Ellestadite (sensu lacto) was first described and named in honor of Dr. Ruben B. Ellestad (1900-1993), American analytical chemist of Minneapolis. Based on the chemical analysis, the type specimen of ellestadite should be considered a hydroxylellestadite (Pasero et al. 2010). Later Harada et al. (1971) described hydroxylellestadite. It was renamed as ellestadite-(OH), and again, by IMA 2010 (Pasero et al. 2010) back to hydroxylellestadite. The crystal structure was refined, first by Sudarsanan (1980), Hughes & Drexler (1991) and later by Onac et al. (2006).

Type Locality:

ⓘ Chichibu mining district (Chichibu mine), Nakatsugawa, Ohtaki-mura, Chichibu City, Saitama Prefecture, Kanto Region, Honshu Island, Japan

A mineral in the Ellestadite Group of the Apatite Supergroup. Fluorellestadite-Hydroxylellestadite Series; Hydroxylapatite-hydroxylellestadite series. The hydroxyl analogue of fluorellestadite.

Formerly called ellestadite-(OH).

It is found in pegmatite veins, skarn and pyrometamorphic deposits.

Sulfate may be substituted by carbonate, at least in part, to give Unnamed (CO3 analogue of hydroxylellestadite) if the 50% rule is met.

Classification of HydroxylellestaditeHide

IMA status:

Approved, 'Grandfathered' (first described prior to 1959)

Strunz 8th ed.:

8/B.27-30

Nickel-Strunz 10th (pending) ed.:

9.AH.25

9 : SILICATES (Germanates)
A : Nesosilicates
H : Nesosilicates with CO₃, SO₄, PO₄, etc.

Dana 8th ed.:

52.4.9.4

52 : NESOSILICATES Insular SiO₄ Groups and O,OH,F,H₂O
4 : Insular SiO₄ Groups and O, OH, F, and H₂O with cations in [6] and/or >[6] coordination

Hey's CIM Ref.:

17.10.21

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate

Physical Properties of HydroxylellestaditeHide

Lustre:

Vitreous

Transparency:

Transparent, Translucent

Colour:

Light orange; Pink, Purple-grey

Hardness:

4½ on Mohs scale

Optical Data of HydroxylellestaditeHide

Type:

Uniaxial (-)

RI values:

n_ω = 1.654 n_ε = 1.650

Max Birefringence:

δ = 0.004

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

Moderate

Chemical Properties of HydroxylellestaditeHide

Formula:

Ca₅(SiO₄)_1.5(SO₄)_1.5(OH)

IMA Formula:

Ca₅(SiO₄)_1.5(SO₄)_1.5OH

Elements listed:

Ca, H, O, S, Si - search for minerals with similar chemistry

Common Impurities:

Al,Fe,Mn,Mg,Sr,Na,K,P,C

Crystallography of HydroxylellestaditeHide

Crystal System:

Hexagonal

Class (H-M):

6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal

Space Group:

P6₃/mcm

Setting:

P6₃/m 2/c 2/m

Cell Parameters:

a = 9.491 Å, c = 6.921 Å

Ratio:

a:c = 1 : 0.729

Unit Cell V:

6.921 Å³

Morphology:

Anhedral masses.

Type Occurrence of HydroxylellestaditeHide

Type Locality:

ⓘ Chichibu mining district (Chichibu mine), Nakatsugawa, Ohtaki-mura, Chichibu City, Saitama Prefecture, Kanto Region, Honshu Island, Japan

General Appearance of Type Material:

Anhedral, cleavable aggregates up to 100 kg. Individual cleavage pieces are up
to 2 cm along the c axis

Synonyms of HydroxylellestaditeHide

Ellestadite-(OH)

IMA1970-026

Other Language Names for HydroxylellestaditeHide

German:Hydroxylellestadit

Japanese:水酸エレスタド石　

Russian:Гидроксилэллестадит
Зллестадит-(OH)

Spanish:Hydroxylellestadita

Relationship of Hydroxylellestadite to other SpeciesHide

Member of:

Ellestadite Group > Apatite Supergroup

Other Members of this group:

Chlorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5Cl	Hex. 6/m : P6₃/m
Fluorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5F	Hex.
Mattheddleite	Pb₅(SiO₄)_1.5(SO₄)_1.5(Cl,OH)	Hex. 6/m : P6₃/m

Forms a series with:

Fluorellestadite	Fluorellestadite-Hydroxylellestadite Series
Hydroxylapatite	Hydroxylapatite-Hydroxylellestadite Series

Common AssociatesHide

Associated Minerals Based on Photo Data:

Ye'elimite	1 photo of Hydroxylellestadite associated with Ye'elimite on mindat.org.
Plombièrite	1 photo of Hydroxylellestadite associated with Plombièrite on mindat.org.

Related Minerals - Nickel-Strunz Grouping Hide

9.AH.05	Iimoriite-(Y)	Y₂[SiO₄][CO₃]	Tric.
9.AH.10	Tundrite-(Ce)	Na₂Ce₂Ti(SiO₄)(CO₃)₂O₂	Tric. 1 : P1
9.AH.10	Tundrite-(Nd)	Na₂(Nd,Ce)₂Ti(SiO₄)(CO₃)₂O₂
9.AH.15	Spurrite	Ca₅(SiO₄)₂(CO₃)	Mon.
9.AH.20	Ternesite	Ca₅(SiO₄)₂(SO₄)	Orth. mmm (2/m 2/m 2/m) : Pnma
9.AH.25	Britholite-(Ce)	(Ce,Ca)₅(SiO₄)₃OH	Hex. 6/m : P6₃/m
9.AH.25	Britholite-(Y)	(Y,Ca)₅(SiO₄)₃OH	Hex. 6/m : P6₃/m
9.AH.25	Chlorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5Cl	Hex. 6/m : P6₃/m
9.AH.25	Fluorbritholite-(Ce)	(Ce,Ca)₅(SiO₄)₃F	Hex. 6/m : P6₃/m
9.AH.25	Fluorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5F	Hex.
9.AH.25	Mattheddleite	Pb₅(SiO₄)_1.5(SO₄)_1.5(Cl,OH)	Hex. 6/m : P6₃/m
9.AH.25	Tritomite-(Ce)	Ce₅(SiO₄,BO₄)₃(OH,O)
9.AH.25	Tritomite-(Y)	Y₅(SiO₄,BO₄)₃(O,OH,F)
9.AH.25	Fluorcalciobritholite	(Ca,REE)₅(SiO₄,PO₄)₃F	Hex. 6/m : P6₃/m
9.AH.25	Fluorbritholite-(Y)	(Y,Ca)₅(SiO₄)₃F	Hex. 6/m : P6₃/m

Related Minerals - Dana Grouping (8th Ed.)Hide

52.4.9.1	Britholite-(Ce)	(Ce,Ca)₅(SiO₄)₃OH	Hex. 6/m : P6₃/m
52.4.9.2	Britholite-(Y)	(Y,Ca)₅(SiO₄)₃OH	Hex. 6/m : P6₃/m
52.4.9.3	Fluorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5F	Hex.
52.4.9.5	Chlorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5Cl	Hex. 6/m : P6₃/m
52.4.9.6	Mattheddleite	Pb₅(SiO₄)_1.5(SO₄)_1.5(Cl,OH)	Hex. 6/m : P6₃/m
52.4.9.7	Karnasurtite-(Ce)	(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si₂O₇)(OH)₄ · 3H₂O
52.4.9.8	Fluorbritholite-(Ce)	(Ce,Ca)₅(SiO₄)₃F	Hex. 6/m : P6₃/m

Related Minerals - Hey's Chemical Index of Minerals Grouping Hide

17.10.1	Nosean	Na₈(Al₆Si₆O₂₄)(SO₄) · H₂O	Iso. 4 3m : P4 3n
17.10.2	Pitiglianoite	Na₆K₂(Al₆Si₆O₂₄)(SO₄) · 2H₂O	Hex.
17.10.3	Vishnevite	(Na,K)₈(Al₆Si₆O₂₄)(SO₄,CO₃) · 2H₂O	Hex. 6 : P6₃
17.10.4	Haüyne	(Na,K)₃(Ca,Na)(Al₃Si₃O₁₂)(SO₄,S,Cl)	Iso. 4 3m : P4 3n
17.10.5	Liottite	(Na,K)₁₆Ca₈(Al₆Si₆O₂₄)₃(SO₄)₅Cl₄	Hex.
17.10.6	Latiumite	(Ca,K)₄(Si,Al)₅O₁₁(SO₄,CO₃)	Mon.
17.10.7	Tuscanite	(K(Ca,Na)₆(Si,Al)₁₀O₂₂[SO₄,CO₃,(OH)₂] · H₂O	Mon.
17.10.8	Microsommite	Na₄K₂Ca₂(Al₆Si₆O₂₄)(SO₄)Cl₂	Hex.
17.10.9	Delhayelite	(Na,K)₁₀Ca₅Al₆Si₃₂O₈₀(Cl₂,F₂,SO₄)₃ · 18H₂O	Orth.
17.10.10	Hydrodelhayelite	KCa₂AlSi₇O₁₇(OH)₂ · 6H₂O	Orth.
17.10.11	Davyne	(Na,K)₆Ca₂(Al₆Si₆O₂₄)(Cl₂,SO₄)₂	Hex. 6/m : P6₃/m
17.10.12	Afghanite	(Na,K)₂₂Ca₁₀(Si₂₄Al₂₄O₉₆)(SO₄)₆Cl₆	Trig. 3m : P3 1c
17.10.13	Franzinite	(Na,K)₆Ca₂(Al₆Si₆O₂₄)(SO₄)₂ · 0.5H₂O	Hex.
17.10.14	Giuseppettite	(Na,K,Ca)_7-8(Al₆Si₆O₂₄)(SO₄,Cl)_1-2	Hex.
17.10.15	Sacrofanite	(Na₆₁K₁₉Ca₃₂)(Si₈₄Al₈₄O₃₃₆)(SO₄)₂₆Cl₂F₆•2H₂O	Hex.
17.10.16	Chessexite	(Na,K)₄Ca₂(Mg,Zn)₃Al₈(SO₄)₁₀(SiO₄)₂ · 40H₂O	Orth.
17.10.17	Innelite	Na₂CaBa₄Ti₃(Si₂O₇)₂(SO₄)₂O₄	Tric. 1 : P1
17.10.18	Thaumasite	Ca₃(SO₄)[Si(OH)₆](CO₃) · 12H₂O	Hex. 6 : P6₃
17.10.19	Ellestadite
17.10.20	Chlorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5Cl	Hex. 6/m : P6₃/m
17.10.22	Fluorellestadite	Ca₅(SiO₄)_1.5(SO₄)_1.5F	Hex.
17.10.23	Mattheddleite	Pb₅(SiO₄)_1.5(SO₄)_1.5(Cl,OH)	Hex. 6/m : P6₃/m
17.10.24	Queitite	Pb₄Zn₂(SO₄)(SiO₄)(Si₂O₇)	Mon. 2 : P2₁
17.10.25	Roeblingite	Pb₂Ca₆Mn²⁺(Si₃O₉)₂(SO₄)₂(OH)₂ · 4H₂O	Mon. 2/m : B2/m
17.10.26	Yoshimuraite	Ba₂Mn₂Ti(Si₂O₇)(PO₄)O(OH)	Tric. 1 : P1
17.10.27	Kegelite	Pb₈Al₄(Si₈O₂₀)(SO₄)₂(CO₃)₄(OH)₈	Mon.
17.10.28	Wenkite	(Ba,K)₄(Ca,Na)₆[(SO₄)₃\|(Si,Al)₂₀O₃₉(OH)₂] · 0.5H₂O	Hex.
17.10.29	Macquartite	Cu₂Pb₇(CrO₄)₄(SiO₄)₂(OH)₂	Mon.
17.10.30	Welinite	Mn²⁺₆(W⁶⁺,Mg)₂(SiO₄)₂(O,OH)₆	Trig. 3 : P3

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for HydroxylellestaditeHide

Reference List:

Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)

Harda, K., Nagashima, K., Nakao, K., Kato, A. (1971) Hydroxylellestadite, a new apatite from Chichibu Mine, Saitama Prefecture, Japan. American Mineralogist: 56: 1507-1518.

Suddarsanan, K. (1980): Structure of hydroxylellestadite. acta Crystallographica. B36: 1636-1639

Rouse, R.C., Dunn, P.J. (1982) A contribution to the crystal chemistry of ellestadite and silicate sulfate apatites. American Mineralogist: 67: 90-96.

Hughes, J.M., Drexler, J.W. (1991) Cation substitution in the apatite tetrahedral site: crystal structures of type hydroxylellestadite and type fermorite. Neues Jahrbuch für Mineralogie, Monatshefte: 1991: 327-336.

Onac, B.P., Effenberger, H., Ettinger, K., Panzaru, S.C. (2006) Hydroxylellestadite from Cioclovina Cave (Romania): microanalytical, structural, and vibrational spectroscopy data. American Mineralogist: 91: 1927-1931.

Pasero, M., Kampf, A.R., Ferraris, C., Pekov, I.V., Rakovan, J.R., White, T.J. (2010) Nomenclature of the apatite supergroup minerals. European Journal of Mineralogy: 22: 163-179. [doi:10.1127/0935-1221/2010/0022-2022]

Hughes, J.M., Rakovan, J.F. (2015) Structurally robust, chemically diverse: Apatite and apatite supergroup minerals. Elements: 11(3): 165-170.

Internet Links for HydroxylellestaditeHide

mindat.org URL:

https://www.mindat.org/min-1958.html
Please feel free to link to this page.

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External Links:

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Look for Hydroxylellestadite on Wikipedia

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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Localities for HydroxylellestaditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.


China
Anhui Province ⓘ Tongling Prefecture	Shengxiu Hou, Zhaolian Liu, and Huande Hu (1985): Acta Mineralogica Sinica 5(4), 327-330

Cuba
Cienfuegos Province ⓘ Arimao-Norte	Лицарев М.А. и др. Гидроксилэллестадит из гранат-волластонитовых скарнов Аримао-Норте (Куба), //Записки ВМО, 1998, N6, c.68-75.; Chukanov, N. V. (2013). Infrared spectra of mineral species: extended library. Springer Science & Business Media.; Zateeva, S. N., Sokol, E. V., & Sharygin, V. V. (2007). Specificity of pyrometamorphic minerals of the ellestadite group. Geology of Ore Deposits, 49(8), 792-805.; Litsarev, M. A., Organova, N. I., Khranach, P., Chukanov, N. V., Kuz’mina, O. V., Kartashov, P. M., ... & Zadov, A. E. (1998). Hydroxylellestadite from the Arimao Norte Garnet–Wollastonite Skarn (Cuba). Zap. Vseross. Mineral. O–va, 127(6), 68-75.

Czech Republic
South Moravia Region Oslavany ⓘ Rosice-Oslavany coalfield	Hršelová, P., Cempírek, J., Houzar, S., Sejkora, J. (2013): S,F,Cl-rich mineral assemblages from burned spoil heaps in the Rosice-Oslavany coalfield, Czech Republic. Can. Mineral.: 51(1): 171-188

France
Provence-Alpes-Côte d'Azur Alpes-de-Haute-Provence ⓘ Saint-Maime mines	Favreau G., Meisser N., Chiappero P.J. (2004), Saint-Maime (Alpes-de-Haute-Provence): un exemple de pyrométamorphisme en région provençale, n°3, pp: 59-92

Germany
Thuringia Gera Ronneburg U deposit ⓘ Lichtenberg Absetzer dump	T. Witzke & F. Rüger: Lapis 1998(7/8), 26-64

Japan (TL)
Honshu Island Kanto Region Saitama Prefecture Chichibu City Ohtaki-mura Nakatsugawa ⓘ Chichibu mining district (Chichibu mine) (TL)	Harda, K., Nagashima, K., Nakao, K., Kato, A. (1971) Hydroxylellestadite, a new apatite from Chichibu Mine, Saitama Prefecture, Japan. American Mineralogist: 56: 1507-1518 Am.Min.:67:90 (1982); Acta Cryst. B36(1980).
ⓘ Daikoku deposit (Daikoku mine)	Yamada, S. (2004) Nihonsan-koubutsu Gojuon-hairetsu Sanchi-ichiranhyou (111 pp.)
ⓘ Doushinkubo	Yamada, S. (2004) Nihonsan-koubutsu Gojuon-hairetsu Sanchi-ichiranhyou (111 pp.)

Palestine
West Bank Hatrurim Formation ⓘ Nabi Musa	Sokol, E.V., Gaskova, O.L., Kokh, S.N., Kozmenko, O.A., Seryotkin, Y.V., Vapnik, Y., Murashko, M.N. (2011): Chromatite and its Cr3+- and Cr6+-bearing precursor minerals from the Nabi Musa Mottled Zone complex, Judean Desert. American Mineralogist 96, 659-674.

Portugal
Guarda District Sabugal Bendada ⓘ Bendada Mines	Schnorrer-Köhler (1991), Mineral Occurrences.

Romania
Caraş-Severin Co. Banat Mts ⓘ Oraviţa Skarns	Marincea, S., Dumitraş. D-G., Ghinet, C, Fransolet, A.-M., Hatert, F. & Rondeaux, M. (2011): Gehlenite from three occurrences of high-temperature skarns, Romania: new mineralogical data. Canadian Mineralogist. 49, 1001-1014
Hunedoara Co. Brad ⓘ Upper Cerboaia Valley	The Canadian Mineralogist Vol. 39, pp. 1405-1434 (2001)
Hunedoara Boșorod ⓘ Cioclovina cave	Onac, B.P., et al. (2006). American Mineralogist: 91: 1927-1931.
ⓘ Cornet Hill	Marincea, Ş., Bilal, E., Verkaeren, J., Pascal, M.-L., and Fonteilles, M. (2001) Superposed paragenesis in spurrite-, tilleyite- and gehlenite-bearing skarns from Cornet Hill, Apuseni Mountains, Romania. Canadian Mineralogist: 39: 1435-1453.; The Canadian Mineralogist Vol. 39, pp. 1405-1434 (2001); Marincea, Ş., Dumitraş, D. G., Călin, N., Anason, A. M., Fransolet, A. M., & Hatert, F. (2013). Spurrite, tilleyite and associated minerals in the exoskarn zone from Cornet Hill (Metaliferi Massif, Apuseni Mountains, Romania). The Canadian Mineralogist, 51(3), 359-375.

Russia
Eastern-Siberian Region Transbaikalia (Zabaykalye) Buriatia Republic (Buryatia) Dovyren Highlands ⓘ Yoko-Dovyrensky Massif	American Mineralogist, Volume 94, pages 323–333, 2009
Northern Caucasus Region Kabardino-Balkarian Republic Baksan Valley ⓘ Upper Chegem volcanic caldera (Verkhnechegemskaya caldera)	Galuskin, E.V., Galuskina, I.O., Kusz, J., Gfeller, F., Armbruster, T., Bailau, R., Dulski, M., Gazeev, V.M., Pertsev, N.N., Zadov, A.E., Dzieržanowski, P. (2015): Mayenite supergroup, part II: Chlorkyuygenite from Upper Chegem, northern Caucasus Kabardino-Balkaria, Russia, a new microporous mayenite supergroup mineral with “zeolitic” H2O. European Journal of Mineralogy. 27, 113-122; Bailau, R., Gałuskin, E. V., Gazeev, V. M., & Gałuskina, I. O. Raman investigation of potential new mineral-Fe 3-analogue of wadalite from calcareous-silicate xenoliths of the Upper Chegem caldera, Northern Caucasus, Russia.
Lakargi Mt. ⓘ Xenolith no. 1	Galuskina, I. O., Galuskin, E. V., Kusz, J., Dzierżanowski, P., Prusik, K., Gazeev, V. M., ... & Dubrovinsky, L. (2013). Dzhuluite, Ca3SbSnFe3+ 3O12, a new bitikleite-group garnet from the Upper Chegem Caldera, Northern Caucasus, Kabardino-Balkaria, Russia. European Journal of Mineralogy, 25(2), 231-239
ⓘ Xenolith no. 3	Galuskin, E.V., Galuskina, I.O., Gazeev, V.M., Dzierżanowski, P., Prusik, K., Pertsev, N.N., Zadov, A.E., Bailau, R., Gurbanov, A.G. (2011): Megawite, CaSnO3: a new perovskite-group mineral from skarns of the Upper Chegem caldera, Kabardino-Balkaria, Northern Caucasus, Russia. Mineralogical Magazine, 75, 2563-2572.
Urals Region Middle Urals Sverdlovskaya Oblast' Sysert' District Polevskoi (Polevskoi Zavod) ⓘ Gumeshevskii Cu Mine (Gumeshevskoye)	Zadov, A. E.; Grabezhev, A. I.; Pertsev, N. N.; Chukanov, N. V.; Pribavkin, S. V. (2006): Tobermorite-plombierite metasomatites of the Gumeshevsk skarn-porphyry copper deposit, Middle Urals. Doklady Earth Sciences 407A, 495-497. ; American Mineralogist, Volume 94, pages 323–333, 2009; Grabezhev, A. I., Pertsev, N. N., Zadov, A. E., Pribavkin, S. V., & Murzin, V. V. (2007). Calcic hydrosilicate metasomatic rocks at the Gumeshevsk skarn-porphyry copper deposit in the central Urals, Russia. Petrology, 15(5), 514-522.

Slovakia
Banská Bystrica Region Banská Štiavnica Co. Vysoká ⓘ Zlatno	Koděra P., Uher P., Ozdín D., Kollárová V., Lexa J., 2009: Monticellit, clintonit a hydroxylellestadit-fluorellestadit: vzácne skarnové minerály na Cu-Au porfýrovo-skarnovom ložisku Vysoká – Zlatno (štiavnický stratovulkán). Mineralia Slovaca, 41, 2, 169-178.; P. UHER, P. KODĚRA, T. VACULOVIČ (2011): Perovskite from Ca-Mg skarn-porphyry deposit Vysoká – Zlatno, Štiavnica stratovolcano, Slovakia. Mineralia Slovaca, 43, 247-254.

USA
California Riverside Co. Crestmore ⓘ Crestmore quarries	RRUFF ID: R060769
Jurupa Valley Jurupa Mts ⓘ Jensen Quarry (Oak Quarry)	Excalibur Mineral Company analysis

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Hydroxylellestadite

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