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Adranosite

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About AdranositeHide

Formula:
(NH4)4NaAl2(SO4)4Cl(OH)2
Crystal System:
Tetragonal
Name:
After the Greek name of the ancient fire god Adranos (Latin: Adranus) who,according to legend, lived under Mount Etna before being driven out by Hephaestus (Latin: Vulcan). Adranos was worshipped all over Sicily, but particularly in the town of Adranus, now named Adrano.
The Al analogue of Adranosite-(Fe).

Unique combination of elements. One of a few ammonium-sodium sulfates among acmonidesite, adranosite-(Fe), lecontite, möhnite, and therasiasite.

In the crystal structure there are: (1) NaO4Cl2 tetragonal square bipyramids, that have common Cl in corners; (2) AlO6 octahedra and SO4 tetrahedra that join to form spiral chains parallel to [001].




Classification of AdranositeHide

Approved
Approval Year:
2008
7.BC.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
30.4.5.

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
4 : Miscellaneous

Chemical Properties of AdranositeHide

Formula:
(NH4)4NaAl2(SO4)4Cl(OH)2
Common Impurities:
K

Crystallography of AdranositeHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:
I41/acd
Cell Parameters:
a = 18.118(3) Å, c = 11.320(3) Å
Ratio:
a:c = 1 : 0.625
Unit Cell V:
3,715.92 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.398 (80)
4.530 (86)
3.202 (47)
3.020 (65)
2.980 (100)
2.739 (36)
2.265 (87)
1.902 (44)

Type Occurrence of AdranositeHide

Synonyms of AdranositeHide

Other Language Names for AdranositeHide

German:Adranosit

Common AssociatesHide

Associated Minerals Based on Photo Data:
D'Ansite-(Fe)2 photos of Adranosite associated with D'Ansite-(Fe) on mindat.org.
Therasiaite1 photo of Adranosite associated with Therasiaite on mindat.org.

Related Minerals - Nickel-Strunz GroupingHide

7.BC.Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso.
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10DorallchariteTlFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig.
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10JarositeKFe3+ 3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Natroalunite-2c(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig.
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso.
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet.
7.BC.25ChlorothioniteK2Cu(SO4)Cl2Orth. mmm (2/m 2/m 2/m) : Pnma
7.BC.30EuchlorineKNaCu3(SO4)3OMon.
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm (2/m 2/m 2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet.
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon.
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon.
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.70ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for AdranositeHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Ciriotti, M.E., Fascio, L. & Pasero, M. (2009) Italian Type Minerals. Edizioni Plus, Università di Pisa, Pisa, Italy, 357 pp.
Demartin, F., Gramaccioli, C.M., Campostrini, I. (2010) Adranosite, (NH4)4NaAl2(SO4)Cl(OH)2, a new ammonium sulfate chloride from La Fossa crater, Vulcano, Aeolian Islands, Italy. Canadian Mineralogist, 48, 315-321.

Internet Links for AdranositeHide

Localities for AdranositeHide

ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Germany
 
  • North Rhine-Westphalia
    • Aachen
      • Alsdorf
Witzke, T., de Wit, F., Kolitsch, U. and Blaß, G. (2015): Mineralogy of the Burning Anna I Coal Mine Dump, Alsdorf, Germany. Chapter 7, pp. 203-240, in: Stracher, G. B., Prakash, A. and Sokol, E. V.: Coal and Peat Fires: A Global Perspective, Volume 3: Case Studies - Coal Fires, Elsevier, 786 pp.
Hungary
 
  • Baranya Co.
    • Mecsek Mts
      • Pécs
Szabó, D., Lovász, A., Weiszburg, T., Szakáll, S., Kristály, F. (2015): Ammonioalunite and adranosite-Al. New mineral species from the burning coal dumps of Pécs-Vasas, Hungary. Poster session presented at: 6th Mineral Sciences in the Carpathians Conference; 2015 May 16-19; Veszprém, Hungary.
Italy
 
  • Campania
    • Phlegrean Volcanic Complex
      • Naples Province
        • Phlegrean Fields
          • Pozzuoli
            • Solfatara di Pozzuoli
- Russo, M., Campostrini, I., Demartin, F. (2017): I minerali di origine fumarolica dei Campi Flegrei: Solfatara di Pozzuoli (Napoli) e dintorni. Micro, 15, 122-192.
  • Sicily
    • Messina Province
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
Demartin, F., Gramaccioli, C.M., Campostrini, I. (2010): Adranosite, (NH4)4NaAl2(SO4)Cl(OH)2, a new ammonium sulfate chloride from La Fossa crater, Vulcano, Aeolian Islands, Italy. Canadian Mineralogist, 48, 315-321.
Mineral and/or Locality  
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