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Tiragalloite

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About TiragalloiteHide

04940100016076018928238.jpg
Paolo Onofrio Tiragallo
Formula:
Mn2+4As5+Si3O12(OH)
Colour:
Orange, brownish orange
Lustre:
Sub-Adamantine
Crystal System:
Monoclinic
Name:
Named after Paolo Onofrio Tiragallo (1905, Carro, La Spezia, Liguria, Italy - 1987), distinguished amateur mineralogist. Conservator and curator of the mineralogical collection of the University of Genoa.
Tiragalloite belongs to a rare class of compounds with As atoms replacing Si atoms in silicate anions, the so-called arsenosilicates (analoguous to the more common alumosilicates and borosilicates, in which Si atoms are replaced by Al atoms and B atoms, respectively). It contains isolated chains consisting of one (ASO4) tetrahedron and three (SiO4) tetrahedra, which are linked by sharing corners. One oxygen atom is protonated, resulting in the anion formula (HAsSi3O13)8-. The tetrahedral sites in the anion are ordered in that the As atoms are only found at the end of the chains, and there is exactly one As atom in each anion.


Classification of TiragalloiteHide

Approved
Approval year:
1979
9.BJ.25

9 : SILICATES (Germanates)
B : Sorosilicates
J : Sorosilicates with Si3O10, Si4O11, etc. anions; cations in octahedral [6] and greater coordination
57.2.1.1

57 : SOROSILICATES Si3O10 Groups and Larger Noncyclic Groups
2 : Insular Si3O10 and Larger Noncyclic Groups with [Si4O13] groups
17.7.7

17 : Silicates Containing other Anions
7 : Silicates with vanadate, arsenate or antimonate

Physical Properties of TiragalloiteHide

Sub-Adamantine
Transparency:
Transparent, Translucent
Colour:
Orange, brownish orange
Cleavage:
Distinct/Good
Good on {100}.
Parting:
Distinct parting, normal to elongation.

Optical Data of TiragalloiteHide

Type:
Biaxial (+)
RI values:
nα = 1.745 nβ = 1.751 nγ = 1.760
2V:
Measured: 38° to 46°, Calculated: 80°
Max Birefringence:
δ = 0.015
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
strong

Chemical Properties of TiragalloiteHide

Formula:
Mn2+4As5+Si3O12(OH)
Common Impurities:
Ti,Al,V,Fe,Ca,Na,K

Crystallography of TiragalloiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 6.66(1) Å, b = 19.92(2) Å, c = 7.67(1) Å
β = 95.71(1)°
Ratio:
a:b:c = 0.334 : 1 : 0.385
Unit Cell V:
1,012.51 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space group P21/n. Nagashima et al. (2010) give a = 6.6783(1), b = 19.9075(3), c = 7.5750(1) Å, β = 95.475(1)°. The lower c value in the latter is also confirmed by SXRD studies of samples from Austria (Uwe Kolitsch, unpubl. data).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0009690TiragalloiteGramaccioli C M, Pilati T, Liborio G (1979) Structure of a manganese(II) arsenatotrisilicate, Mn4[AsSi3O12(OH)]: The presence of a new tetrapolyphosphate-like anion Acta Crystallographica B35 2287-22911979Molinello, near Chiavari, Liguria,0293
0019902TiragalloiteNagashima M, Armbruster T (2010) Ardennite, tiragalloite and medaite: structural control of (As5+,V5+,Si4+)O4 tetrahedra in silicates Mineralogical Magazine 74 55-712010Gambatesa mine, Val Graveglia, Liguria, Italy0293
CIF Raw Data - click here to close

Epitaxial Relationships of TiragalloiteHide

Epitaxial Minerals:
RhodoniteCaMn3Mn[Si5O15]
Epitaxy Comments:
(010)[001]tir // (010)[100]rho (Roth & Meisser, 2011)

Type Occurrence of TiragalloiteHide

Synonyms of TiragalloiteHide

Other Language Names for TiragalloiteHide

Common AssociatesHide

ArseniopleiteNaCaMnMn2(AsO4)3
RhodoniteCaMn3Mn[Si5O15]
Associated Minerals Based on Photo Data:
5 photos of Tiragalloite associated with RhodoniteCaMn3Mn[Si5O15]

Related Minerals - Nickel-Strunz GroupingHide

9.BJ.ArsenmedaiteMn2+6 As5+Si5O18(OH)Mon. 2/m
9.BJ.05OrientiteCa8Mn3+10(SiO4)3(Si3O10)3(OH)10 · 4H2O Orth.
9.BJ.10RosenhahniteHCa3[Si3O9(OH)]Tric.
9.BJ.15TrabzoniteCa4(Si3O9)(OH)2Orth. mm2 : Ama2
9.BJ.20Thalénite-(Y)Y3Si3O10FMon.
9.BJ.30MedaiteMn2+6V5+Si5O18(OH)Mon.
9.BJ.35RuiziteCa2Mn3+2[Si4O11(OH)2](OH)2 · 2H2OMon. 2
9.BJ.40Ardennite-(As)Mn2+4Al4(AlMg)(AsO4)(SiO4)2(Si3O10)(OH)6Orth. mmm (2/m 2/m 2/m)
9.BJ.40Ardennite-(V)Mn2+4Al4(AlMg)(VO4)(SiO4)2(Si3O10)(OH)6Orth. mmm (2/m 2/m 2/m) : Pmmn
9.BJ.45KilchoaniteCa6(SiO4)(Si3O10)Orth.
9.BJ.50KornerupineMg3Al6(Si,Al,B)5O21(OH)Orth. mmm (2/m 2/m 2/m)
9.BJ.50Prismatine(◻,Fe,Mg)(Mg,Al,Fe)5Al4Si2(Si,Al)2(B,Si,Al)(O,OH,F)22Orth.
9.BJ.55ZunyiteAl13Si5O20(OH,F)18ClIso. 4 3m : F4 3m
9.BJ.60HubeiteCa2Mn2+Fe3+Si4O12(OH) · 2H2OTric.
9.BJ.65Cassagnaite(Ca,Mn2+)4(Fe3+,Mn3+,Al)4(V3+,Mg,Al)2(Si3O10)(SiO4)2(OH,O)8Orth. mmm (2/m 2/m 2/m) : Cmcm

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

17.7.1SuzukiiteBaVSi2O7Orth.
17.7.2FranciscaniteMn2+6(V5+,◻)2(SiO4)2(O,OH)6Hex.
17.7.3Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
17.7.4Ardennite-(As)Mn2+4Al4(AlMg)(AsO4)(SiO4)2(Si3O10)(OH)6Orth. mmm (2/m 2/m 2/m)
17.7.5MedaiteMn2+6V5+Si5O18(OH)Mon.
17.7.6JohninnesiteNa2Mn2+9Mg7(OH)8[AsO4]2[Si6O17]2Tric.
17.7.8DixeniteCuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6Trig.
17.7.9AsbecasiteCa3(Ti,Sn4+)Be2(AsO3)6(SiO4)2Trig. 3m : P3c1
17.7.10McgoverniteMn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21Trig. 3m (3 2/m)
17.7.11KraissliteZn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16Orth. 2 2 2 : C2 2 21
17.7.12SchalleriteMn2+16As3Si12O36(OH)17Trig. 3m : P3m1
17.7.13Nelenite(Mn,Fe)16(Si12O30)(OH)14[As3+3O6(OH)3]Mon.
17.7.14KoliciteMn2+7Zn4(AsO4)2(SiO4)2(OH)8Orth. mmm (2/m 2/m 2/m) : Cmca
17.7.15YeatmaniteZn6Mn2+9Sb5+2(SiO4)4O12Tric.
17.7.16WelshiteCa4Mg9Sb3O4[Si6Be3AlFe2O36]Tric. 1 : P1
17.7.17Katoptrite(Mn2+,Mg)13(Al,Fe3+)4Sb5+2(SiO4)2O20Mon. 2/m : B2/m
17.7.18ParweliteMn10Sb2As2Si2O24Mon. m : Bb
17.7.19LångbaniteMn2+4Mn3+9Sb5+O16(SiO4)2Trig. 3m : P3m1
17.7.20ChapmaniteFe3+2Sb3+(Si2O5)O3(OH)Mon. m : Bm
17.7.21Cervandonite-(Ce)(Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH)Trig. 3m : R3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for TiragalloiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Rendiconti Società Italiana di Mineralogia e Petrologia (1979) 35: 145-149.
Gramaccioli, C.M., Griffin, W.L., Mottana, A. (1980) Tiragalloite, Mn4[AsSi3O12(OH)], a new mineral and the first example of arsenatotrisilicate. American Mineralogist: 65: 947-952.
Gramaccioli, C.M., Pilati, T., Liborio, G. (1979) Structure of manganese(II) arsenatotrisilicate, Mn4[AsSi3O12(OH)]: the presence of a new tetrapolyphosphate-like anion. Acta Crystallographica: B35: 2287-2291.
Nagashima, M., Armbruster, T. (2010) Ardennite, tiragalloite and medaite: structural control of (As5+,V5+,Si4+)O4 tetrahedra in silicates. Mineralogical Magazine: 74: 55-71.

Internet Links for TiragalloiteHide

Localities for TiragalloiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Austria
 
  • Tyrol
    • Innsbruck-Land District
      • Navis
Kolitsch, U., Schachinger, T., Auer, C. (2019): 2113) Akatoreit(?), Albit, Ardennit-(As), Ardennit-(V), „Ardennit-(Si)“, Baryt, Brandtit(?) (oder unbenanntes Ca2Mn(AsO4)2?), Coelestin, Fluorapatit, Fluorcalcioroméit, Frankdicksonit(?), Friedelit, Ganophyllit(?), Hämatit, Hausmannit, Hollandit, Jacobsit, Klinochlor, Kutnohorit, Manganberzeliit, Manganiandrosit-(La)-Manganiakasakait-(La)-Mischkristalle, Muskovit, Opal(?), Pennantit, Piemontit(?), Pyrobelonit, Pyrophanit, Quarz, Rhodochrosit, Rhodonit, Sarkinit, Schallerit, Spessartin, Svabit, Tephroit, Tilasit und Tiragalloit vom Navisbach, Navistal, Nordtirol. Pp. 251-260 in Walter, F. et al. (2019): Neue Mineralfunde aus Österreich LXVIII. Carinthia II, 209./129., 237-362.
BRANDSTÄTTER, F., GRILL, J., NIEDERMAYR, G. & WALTER, F. (2015): 1927) Bementit, Bixbyit, Kutnohorit, Manganberzeliit, Tilasit, Tiragalloit, Todorokit und andere Mineralien von Navis, Tirol. Pp. 232-234 in NIEDERMAYR, G. et al. (2015): Neue Mineralfunde aus Österreich LIX. Carinthia II, 205./125., 207-280.
    • Lienz District
      • Kals am Großglockner
        • Kals valley
Abrecht, J. (1990) An As-rich manganiferous mineral assemblage from the Ködnitz Valley (Eastern Alps, Austria): Geology, mineralogy, genetic considerations, and implications for metamorphic Mn deposits. Neues Jahrbuch für Mineralogie, Monatshefte 1990, 363-375.
Italy
 
  • Aosta Valley
    • Saint-Marcel
Cenki-Tok, B. & Chopin, C. (2006): Coexisting calderite and spessartine garnets in eclogite-facies metacherts of the Western Alps. Mineralogy and Petrology, 88, 47-68.
  • Liguria
    • Genoa
      • Ne
Redazionale (2005): Sistematica ligure: resoconto 2005. Notiziario di Mineralogia del Ferrania Club, 19 , 3-5.
[Rend.Soc.It.Min.Petrol.(1979) 35, 145-149; MinRec 32:355]
        • Reppia
          • Monte Copello
Rivista Mineralogica Italiana, (4), 131
    • La Spezia Province
      • Borghetto di Vara
Analyses of Anthony Kampf of Natural History museum of Los Angeles - U.S.A.; Balestra, C., Castellaro, F., Kampf, A.R., Vajda, E., and Esposito, M. (2020) La miniera di Cerchiara, Borghetto di Vara, Levante Ligure: recenti identificazioni e stato dell’arte. Micro, 18, 2-29 (in Italian).
      • Maissana
Analyses of Anthony Kampf of Natural History museum of Los Angeles - U.S.A.
  • Lombardy
    • Sondrio Province
      • Lanzada
Callegari, A., Sciesa, E., Bedognè, F. (1992) Primo ritrovamento di tiragalloite in Valmalenco (Sondrio, Italia Settentrionale). Il Naturalista Valtellinese - Atti Mus. civ. Stor. nat. Morbegno, 3, 3-9. Bedognè, F., Montrasio, A., Sciesa, E. (1993) I minerali della provincia di Sondrio: Valmalenco. Bettini, Sondrio, 275 pp. Bedognè, F., Montrasio, A., Sciesa, E. (2006) I minerali della media-alta Valtellina, delle Orobie valtellinesi e della Val Poschiavo. Aggiornamenti sulle altre località della provincia di Sondrio. Bettini, Sondrio, 255 pp. Bedognè, F. (2011) Microminerali della Valmalenco. Nuove segnalazioni e aggiornamenti. Riv. Mineral. It., 35, 1, 40-45.; Oberti R, Boiocchi M, Hawthorne F C, Ciriotti M E, Revheim O, Bracco R (2018) Clino-suenoite, a newly approved magnesium-iron-manganese amphibole from Valmalenco, Sondrio, Italy. Mineralogical Magazine 82, 189-198; Callegari, A. M., Boiocchi, M., Zema, M., Tarantino, S. C. (2020): Structure refinement and new crystal-chemical data for tiragalloite (Mn2+3.86Ca0.10)Σ3.96(As5+0.85V5+0.02Si0.19)Σ1.06Si3O12(OH) from the Scerscen glacier, Val Malenco, Italy. Periodico di Mineralogia 89, 77-87.
Lapis, 19 (10), 15-21+86.
  • Piedmont
    • Cuneo Province
      • Canosio
        • Vallone della Valletta
Bracco R. (2014) Sempre novità "estere". Segnalazioni in breve. Prie, 10, 48; Cámara, F., Bittarello, E., Ciriotti, M.E., Nestola, F., Radica, F., Marchesini, M. (2015) Arsenic-bearing new mineral species from Valletta mine, Maira Valley, Piedmont, Italy: II. Braccoite, NaMn2+5[Si5AsO17(OH)](OH), description and crystal structure. Mineralogical Magazine, 79, 171-189; Kampf, A.R., Cámara, F., Ciriotti, M.E., Nash, B.P., Balestra, C., Chiappino, L. (2016): Castellaroite, Mn2+3(AsO4)2⋅4.5H2O, a new mineral from Italy related to metaswitzerite. European Journal of Mineralogy, 28, 687-696; Cámara, F., Bittarello, E., Ciriotti, M.E., Nestola, F., Radica, F., Massimi, F., Balestra, C., Bracco, R. (2017a) As-bearing new mineral species from Valletta mine, Maira Valley, Piedmont, Italy: III. Canosioite, Ba2Fe3+(AsO4)2(OH), description and crystal structure. Mineralogical Magazine, 81, 305–317.
    • Metropolitan City of Turin
      • Salbertrand
Piccoli, G.C., Maletto, G., Bosio, P., Lombardo, B. (2007): Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" Alba, Ed., Alba (Cuneo) 607 pp.
Piccoli, G.C., Maletto, G., Bosio, P., Lombardo, B. (2007). Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" Alba, Ed., Alba (Cuneo) 607 pp.
Japan
 
  • Kagoshima Prefecture
    • Oshima District
      • Yamato village
Fujiwara et al. (2005) Kobutsu-Gakkai Koen-Yoshi, 149; Nakao et al. (2005): Annual Meeting of the Mineral. Soc. of Japan, 129.
Switzerland
 
  • Grisons
    • Viamala Region
      • Ferrera
        • Ausserferrera
Brugger, J., Krivovichev, S., Meisser, N., Ansermet, S., and Armbruster, T. (2006) Scheuchzerite, Na(Mn,Mg)9[VSi9O28(OH)](OH)3, a new single-chain silicate. American Mineralogist: 91: 937-943.
      • Rheinwald
        • Splügen
Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): "Mineralienlexikon der Schweiz", Wepf (Basel), p. 404.; Roth, P. & Meisser, N. (2011): I minerali dell'Alpe Tanatz. Passo dello Spluga (Grigioni, Svizzera). Rivista Mineralogica Italiana, 2/2011, 90-99; Roth, P. (2011): Epitassia di tiragalloite su rodonite, Alpe Tanatz, Passo dello Spluga (Grigioni, Svizzera). Rivista Mineralogica Italiana, 2/2011, 100-103.
 
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