Pinnoite
A valid IMA mineral species - grandfathered
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About Pinnoite
Formula:
Mg[B2O(OH)6]
Colour:
Yellow to yellow-green; yellow in transmitted light
Lustre:
Vitreous
Hardness:
3½
Specific Gravity:
2.27
Crystal System:
Tetragonal
Name:
Named in honor of Johann Friedrich Hermann Pinno (16 March 1831, Kleinkamsdorf, Prussia, German Empire - 6 September 1902, Berlin-Charlottenburg, German Empire), Chief Councillor of Mines, Halle, Germany.
Type Locality:
This page provides mineralogical data about Pinnoite.
Unique Identifiers
Mindat ID:
3217
Long-form identifier:
mindat:1:1:3217:5
GUID
(UUID V4):
(UUID V4):
7f70f453-b922-488b-98a1-73b36ed98898
Classification of Pinnoite
Approved, 'Grandfathered' (first described prior to 1959)
First published:
1884
6.BB.05
6 : BORATES
B : Diborates
B : Neso-diborates with double tetrahedra B2O(OH)6; 2(2T)
6 : BORATES
B : Diborates
B : Neso-diborates with double tetrahedra B2O(OH)6; 2(2T)
25.2.3.1
25 : ANHYDROUS BORATES CONTAINING HYDROXYL OR HALOGEN
2 : Diborates
25 : ANHYDROUS BORATES CONTAINING HYDROXYL OR HALOGEN
2 : Diborates
9.2.8
9 : Borates
2 : Borates of Be and Mg
9 : Borates
2 : Borates of Be and Mg
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Pno | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Pinnoite
Vitreous
Transparency:
Translucent
Colour:
Yellow to yellow-green; yellow in transmitted light
Hardness:
3½ on Mohs scale
Fracture:
Irregular/Uneven
Density:
2.27 g/cm3 (Measured) 2.29 g/cm3 (Calculated)
Optical Data of Pinnoite
Type:
Uniaxial (+)
RI values:
nω = 1.565 nε = 1.575
Max Birefringence:
δ = 0.010
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Chemical Properties of Pinnoite
Formula:
Mg[B2O(OH)6]
IMA Formula:
MgB2O(OH)6
Elements listed:
Crystallography of Pinnoite
Crystal System:
Tetragonal
Class (H-M):
4/m - Dipyramidal
Space Group:
P42/m
Cell Parameters:
a = 7.617 Å, c = 8.19 Å
Ratio:
a:c = 1 : 1.075
Unit Cell V:
475.17 ų (Calculated from Unit Cell)
Morphology:
Crystals short prismatic [001], rare. Commonly crystalline, fine-granular to faintly fibrous. Nodules with radiated fibrous structure and a crystalline surface.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0009203 | Pinnoite | Paton F, MacDonald S G G (1957) The crystal structure of pinnoite Acta Crystallographica 10 653-656 | 1957 | Stassfurt, Germany | 0 | 293 | |
0009314 | Pinnoite | Krogh-Moe J (1967) A note on the structure of pinnoite Acta Crystallographica 23 500-501 | 1967 | 0 | 293 | ||
0015585 | Pinnoite | Genkina E A, Malinovskii Y A (1983) Refinement of the structure of pinnoite: Location of hydrogen atoms Soviet Physics Crystallography 28 475-477 | 1983 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
5.39 Å | (100) |
2.309 Å | (70) |
2.045 Å | (50) |
3.61 Å | (40) |
3.14 Å | (40) |
2.252 Å | (35) |
1.905 Å | (30) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
25 : Evaporites (prebiotic) |
Type Occurrence of Pinnoite
General Appearance of Type Material:
Nodules with a faint fibrous internal structure.
Place of Conservation of Type Material:
No designated type material.
Geological Setting of Type Material:
Upper Kainite layers of a salt deposit.
Associated Minerals at Type Locality:
Reference:
Staute, H. (1884) Pinnoit, ein neues Borat von Stassfurt. Berichte der Deutschen Chemischen Gesellschaft: 17: 1584-1586.
Other Language Names for Pinnoite
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
6.BB.10 | Pentahydroborite | CaB2O(OH)6 · 2H2O | Tric. 1 : P1 |
Other Information
Notes:
Soluble in dilute acids. Dissolves in boiling water with the formation of an alkaline solution with a flocculent precipitate which re-dissolves upon cooling of the solution.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
References for Pinnoite
Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Staute, H. (1884) Pinnoit, ein neues Borat von Stassfurt. Berichte der Deutschen Chemischen Gesellschaft: 17: 1584-1586.
Luedecke, O. (1885) Beobachtungen an Stassfurter Vorkommnissen (Pinnoit, Pikromerit, Kainit und Steinsalz). Zeitschrift für Naturwissenschaften, Halle: 58: 645-662.
Boeke, H.E. (1910) Ueber die Borate der Kalisalzlagerstatten. Centralblatt für Mineralogie, Geologie und Paleontologie, Stuttgart: 531-539.
Goldschmidt, V. (1920) Atlas der Krystallformen. 9 volumes, atlas, and text, vol. 6: 155.
Stadler, H.P. (1947) The Cell Dimensions and Space-Group of Pinnoite. Mineralogical Magazine: 28: 26-28.
Palache, C., Berman, H., Frondel, C. (1951) The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged: 334-335.
Paton, F., MacDonald, S.G.G. (1957) The crystal structure of pinnoite. Acta Crystallographica: 10: 653-656.
Krogh-Moe, J. (1967) A note on the structure of pinnoite. Acta Crystallographica: 23: 500-501.
Genkina, E.A., Malinovskii, Y.A. (1983) Refinement of the structure of pinnoite: Location of hydrogen atoms. Soviet Physics - Crystallography (Krystallografiya): 28: 475-477.
Grew, E.S., and Anovitz, L.M. (1996) BORON: Mineralogy, Petrology and Geochemistry, second edition, as revised (2002).
Strunz, H. (1997) Classification of borate minerals. European Journal of Mineralogy: 9: 225-232.
Frost, R.L., Xi, Y. (2014) Vibrational spectroscopy of the borate mineral pinnoite MgB2O(OH)6. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy: 117: 428-433.
Lin, F., Dong, Y., Peng, J., Wang, L., Li, W. (2016). Synthesis and formation mechanism of pinnoite by the phase transition process. Phase Transitions: 89(6): 558-567.
Yu, J., Hong, R., Gao, C., Cheng, A., Zhang, L. (2018) Pinnoite deposit in DaQaidam saline lake, Qaidam Basin, China: hydroclimatic, sedimentologic, and geochemical constraints. Minerals: 8(6): 258.
Internet Links for Pinnoite
mindat.org URL:
https://www.mindat.org/min-3217.html
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Localities for Pinnoite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Argentina | |
| Alonso, R. N. (1999). On the origin of La Puna borates. Acta geológica hispánica, 34(2), 141-166. |
China | |
Kezao Chen (1992): Quaternary Sciences 3(8), 193-202 | |
| Keqin Cai and Ziqiang Qian (1982): Acta Mineralogica Sinica 2(4), 290-295; Shaoxiu Yang (1991): Journal of Lake Sciences 3(1), 1-10; Garrett, D.E. (1998): Borates: Handbook of deposits, processing, properties, and use. Academic Press (San Diego, London), 491 pp.; Qingzhong Wang, Yingkai Xiao, Chonggeng Zhang, Haizhen Wei, and Zhiqi Zhao (2001): Bulletin of Mineralogy, Petrology and Geochemistry 20(4), 344-366; Zheng, M. P., Qi, W., & Yuan, H. R. (2005). Characteristics of salt lake boron deposits and magnesium borate deposits of the Qinghai-Tibet Plateau, China. In Mineral Deposit Research: Meeting the Global Challenge (pp. 1123-1125). Springer Berlin Heidelberg. Yu, J., Hong, R., Gao, C., Cheng, A., Zhang, L. (2018) Pinnoite deposit in DaQaidam saline lake, Qaidam Basin, China: hydroclimatic, sedimentologic, and geochemical constraints. Minerals: 8(6): 258. |
Dapeng Sun (1991): Journal of Mineralogy and Petrology 12(4), 57-65; Shaoxiu Yang (1991): Journal of Lake Sciences 3(1), 1-10; Xiyu Zheng (1994): Journal of Lake Sciences 6(3), 267-275; Garrett, D.E. (1998): Borates: Handbook of deposits, processing, properties, and use. Academic Press (San Diego, London), 491 pp.; Qingzhong Wang, Yingkai Xiao, Chonggeng Zhang, Haizhen Wei, and Zhiqi Zhao (2001): Bulletin of Mineralogy, Petrology and Geochemistry 20(4), 344-366 | |
| Xiyu Zheng and Shengsong Yu (1981): Scientia Geographica Sinica 1(1), 66-76; Mianping Zheng and Wengao Liu (1982): Geological Review 28(3), 263-266; Zheng Xiyu (1984): Chinese Journal of Oceanology and Limnology 2(2), 218-226; Shaoxiu Yang (1991): Journal of Lake Sciences 3(1), 1-10; Xiyu Zheng (1994): Journal of Lake Sciences 6(3), 267-275; Qingzhong Wang, Yingkai Xiao, Chonggeng Zhang, Haizhen Wei, and Zhiqi Zhao (2001): Bulletin of Mineralogy, Petrology and Geochemistry 20(4), 344-366; Xifang Liu and Mianping Zheng (2010): Acta Geologica Sinica 89(11), 1601-1612 |
Xifang Liu and Mianping Zheng (2010): Acta Geologica Sinica 89(11), 1601-1612 | |
| Bingxiao Li (1992): Journal of Lake Sciences 4(1), 48-55 |
Germany | |
| Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 368. |
| Milch, L. (1891): Über ein neues krystallisiertes Borat von Stassfurt.- Z. Kryst. 18, 478-480; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 334-335. |
Luedecke, O. (1891): Über Heintzit, ein neues Borat von Leopoldshall.- Z. Kryst. 18, 481-485; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 334, 368. | |
| Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 334. |
Kazakhstan | |
| Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow |
| World of Stones #1; Evseev, A. A. (1995) Kazaknstan and Middle Asia. A brief Mineralogical Guide. World of Stone 8:24-30; Pekov, I. V. & Abramov, D. V. (1993): Boron deposit of the Inder and its minerals. World of Stones, 1, 23-30. |
Russia | |
| Mazurov, M.P., Grishina, S.N., Istomin, V.E., and Titov, A.T. (2007): Geology of Ore Deposits 49(4), 271-284.; Mazurov et al (2007) Geology of Ore Deposits, 49, 271–284. |
USA | |
| Crowley, J.K. (1996) Mg- and K-bearing borates and associated evaporites at Eagle Borax Spring, Death Valley, California; a spectroscopic exploration. Economic Geology: 91: 622-635. |
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Inder B deposit and salt dome, Inder, Atyrau Region, Kazakhstan