Hydroxylellestadite
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About Hydroxylellestadite
Formula:
Ca5(SiO4)1.5(SO4)1.5(OH)
Colour:
Light orange; Pink, Purple-grey
Lustre:
Vitreous
Hardness:
4½
Crystal System:
Hexagonal
Member of:
Name:
Ellestadite (sensu lacto) was first described and named in honor of Dr. Ruben B. Ellestad (1900-1993), American analytical chemist of Minneapolis. Based on the chemical analysis, the type specimen of ellestadite should be considered a hydroxylellestadite (Pasero et al. 2010). Later Harada et al. (1971) described hydroxylellestadite. It was renamed as ellestadite-(OH), and again, by IMA 2010 (Pasero et al. 2010) back to hydroxylellestadite. The crystal structure was refined, first by Sudarsanan (1980), Hughes & Drexler (1991) and later by Onac et al. (2006).
A mineral in the Ellestadite Group of the Apatite Supergroup. Fluorellestadite-Hydroxylellestadite Series; Hydroxylapatite-hydroxylellestadite series. The hydroxyl analogue of fluorellestadite.
Formerly called ellestadite-(OH).
It is found in pegmatite veins, skarn and pyrometamorphic deposits.
Sulfate may be substituted by carbonate, at least in part, to give Unnamed (CO3 analogue of hydroxylellestadite) if the 50% rule is met.
Formerly called ellestadite-(OH).
It is found in pegmatite veins, skarn and pyrometamorphic deposits.
Sulfate may be substituted by carbonate, at least in part, to give Unnamed (CO3 analogue of hydroxylellestadite) if the 50% rule is met.
Classification of Hydroxylellestadite
Approved, 'Grandfathered' (first described prior to 1959)
8/B.27-30
9.AH.25
9 : SILICATES (Germanates)
A : Nesosilicates
H : Nesosilicates with CO3, SO4, PO4, etc.
9 : SILICATES (Germanates)
A : Nesosilicates
H : Nesosilicates with CO3, SO4, PO4, etc.
52.4.9.4
52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
4 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordination
52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
4 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordination
17.10.21
17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate
Physical Properties of Hydroxylellestadite
Vitreous
Transparency:
Transparent, Translucent
Colour:
Light orange; Pink, Purple-grey
Hardness:
4½ on Mohs scale
Optical Data of Hydroxylellestadite
Type:
Uniaxial (-)
RI values:
nω = 1.654 nε = 1.650
Max Birefringence:
δ = 0.004
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Chemical Properties of Hydroxylellestadite
Formula:
Ca5(SiO4)1.5(SO4)1.5(OH)
IMA Formula:
Ca5(SiO4)1.5(SO4)1.5OH
Common Impurities:
Al,Fe,Mn,Mg,Sr,Na,K,P,C
Crystallography of Hydroxylellestadite
Crystal System:
Hexagonal
Class (H-M):
6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal
Space Group:
P63/mcm
Setting:
P63/m 2/c 2/m
Cell Parameters:
a = 9.491 Å, c = 6.921 Å
Ratio:
a:c = 1 : 0.729
Unit Cell V:
6.921 ų
Z:
2
Morphology:
Anhedral masses.
Type Occurrence of Hydroxylellestadite
General Appearance of Type Material:
Anhedral, cleavable aggregates up to 100 kg. Individual cleavage pieces are up
to 2 cm along the c axis
to 2 cm along the c axis
Synonyms of Hydroxylellestadite
Other Language Names for Hydroxylellestadite
Relationship of Hydroxylellestadite to other Species
Member of:
Other Members of this group:
| Chlorellestadite | Ca5(SiO4)1.5(SO4)1.5Cl | Hex. 6/m : P63/m |
| Fluorellestadite | Ca5(SiO4)1.5(SO4)1.5F | Hex. |
| Mattheddleite | Pb5(SiO4)1.5(SO4)1.5(Cl,OH) | Hex. 6/m : P63/m |
Forms a series with:
Common Associates
Associated Minerals Based on Photo Data:
| Ye'elimite | 1 photo of Hydroxylellestadite associated with Ye'elimite on mindat.org. |
| Plombièrite | 1 photo of Hydroxylellestadite associated with Plombièrite on mindat.org. |
Related Minerals - Nickel-Strunz Grouping
| 9.AH.05 | Iimoriite-(Y) | Y2[SiO4][CO3] | Tric. |
| 9.AH.10 | Tundrite-(Ce) | Na2Ce2Ti(SiO4)(CO3)2O2 | Tric. 1 : P1 |
| 9.AH.10 | Tundrite-(Nd) | Na2(Nd,Ce)2Ti(SiO4)(CO3)2O2 | |
| 9.AH.15 | Spurrite | Ca5(SiO4)2(CO3) | Mon. |
| 9.AH.20 | Ternesite | Ca5(SiO4)2(SO4) | Orth. mmm (2/m 2/m 2/m) : Pnma |
| 9.AH.25 | Britholite-(Ce) | (Ce,Ca)5(SiO4)3OH | Hex. 6/m : P63/m |
| 9.AH.25 | Britholite-(Y) | (Y,Ca)5(SiO4)3OH | Hex. 6/m : P63/m |
| 9.AH.25 | Chlorellestadite | Ca5(SiO4)1.5(SO4)1.5Cl | Hex. 6/m : P63/m |
| 9.AH.25 | Fluorbritholite-(Ce) | (Ce,Ca)5(SiO4)3F | Hex. 6/m : P63/m |
| 9.AH.25 | Fluorellestadite | Ca5(SiO4)1.5(SO4)1.5F | Hex. |
| 9.AH.25 | Mattheddleite | Pb5(SiO4)1.5(SO4)1.5(Cl,OH) | Hex. 6/m : P63/m |
| 9.AH.25 | Tritomite-(Ce) | Ce5(SiO4,BO4)3(OH,O) | |
| 9.AH.25 | Tritomite-(Y) | Y5(SiO4,BO4)3(O,OH,F) | |
| 9.AH.25 | Fluorcalciobritholite | (Ca,REE)5(SiO4,PO4)3F | Hex. 6/m : P63/m |
| 9.AH.25 | Fluorbritholite-(Y) | (Y,Ca)5(SiO4)3F | Hex. 6/m : P63/m |
Related Minerals - Dana Grouping (8th Ed.)
| 52.4.9.1 | Britholite-(Ce) | (Ce,Ca)5(SiO4)3OH | Hex. 6/m : P63/m |
| 52.4.9.2 | Britholite-(Y) | (Y,Ca)5(SiO4)3OH | Hex. 6/m : P63/m |
| 52.4.9.3 | Fluorellestadite | Ca5(SiO4)1.5(SO4)1.5F | Hex. |
| 52.4.9.5 | Chlorellestadite | Ca5(SiO4)1.5(SO4)1.5Cl | Hex. 6/m : P63/m |
| 52.4.9.6 | Mattheddleite | Pb5(SiO4)1.5(SO4)1.5(Cl,OH) | Hex. 6/m : P63/m |
| 52.4.9.7 | Karnasurtite-(Ce) | (Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2O | |
| 52.4.9.8 | Fluorbritholite-(Ce) | (Ce,Ca)5(SiO4)3F | Hex. 6/m : P63/m |
Related Minerals - Hey's Chemical Index of Minerals Grouping
| 17.10.1 | Nosean | Na8(Al6Si6O24)(SO4) · H2O | Iso. 4 3m : P4 3n |
| 17.10.2 | Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O | Hex. |
| 17.10.3 | Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O | Hex. 6 : P63 |
| 17.10.4 | Haüyne | (Na,K)3(Ca,Na)(Al3Si3O12)(SO4,S,Cl) | Iso. 4 3m : P4 3n |
| 17.10.5 | Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 | Hex. |
| 17.10.6 | Latiumite | (Ca,K)4(Si,Al)5O11(SO4,CO3) | Mon. |
| 17.10.7 | Tuscanite | (K(Ca,Na)6(Si,Al)10O22[SO4,CO3,(OH)2] · H2O | Mon. |
| 17.10.8 | Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 | Hex. |
| 17.10.9 | Delhayelite | (Na,K)10Ca5Al6Si32O80(Cl2,F2,SO4)3 · 18H2O | Orth. |
| 17.10.10 | Hydrodelhayelite | KCa2AlSi7O17(OH)2 · 6H2O | Orth. |
| 17.10.11 | Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 | Hex. 6/m : P63/m |
| 17.10.12 | Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 | Trig. 3m : P3 1c |
| 17.10.13 | Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O | Hex. |
| 17.10.14 | Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 | Hex. |
| 17.10.15 | Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6•2H2O | Hex. |
| 17.10.16 | Chessexite | (Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2O | Orth. |
| 17.10.17 | Innelite | Na2CaBa4Ti3(Si2O7)2(SO4)2O4 | Tric. 1 : P1 |
| 17.10.18 | Thaumasite | Ca3(SO4)[Si(OH)6](CO3) · 12H2O | Hex. 6 : P63 |
| 17.10.19 | Ellestadite | ||
| 17.10.20 | Chlorellestadite | Ca5(SiO4)1.5(SO4)1.5Cl | Hex. 6/m : P63/m |
| 17.10.22 | Fluorellestadite | Ca5(SiO4)1.5(SO4)1.5F | Hex. |
| 17.10.23 | Mattheddleite | Pb5(SiO4)1.5(SO4)1.5(Cl,OH) | Hex. 6/m : P63/m |
| 17.10.24 | Queitite | Pb4Zn2(SO4)(SiO4)(Si2O7) | Mon. 2 : P21 |
| 17.10.25 | Roeblingite | Pb2Ca6Mn2+(Si3O9)2(SO4)2(OH)2 · 4H2O | Mon. 2/m : B2/m |
| 17.10.26 | Yoshimuraite | Ba2Mn2Ti(Si2O7)(PO4)O(OH) | Tric. 1 : P1 |
| 17.10.27 | Kegelite | Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 | Mon. |
| 17.10.28 | Wenkite | (Ba,K)4(Ca,Na)6[(SO4)3|(Si,Al)20O39(OH)2] · 0.5H2O | Hex. |
| 17.10.29 | Macquartite | Cu2Pb7(CrO4)4(SiO4)2(OH)2 | Mon. |
| 17.10.30 | Welinite | Mn2+6(W6+,Mg)2(SiO4)2(O,OH)6 | Trig. 3 : P3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
References for Hydroxylellestadite
Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Harda, K., Nagashima, K., Nakao, K., Kato, A. (1971) Hydroxylellestadite, a new apatite from Chichibu Mine, Saitama Prefecture, Japan. American Mineralogist: 56: 1507-1518.
Suddarsanan, K. (1980): Structure of hydroxylellestadite. acta Crystallographica. B36: 1636-1639
Rouse, R.C., Dunn, P.J. (1982) A contribution to the crystal chemistry of ellestadite and silicate sulfate apatites. American Mineralogist: 67: 90-96.
Hughes, J.M., Drexler, J.W. (1991) Cation substitution in the apatite tetrahedral site: crystal structures of type hydroxylellestadite and type fermorite. Neues Jahrbuch für Mineralogie, Monatshefte: 1991: 327-336.
Onac, B.P., Effenberger, H., Ettinger, K., Panzaru, S.C. (2006) Hydroxylellestadite from Cioclovina Cave (Romania): microanalytical, structural, and vibrational spectroscopy data. American Mineralogist: 91: 1927-1931.
Pasero, M., Kampf, A.R., Ferraris, C., Pekov, I.V., Rakovan, J.R., White, T.J. (2010) Nomenclature of the apatite supergroup minerals. European Journal of Mineralogy: 22: 163-179. [doi:10.1127/0935-1221/2010/0022-2022]
Hughes, J.M., Rakovan, J.F. (2015) Structurally robust, chemically diverse: Apatite and apatite supergroup minerals. Elements: 11(3): 165-170.
Internet Links for Hydroxylellestadite
mindat.org URL:
https://www.mindat.org/min-1958.html
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Localities for Hydroxylellestadite
ⓘ - Click for further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)
All localities listed without proper references should be considered as questionable.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
China | |
| Shengxiu Hou, Zhaolian Liu, and Huande Hu (1985): Acta Mineralogica Sinica 5(4), 327-330 |
Cuba | |
| Лицарев М.А. и др. Гидроксилэллестадит из гранат-волластонитовых скарнов Аримао-Норте (Куба), //Записки ВМО, 1998, N6, c.68-75.; Chukanov, N. V. (2013). Infrared spectra of mineral species: extended library. Springer Science & Business Media.; Zateeva, S. N., Sokol, E. V., & Sharygin, V. V. (2007). Specificity of pyrometamorphic minerals of the ellestadite group. Geology of Ore Deposits, 49(8), 792-805.; Litsarev, M. A., Organova, N. I., Khranach, P., Chukanov, N. V., Kuz’mina, O. V., Kartashov, P. M., ... & Zadov, A. E. (1998). Hydroxylellestadite from the Arimao Norte Garnet–Wollastonite Skarn (Cuba). Zap. Vseross. Mineral. O–va, 127(6), 68-75. |
Czech Republic | |
| Hršelová, P., Cempírek, J., Houzar, S., Sejkora, J. (2013): S,F,Cl-rich mineral assemblages from burned spoil heaps in the Rosice-Oslavany coalfield, Czech Republic. Can. Mineral.: 51(1): 171-188 |
France | |
| Favreau G., Meisser N., Chiappero P.J. (2004), Saint-Maime (Alpes-de-Haute-Provence): un exemple de pyrométamorphisme en région provençale, n°3, pp: 59-92 |
Germany | |
| T. Witzke & F. Rüger: Lapis 1998(7/8), 26-64 |
Japan (TL) | |
| Harda, K., Nagashima, K., Nakao, K., Kato, A. (1971) Hydroxylellestadite, a new apatite from Chichibu Mine, Saitama Prefecture, Japan. American Mineralogist: 56: 1507-1518 Am.Min.:67:90 (1982); Acta Cryst. B36(1980). |
| Yamada, S. (2004) Nihonsan-koubutsu Gojuon-hairetsu Sanchi-ichiranhyou (111 pp.) | |
| Yamada, S. (2004) Nihonsan-koubutsu Gojuon-hairetsu Sanchi-ichiranhyou (111 pp.) | |
Palestine | |
| Sokol, E.V., Gaskova, O.L., Kokh, S.N., Kozmenko, O.A., Seryotkin, Y.V., Vapnik, Y., Murashko, M.N. (2011): Chromatite and its Cr3+- and Cr6+-bearing precursor minerals from the Nabi Musa Mottled Zone complex, Judean Desert. American Mineralogist 96, 659-674. |
Portugal | |
| Schnorrer-Köhler (1991), Mineral Occurrences. |
Romania | |
| Marincea, S., Dumitraş. D-G., Ghinet, C, Fransolet, A.-M., Hatert, F. & Rondeaux, M. (2011): Gehlenite from three occurrences of high-temperature skarns, Romania: new mineralogical data. Canadian Mineralogist. 49, 1001-1014 |
| The Canadian Mineralogist Vol. 39, pp. 1405-1434 (2001) |
| Onac, B.P., et al. (2006). American Mineralogist: 91: 1927-1931. |
| Marincea, Ş., Bilal, E., Verkaeren, J., Pascal, M.-L., and Fonteilles, M. (2001) Superposed paragenesis in spurrite-, tilleyite- and gehlenite-bearing skarns from Cornet Hill, Apuseni Mountains, Romania. Canadian Mineralogist: 39: 1435-1453.; The Canadian Mineralogist Vol. 39, pp. 1405-1434 (2001); Marincea, Ş., Dumitraş, D. G., Călin, N., Anason, A. M., Fransolet, A. M., & Hatert, F. (2013). Spurrite, tilleyite and associated minerals in the exoskarn zone from Cornet Hill (Metaliferi Massif, Apuseni Mountains, Romania). The Canadian Mineralogist, 51(3), 359-375. | |
Russia | |
| Galuskin, E.V., Galuskina, I.O., Kusz, J., Gfeller, F., Armbruster, T., Bailau, R., Dulski, M., Gazeev, V.M., Pertsev, N.N., Zadov, A.E., Dzieržanowski, P. (2015): Mayenite supergroup, part II: Chlorkyuygenite from Upper Chegem, northern Caucasus Kabardino-Balkaria, Russia, a new microporous mayenite supergroup mineral with “zeolitic” H2O. European Journal of Mineralogy. 27, 113-122; Bailau, R., Gałuskin, E. V., Gazeev, V. M., & Gałuskina, I. O. Raman investigation of potential new mineral-Fe 3-analogue of wadalite from calcareous-silicate xenoliths of the Upper Chegem caldera, Northern Caucasus, Russia. |
| Galuskina, I. O., Galuskin, E. V., Kusz, J., Dzierżanowski, P., Prusik, K., Gazeev, V. M., ... & Dubrovinsky, L. (2013). Dzhuluite, Ca3SbSnFe3+ 3O12, a new bitikleite-group garnet from the Upper Chegem Caldera, Northern Caucasus, Kabardino-Balkaria, Russia. European Journal of Mineralogy, 25(2), 231-239 |
| Galuskin, E.V., Galuskina, I.O., Gazeev, V.M., Dzierżanowski, P., Prusik, K., Pertsev, N.N., Zadov, A.E., Bailau, R., Gurbanov, A.G. (2011): Megawite, CaSnO3: a new perovskite-group mineral from skarns of the Upper Chegem caldera, Kabardino-Balkaria, Northern Caucasus, Russia. Mineralogical Magazine, 75, 2563-2572. | |
| Zadov, A. E.; Grabezhev, A. I.; Pertsev, N. N.; Chukanov, N. V.; Pribavkin, S. V. (2006): Tobermorite-plombierite metasomatites of the Gumeshevsk skarn-porphyry copper deposit, Middle Urals. Doklady Earth Sciences 407A, 495-497. ; American Mineralogist, Volume 94, pages 323–333, 2009; Grabezhev, A. I., Pertsev, N. N., Zadov, A. E., Pribavkin, S. V., & Murzin, V. V. (2007). Calcic hydrosilicate metasomatic rocks at the Gumeshevsk skarn-porphyry copper deposit in the central Urals, Russia. Petrology, 15(5), 514-522. |
| American Mineralogist, Volume 94, pages 323–333, 2009 |
Slovakia | |
| Koděra P., Uher P., Ozdín D., Kollárová V., Lexa J., 2009: Monticellit, clintonit a hydroxylellestadit-fluorellestadit: vzácne skarnové minerály na Cu-Au porfýrovo-skarnovom ložisku Vysoká – Zlatno (štiavnický stratovulkán). Mineralia Slovaca, 41, 2, 169-178.; P. UHER, P. KODĚRA, T. VACULOVIČ (2011): Perovskite from Ca-Mg skarn-porphyry deposit Vysoká – Zlatno, Štiavnica stratovolcano, Slovakia. Mineralia Slovaca, 43, 247-254. |
USA | |
| RRUFF ID: R060769 |
| Excalibur Mineral Company analysis |
Chichibu mining district, Nakatsugawa, Ohtaki-mura, Chichibu City, Saitama Prefecture, Kanto Region, Honshu Island, Japan