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Fluoro-pedrizite

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05470240014948283436256.jpg
Fluoro-pedrizite

Tastyg Spodumene deposit, Erzinsky District, Tuva, Russia
05470240014948283436256.jpg
Fluoro-pedrizite

Tastyg Spodumene deposit, Erzinsky District, Tuva, Russia
05470240014948283436256.jpg
Fluoro-pedrizite

Tastyg Spodumene deposit, Erzinsky District, Tuva, Russia
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About Fluoro-pedriziteHide

Formula:
NaLi2(Mg2Al2Li)(Si8O22)F2
The pedrizite group minerals are lithium amphiboles defined with:
A(Na+K+2Ca)> 0.5 apfu and
CLi > 0,5 apfu

Fluoro-pedrizite is defined with
A position: Na dominant
C2+ position: Mg dominant
C3+ position: Al dominant
W position: F dominant
Crystal System:
Monoclinic
Name:
For being the F-analogue of pedrizite.
Fluoro-pedrizite was originally described as fluoro-sodic-pedrizite by Oberti et al. 2005 (IMA 2004-002) from the holotype material of clinoholmquistite as EMP and SIMS analysis and structure refinement showed that the sample consisted of a mixture of two distinct amphibole compositions, tremolite and a new amphibole end-member, fluoro-sodic-pedrizite.


Classification of Fluoro-pedriziteHide

IMA status notes:
Published without approval
Approval history:
Published without approval: 2012
Strunz 8th ed.:
8/F.08-82
Nickel-Strunz 10th (pending) ed.:
9.DE.25

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles

Chemical Properties of Fluoro-pedriziteHide

Formula:
NaLi2(Mg2Al2Li)(Si8O22)F2

The pedrizite group minerals are lithium amphiboles defined with:
A(Na+K+2Ca)> 0.5 apfu and
CLi > 0,5 apfu

Fluoro-pedrizite is defined with
A position: Na dominant
C2+ position: Mg dominant
C3+ position: Al dominant
W position: F dominant
Elements listed:
Al, F, Li, Mg, Na, O, Si - search for minerals with similar chemistry

Crystallography of Fluoro-pedriziteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Cell Parameters:
a = 9.357 Å, b = 17.58 Å, c = 5.267 Å
β = 102.37°
Ratio:
a:b:c = 0.532 : 1 : 0.3
Unit Cell V:
846.29 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.11 Å(56)
4.39 Å(54)
3.371 Å(43)
3.002 Å(66)
2.869 Å(26)
2.675 Å(100)
Comments:
From type description.

First Recorded Occurrence of Fluoro-pedriziteHide

Synonyms of Fluoro-pedriziteHide

Other Language Names for Fluoro-pedriziteHide

Relationship of Fluoro-pedrizite to other SpeciesHide

Member of:
Pedrizite Root Name Group > Lithium Amphibole Subgroup > w(OH, F, Cl)-dominant Amphibole Group > Amphibole Supergroup
Other Members of this group:
Ferri-fluoro-pedriziteNaLi2(LiMg2Fe3+2)(Si8O22)F2
Ferri-pedrizite[Na][Li2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
Ferro-ferri-fluoro-pedriziteNaLi2(LiFe2+2Fe3+2)(Si8O22)F2
Ferro-ferri-pedrizite[Na][Li2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
Ferro-fluoro-pedriziteNa(Li2)(Fe2+2Al2Li)[Si8O22]F2Mon. 2/m : B2/m
Ferro-pedriziteNaLi2(Fe2+2Al2Li)Si8O22(OH)2Mon. 2/m : B2/m
PedriziteNaLi2(LiMg2Al2)(Si8O22)(OH)2Mon. 2/m : B2/m

Related Minerals - Nickel-Strunz GroupingHide

9.DE.Clino-suenoite◻{Mn2+2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Cummingtonite◻{Mg2}{Mg5}(Si8O22)(OH)2Mon.
9.DE.05Clino-holmquistite Root Name Group◻{Li2}{Z2+3Z3+2}(Si8O22)(OH,F,Cl)2Mon.
9.DE.05Grunerite◻{Fe2+2}{Fe2+5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.05Permanganogrunerite◻{Mn2+2}{Mn2+5}(Si8O22)(OH)2Mon.
9.DE.05Ferri-fluoro-leakeite{Na}{Na2}{Mg2Fe3+2Li}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Actinolite◻Ca2(Mg4.5-2.5Fe0.5-2.5)Si8O22OH2Mon. 2/m : B2/m
9.DE.10Ferri-tschermakite◻{Ca2}{Mg3Fe3+2}(Al2Si6O22)(OH)2Mon.
9.DE.10Ferro-actinolite◻Ca2Fe2+5(Si8O22)OH2Mon.
9.DE.10Ferro-hornblende◻Ca2(Fe2+4Al)(Si7Al)O22(OH)2Mon.
9.DE.10Ferro-tschermakite◻{Ca2}{Fe2+3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10JoesmithitePb2+Ca2(Mg3Fe3+2)(Si6Be2)O22(OH)2Mon.
9.DE.10Magnesio-hornblende◻Ca2(Mg4Al)(Si7Al)O22(OH)2Mon. 2/m : B2/m
9.DE.10Tremolite◻{Ca2}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Tschermakite◻(Ca2)(Mg3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.10CannilloiteCaCa2(Mg4Al)(Si5Al3O22)OH2Mon.
9.DE.10Fluoro-cannilloiteCaCa2(Mg4Al)(Si5Al3)O22F2Mon.
9.DE.10Parvo-manganotremolite◻{CaMn2+}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.10Fluoro-tremolite◻{Ca2}{Mg5}(Si8O22)F2Mon. 2/m : B2/m
9.DE.10Ferro-ferri-hornblende◻Ca2(Fe2+4Fe3+)(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.15EdeniteNaCa2Mg5(Si7Al)O22OH2Mon.
9.DE.15Ferro-edeniteNaCa2Fe2+5(Si7Al)O22OH2Mon.
9.DE.15Ferro-kaersutiteNaCa2{Fe2+3AlTi}(Si6Al2O22)O2Mon.
9.DE.15Ferro-pargasiteNaCa2(Fe2+4Al)(Si6Al2)O22(OH)2Mon.
9.DE.15HastingsiteNaCa2(Fe2+4Fe3+)(Si6Al2)O22OH2Mon.
9.DE.15KaersutiteNaCa2(Mg3AlTi4+)(Si6Al2)O22O2Mon.
9.DE.15Magnesio-hastingsiteNaCa2(Mg4Fe3+)(Si6Al2)O22(OH)2Mon.
9.DE.15PargasiteNaCa2(Mg4Al)(Si6Al2)O22(OH)2Mon. 2/m : B2/m
9.DE.15Sadanagaite{Na}{Ca2}{Mg3Al2}(Si5Al3O22)(OH)2Mon.
9.DE.15Fluoro-edeniteNaCa2Mg5(Si7Al)O22F2Mon. 2/m : P2/m
9.DE.15Potassic-ferro-ferri-sadanagaite{K}{Ca2}{Fe2+3Fe3+2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-sadanagaite{K}{Ca2}{Mg3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Potassic-pargasiteKCa2(Mg4Al)(Si6Al2)O22(OH)2Mon.
9.DE.15Potassic-ferro-sadanagaite{K}{Ca2}{Fe2+3Al2}(Al3Si5O22)(OH)2Mon.
9.DE.15Magnesio-fluoro-hastingsiteNaCa2(Mg4Fe3+)(Si6Al2)O22F2Mon. 2/m : B2/m
9.DE.15Potassic-fluoro-hastingsiteKCa2(Fe2+4Fe3+)(Si6Al2)O22F2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-hastingsiteKCa2(Fe2+4Fe3+)(Si6Al2)O22Cl2Mon. 2/m : B2/m
9.DE.15Fluoro-pargasiteNaCa2(Mg4Al)(Si6Al2)O22F2Mon. 2/m : B2/m
9.DE.15Parvo-mangano-edenite{Na}{CaMn2+}{Mg5}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-chloro-pargasiteKCa2(Mg4Al)(Si6Al2)O22Cl2Mon. 2/m : B2/m
9.DE.15Potassic-ferro-chloro-edeniteKCa2Fe2+5(AlSi7O22)Cl2
9.DE.15Potassic-magnesio-hastingsiteKCa2(Mg4Fe3+)(Si6Al2)O22(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-ferro-pargasiteKCa2(Fe2+4Al)(Si6Al2)O22(OH)2Mon. 2/m : B2/m
9.DE.15Chromio-pargasite{Na}{Ca2}{Mg4Cr3+}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.15Potassic-fluoro-pargasiteKCa2(Mg4Al)(Si6Al2)O22F2Mon. 2/m : B2/m
9.DE.15Ferri-kaersutiteNaCa2(Mg3Fe3+Ti)(Si6Al2O22)O2Mon. 2/m : B2/m
9.DE.15Vanadio-pargasiteNaCa2(Mg3+4V)(Al2Si6)O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-taramiteNa(CaNa)(Fe2+3Al2)(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Barroisite◻{CaNa}{Mg3Al2}(AlSi7O22)(OH)2Mon.
9.DE.20Ferro-ferri-barroisite◻(CaNa)(Fe2+3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-winchite◻[CaNa][Fe2+4(Fe3+,Al)]Si8O22(OH)2
9.DE.20Ferri-barroisite◻(CaNa)(Mg3Fe3+2)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-taramiteNa(CaNa)(Fe2+3Fe3+2)(Al2Si6O22)(OH)2
9.DE.20Ferro-ferri-katophoriteNa(NaCa)(Fe2+4Fe3+)(Si7Al)O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-barroisite◻{CaNa}{Fe2+3Al2}(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.20Ferro-richterite{Na}{CaNa}{Fe2+5}(Si8O22)(OH)2Mon.
9.DE.20Ferro-winchite ◻{CaNa}{Fe2+4Al}(Si8O22)(OH)2Mon.
9.DE.20Ferro-katophorite{Na}{CaNa}{Fe2+4Al}[(AlSi7)O22](OH)2Mon. 2/m : B2/m
9.DE.20Ferri-katophoriteNa(CaNa)(Mg4Fe3+)(AlSi7O22)(OH)2Mon.
9.DE.20Ferri-taramiteNa(CaNa)(Mg3Fe3+2)(Al2Si6O22)(OH)2Mon.
9.DE.20Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2Mon.
9.DE.20Richterite{Na}{NaCa}{Mg5}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.20Winchite◻{CaNa}{Mg4Al}(Si8O22)(OH)2Mon. 2/m
9.DE.20Taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-richterite{Na}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon. 2/m
9.DE.20Katophorite{Na}{CaNa}{Mg4Al}[(AlSi7)O22](OH)2Mon. 2/m : B2/m
9.DE.20Potassic-fluoro-richterite{K}{CaNa}{Mg5}(Si8O22)(F,OH)2Mon.
9.DE.20Potassic-richterite{K}{CaNa}{Mg5}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Ferri-ghoseite◻[Mn2+Na][Mg4Fe3+]Si8O22(OH)2Mon. 2/m
9.DE.20Ferri-winchite◻[CaNa][Mg4(Fe3+,Al)]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.20Fluoro-taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)F2Mon. 2/m : B2/m
9.DE.20Fluoro-katophoriteNa(CaNa)(Mg4Al)(AlSi7O22)F2Mon.
9.DE.20Ferri-fluoro-katophoriteNa(CaNa)(Mg4Fe3+)(AlSi7O22)F2Mon. 2/m : B2/m
9.DE.25Arfvedsonite[Na][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25EckermanniteNaNa2(Mg4Al}Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-eckermanniteNaNa2(Fe2+4Al)Si8O22(OH)2Mon.
9.DE.25Ferro-glaucophane◻[Na2][Fe2+3Al2]Si8O22(OH)2Mon.
9.DE.25Glaucophane◻[Na2][Mg3Al2]Si8O22(OH)2Mon.
9.DE.25Potassic-mangani-leakeite[(Na,K)][Na2][Mg2Mn3+2Li]Si8O22(OH)2Mon.
9.DE.25Mangano-ferri-eckermannite{Na}{Na2}{Mn2+4Fe3+}Si8O22(OH)2Mon.
9.DE.25Ferri-leakeite[Na][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Magnesio-riebeckite◻{Na2}{Mg3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-arfvedsonite{Na}{Na2}{Mg4Fe3+}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25NybøiteNaNa2(Mg3Al2)(AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.25Riebeckite◻[Na2][Fe2+3Fe3+2]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangano-mangani-ungarettiiteNaNa2(Mn2+2Mn3+3)(Si8O22)O2Mon.
9.DE.25Ferro-ferri-nybøiteNaNa2[(Fe2+3,Mg)Fe3+2](AlSi7O22)(OH)2Mon. 2/m : B2/m
9.DE.25Clino-ferro-ferri-holmquistite◻{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferri-nybøiteNaNa2(Mg3Fe3+2](AlSi7O22)(OH)2Mon.
9.DE.25Ferro-ferri-leakeite[Na][Na2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Ferro-ferri-fluoro-leakeiteNa(Na2)(Fe2+2Fe3+2Li)(Si8O22)(F)2Mon.
9.DE.25Sodic-ferri-clinoferroholmquistiteNa0.5{Li2}{Fe2+3Fe3+2}(Si8O22)(OH)2Mon.
9.DE.25Magnesio-fluoro-arfvedsonite[Na][Na2][Mg4Fe3+][Si8O22](F,OH)2Mon.
9.DE.25Ferri-pedrizite[Na][Li2][Mg2Fe3+2Li]Si8O22(OH)2Mon.
9.DE.25Potassic-ferri-leakeite[K][Na2][Mg2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Fluoro-nybøiteNaNa2(Mg3Al2)(AlSi7O22)(F,OH)2Mon. 2/m : B2/m
9.DE.25Mangani-dellaventuraiteNaNa2(MgMn3+2Ti4+Li)Si8O22O2Mon. 2/m : B2/m
9.DE.25Potassic-arfvedsonite[(K,Na)][Na2][Fe2+4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Mangani-obertiiteNaNa2(Mg3Mn3+Ti4+)Si8O22O2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-fluoro-arfvedsonite[(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]Mon. 2/m : B2/m
9.DE.25Ferro-ferri-pedrizite[Na][Li2][Fe2+2Fe3+2Li]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Potassic-magnesio-arfvedsonite[K][Na2][Mg4Fe3+]Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25PedriziteNaLi2(LiMg2Al2)(Si8O22)(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-pedriziteNaLi2(Fe2+2Al2Li)Si8O22(OH)2Mon. 2/m : B2/m
9.DE.25Ferro-fluoro-pedriziteNa(Li2)(Fe2+2Al2Li)[Si8O22]F2Mon. 2/m : B2/m
9.DE.25Fluoro-leakeiteNaNa2(Mg2Al2Li)(Si8O22)F2Mon. 2/m : B2/m
9.DE.25Ferro-ferri-obertiiteNaNa2(Fe2+3Fe3+Ti)Si8O22O2Mon. 2/m : B2/m
9.DE.25Ferri-obertiiteNaNa2(Mg3Fe3+Ti)Si8O22O2Mon. 2/m : B2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Fluoro-pedriziteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Ginzburg, I.V. (1965) Holmquistite and its structural variety clinoholmquistite.
Trudy Mineral. Muzeya Akad. Nauk SSSR: 16: 73-89 (in Russian).
Oberti, R., Cámara, F., Ottolini, L. (2005) Clinoholmquistite discredited: The new amphibole end-member fluoro-sodic-pedrizite. The American Mineralogist: 90: 732-736.
Hawthorne, F.C., Oberti, R. (2006) On the classification of amphiboles. The Canadian Mineralogist: 44: 1-21.
Hawthorne, F.C., Oberti, R., Harlow, G.E., Maresch, W.V., Martin, R.F., Schumacher, J.C., Welch, M.D. (2012) Nomenclature of the amphibole supergroup. American Mineralogist: 97: 2031-2048.

Internet Links for Fluoro-pedriziteHide

Localities for Fluoro-pedriziteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Russia (FRL)
 
  • Tuva
    • Erzinsky District
Oberti, R., Cámara, F., Ottolini, L. (2005): Clinoholmquistite discredited: The new amphibole end-member fluoro-sodic-pedrizite. The American Mineralogist, 90, 732-736.
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