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Hureaulite

A valid IMA mineral species - grandfathered
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About HureauliteHide

Formula:
Mn2+5(PO3OH)2(PO4)2 · 4H2O
Colour:
Commonly pink to colorless, also Red, orange, orange-red, reddish brown, yellowish brown, violet-rose, amber, gray
Lustre:
Vitreous, Sub-Vitreous, Greasy
Hardness:
5
Specific Gravity:
3.15 - 3.20
Crystal System:
Monoclinic
Name:
Named by François Alluaud II in 1825 for the type locality, the village of Hureaux, Haute Vienne Department, Limousin, France. A diacritical mark has been used in the name, "huréaulite", but the town does not use a diacritical mark in its name. In 1912, Waldemar Schaller named a red mineral from Pala, California, USA, "palaite", but the mineral has proved to be only a color variety of hureaulite. Baldaufite was named in 1925 by Franz Mullbauer. De Jesus (1933) named pseudopalaite.
Hureaulite Group.

Originally sometimes called huréaulite; spelling re-defined by Burke (2008).

Study of Gatta (2016) on the material from Jocão pegmatite shows that in the structure there are/is: (1) 5 independent H sites, (2) no zeolitic water, (3) two water molecules standing for vertices of (Mn,Fe) octahedra, (4) only divalent Fe, (5) complex hydrogen bonding system. Iron occupies mostly the M2 site.




Unique IdentifiersHide

Mindat ID:
1952
Long-form identifier:
mindat:1:1:1952:7
GUID
(UUID V4):
0e18ee84-cb12-4c26-99c0-7c756e5b0d9b

IMA Classification of HureauliteHide

Approved, 'Grandfathered' (first described prior to 1959)
First published:
1825

Classification of HureauliteHide

8.CB.10

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
B : With only medium-sized cations, RO4:H2O = 1:1
39.2.1.1

39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
2 : (AB)5[HXO4]2[XO4]2.xH2O
19.12.22

19 : Phosphates
12 : Phosphates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
HurIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
HurThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of HureauliteHide

Vitreous, Sub-Vitreous, Greasy
Transparency:
Transparent, Translucent
Comment:
Bright
Colour:
Commonly pink to colorless, also Red, orange, orange-red, reddish brown, yellowish brown, violet-rose, amber, gray
Streak:
Nearly white
Hardness:
Tenacity:
Brittle
Cleavage:
Distinct/Good
{100}, good.
Fracture:
Irregular/Uneven
Density:
3.15 - 3.20 g/cm3 (Measured)    3.23 g/cm3 (Calculated)
Comment:
Measured values on Vilate material; 3.15 on Branchville material.

Optical Data of HureauliteHide

Type:
Biaxial (-)
RI values:
nα = 1.637 - 1.657 nβ = 1.645 - 1.667 nγ = 1.649 - 1.671
2V:
Measured: 75° to 82°, Calculated: 70° to 84°
Birefringence:
0.015
Max Birefringence:
δ = 0.012 - 0.014
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v very strong; crossed.
Optical Extinction:
X = b, Z^c ~ 61°-75°
Pleochroism:
Visible
Comments:
X = Colourless
Y = Yellow to light pink
Z = Reddish yellow to reddish brown
Comments:
Fe substitution increases RI, a few chemical analyses show Fe>Mn.

Chemistry of HureauliteHide

Mindat Formula:
Mn2+5(PO3OH)2(PO4)2 · 4H2O

Crystallography of HureauliteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 17.594(10) Å, b = 9.086(5) Å, c = 9.404(5) Å
β = 96.67(8)°
Ratio:
a:b:c = 1.936 : 1 : 1.035
Unit Cell V:
1493.14 ų
Z:
4
Morphology:
Crystals short prismatic [001] with large sloping termination; tabular {100} at times; equant. Crystals individuals or in groups; fascicled at times. Massive, compact, scaly, or imperfectly fibrous.
Comment:
C2/c setting

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000314HureauliteMoore P B, Araki T (1973) Hureaulite, Mn5(H2O)4[PO3(OH)]2[PO4]2: Its atomic arrangement American Mineralogist 58 302-30719730293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.75 Å(40)
8.09 Å(70)
4.55 Å(40)
3.20 Å(30)
3.15 Å(100)
2.99 Å(70)
2.63 Å(40)
2.19 Å(30)
Comments:
ICDD 39-146; also 16-383

Geological EnvironmentHide

Paragenetic Mode(s):
Geological Setting:
Granite pegmatite late stage phosphate mineralization.

Type Occurrence of HureauliteHide

Geological Setting of Type Material:
Zone of altered Triphylite in granite pegmatite
Associated Minerals at Type Locality:
Reference:
Vauquelin, L.N. (1825) Analyse de l´huraulite, minéral trouvé dans la commune d´Hureaux. Annales de Chimie et de Physique: 3: 302-307.

Synonyms of HureauliteHide

Other Language Names for HureauliteHide

Varieties of HureauliteHide

BastiniteA lithian variety of Hureaulite which has a characteristic platy morphology.

Relationship of Hureaulite to other SpeciesHide

Other Members of this group:
ChongiteCa3Mg2(AsO4)2(AsO3OH)2 · 4H2OMon. 2/m : B2/b
GiftgrubeiteCaMn2Ca2(AsO4)2(AsO3OH)2 · 4H2OMon. 2/m : B2/b
MiguelromeroiteMnMn2Mn2(AsO4)2(HAsO4)2 · 4H2OMon. 2/m : B2/b
NyholmiteCd3Zn2(AsO4)2(HAsO4)2 · 4H2OMon. 2/m : B2/b
SainfelditeCa5(AsO4)2(AsO3OH)2 · 4H2OMon. 2/m : B2/b
VillyaelleniteMnMn2Ca2(AsO4)2(HAsO4)2 · 4H2OMon. 2/m : B2/b

Common AssociatesHide

Associated Minerals Based on Photo Data:
158 photos of Hureaulite associated with RockbridgeiteFe2+Fe3+4(PO4)3(OH)5
112 photos of Hureaulite associated with CorreianevesiteFe2+Mn2+2(PO4)2 · 3H2O
49 photos of Hureaulite associated with StrengiteFePO4 · 2H2O
45 photos of Hureaulite associated with BarbosaliteFe2+Fe3+2(PO4)2(OH)2
41 photos of Hureaulite associated with VivianiteFe2+Fe2+2(PO4)2 · 8H2O
41 photos of Hureaulite associated with LeucophosphiteKFe3+2(PO4)2(OH) · 2H2O
32 photos of Hureaulite associated with PhosphosideriteFePO4 · 2H2O
29 photos of Hureaulite associated with TriphyliteLiFe2+PO4
24 photos of Hureaulite associated with Jahnsite GroupXM1M22M32(H2O)8(OH)2(PO4)4
20 photos of Hureaulite associated with TavoriteLiFe3+(PO4)(OH)

Related Minerals - Strunz-mindat GroupingHide

8.CB.KrupičkaiteCu6[AsO3(OH)]6 · 8H2OMon. 2/m : P21/b
8.CB.ErmeloiteAl(PO4) · H2OMon. 2/m : B2/b
8.CB.05SerrabrancaiteMnPO4 · H2OMon. 2/m : B2/b
8.CB.10VillyaelleniteMnMn2Ca2(AsO4)2(HAsO4)2 · 4H2OMon. 2/m : B2/b
8.CB.10UM1997-09-AsO:CaHMgZn(Mg,Ca,Zn)5(AsO4)2(HAsO4)2 · 4H2OMon.
8.CB.10NyholmiteCd3Zn2(AsO4)2(HAsO4)2 · 4H2OMon. 2/m : B2/b
8.CB.10MiguelromeroiteMnMn2Mn2(AsO4)2(HAsO4)2 · 4H2OMon. 2/m : B2/b
8.CB.10GiftgrubeiteCaMn2Ca2(AsO4)2(AsO3OH)2 · 4H2OMon. 2/m : B2/b
8.CB.15KrautiteMn(HAsO4) · H2OMon. 2 : P21
8.CB.20CobaltkoritnigiteCo(AsO3OH) · H2OTric. 1 : P1
8.CB.20KoritnigiteZn(AsO3OH) · H2OTric. 1 : P1
8.CB.20MagnesiokoritnigiteMg(AsO3OH) · H2OTric. 1 : P1
8.CB.25YvoniteCu(HAsO4) · 2H2OTric. 1 : P1
8.CB.30GeminiteCu2+(AsO3OH) · H2OTric. 1 : P1
8.CB.35SchubneliteFe3+VO4 · H2OTric. 1 : P1
8.CB.40RadovaniteCu2Fe3+(AsO4)(HAs3+O3)2 · H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.CB.45KazakhstaniteFe3+5V4+3V5+12O39(OH)9 · 9H2OMon.
8.CB.50KolovratiteNixZny(VO4)0.67(x+y) · nH2O
8.CB.60BurgessiteCo2(H2O)4[AsO3(OH)]2(H2O)Mon. 2/m
8.CB.60HonzaiteNi2(AsO3OH)2 · 5H2OMon. 2/m : P21/m
8.CB.65CarditeZn5.5(AsO4)2(AsO3OH)(OH)3 · 3H2OOrth. mmm (2/m 2/m 2/m) : Cmcm

Fluorescence of HureauliteHide

Not fluorescent.

Other InformationHide

Notes:
Readily soluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HureauliteHide

References for HureauliteHide

Reference List:

Localities for HureauliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Córdoba Province
    • San Alberto Department
      • Tránsito District
        • Pampa de Achala
Gay et al. (1991) +1 other reference
  • San Luis Province
    • Coronel Pringles Department
      • El Trapiche
        • La Florida
OYARZABAL et al. (H2O)
      • Totoral pegmatitic field
OYARZABAL et al. (H2O)
OYARZABAL et al. (H2O)
    • San Martín Department
Roda-Robles et al. (2012)
Australia
 
  • South Australia
    • Eyre Peninsula
      • Middleback Range
        • Iron Knob
    • Olary Province
      • Boolcoomatta Reserve (Boolcoomata Station)
  • Western Australia
    • Port Hedland Shire
      • Abydos Station
        • Wodgina
Jacobson et al. (2007)
      • Strelley Station
Jacobson et al. (2007)
Brazil
 
  • Minas Gerais
    • Água Boa
Dunn et al. (1978)
    • Conselheiro Pena
      • Barra do Cuieté
[var: Bastinite] King (n.d.)
sergio varvello
Baijot et al. (2014) +1 other reference
Sergio Varvello collection +1 other reference
Carlos Barbosa specimen
      • Ferruginha
Sergio Varvello photo
    • Divino das Laranjeiras
Carlos Barbosa specimen
Collect on mineral trip
fabreminerals specimen
    • Galiléia
      • Sapucaia do Norte
Atencio et al. (2004)
Cassedanne et al. (1999) +1 other reference
    • Itinga
      • Jenipapo pegmatite field
Sergio Varvello collection
      • Taquaral
        • Piauí Valley
Carlos Barbosa specimen
    • Mendes Pimentel
Atencio et al. (2006)
  • Pará
    • Canaã dos Carajás
      • Serra Sul Project
        • S11D Deposit
Piló et al. (2023)
  • Paraíba
    • Frei Martinho
Cassedanne et al. (1991)
    • Pedra Lavrada
Murdoch (1955)
Wegner et al. (1998)
    • Picuí
Sergio Varvello collection
  • Rio Grande do Norte
    • Parelhas
Amores et al. (2014) +1 other reference
Canada
 
  • British Columbia
    • Revelstoke Mining Division
      • Revelstoke
DIXON et al. (2014)
Czech Republic
 
  • Plzeň Region
    • Domažlice District
      • Otov
Č +4 other references
DR Congo
 
  • South Kivu
    • Mwenga Territory
Thoreau (1957)
Finland
 
  • North Karelia
    • Tohmajärvi
Teertstra et al. (1993)
  • Pirkanmaa
    • Orivesi
      • Eräjärvi area
Lahti (1981)
Lahti (1981)
Geological Survey of Finland Bulletin ... +1 other reference
  • South Ostrobothnia
    • Kuortane
Joel Dyer collection
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Bellac
        • Bessines-sur-Gartempe
perso.wanadoo.fr (2004)
        • Razès
          • Chanteloube
Palache et al. (1951)
Anthony et al. (2000)
Boisson (1988)
      • Limoges
        • Saint-Sylvestre
Palache et al. (1951) +1 other reference
  • Occitanie
    • Pyrénées-Orientales
      • Céret
        • Collioure
BERBAIN. C et al. (2016)
Germany
 
  • Bavaria
    • Lower Bavaria
      • Regen District
        • Zwiesel
          • Rabenstein
Weiß (1990)
    • Upper Palatinate
      • Neustadt an der Waldnaab District
        • Waidhaus
          • Hagendorf
Dill H.G.: "Mineralogical and chemical ... +1 other reference
www.berthold-weber.de (2001) +1 other reference
Wittern (2001) +1 other reference
  • North Rhine-Westphalia
    • Arnsberg
      • Märkischer Kreis
        • Iserlohn
          • Letmathe
Blaß et al. (1994) +1 other reference
Japan
 
  • Ibaraki Prefecture
    • Kasumigaura City
      • Chiyoda-machi
Matsubara & Kato (1996)
Kazakhstan
 
  • East Kazakhstan Region
    • Ulan District
      • Belogorskiy
Pekov (1998)
Madagascar
 
  • Amoron'i Mania
    • Ambatofinandrahana District
      • Mandrosonoro
Behier (1960)
  • Haute Matsiatra
    • Ikalamavony District
      • Fitampito
Behier (1960)
Morocco
 
  • Drâa-Tafilalet Region
    • Ouarzazate Province
      • Amerzgane Cercle
        • Ouisselsate Caïdat
FRANSOLET (1974)
  • Marrakesh-Safi Region
    • Rehamna Province
      • Sidi Bou Othmane Cercle
        • Jebilet Mtn (Djebilet Mtn)
          • Sidi Bou Othmane
Favreau (2012)
Mozambique
 
  • Zambezia Province
Wilson et al. (2000)
    • Gilé District
Neves et al. (1968)
Namibia
 
  • Erongo Region
    • Dâures Constituency
von Bezing (2007)
Keller (1985)
    • Karibib Constituency
      • Etusis Farm 75
von Bezing (2007)
      • Okatjimukuju Farm 55 (Friedrichsfelde Farm)
P. Keller and O. von Knorring
      • Okongava Ost Farm 72
Keller et al. (2007)
von Bezing (2007)
Bezing et al. (2007)
      • Tsaobismund Farm 85
von Bezing (2007)
Contrib Mineral Petrol (1986)
  • ǁKaras Region
    • Berseba Constituency
von Bezing (2007)
Norway
 
  • Nordland
    • Meløy
      • Holandsfjorden
Kristiansen (1972) +1 other reference
Poland
 
  • Lower Silesian Voivodeship
    • Dzierżoniów County
      • Gmina Niemcza
        • Gilów
Pieczka A.
      • Piława Górna
        • DSS Piława Górna Quarry
Pieczka et al. (2015) +1 other reference
    • Świdnica County
      • Gmina Świdnica
Włodek et al. (2015)
        • Michałkowa pegmatites
Pieczka et al. (2015) +1 other reference
Barsch O.
Portugal
 
  • Guarda
    • Gouveia
      • Folgosinho
Garate et al. (2012)
    • Guarda
Identified by C. Rewitzer
      • Vela
Pedro Alves collection.
    • Sabugal
      • Bendada
Schnorrer-Köhler (1991)
Pedro Alves collection
  • Viana do Castelo
    • Ponte da Barca
      • Touvedo (São Lourenço e Salvador)
Self-collected by Pedro Alves.
    • Viana do Castelo
4 +4 other references
  • Vila Real
    • Vila Pouca de Aguiar
      • Alfarela de Jales
Neves (1960)
  • Viseu
Palache et al. (1951)
      • Mangualde (Mesquitela e Cunha Alta)
Gramaccioli (1981) +3 other references
Pedro Alves collection (p-XRD and SEM EDS analysed samples)
Rui Nunes February +1 other reference
    • Penalva do Castelo
      • Castelo de Penalva
António Joaquim Monteiro
    • Sátão
      • Ferreira de Aves
        • Aldeia Nova
    • Vila Nova de Paiva
Identified in Rebentão Mine
      • Queiriga
        • Lagares do Estanho Mines
Nuno Afonso collection
Romania
 
  • Sibiu County
    • Lotru-Cibin Mountains
Androne et al. (2005)
Rwanda
 
  • Western Province
    • Ngororero District
      • Muhororo
Bertossa (1968) +1 other reference
South Africa
 
  • Northern Cape
    • ZF Mgcawu District Municipality
      • Kai !Garib Local Municipality
        • Kenhardt
Cairncross et al. (1995)
Spain
 
  • Castile and Leon
    • Salamanca
Roda et al. (2001)
      • Garcirrey
Encarnación Roda-Robles (2007)
    • Zamora
      • Villar del Buey
Roda-Robles et al. (1998)
  • Galicia
    • Pontevedra
      • Forcarei
Calvo Rebollar (2015)
      • Gondomar
        • Vincios
          • Galiñeiro Complex
NÚÑEZ-GARCÍA et al. (2012) +1 other reference
Switzerland
 
  • Ticino
    • Locarno
      • Brissago
Stalder et al. (1998)
USA
 
  • Alabama
    • Coosa County
Rocks & Minerals: 70 (5)
  • Arizona
    • Yavapai County
      • Eureka Mining District
        • Hillside
          • Bagdad Mine area
Leavens (1967) +1 other reference
Jahns (1952) +1 other reference
        • Independence Gulch
London et al. (1982)
Jahns (1952)
  • California
    • San Diego County
      • Jacumba
        • Tule Mountain (Mount Tule; Tulley Mountain)
Fisher (2002)
      • Pala Mining District
        • Pala
          • Chief Mountain
Mineralogical Record (2002)
Jahns et al. (1951)
Palache et al. (1951) +2 other references
San Diego Mining Company (2022)
  • Connecticut
    • Fairfield County
      • Redding (Reading)
        • Branchville
Brush and Dana (1890) +3 other references
    • Middlesex County
      • East Hampton (Chatham)
Schooner (circa 1990)
      • Portland
        • Collins Hill
          • Strickland pegmatite
Schooner (circa 1985) +2 other references
  • Maine
    • Androscoggin County
      • Poland
King et al. (1994)
    • Oxford County
      • Buckfield
King (2000)
      • Greenwood
W. B. Thompson et al. (2005)
        • Uncle Tom Mountain
Mineral News (1995) +1 other reference
      • Newry
King et al. (1994) +1 other reference
      • Paris
Mineralogical Record 22:382 +2 other references
      • Rumford
Tim Blake and Scott Soucey specimens
      • Stoneham
W. B. Thompson et al. (2005)
Thompson et al. (1998)
  • Nevada
Castor et al. (2004)
  • New Hampshire
    • Cheshire County
Robert Whitmore collection
      • Walpole
Bob Janules collection
    • Grafton County
      • Groton
Rocks & Minerals: 80: 252.
Palache et al. (1951) +1 other reference
      • Orange
Thompson et al. (2022)
    • Strafford County
      • Strafford
        • Parker Mountain
Rocks & Minerals 80:4 pp234-241
  • North Carolina
    • Cleveland County
      • Kings Mountain
Horton et al. (1981) +1 other reference
  • South Dakota
    • Custer County
      • Custer Mining District
        • Berne
Smith et al. (2000)
        • Custer
Peacor (1969) +1 other reference
[var: Bastinite] Am Min (1946)
Smith et al. (2000)
Smith et al. (2000)
Smith et al. (2000)
        • Fourmile
Campbell et al. (1985)
        • Pringle
          • Cicero Peak
[var: Bastinite] King (n.d.)
      • Custer State Park
        • The Needles
Smith et al. (2000)
    • Pennington County
      • Hill City Mining District
Smith et al. (2000)
      • Keystone Mining District
        • Glendale
[var: Bastinite] Karl Volkman specimen
Smith et al. (2000)
Smith et al. (2000)
        • Keystone
Peacor et al. (1984)
Rocks & Minerals: 57: 160 +1 other reference
Smith et al. (2000)
  • Wisconsin
    • Florence County
      • Fern
        • Pine River pegmatites
Falster et al. (1996)
 
Mineral and/or Locality  
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