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Nagashimalite

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About NagashimaliteHide

Otokichi Nagashima
Formula:
Ba4(V,Ti)4B2Si8O27(O,OH)2Cl
Colour:
Greenish-black
Lustre:
Vitreous, Sub-Metallic
Hardness:
6
Specific Gravity:
4.08
Crystal System:
Orthorhombic
Name:
Named in honor of Otokichi Nagashima (長島 乙吉) (2 September 1890 - 4 December 1969), pioneer Japanese amateur mineralogist.
This page provides mineralogical data about Nagashimalite.


Classification of NagashimaliteHide

Approved
First Published:
1980
9.CE.20

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
64.3.1.3

64 : CYCLOSILICATES Rings with Other Anions and Insular Silicate Groups
3 : Rings with Other Anions and Insular Silicate Groups: 4-membered rings with [Si2O7] dimers
17.5.36

17 : Silicates Containing other Anions
5 : Borosilicates

Physical Properties of NagashimaliteHide

Vitreous, Sub-Metallic
Colour:
Greenish-black
Streak:
green
Hardness:
Hardness:
VHN100=606 - 681 kg/mm2 - Vickers
Cleavage:
None Observed
Density:
4.08 g/cm3 (Measured)    4.14 g/cm3 (Calculated)

Optical Data of NagashimaliteHide

Type:
Biaxial (+)
RI values:
nα = 1.750 nβ = 1.753 nγ = 1.780
2V:
Measured: 30° , Calculated: 38°
Max Birefringence:
δ = 0.030
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r > v strong
Pleochroism:
Strong
Comments:
X= greenish-yellow
Y= green
Z= greenish-brown

Chemical Properties of NagashimaliteHide

Formula:
Ba4(V,Ti)4B2Si8O27(O,OH)2Cl
IMA Formula:
Ba4(V3+,Ti)4(O,OH)2[B2Si8O27]Cl
Common Impurities:
Mn,H2O

Crystallography of NagashimaliteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pmmn
Cell Parameters:
a = 13.937 Å, b = 12.122 Å, c = 7.116 Å
Ratio:
a:b:c = 1.15 : 1 : 0.587
Unit Cell V:
1,202.21 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Tabular to elongated crystals, sub=parallel aggregates.

Type Occurrence of NagashimaliteHide

Place of Conservation of Type Material:
National Science Museum, Tokyo
Reference:
Matsubara, S., Kato, A. (1980) Nagashimalite, Ba4(V3+, Ti)4[(O,OH)2|Cl|Si8B2O27], a new mineral from the Mogurazawa mine, Gumma prefecture, Japan. Mineralogical Journal: 10: 122-130.

Synonyms of NagashimaliteHide

Other Language Names for NagashimaliteHide

Simplified Chinese:纤硅钒钡石
Traditional Chinese:纖矽釩鋇石

Related Minerals - Nickel-Strunz GroupingHide

9.CE.05PapagoiteCaCu[H3AlSi2O9]Mon.
9.CE.10VerplanckiteBa2(Mn,Fe,Ti)Si2O6(O,OH,Cl,F)2 · 3H2O or nearHex.
9.CE.15BaotiteBa4Ti8Si4O28ClTet. 4/m : I41/a
9.CE.20TaramelliteBa4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm (2/m 2/m 2/m) : Pmmn
9.CE.20TitantaramelliteBa4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2ClxOrth.
9.CE.25Bario-orthojoaquinite(Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2OOrth.
9.CE.25Byelorussite-(Ce)NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2O
9.CE.25Joaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2OMon. 2 : B2
9.CE.25Orthojoaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2O
9.CE.25StrontiojoaquiniteSr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2OMon.
9.CE.25Strontio-orthojoaquinite(Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2OOrth.
9.CE.25Orthojoaquinite-(La)NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2OOrth.
9.CE.30eLabuntsovite-MnNa4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2OMon.
9.CE.30aNenadkevichite(Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2OOrth. mmm (2/m 2/m 2/m) : Pbam
9.CE.30dLemmleinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2OOrth.
9.CE.30aKorobitsyniteNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2OOrth. mmm (2/m 2/m 2/m) : Pbam
9.CE.30cKuzmenkoite-MnK2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2OMon.
9.CE.30bVuoriyarvite-KK2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2OMon.
9.CE.30bTsepinite-NaNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon.
9.CE.30cKarupmøllerite-Ca(Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2O
9.CE.30eLabuntsovite-MgNa4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon.
9.CE.30eLabuntsovite-FeNa4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon.
9.CE.30dLemmleinite-BaNa2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon. 2/m : B2/m
9.CE.30cGjerdingenite-FeK2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30hNeskevaaraite-FeK3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2OMon. m : Bm
9.CE.30bTsepinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. 2/m : B2/m
9.CE.30bParatsepinite-BaBa4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2O
9.CE.30bTsepinite-CaCa(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. 2/m : B2/m
9.CE.30hAlsakharovite-ZnNaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30cGjerdingenite-MnK2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30cLepkhenelmite-Zn(Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30bTsepinite-SrSr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30bParatsepinite-Na(Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8·nH2O n ~ 8Mon. 2/m : B2/m
9.CE.30fParalabuntsovite-MgNa8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2OMon. 2/m
9.CE.30cGjerdingenite-CaK2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30cGjerdingenite-NaK2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2OMon. 2/m : B2/m
9.CE.30hGutkovaite-MnK2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon.
9.CE.30cKuzmenkoite-ZnK2Zn(Ti,Nb)4(Si4O12)2(OH,O)4·6-8H2OMon. m : Bm
9.CE.30gOrganovaite-MnK2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2OMon. 2/m : B2/m
9.CE.30gOrganovaite-ZnK2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O
9.CE.30gParakuzmenkoite-Fe(K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2OMon. 2/m : B2/m
9.CE.30cBurovaite-Ca(Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2OMon. 2/m : B2/m
9.CE.45Komarovite(Ca,Mn)Nb2[O3|Si2O7] · 3.5H2OOrth.
9.CE.45Natrokomarovite(Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2OOrth.

Related Minerals - Dana Grouping (8th Ed.)Hide

64.3.1.1TaramelliteBa4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm (2/m 2/m 2/m) : Pmmn
64.3.1.2TitantaramelliteBa4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2ClxOrth.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

17.5.1ManandoniteLi2Al4(Si2AlB)O10(OH)8Orth.
17.5.2ReedmergneriteNaBSi3O8Tric.
17.5.3SearlesiteNa(H2BSi2O7)Mon. 2 : P21
17.5.4OleniteNa(Al3)Al6(Si6O18)(BO3)3O3(OH)Trig.
17.5.5ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
17.5.6KalborsiteK6Al4BSi6O20(OH)4ClTet.
17.5.7BoromuscoviteKAl2(BSi3O10)(OH)2Mon.
17.5.8PoudretteiteKNa2B3Si12O30Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
17.5.9LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
17.5.10DatoliteCaB(SiO4)(OH)Mon. 2/m : P21/b
17.5.11DanburiteCaB2Si2O8Orth. mmm (2/m 2/m 2/m)
17.5.12HowliteCa2B5SiO9(OH)5Mon. 2/m : P21/b
17.5.13BakeriteCa4(H5B5Si3O20)Mon. 2/m : P21/b
17.5.14OyeliteCa10Si8B2O29 · 12.5H2OOrth.
17.5.15KornerupineMg3Al6(Si,Al,B)5O21(OH)Orth. mmm (2/m 2/m 2/m)
17.5.16HarkeriteCa12Mg4Al(BO3)3(SiO4)4(CO3)5 · H2OTrig. 3m (3 2/m) : R3m
17.5.17SerendibiteCa4[Mg6Al6]O4[Si6B3Al3O36]Tric. 1 : P1
17.5.18Stillwellite-(Ce)(Ce,La,Ca)BSiO5
17.5.19Tadzhikite-(Ce)Ca4Ce3+2Ti◻(B4Si4O22)(OH)2Mon.
17.5.20Melanocerite-(Ce)(Ce,Ca)5(SiO4,BO4)3(OH,0)Hex.
17.5.21Okanoganite-(Y)(Na,Ca)3(Y,Ce)12Si6B2O27F14
17.5.22Tritomite-(Ce)Ce5(SiO4,BO4)3(OH,O)
17.5.23Tritomite-(Y)Y5(SiO4,BO4)3(O,OH,F)
17.5.24Cappelenite-(Y)Ba(Y,Ce)6Si3B6O24F2Trig. 3 : P3
17.5.25Dumortierite(Al,Fe3+)7(SiO4)3(BO3)O3Orth. mmm (2/m 2/m 2/m)
17.5.26Holtite(Ta0.60.4)Al6BSi3O18(O,OH)2.25Orth. mmm (2/m 2/m 2/m) : Pnma
17.5.27DraviteNa(Mg3)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
17.5.28 FerridraviteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3O
17.5.29Axinite-(Mg)Ca2MgAl2BSi4O15OHTric.
17.5.30Uvite SeriesCa(Mg3)MgAl5(Si6O18)(BO3)3(OH)3(F/OH)Trig. 3m : R3m
17.5.31GarrelsiteBa3NaSi2B7O16(OH)4Mon.
17.5.32TienshaniteKNa3Na6Ca2Ba6Mn6(Ti4+,Nb)6B12Si36O114(O,OH,F)11Hex. 6/m : P6/m
17.5.33LeucospheniteBaNa4Ti2B2Si10O30Mon.
17.5.34TaramelliteBa4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm (2/m 2/m 2/m) : Pmmn
17.5.35TitantaramelliteBa4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2ClxOrth.
17.5.37Chromium-draviteNa(Mg3)Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig.
17.5.38WawayandaiteCa6Mn2BBe9Si6O23(OH,Cl)15Mon.
17.5.39Werdingite(Mg,Fe)2Al14Si4B4O37Tric.
17.5.40Axinite-(Mn)Ca2Mn2+Al2BSi4O15(OH)Tric. 1 : P1
17.5.41AxiniteTric.
17.5.42TinzeniteCa2Mn2+4Al4[B2Si8O30](OH)2Tric.
17.5.44SchorlNa(Fe2+3)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
17.5.45Fluor-buergeriteNa(Fe3+3)Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
17.5.46FeruviteCa(Fe2+)3MgAl5(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
17.5.47Axinite-(Fe)Ca2Fe2+Al2BSi4O15OHTric. 1 : P1
17.5.48HomiliteCa2(Fe2+,Mg)B2Si2O10Mon. 2/m : P21/b
17.5.49Grandidierite(Mg,Fe2+)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm (2/m 2/m 2/m)
17.5.50Hyalotekite(Pb,Ba,K)4(Ca,Y)2(B,Be)2(Si,B)2Si8O28(F,Cl)Tric. 1 : P1
17.5.51Hellandite-(Y)(Ca,REE)4Y2Al◻2(B4Si4O22) (OH)2Mon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for NagashimaliteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Matsubara, S., Kato, A. (1980) Nagashimalite, Ba4(V3+, Ti)4[(O,OH)2|Cl|Si8B2O27], a new mineral from the Mogurazawa mine, Gumma prefecture, Japan. Mineralogical Journal: 10: 122-130.
Fleischer, M., Cabri, L.J. (1981) New mineral names. American Mineralogist: 66: 637-639.
Matsubara, S. (1980) The crystal structure of nagashimalite, Ba4(V3+,Ti)4[(O,OH)2|Cl|Si8B2O27]. Mineralogical Journal: 10: 131-142.
Grew, E.S., and Anovitz, L.M. (1996) BORON: Mineralogy, Petrology and Geochemistry, second edition, as revised (2002).

Internet Links for NagashimaliteHide

Localities for NagashimaliteHide

ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Japan (TL)
 
  • Honshu Island
    • Kanto Region
      • Gunma Prefecture
        • Kiryuu City
Matsubara, S., & Kato, A. (1980) Nagashimalite, Ba4 (V3+, Ti) 4 [(O, OH) 2| Cl| Si8B2O27], a new mineral from the Mogurazawa mine, Gumma prefecture, Japan. Mineralogical Journal, 10(3), 122-130.
    • Tohoku Region
      • Iwate Prefecture
        • Shimohei-gun
          • Tanohata-mura
Satoshi Matsubara, et al (2008) JAKOKA: 2008 Annual Meeting of the Japan Association of Mineralogical Sciences, R4-02
Matsubara, S., Miyawaki, R., Yokoyama, K., Shigeoka, M., Miyajima, H., Suzuki, Y., ... & Ishibashi, T. (2010). Momoiite and nagashimalite from the Tanohata mine, Iwate Prefecture, Japan. Bulletin of the National Museum of Nature and Science C, 36, 1-6.
Mineral and/or Locality  
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