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Manitobaite

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About ManitobaiteHide

Flag of Manitoba
Formula:
Na16Mn2+ 25Al8(PO4)30
Colour:
Dark green to brown
Lustre:
Sub-Vitreous, Resinous
Hardness:
5 - 5½
Specific Gravity:
3.621
Crystal System:
Monoclinic
Name:
Named in 2010 by Scott T. Ercit, Kimberley T. Tait, Mark A. Cooper, Yassir Abdu, Neil A. Ball, Alan J. Anderson, Petr ČernÝ, Frank C. Hawthorne for the province where the type locality is.
Alluaudite group.


Classification of ManitobaiteHide

Approved
Approval Year:
2009
First Published:
2010
8.AC.18

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
38.2.10.

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3

Physical Properties of ManitobaiteHide

Sub-Vitreous, Resinous
Transparency:
Translucent
Colour:
Dark green to brown
Streak:
Pale greenish brown
Hardness:
5 - 5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{010}
Fracture:
Irregular/Uneven, Hackly
Density:
3.621(6) g/cm3 (Measured)    3.628 g/cm3 (Calculated)

Optical Data of ManitobaiteHide

Type:
Biaxial (-)
RI values:
nα = 1.682 nβ = 1.691 nγ = 1.697
2V:
Measured: 78° , Calculated: 78°
Birefringence:
0.015
Max Birefringence:
δ = 0.015
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r>v, medium
Optical Extinction:
X^a = 32°, Y // B, Z^c = 20°
Pleochroism:
Strong
Comments:
X = orange brown, Y = green, Z = greenish brown; Y ≥ Z > X

Chemical Properties of ManitobaiteHide

Formula:
Na16Mn2+ 25Al8(PO4)30
IMA Formula:
Na16Mn2+25Al8(PO4)30

Crystallography of ManitobaiteHide

Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Space Group:
Pb
Setting:
Pc
Cell Parameters:
a = 13.451(7) Å, b = 12.5266(7) Å, c = 26.6765(13) Å
β = 101.582(1)°
Ratio:
a:b:c = 1.074 : 1 : 2.13
Unit Cell V:
4,403.34 ų (Calculated from Unit Cell)
Z:
2

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.260 (20)
3.494 (47)
3.078 (27)
2.881 (21)
2.730 (50)
2.715 (100)
2.524 (20)
2.518 (22)

Type Occurrence of ManitobaiteHide

General Appearance of Type Material:
Dark green to brown resinous masses
Place of Conservation of Type Material:
Royal Ontario Museum (M53321)
Geological Setting of Type Material:
Granite pegmatite
Associated Minerals at Type Locality:

Synonyms of ManitobaiteHide

Relationship of Manitobaite to other SpeciesHide

Other Members of this group:
Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon.
Alluaudite-Ca□4Ca4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
Alluaudite-Na□4Na4Mn2+4Fe3+8(PO4)12Mon. 2/m : B2/b
Arseniopleite(Ca,Na)NaMn2+(Mn2+,Mg,Fe2+)2(AsO4)3Mon. 2/m : P2/b
BadaloviteNa2Mg2Fe(AsO4)3Mon. 2/m : B2/b
BradaczekiteNaCu4(AsO4)3Mon. 2/m : B2/b
CalciojohilleriteNaCaMg3(AsO4)3Mon. 2/m : B2/b
CamanchacaiteNaCaMg2[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
CanutiteNaMn3[AsO4][AsO3(OH)]2Mon. 2/m : B2/b
Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
ErikapohliteCu3(Zn,Cu,Mg)4Ca2(AsO4)6·2H2O Mon. 2/m : B2/m
Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3
Ferroalluaudite-NaNaNa4Na4Fe2+4Fe3+8(PO4)12Mon. 2/m : B2/m
FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.
GroatiteNaCaMn2(PO4)(HPO4)2Mon. 2/m : B2/b
HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
Hagendorfite-(Na)(Na)Fe2+Mn2+(PO4)-(Na)(Na)Mon. 2/m : B2/b
HatertiteNa2(Ca,Na)(Fe3+,Cu)2(AsO4)3Mon. 2/m : B2/b
JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
KeyiteCu2+3Zn4Cd2(AsO4)6 · 2H2OMon. 2/m
KhrenoviteNa3Fe3+2(AsO4)3Mon. 2/m : B2/b
Maghagendorfite(□,Na,)(Na,Ca,Fe2+)Mn(Mg,Fe2+,Fe3+)3(PO4)3Mon.
MagnesiocanutiteNaMnMg2[AsO4]2[AsO2(OH)2]Mon. 2/m : B2/b
Magnesiohatertite(Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3Mon. 2/m : B2/b
NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
O'DanieliteNa(Zn,Mg)3H2(AsO4)3Mon. 2/m : B2/b
ParaberzeliiteNaCa2Mg2(AsO4)3Mon. 2/m : B2/b
VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
YazganiteNaFe3+2(Mg,Mn2+)(AsO4)3 · H2OMon. 2/m : B2/b
ZhanghuifeniteNa3Mn4Mg2Al(PO4)6Mon. 2/m
ZincobradaczekiteNaZn2Cu2(AsO4)3Mon. 2/m : B2/b

Related Minerals - Nickel-Strunz GroupingHide

8.AC.WopmayiteCa6Na3□Mn(PO4)3(PO3OH)4 Trig. 3m : R3c
8.AC.05HowardevansiteNaCuFe2(VO4)3Tric. 1 : P1
8.AC.10Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon.
8.AC.10Arseniopleite(Ca,Na)NaMn2+(Mn2+,Mg,Fe2+)2(AsO4)3Mon. 2/m : P2/b
8.AC.10Caryinite(Na,Pb)(Ca,Na)CaMn2+2(AsO4)3Mon. 2/m
8.AC.10Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3
8.AC.10HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
8.AC.10JohilleriteNa(Mg,Zn)3Cu(AsO4)3Mon. 2/m : B2/b
8.AC.10Maghagendorfite(□,Na,)(Na,Ca,Fe2+)Mn(Mg,Fe2+,Fe3+)3(PO4)3Mon.
8.AC.10NickenichiteNa0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3Mon. 2/m : B2/b
8.AC.10VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
8.AC.10FerrohagendorfiteNaCaFe2+Fe2+2(PO4)3Mon.
8.AC.10BradaczekiteNaCu4(AsO4)3Mon. 2/m : B2/b
8.AC.10YazganiteNaFe3+2(Mg,Mn2+)(AsO4)3 · H2OMon. 2/m : B2/b
8.AC.10GroatiteNaCaMn2(PO4)(HPO4)2Mon. 2/m : B2/b
8.AC.15BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m : P2/b
8.AC.15Ferrowyllieite(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15QingheiiteNaMn3+Mg(Al,Fe3+)(PO4)3Mon. 2/m : P21/b
8.AC.15Rosemaryite(Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3Mon. 2/m : P21/b
8.AC.15Wyllieite(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3Mon. 2/m
8.AC.15Ferrorosemaryite◻NaFe2+Fe3+Al(PO4)3Mon.
8.AC.15Qingheiite-(Fe2+)Na2Fe2+MgAl(PO4)3Mon. 2/m : P21/m
8.AC.20MarićiteNaFe2+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
8.AC.25Berzeliite(NaCa2)Mg2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25ManganberzeliiteNaCa2Mn2+2(AsO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25Palenzonaite(Ca,Na)3CaMn2+2(VO4)3Iso. m3m (4/m 3 2/m) : Ia3d
8.AC.25SchäferiteCa2NaMg2(VO4)3Iso.
8.AC.30BrianiteNa2CaMg(PO4)2Mon. 2/m : P21/b
8.AC.35Vitusite-(Ce)Na3(Ce,La,Nd)(PO4)2Orth. mm2 : Pca21
8.AC.40Olgite(Sr,Ba)(Na,Sr,REE)2Na(PO4)2Trig. 3m (3 2/m) : P3m1
8.AC.40Bario-olgite(Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · Trig. 3 : P3
8.AC.45StrontiowhitlockiteSr9Mg(PO4)6(HPO4)Trig. 3m : R3c
8.AC.45WhitlockiteCa9Mg(PO4)6(HPO4)Trig. 3m : R3c
8.AC.45MerrilliteCa9NaMg(PO4)7Trig. 3m : R3m
8.AC.45TuiteCa3(PO4)2Trig. 3m (3 2/m) : R3m
8.AC.45FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m : R3c
8.AC.50Chladniite{Ca}{Na8}{Ca4Na4}{(Mg,Fe2+)43}(PO4)36Trig. 3 : R3
8.AC.50Fillowite{Mn2+}{Na8}{Ca4Na4}{(Mn2+,Fe2+)43}(PO4)36Trig. 3 : R3
8.AC.50JohnsomervilleiteNa10Ca6Mg18Fe25(PO4)36Trig.
8.AC.50Galileiite{Fe2+}{Na8}{Fe2+4Na4}{Fe2+43}(PO4)36Trig. 3 : R3
8.AC.50Stornesite-(Y){(Y, Ca)}{Na62}{(Ca,Na)8}{(Mg,Fe2+)43}(PO4)36Trig. 3 : R3
8.AC.50XenophylliteNa4Fe2+7(PO4)6Tric. 1 : P1
8.AC.55HarrisoniteCa(Fe2+,Mg)6(PO4)2(SiO4)2Trig.
8.AC.60KosnariteKZr2(PO4)3Trig. 3m (3 2/m) : R3c
8.AC.65Panethite(Na,Ca)2(Mg,Fe2+)2(PO4)2Mon. 2/m : P21/b
8.AC.70StanfielditeCa4Mg5(PO4)6Mon.
8.AC.75RonneburgiteK2MnV4O12Mon. 2/m
8.AC.80Tillmannsite(Ag3Hg)(VO4,AsO4)Tet. 4 : I4
8.AC.85FilatoviteK(Al,Zn)2(As,Si)2O8Mon. 2/m

Fluorescence of ManitobaiteHide

Not fluorescent in UV

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for ManitobaiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Williams, P.A., Hatert, F., Pasero, M. (2009) New minerals approved in 2009. in International Mineralogical Association, 1-34.
Ercit, S.T., Tait, K.T., Cooper, M.A., Abdu, Y., Ball, N.A., Anderson, A.J., Černý, P., Hawthorne, F.C. (2010) Manitobaite, Na16Mn2+25Al8(PO4)30, a new phosphate mineral species from Cross Lake, Manitoba, Canada. Canadian Mineralogist: 48: 1455-1463.
Tait, K.T., Ercit, S.T., Abdu, Y., Černý, P., Hawthorne, F.C. (2011) The crystal structure and crystal chemistry of manitobaite, ideally Na16□Mn2+25Al8(PO4)30, from Cross Lake, Manitoba, Canada. Canadian Mineralogist: 49: 1221-1242.
Gatta, G.D., Cámara, F., Tait, K.T., Belakovskiy, D. (2012) New mineral names. American Mineralogist: 97: 2064-2072.

Internet Links for ManitobaiteHide

Localities for ManitobaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Manitoba
    • Cross Lake
      • North Group
Ercit, T.S. et al. (2010) Manitobaite, a new phosphate species from Cross Lake, Manitobaite, Canada,Canadian Mineralogist 48, 1455-1463
Mineral and/or Locality  
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