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Andrianovite

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About AndrianoviteHide

Formula:
Na12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5
Colour:
light yellow
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.93
Crystal System:
Trigonal
Member of:
Name:
Named in honor of Valeriy Ivanovich Andrianov (Валерия Ивановича Андрианова) (1938-1991), a prominent Russian mathematical crystallographer, developer of the AREN package of programs for structural study of minerals with mixed composition.

Classification of AndrianoviteHide

Approved
Approval Year:
2007
First Published:
2008
9.CO.10

9 : SILICATES (Germanates)
C : Cyclosilicates
O : [Si9O27]18- 9-membered rings
64.1.2.4

64 : CYCLOSILICATES Rings with Other Anions and Insular Silicate Groups
1 : Rings with Other Anions and Insular Silicate Groups with mixed ring types

Physical Properties of AndrianoviteHide

Vitreous
Transparency:
Transparent
Colour:
light yellow
Streak:
white
Hardness:
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
parallel to (001)
Fracture:
Step-Like
Density:
2.93(2) g/cm3 (Measured)    3.02 g/cm3 (Calculated)

Optical Data of AndrianoviteHide

Type:
Uniaxial (-)
RI values:
nω = 1.622() nε = 1.617(2)
Max Birefringence:
δ = 0.005
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Pleochroism:
Non-pleochroic

Chemical Properties of AndrianoviteHide

Formula:
Na12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O,H2O,OH)5

Crystallography of AndrianoviteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3m
Cell Parameters:
a = 14.281 Å, c = 30.243 Å
Ratio:
a:c = 1 : 2.118
Unit Cell V:
5,341.62 ų (Calculated from Unit Cell)
Z:
3

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.447 (60)
5.719 (40)
4.322 (71)
3.540 (38)
3.222 (70)
3.170 (50)
2.982 (100)
2.860 (94)

Type Occurrence of AndrianoviteHide

General Appearance of Type Material:
Rims on eudialyte
Place of Conservation of Type Material:
Fersman Mineralogical Museum
Geological Setting of Type Material:
Pegmatite
Reference:
Khomyakov, A.P., Nechelyustov, G.N., Rastsvetaeva, R.K., Rozenberg, K.A. (2008) Andrianovite, Na12(K,Sr,Ce)3Ca6Mn3Zr3NbSi25O73(O,H2O,OH)5-a new potassium-rich mineral of the eudialyte group from Khibiny alkaline massif, Kola Peninsula, Russia. Zapiski RMO (Proceedings of the Russian Mineralogical Society): 137(2): 43-52.

Synonyms of AndrianoviteHide

Relationship of Andrianovite to other SpeciesHide

Member of:
Other Members of this group:
AlluaiviteNa19(Ca,Mn)6(Ti,Nb)3Si26O74Cl · 2H2OTrig. 3m (3 2/m) : R3m
Aqualite(H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9ClTrig. 3 : R3
CarbokentbrooksiteNa11-12(Na,Ce)3Ca6Mn3Zr3Nb[(OH)3|CO3|(Si3O9)2|(Si9O27)2SiO] · H2OTrig. 3m : R3m
DavinciiteNa12K3Ca6Fe2+3Zr3(Si26O73OH)Cl2 Trig. 3m : R3m
DualiteNa30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn[Si51O144](OH,H2O,Cl)9Trig. 3m : R3m
EudialyteNa15Ca6(Fe2+,Mn2+)3Zr3[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
FeklicheviteNa11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5Trig. 3m : R3m
FengchengiteNa123(Ca,Sr)6Fe3+3 Zr3Si(Si25O73)(H2O,OH)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2Trig. 3m : R3m
GeorgbarsanoviteNa12(Mn,Sr,REE)3Ca6Fe2+3Zr3NbSi25O76Cl2·H2OTrig. 3m : R3m
GolysheviteNa10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3 · H2OTrig. 3m : R3m
Hydrorastsvetaevite(Na11(H3O)11K6(H2O)1.5Sr)Ca12Fe3Na2MnZr6Si52O144(OH)4.5Cl3.5Trig. 3m : R3m
Ikranite(Na,H3O)15(Ca,Mn2+)6Fe3+2Zr3-4[Cl|(H0-3Si3O9)2|{(Si9O27)2,(Si9O27)2SiO}] · 2-3H2OTrig. 3m : R3m
Ilyukhinite(H3O,Na)14Ca6Mn2Zr3Si26O72(OH)2·3H2OTrig. 3m : R3m
Johnsenite-(Ce)Na12Ce3Ca6Mn3Zr3WSi25O73(CO3)(OH)2Trig. 3m : R3m
Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2OTrig. 3m : R3m
KhomyakoviteNa12Sr3Ca6Fe3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
Labyrinthite(Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3Trig. 3 : R3
ManganoeudialyteNa14Ca6Mn3Zr3[Si26O72(OH)2](H2O,Cl,O,OH)6Trig. 3m : R3m
ManganokhomyakoviteNa12Sr3Ca6Mn3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
MogoviditeNa9(Ca,Na)12Fe2Zr3Si25O72(CO3) (OH)4Trig. 3m : R3m
OneilliteNa15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2Trig. 3 : R3
RaslakiteNa15Ca3Fe2+3(Na,Zr)3Zr3Nb<0.5[(Cl,OH)|(Si3O9)2|(Si9O27)2SiO] · 3(OH,H2O)Trig. 3
RastsvetaeviteNa27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2Trig. 3m : R3m
SiudaiteNa8(Mn2+2Na)Ca6(Fe3+,Mn2+)3Zr3NbSi24(Si,◻,Ti)O74(OH)2Cl·5H2OTrig. 3m : R3m
TaseqiteNa12Sr3Ca6Fe3Zr3Nb[Cl2|(Si3O9)2|(Si9O27)2SiO] · 3(O,OH,H2O)Trig. 3m : R3m
UM1971-22-SiO:CaClFeHMgMnNaNbZrNa12Ca5(Ce,La,Y,Ca)Zr3(Zr,Nb)(Fe,Mn)3[Si9O24-26(OH)1-3]2[Si3O9]2ClTrig. 3m : R3m
UM1990-79-SiO:CaClFeHMnNaNbREEZrNa14Ca5(Mg,Ca,Mn)Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Zr)3(Mn,Na,Ce,La,Y)(Na,H2O,K,Sr)(OH)4-5(OH,Cl)
UM1990-80-SiO:CaFeHMnNaNbREEZrNa14Ca4(Mn,Ca)2Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Mn,Al,Ti)3(Na,Ce,La,Y,Mn)(Na,H2O,K,Sr)(OH)7-8
UM1998-21-SiO:CaCeClHMnNaZrNa16Ca6(Mn,Ce)3Zr3(Si3O9)2(Si9O27)2(OH,Cl)4Trig. 3m : R3m
UM1999-36-SiO:CaCeHMnNaNbSrZrNa17(Ca,Ce,Sr)2Mn3(Zr,Nb)4Si25O73(O,OH,F,Cl)5Trig. 3 : R3
UM2000-66-SiO:CaClFeHMnNaNbSrZrNa12(Ca,Mn)6(Sr,Na,K)3(Fe,Mn)3(Zr,Nb)4Si25O66(OH,Cl)11Trig. 3m : R3m
UM2003-39-SiO:CaClFeHHfNaNbSrTaTiZrNa12(Na,K,Mn,Sr)2Ca5(Ca,Mn)(Zr,Hf)3(Fe,◻,Ta)3(Si,Nb,W)(Si,Al,Ti)Si24O72(OH,O)3.5Cl•1.2H2O
UM2004-51-SiO:CaClFFeHNaNbTiNa16Ca6(Fe,Mn)3Zr3(Ti,Nb)Si26O72FCl0.5•nH2OTrig. 3m : R3m
UM2006-17-SiO:CaClFFeHMnNaZrNa15(Ca3Mn3)Zr3(Fe,Zr)3SiSi(Si3O9)2(Si9O27)2O2(OH,F,Cl)3•2H2O
UM2006-18-SiO:CaClFFeHMnNaZrNa15Ca3(Mn,Fe)3Zr3(Zr,Na)3(Si,Nb)(S,Ti,Si)(Si3O9)2(Si9O27)2(O,OH)5(Cl,F,H2O)
UM2006-28-SiO:CaHMnNaZrNa33Ca12Zr6Mn3(Mn,Nb,Ti)2Si50O132(O,OH)12(OH,H2O,Cl)10
UM2010-06-SiO:CaFeHMnNaNbREETiZr[Na,(H3O)]15(Ca3Mn3)Na3Zr3(Si,Ti)[Si25O72OH](OH)2·2H2O
Unnamed (Eudialyte 3248)Na29Ca12Zr6[Si48O132(O,OH)12]{[Na]4[Si]2}{[Mn]3[Mn,Nb,Ti]2}(OH,H2O,Cl)10Trig. 3m (3 2/m) : R3m
Unnamed (Hydrated Hydrous Na-Ca-Mn-Fe-Zr-Ti Silicate Chloride)Na37Ca10Mn2FeZr6Si50(Ti,Nb)2O144(OH)5Cl3·H2OTrig. 3m : R3m
VoronkoviteNa15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl · H2OTrig. 3 : R3
Zirsilite-(Ce)Na11-12(Ce,Na)3Ca6Mn3Zr3Nb(Si19O55)(Si3O9)2(CO3)(OH)3 · H2OTrig. 3m : R3m

Related Minerals - Nickel-Strunz GroupingHide

9.CO.10AlluaiviteNa19(Ca,Mn)6(Ti,Nb)3Si26O74Cl · 2H2OTrig. 3m (3 2/m) : R3m
9.CO.10EudialyteNa15Ca6(Fe2+,Mn2+)3Zr3[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m (3 2/m) : R3m
9.CO.10FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2Trig. 3m : R3m
9.CO.10Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2OTrig. 3m : R3m
9.CO.10KhomyakoviteNa12Sr3Ca6Fe3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
9.CO.10ManganokhomyakoviteNa12Sr3Ca6Mn3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
9.CO.10OneilliteNa15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2Trig. 3 : R3
9.CO.10RaslakiteNa15Ca3Fe2+3(Na,Zr)3Zr3Nb<0.5[(Cl,OH)|(Si3O9)2|(Si9O27)2SiO] · 3(OH,H2O)Trig. 3
9.CO.10FeklicheviteNa11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5Trig. 3m : R3m
9.CO.10CarbokentbrooksiteNa11-12(Na,Ce)3Ca6Mn3Zr3Nb[(OH)3|CO3|(Si3O9)2|(Si9O27)2SiO] · H2OTrig. 3m : R3m
9.CO.10Zirsilite-(Ce)Na11-12(Ce,Na)3Ca6Mn3Zr3Nb(Si19O55)(Si3O9)2(CO3)(OH)3 · H2OTrig. 3m : R3m
9.CO.10Ikranite(Na,H3O)15(Ca,Mn2+)6Fe3+2Zr3-4[Cl|(H0-3Si3O9)2|{(Si9O27)2,(Si9O27)2SiO}] · 2-3H2OTrig. 3m : R3m
9.CO.10TaseqiteNa12Sr3Ca6Fe3Zr3Nb[Cl2|(Si3O9)2|(Si9O27)2SiO] · 3(O,OH,H2O)Trig. 3m : R3m
9.CO.10RastsvetaeviteNa27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2Trig. 3m : R3m
9.CO.10GolysheviteNa10Ca3Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2CO3(OH)3 · H2OTrig. 3m : R3m
9.CO.10Labyrinthite(Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3Trig. 3 : R3
9.CO.10Johnsenite-(Ce)Na12Ce3Ca6Mn3Zr3WSi25O73(CO3)(OH)2Trig. 3m : R3m
9.CO.10MogoviditeNa9(Ca,Na)12Fe2Zr3Si25O72(CO3) (OH)4Trig. 3m : R3m
9.CO.10GeorgbarsanoviteNa12(Mn,Sr,REE)3Ca6Fe2+3Zr3NbSi25O76Cl2·H2OTrig. 3m : R3m
9.CO.10Aqualite(H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9ClTrig. 3 : R3
9.CO.10DualiteNa30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn[Si51O144](OH,H2O,Cl)9Trig. 3m : R3m
9.CO.10VoronkoviteNa15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl · H2OTrig. 3 : R3
9.CO.10UM1999-36-SiO:CaCeHMnNaNbSrZrNa17(Ca,Ce,Sr)2Mn3(Zr,Nb)4Si25O73(O,OH,F,Cl)5Trig. 3 : R3
9.CO.10UM2000-66-SiO:CaClFeHMnNaNbSrZrNa12(Ca,Mn)6(Sr,Na,K)3(Fe,Mn)3(Zr,Nb)4Si25O66(OH,Cl)11Trig. 3m : R3m
9.CO.10ManganoeudialyteNa14Ca6Mn3Zr3[Si26O72(OH)2](H2O,Cl,O,OH)6Trig. 3m : R3m
9.CO.10UM1990-78-SiO:CaClFeHKNaZr(H3O)7(Na,K)5(Ca,Sr,Mn)6Zr3[Si3O7(O,OH)2]2[Si9O23(O,OH)4]2[SiNaFe(Zr,Ti,Al,Nb)□]Cl1.5(O,OH)Trig. 3m : R3m
9.CO.10UM1990-79-SiO:CaClFeHMnNaNbREEZrNa14Ca5(Mg,Ca,Mn)Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Zr)3(Mn,Na,Ce,La,Y)(Na,H2O,K,Sr)(OH)4-5(OH,Cl)
9.CO.10UM1971-22-SiO:CaClFeHMgMnNaNbZrNa12Ca5(Ce,La,Y,Ca)Zr3(Zr,Nb)(Fe,Mn)3[Si9O24-26(OH)1-3]2[Si3O9]2ClTrig. 3m : R3m
9.CO.10UM1998-21-SiO:CaCeClHMnNaZrNa16Ca6(Mn,Ce)3Zr3(Si3O9)2(Si9O27)2(OH,Cl)4Trig. 3m : R3m

Related Minerals - Dana Grouping (8th Ed.)Hide

64.1.2.1Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2OTrig. 3m : R3m
64.1.2.2FerrokentbrooksiteNa15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3Cl2Trig. 3m : R3m
64.1.2.3CarbokentbrooksiteNa11-12(Na,Ce)3Ca6Mn3Zr3Nb[(OH)3|CO3|(Si3O9)2|(Si9O27)2SiO] · H2OTrig. 3m : R3m
64.1.2.5KhomyakoviteNa12Sr3Ca6Fe3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
64.1.2.6ManganokhomyakoviteNa12Sr3Ca6Mn3Zr3W[Si25O73](O,OH,H2O)3(OH,Cl)2Trig. 3m : R3m
64.1.2.7Johnsenite-(Ce)Na12Ce3Ca6Mn3Zr3WSi25O73(CO3)(OH)2Trig. 3m : R3m
64.1.2.8GeorgbarsanoviteNa12(Mn,Sr,REE)3Ca6Fe2+3Zr3NbSi25O76Cl2·H2OTrig. 3m : R3m

Other InformationHide

Notes:
gelates in 50% HCl and HNO3 at room temperature
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for AndrianoviteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Rastsvetaeva, R.K., Rozenberg, K.A., Khomyakov, A.P. (2005) Crystal structure of a K analogue of kentbrooksite. Doklady Chemistry: 403: 148-151.
Khomyakov, A.P., Nechelyustov, G.N., Rastsvetaeva, R.K., Rozenberg, K.A. (2008) Andrianovite, Na12(K,Sr,Ce)3Ca6Mn3Zr3NbSi25O73(O,H2O,OH)5-a new potassium-rich mineral of the eudialyte group from Khibiny alkaline massif, Kola Peninsula, Russia. Zapiski RMO (Proceedings of the Russian Mineralogical Society): 137(2): 43-52. [English translation: Geology of Ore Deposits 50,705-712(2008)]

Internet Links for AndrianoviteHide

Localities for AndrianoviteHide

ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Murmanskaya Oblast'
    • Khibiny Massif
      • Koashva Mt
Khomyakov, A.P., Nechelyustov, G.N., Rastsvetaeva, R.K., Rozenberg, K.A. (2008): Andrianovite, Na12(K,Sr,Ce)3Ca6Mn3Zr3NbSi25O73(O,H2O,OH)5-a new potassium-rich mineral of the eudialyte group from Khibiny alkaline massif, Kola Peninsula, Russia. Zapiski RMO (Proceedings of the Russian Mineralogical Society), 137(2), 43-52. [English translation: Geology of Ore Deposits 50,705-712(2008)]
Mineral and/or Locality  
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