculated: 64°
Birefringence:
0.007-0.009
Max Birefringence:
δ = 0.005 - 0.007
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
strong
Optical Extinction:
Z=c

Chemical Properties of HillebranditeHide

Formula:
Ca2(SiO3)(OH)2
IMA Formula:
Ca2SiO3(OH)2
Common Impurities:
Ti,Al,Fe,Mn,Mg,Na,K

Crystallography of HillebranditeHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Cmcm
Cell Parameters:
a = 3.63 Å, b = 16.31 Å, c = 11.82 Å
β = 90°
Ratio:
a:b:c = 0.223 : 1 : 0.725
Unit Cell V:
699.81 ų (Calculated from Unit Cell)
Z:
12
Morphology:
Rod-like to fibrous
Comment:
Non-standard setting Cmc21; also momoclinic with beta = 90 degrees

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001745HillebranditeDai Y S, Post J E (1995) Crystal structure of hillebrandite: A natural analogue of calcium silicate hydrate (CSH) phases in Portland cement American Mineralogist 80 841-84419950293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.81 Å(30)
3.36 Å(20)
3.03 Å(30)
2.93 Å(100)
2.84 Å(20)
2.79 Å(30)
2.25 Å(20)
1.82 Å(40)
Comments:
42-538

Type Occurrence of HillebranditeHide

General Appearance of Type Material:
White fibers in dense aggregates
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 86531.
Geological Setting of Type Material:
High temperature contact metamorphic mineral in marbles
Associated Minerals at Type Locality:

Other Language Names for HillebranditeHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Hillebrandite associated with VesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9
3 photos of Hillebrandite associated with SpurriteCa5(SiO4)2(CO3)
2 photos of Hillebrandite associated with CalciteCaCO3
2 photos of Hillebrandite associated with WollastoniteCaSiO3
2 photos of Hillebrandite associated with MonticelliteCaMgSiO4
2 photos of Hillebrandite associated with ChegemiteCa7(SiO4)3(OH)2
2 photos of Hillebrandite associated with LarniteCa2SiO4

Related Minerals - Nickel-Strunz GroupingHide

9.DG.Barrydawsonite-(Y)Na1.5Y0.5CaSi3O8(OH)Mon. 2/m : P21/b
9.DG.05BustamiteCaMn2+(Si2O6)Tric. 1 : P1
9.DG.05FerrobustamiteCaFe2+(Si2O6)Tric.
9.DG.05PectoliteNaCa2Si3O8(OH)Tric. 1 : P1
9.DG.05SeranditeNaMn2+2Si3O8(OH)Tric. 1 : P1
9.DG.05WollastoniteCaSiO3Tric. 1 : P1
9.DG.05Wollastonite-1ACaSiO3Tric. 1 : P1
9.DG.07CascanditeCaScSi3O8(OH)Tric. 1
9.DG.08Plombièrite[Ca4Si6O16(OH)2 · 2H2O] · (Ca · 5H2O)Orth.
9.DG.10Clinotobermorite[Ca4Si6O17 · 2H2O] · (Ca · 3H2O)Mon.
9.DG.10RiversideiteCa5(HSi3O9)2 · 2H2OOrth.
9.DG.10Tobermorite[Ca4Si6O17 · 2H2O] · (Ca · 3H2O)Orth.
9.DG.15FoshagiteCa4(Si3O9)(OH)2Tric.
9.DG.20JenniteCa9(Si3O9)2(OH)8 · 8H2OTric.
9.DG.25ParaumbiteK3Zr2H(Si3O9)2 · nH2OOrth.
9.DG.25UmbiteK2(Zr,Ti)Si3O9 · H2OOrth.
9.DG.30SørenseniteNa4SnBe2Si6O16(OH)4Mon. 2/m : B2/b
9.DG.35XonotliteCa6(Si6O17)(OH)2Mon. 2/m
9.DG.45ZoriteNa8(Ti,Nb)5(Si6O17)2(OH,O)5 · 14H2OOrth.
9.DG.45ChivruaiiteCa4(Ti,Nb)5(Si6O17)2(OH,O)5 · 13-14H2OOrth. mmm (2/m 2/m 2/m) : Cmmm
9.DG.50Haineaultite(Na,Ca)5Ca(Ti,Nb)5(Si6O17)2(OH,F)8 · 5H2OOrth. 2 2 2 : C2 2 2
9.DG.55EpididymiteNa2Be2Si6O15 · H2OOrth. mmm (2/m 2/m 2/m) : Pnma
9.DG.60EudidymiteNa2Be2Si6O15 · H2OMon. 2/m : B2/b
9.DG.65ElpiditeNa2ZrSi6O15 · 3H2OOrth.
9.DG.70Fenaksite(K,Na)4(Fe,Mn)2(Si4O10)2(OH,F)Tric.
9.DG.70LitidioniteCuNaKSi4O10Tric.
9.DG.70ManaksiteKNaMnSi4O10Tric.
9.DG.75TinaksiteK2Na(Ca,Mn2+)2TiO[Si7O18(OH)]Tric.
9.DG.75TokkoiteK2Ca4[Si7O18(OH)](OH,F)Tric.
9.DG.75SenkevichiteCsKNaCa2TiO[Si7O18](OH)Tric. 1 : P1
9.DG.80CanasiteK3Na3Ca5Si12O30(OH)4Mon.
9.DG.80FluorcanasiteK3Na3Ca5Si12O30F4 · H2OMon. m : Bm
9.DG.85MiseriteK1.5-x(Ca,Y,REE)5(Si6O15)(Si2O7)(OH,F)2 · yH2OTric.
9.DG.90FrankameniteK3Na3Ca5(Si12O30)(F,OH)4 · H2OTric.
9.DG.92Charoite(K,Sr)15-16(Ca,Na)32[Si6O11(O,OH)6]2[Si12O18(O,OH)12]2[Si17O25(O,OH)18]2(OH,F)4 · ~3H2OMon. 2/m : P21/m
9.DG.95YuksporiteK4(Ca,Na)14(Sr,Ba)2(◻,Mn,Fe)(Ti,Nb)4(O,OH)4(Si6O17)2(Si2O7)3(H2O,OH)3Orth.
9.DG.97Eveslogite(Na,K,Ca,Sr,Ba)48 [(Ti,Nb,Mn,Fe2+)12Si48O144(OH)12](F,OH,Cl)14Mon. 2/m : P2/m

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

14.5.1WollastoniteCaSiO3Tric. 1 : P1
14.5.2Wollastonite-7TCaSiO3
14.5.3Wollastonite-2MCaSiO3Mon. 2/m : P21/b
14.5.4RankiniteCa3Si2O7Mon. 2/m : P21/b
14.5.5KilchoaniteCa6(SiO4)(Si3O10)Orth.
14.5.6LarniteCa2SiO4Mon. 2/m
14.5.7BredigiteCa7Mg(SiO4)4Orth.
14.5.8HatruriteCa3(SiO4)OTrig.
14.5.9RosenhahniteHCa3[Si3O9(OH)]Tric.
14.5.10DellaiteCa6Si3O11(OH)2Tric.
14.5.11AfwilliteCa3(HSiO4)2 · 2H2OMon. m : Bb
14.5.12XonotliteCa6(Si6O17)(OH)2Mon. 2/m
14.5.13FoshagiteCa4(Si3O9)(OH)2Tric.
14.5.15JaffeiteCa6(Si2O7)(OH)6Trig. 3 : P3
14.5.16SuoluniteCa2(H2Si2O7) · H2OOrth.
14.5.17KillalaiteCa6.4(H0.6Si2O7)2(OH)2Mon.
14.5.18OkeniteCa10Si18O46 · 18H2OTric. 1 : P1
14.5.19RiversideiteCa5(HSi3O9)2 · 2H2OOrth.
14.5.20TrabzoniteCa4(Si3O9)(OH)2Orth. mm2 : Ama2
14.5.21GyroliteNaCa16Si23AlO60(OH)8 · 14H2OTric. 1 : P1
14.5.22FoshallasiteCa3[Si2O7] · 3H2O(?)
14.5.23Tobermorite[Ca4Si6O17 · 2H2O] · (Ca · 3H2O)Orth.
14.5.24Clinotobermorite[Ca4Si6O17 · 2H2O] · (Ca · 3H2O)Mon.
14.5.25NekoiteCa3Si6O15 · 7H2OTric. 1 : P1
14.5.26Plombièrite[Ca4Si6O16(OH)2 · 2H2O] · (Ca · 5H2O)Orth.
14.5.27JenniteCa9(Si3O9)2(OH)8 · 8H2OTric.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for HillebranditeHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Wright, F.E. (1908) On three contact minerals from Valardeña, Durango, Mexico. (Gehlenite, spurrite and hillebrandite). American Journal of Science: 176: 545-554.
Claringbull, G.F. (1953) Mineralogical Society (London). American Mineralogist: 38: 734-737.
Dai, Y., Post, J.E. (1995) Crystal structure of hillebrandite: A natural analogue of calcium silicate hydrate (CSH) phases in Portland cement. American Mineralogist: 80: 841-844.
Xu, H., Buseck, P.R. (1996) TEM investigation of the domain structure and superstructure in hillebrandite, Ca2SiO3(OH)2. American Mineralogist: 81: 1371-1374.
Zadov, A.E., Pertsev, N.N., Belakovsky, D.I., Chukanov, N.V., Kuznetsova, O.Y. (2004) Foshagite and hillebrandite from skarn xenoliths of Ioko-Dovyrensky massif. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 133(1): 73-83.

Internet Links for HillebranditeHide

Localities for HillebranditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Australia
 
  • Tasmania
    • Huon Valley municipality
      • Huon-Channel region
        • Weld River district
R Bottrill in prep
Germany
 
  • Rhineland-Palatinate
    • Vulkaneifel District
      • Daun
        • Üdersdorf
Blaß, G. and Kruijen, F. (2015) Neuigkeiten aus der Vulkaneifel (II/2015). Mineralien-Welt, 26(5), 80-90.
Israel
 
  • Southern District (HaDarom District)
    • Tamar Regional Council
Galuskin, E.V., Gfeller, F., Armbruster, T., Sharygin, V.V., Galuskina, I.O., Krivovichev, S.V., Vapnik, Y., Murashko, M., Dzierżanowski, P., Wirth, R. (2015): Mayenite supergroup, part III: Fluormayenite, Ca12Al14O32[□4F2], and fluorkyuygenite, Ca12Al14O32[(H2O)4F2], two new minerals from pyrometamorphic rocks of the Hatrurim Complex, South Levant. European Journal of Mineralogy, 27, 123-136
Sharygin, Victor V.; Yakovlev, Grigory A.; Wirth, Richard; Seryotkin, Yurii V.; Sokol, Ellina V.; Nigmatulina, Elena N.; Karmanov, Nikolai S.; Pautov, Leonid A. (2019) Nataliakulikite, Ca4Ti2(Fe3+,Fe2+)(Si,Fe3+,Al)O11, a New Perovskite-Supergroup Mineral from Hatrurim Basin, Negev Desert, Israel. Minerals 9, no. 11: 700.
Japan
 
  • Hiroshima Prefecture
    • Shoubara City
Kusachi et al (1971) Koubutsugaku Zasshi, 10, 296-304.; Kusachi, I., Numano, T., & Henmi, K. (1971). Contact minerals from Kushiro, Hiroshima Prefecture; 3, Foshagite, Hillebrandite and Scawtite. Journal of the Mineralogical Society of Japan, 10, 296-304.
Yamada, S. (2004) Nihonsan-koubutsu Gojuon-hairetsu Sanchi-ichiranhyou (111 pp.)
  • Okayama Prefecture
    • Takahashi City
      • Bicchu-cho (Bitchu-cho)
        • Fuka
Mineralogical Journal Vol. 14 (1989) , No. 7 pp 299-302; KUSACHI, I., & HENMI, C. (1991). Sillenite from Fuka, Okayama prefecture, Japan. Mineralogical Journal, 15(8), 343-348.
Mexico (TL)
 
  • Durango
    • Cuencamé Municipality
      • Velardeña District
        • Velardeña
Amer.J.Sci., ser. 4 (1908) 26, 545-554; Panczner (1987): 234.; Wright F E (1908) On three contact minerals from Valardeña, Durango, Mexico. (Gehlenite, spurrite and hillebrandite). American Journal of Science 176, 545-554
Middle East
 
Gross, S. (1977): The Mineralogy of the Hatrurim Formation, Israel. Geological Survey of Israel, Bulletin no. 70, 80 pp.
Namibia
 
  • Otjozondjupa Region
    • Grootfontein
      • Kombat
Dunn, P.J. (1991), Rare minerals of the Kombat Mine, Mineralogical Record: 22(6): 421-425.
Norway
 
  • Telemark
    • Skien
Jamtveit B., Dahlgren S. and Austrheim H. (1997): High-grade contact metamorphism of calcareous rocks from the Oslo Rift, Southern Norway. American Mineralogist. 82 : 1241 - 1254
Palestine
 
  • West Bank
    • Quds Governorate
Galuskin, E.V., Gfeller, F., Armbruster, T., Sharygin, V.V., Galuskina, I.O., Krivovichev, S.V., Vapnik, Y., Murashko, M., Dzierżanowski, P., Wirth, R. (2015): Mayenite supergroup, part III: Fluormayenite, Ca12Al14O32[□4F2], and fluorkyuygenite, Ca12Al14O32[(H2O)4F2], two new minerals from pyrometamorphic rocks of the Hatrurim Complex, South Levant. European Journal of Mineralogy, 27, 123-136.
Russia
 
  • Kabardino-Balkaria
    • Baksan Valley
Bailau, R., Gałuskin, E. V., Gazeev, V. M., & Gałuskina, I. O. Raman investigation of potential new mineral-Fe 3-analogue of wadalite from calcareous-silicate xenoliths of the Upper Chegem caldera, Northern Caucasus, Russia.
        • Lakargi Mountain
Galuskina, I.O., Krüger, B., Galuskin, E.V. ,Armbruster, T., Gazeev, V.M., Włodyka, R., Dulski, M. & Dzierżanowski, P. (2015): Fluorchegemite, Ca7(SiO4)3F2, a new mineral from the edgrewitebearing endoskarn zone of an altered xenolith in ignimbrites from Upper Chegem Caldera, Northern Caucasus, Kabardina-balkaria, Russia; Occurrence, crystal structure, and new data on the mineral assemblages. Canadian Mineralogist. 53, 325-344.
  • Murmansk Oblast
    • Turii Cape
Keith Bell, Elizabeth Ann Dunworth, Andrei G. Bulakh, and Valeriy V. Ivanikov (1996) Alkaline rocks of the Turiy Peninsula, Russia, including type-locality turjaite and turjite; a review. Can Mineral, v. 34, p. 265-280
  • Sverdlovsk Oblast
    • Asbest
Antonov A.A. [Антонов А.А.] (2003): Mineralogy of rodingites of the Bazhenovsk ultrabasic massif [Минералогия родингитов Баженовского гипербазитого массива]. Nauka, Sankt-Peterburg, 129 pp. (in Russian).
Saudi Arabia
 
  • Ha'il Region
Mineralogical Record (1977) 8:391
South Africa
 
Buick, I.S., Gibson, R., Wallmach, T. and Metz, J. 2000. The occurrence of cuspidine, foshagite and hillebrandite in calc-silicate xenoliths from the Bushveld Complex, South Africa. South African Journal of Geology, 103, 249-254.
Turkey
 
  • Rize Province
Am Min 73:11-12 p 1497; Sarp H, Burri G (1987) Yeni bir mineral, trabzonit, Ca4 Si3 O10 2H2O. Bulletin of the Geological Society of Turkey 30, 57-60; Armbruster T, Yang P, Liebich B W (1996) Mechanism of the SiO4 for CO3 substitution in defernite, Ca6(CO3)1.58(Si2O7)0.21(OH)7[Cl0.50(OH)0.08(H2O)0.42]: a single-crystal X-ray study at 100 K. American Mineralogist 81, 625-631; Taner, M. F., Martin, R. F., & Gault, R. A. (2013). The Mineralogy of Skarns of the Spurrite–Merwinite Subfacies, Sanidinite Facies, Güneyce–Ikizdere Area, Eastern Black Sea, Turkey. The Canadian Mineralogist, 51(6), 893-911.
USA
 
  • Arizona
    • Cochise County
Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 251, 414; Butler, B.S., et al (1938b), Geology and ore deposits of the Tombstone district, AZ, AZ Bur. Mines Bull. 143; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 97, 103.
  • California
    • Riverside Co.
      • Crestmore
        • Crestmore quarries
          • Sky Blue Hill
Eakle, Arthur Starr (1925a), Foshagite, a new silicate from Crestmore, California: American Mineralogist: 10: 97-99; Vigfussen, V.A. (1931), The system CaO-SiO2-H2O, hillebrandite and foshagite: American Journal of Science, 5th series: 21: 76; Woodford, A.O., Crippen, R.A., and Garner, K.B. (1941) Section Across Commercial Quarry, Crestmore, California. American Mineralogist: 26: 352-381; Woodford, A.O. (1943), Crestmore minerals: California Division Mines Report 39: 357; Pemberton, H. Earl (1983), Minerals of California; Van Nostrand Reinholt Press: 477.
Woodford, A.O., Crippen, R.A., and Garner, K.B. (1941) Section Across Commercial Quarry, Crestmore, California. American Mineralogist: 26: 352-381.
  • Washington
    • Snohomish Co.
      • Sultan Mining District
        • Sultan Basin
          • Vesper Peak
Huntting, M. (1956): Inventory of Washington Minerals, Part II, Metallic Minerals, Vol. 1, p.83; Cannon, B. (1975): Minerals of Washington, p.105
 
Mineral and/or Locality  
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