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Katoite

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About KatoiteHide

Formula:
Ca3Al2(SiO4)3-x(OH)4x (x = 1.5-3)
Colour:
Colourless
Lustre:
Vitreous
Hardness:
5 - 6
Crystal System:
Isometric
Name:
Named in 1984 by E. Passaglia and R. Rinaldi in honor of Akira Kato (加藤 昭) (b. 19 June 1931, Tokyo prefecture, Japan), Department of Geology, National Science Museum, Ueno, Tokyo, Japan. Former president of the international Mineralogical Association.
Grossular-Katoite Series. Hibschite-Katoite Series.
Ungrouped member of the Garnet Supergroup.

For x = 3, i.e. the end member, the species is also known as C3AH6 ("Tricalcium aluminate hydrate") in hydrated cement.
See also hydrogarnet.


Classification of KatoiteHide

Approved
Approval Year:
1982
9.AD.25

9 : SILICATES (Germanates)
A : Nesosilicates
D : Nesosilicates without additional anions; cations in [6] and/or greater coordination
51.4.3d.2

51 : NESOSILICATES Insular SiO4 Groups Only
4 : Insular SiO4 Groups Only with cations in [6] and >[6] coordination
16.9.17

16 : Silicates Containing Aluminum and other Metals
9 : Aluminosilicates of Ca

Physical Properties of KatoiteHide

Vitreous
Colour:
Colourless
Streak:
White
Hardness:
5 - 6 on Mohs scale

Optical Data of KatoiteHide

Type:
Isotropic

Chemical Properties of KatoiteHide

Formula:
Ca3Al2(SiO4)3-x(OH)4x (x = 1.5-3)
IMA Formula:
Ca3Al2(OH)12
Common Impurities:
Mg,S

Crystallography of KatoiteHide

Crystal System:
Isometric
Cell Parameters:
a = 12.35 Å
Unit Cell V:
1,883.65 ų (Calculated from Unit Cell)
Comment:
Synthetic katoite has a = 12.5731(2) A (Lager et al., 2002).

Type Occurrence of KatoiteHide

Synonyms of KatoiteHide

Other Language Names for KatoiteHide

German:Katoit
Russian:Катоит
Spanish:Katoita

Relationship of Katoite to other SpeciesHide

Other Members of this group:
Berzeliite Group
Bitikleite Group
BlythiteMn2+3Mn3+2[SiO4]3
CryolithioniteNa3Li3[AlF6]2Iso. m3m (4/m 3 2/m) : Ia3d
Garnet GroupX3Z2(SiO4)3
Henritermierite Group
KhohariteMg3Fe3+2(SiO4)3
Schorlomite Group
SkiagiteFe2+3Fe3+2[SiO4]3
UM1984-37-SiO:CrMnMn2+3(Cr3+,Mn3+)2Si3O12
YafsoaniteCa3Zn3(TeO6)2Iso. m3 (2/m 3)
Forms a series with:

Common AssociatesHide

Associated Minerals Based on Photo Data:
Magnetite1 photo of Katoite associated with Magnetite on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

9.AD.AdrianiteCa12(Al4Mg3Si7)O32Cl6Iso. 4 3m : I4 3d
9.AD.05LarniteCa2SiO4Mon.
9.AD.10Calcio-olivineCa2SiO4Orth. mmm (2/m 2/m 2/m)
9.AD.15MerwiniteCa3Mg(SiO4)2Mon. 2/m : P21/b
9.AD.20BredigiteCa7Mg(SiO4)4Orth.
9.AD.25AndraditeCa3Fe3+2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25AlmandineFe2+3Al2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25Calderite(Mn2+,Ca)3(Fe3+,Al)2(SiO4)3Iso.
9.AD.25GoldmaniteCa3V3+2(SiO4)3Iso.
9.AD.25GrossularCa3Al2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25HenritermieriteCa3(Mn3+,Al)2(SiO4)2(OH)4Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
9.AD.25HibschiteCa3Al2(SiO4)3-x(OH)4xIso. m3m (4/m 3 2/m) : Ia3d
9.AD.25HydroandraditeCa3Fe3+2(SiO4)3-x(OH)4x
9.AD.25KimzeyiteCa3(Zr,Ti)2((Si,Al,Fe3+)O4)3Iso.
9.AD.25KnorringiteMg3Cr2(SiO4)3Iso.
9.AD.25MajoriteMg3(Fe2+,Si,Al)2(SiO4)3Iso.
9.AD.25MorimotoiteCa3(Ti,Fe2+,Fe3+)2((Si,Fe3+)O4)3Iso.
9.AD.25PyropeMg3Al2(SiO4)3Iso.
9.AD.25SchorlomiteCa3(Ti,Fe3+)2((Si,Fe3+)O4)3Iso.
9.AD.25SpessartineMn2+3Al2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25UvaroviteCa3Cr2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25Wadalite(Ca,Mg)6(Al,Fe3+)4((Si,Al)O4)3O4Cl3Iso. 4 3m : I4 3d
9.AD.25HoltstamiteCa3(Al,Mn3+)2(SiO4)2(OH)4Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
9.AD.25KerimasiteCa3Zr2(SiO4)(Fe3+O4)2Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25ToturiteCa3Sn2(SiO4)(Fe3+O4)2Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25Momoiite(Mn2+,Ca)3V3+2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25EltyubyuiteCa12Fe3+10Si4O32Cl6Iso. 4 3m : I4 3d
9.AD.25HutcheoniteCa3Ti2(SiAl2)O12Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.30CoffiniteU(SiO4) · nH2OTet.
9.AD.30HafnonHfSiO4Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
9.AD.30ThoriteTh(SiO4)Tet.
9.AD.30ZirconZr(SiO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
9.AD.30Stetindite-(Ce)Ce(SiO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
9.AD.35HuttoniteThSiO4Mon.
9.AD.35Tombarthite-(Y)Y4(Si,H4)4O12-x(OH)4+2xMon.
9.AD.40EulytineBi4(SiO4)3Iso. 4 3m : I4 3d
9.AD.45ReiditeZrSiO4Tet. 4/m : I41/a

Related Minerals - Dana Grouping (8th Ed.)Hide

51.4.3d.1HibschiteCa3Al2(SiO4)3-x(OH)4xIso. m3m (4/m 3 2/m) : Ia3d

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

16.9.1GehleniteCa2Al(AlSiO7)Tet. 4 2m : P4 21m
16.9.2AnorthiteCa(Al2Si2O8)Tric. 1 : P1
16.9.3Yoshiokaite(Ca,Na)[Al(Al,Si)O4]Trig. 3 : P3
16.9.4SvyatoslaviteCa(Al2Si2O8)Orth.
16.9.5DmisteinbergiteCa(Al2Si2O8)Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
16.9.6GrossularCa3Al2(SiO4)3Iso. m3m (4/m 3 2/m) : Ia3d
16.9.7VuagnatiteCaAl(SiO4)(OH)Orth.
16.9.8Zoisite{Ca2}{Al3}(Si2O7)(SiO4)O(OH)Orth. mmm (2/m 2/m 2/m) : Pnma
16.9.9Clinozoisite{Ca2}{Al3}(Si2O7)(SiO4)O(OH)Mon. 2/m : P21/m
16.9.10PrehniteCa2Al2Si3O10(OH)2Orth. mm2
16.9.11KamaishiliteCa2(Al2SiO6)(OH)2Tet.
16.9.12BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
16.9.13MargariteCaAl2(Al2Si2O10)(OH)2Mon.
16.9.14ChantaliteCaAl2(SiO4)(OH)4Tet. 4/m : I41/a
16.9.15CebolliteCa5Al2(SiO4)3(OH)4Orth.
16.9.18LawsoniteCaAl2(Si2O7)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
16.9.19ParthéiteCa2(Si4Al4) O15 (OH)2•4H2OMon. 2/m : B2/b
16.9.20WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m
16.9.21VertumniteCa4Al4Si4O6(OH)24 · 3H2OMon. 2/m : P21/m
16.9.22ScoleciteCaAl2Si3O10 · 3H2OMon. m : Bb
16.9.23LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
16.9.24YugawaraliteCaAl2Si6O16 · 4H2OMon.
16.9.25Gismondine-CaCaAl2Si2O8 · 4H2O
16.9.26EpistilbiteCaAl2Si6O16 · 5H2OMon.
16.9.27GoosecreekiteCa[Al2Si6O16] · 5H2OMon.
16.9.28CowlesiteCaAl2Si3O10 · 6H2OOrth.
16.9.30StelleriteCa4(Si28Al8)O72 · 28H2OOrth. mmm (2/m 2/m 2/m) : Fmmm
16.9.31SträtlingiteCa2Al2SiO7 · 8H2OTrig.
16.9.32AmstalliteCaAl(Si,Al)4O8(OH)4 · (H2O,Cl)Mon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for KatoiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Cohen-Addad, C., Ducros, P., and Bertaut, E.F. (1967) Étude de la substitution du groupement SiO4 par (OH)4 dans les composés Al2Ca3(OH)12 et Al2Ca3(SiO4)2.16(OH)3.36 de type grenat. Acta Crystallographica, 23, 220–230.
Foreman, D.W. Jr. (1968) Neutron and X-ray diffraction study of Ca3Al2(O4D4)3, a garnetoid. The Journal of Chemical Physics, 48, 3037–3041.
Passaglia, E., Rinaldi, R. (1984) Katoite, a new member of the Ca3Al2(SiO4)3{Ca3Al2(OH)12 series and a new nomenclature for the hydrogrossular group of minerals. Bulletin de Minéralogie: 107: 605-618.
Dunn, P.J., Fleischer, M., Langley, R.H., Shigley, J.E., Zilczer, J.A. (1985) New mineral names. American Mineralogist: 70: 871-881.
Sacerdoti, M., Passaglia, E. (1985) The crystal structure of katoite and implications within the hydrogrossular group of minerals. Bulletin de Minéralogie: 108: 1-8.
Lager, G.A., Armbruster, T., and Faber, G. (1987) Neutron and X-ray diffraction study of hydrogarnet Ca3Al2(O4H4)3. American Mineralogist, 72, 756–765.
Canadian Mineralogist: (1990): 28: 87.
Rossman, G.R., and Aines, R.D. (1991) The hydrous components in garnets: Grossular-hydrogrossular. American Mineralogist, 76, 1153–1164.
Milman, V., Winkler, B., Nobes, R.H., Akhmatchaya, E.V., Pickard, C.J., White, J.A. (2000) Garnets: structure, compressibility, dynamics, and disorder. Journal of the Minerals, Metals and Materials Society: 52(7): 22-25.
Lager, G.A., Downs, R.T., Origlieri, M., Garoutte, R. (2002) High-pressure single-crystal X-ray diffraction study of katoite hydrogarnet: Evidence for a phase transition from Ia3d -> I43d symmetry at 5 GPa. American Mineralogist: 87: 642-647. [synthetic sample]
Ferro, O., Galli, E., Papp, G., Quartieri, S., Szakall, S., Vezzalini, G. (2003) A new occurrence of katoite and re-examination of the hydrogrossular group. European Journal of Mineralogy: 15: 419-426.
Blass, G., Graf, H.W., Sebold, D. (2004) Über "Hydrogrossulare" sowie einen Neufund des seltenen Hydrogranats Katoit vom Bellerberg, Eifel. Mineralien-Welt: 15(6): 16-20. (in German)
Kolesov, B.A., Geiger, C.A. (2005) The vibrational spectrum of synthetic hydrogrossular (katoite) Ca3Al2(O4H4)3: a low-temperature IR and Raman spectroscopic study. American Mineralogist: 90: 1335-1341.
Teertstra, D.K. (2006) Index-of-refraction and unit-cell constraints on cation valence and pattern of order in garnet-group minerals. Canadian Mineralogist: 44: 341-346.
Grew, E.S., Locock, A.J., Mills, S.J., Galuskina, I.O., Galuskin, E.V., Hålenius, U. (2013) Nomenclature of the garnet supergroup. American Mineralogist: 98: 785-811.
Lacivita, V., Mahmoud, A., Erba, A., D'Arco, P., Mustapha, S. (2015) Hydrogrossular, Ca3Al2(SiO4)3-x(H4O4)x: An ab initio investigation of its structural and energetic properties. American Mineralogist: 100: 2637-2649.
Geng, G., Myers, R.J., Kilcoyne, A.L.D., Ha, J., Monteiro, P.J.M. (2017) Ca L2,3-edge near edge X-ray absorption fine structure of tricalcium aluminate, gypsum, and calcium (sulfo)aluminate hydrates. American Mineralogist: 102: 900-908.
Geiger, C.A. & Rossman, G.R. (2018): IR spectroscopy and OH− in silicate garnet: The long quest to document the hydrogarnet substitution. American Mineralogist, 103, 384–393.
D.A. Keen, D.S. Keeble, T.D. Bennett (2018): Neutron and X-ray total scattering study of hydrogen disorder in fully hydrated hydrogrossular, Ca3Al2(O4H4)3. Phys. Chem. Minerals 45, 333-342.

Internet Links for KatoiteHide

Localities for KatoiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Germany
 
  • Bavaria
    • Franconia
      • Maroldsweisach
Wittern: "Mineralfundorte in Deutschland", 2001
  • Rhineland-Palatinate
    • Eifel
      • Mayen
        • Ettringen
          • Bellerberg volcano
Blass, G., Graf, H.W., Sebold, D. (2004): Über "Hydrogrossulare" sowie einen Neufund des seltenen Hydrogranats Katoit vom Bellerberg, Eifel. Mineralien-Welt 15 (6), 16-20.
Galuskin, E.V., Krüger, B., Krüger, H., Blass, G., Widmer, R., Galuskina, I.O. (2016): Wernerkrauseite, CaFe3+2Mn4+O6 - the first non-stoichiometric post-spinel mineral, from Bellerberg volcano, Eifel, Germany. European Journal of Mineralogy, 28, 485-493
Hungary
 
  • Pest Co.
    • Szentendre
      • Dunabogdány
Topographia Mineralogica Hungariae VI.; Harangi, S. et al. (2009): Dunabogdány: Zeolites, laccolith, contact zone, Field Trip 2, 9th September 2009. MinPet2009 field trip booklet, 17 pp.
  • Veszprém Co.
    • Balaton Uplands
      • Tapolcai Basin
        • Uzsa (Uzsabánya)
Israel
 
  • Negev
Gross, S. (1977): The Mineralogy of the Hatrurim Formation, Israel. Geological Survey of Israel, Bulletin no. 70, 80 pp.
Galuskin, E.V., Gfeller, F., Armbruster, T., Sharygin, V.V., Galuskina, I.O., Krivovichev, S.V., Vapnik, Y., Murashko, M., Dzierżanowski, P., Wirth, R. (2015): Mayenite supergroup, part III: Fluormayenite, Ca12Al14O32[□4F2], and fluorkyuygenite, Ca12Al14O32[(H2O)4F2], two new minerals from pyrometamorphic rocks of the Hatrurim Complex, South Levant. European Journal of Mineralogy, 27, 123-136
Galuskin, E.V., Galuskina, I.O., Gfeller, F., Krüger, B., Kusz, J., Vapnik, Y., Dulski, M., Dzierżanowski, P. (2016): Silicocarnotite, Ca5[(SiO4)(PO4)](PO4), a new ‘old’ mineral from the Negev Desert, Israel, and the ternesite-silicocarnotite solid solution: indicators of high-temperature alteration of pyrometamorphic rocks of the Hatrurim Complex, Southern Levant. European Journal of Mineralogy: 28: 105-12.
Italy (TL)
 
  • Latium
    • Viterbo Province
      • Montalto di Castro
        • Pietra Massa Locality
Passaglia, E. & Turconi, B. (1982): Silicati ed altri minerali di Montalto di Castro - VT. Rivista Mineralogica Italiana, 4/1982, 97-110.
Norway
 
  • Telemark
    • Skien
Jamtveit B., Dahlgren S. and Austrheim H. (1997): High-grade contact metamorphism of calcareous rocks from the Oslo Rift, Southern Norway. American Mineralogist. 82 : 1241 - 1254
Palestine
 
  • West Bank
    • Hatrurim Formation
Galuskin, E.V., Gfeller, F., Armbruster, T., Sharygin, V.V., Galuskina, I.O., Krivovichev, S.V., Vapnik, Y., Murashko, M., Dzierżanowski, P., Wirth, R. (2015): Mayenite supergroup, part III: Fluormayenite, Ca12Al14O32[□4F2], and fluorkyuygenite, Ca12Al14O32[(H2O)4F2], two new minerals from pyrometamorphic rocks of the Hatrurim Complex, South Levant. European Journal of Mineralogy, 27, 123-136.
Mineral and/or Locality  
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