Zabuyelite
A valid IMA mineral species
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About Zabuyelite
Satellite photo showing Lake Zabuye and other lakes
Chabyer Caka, Zhongba Co., Xigazê Prefecture, Tibet, China
Chabyer Caka, Zhongba Co., Xigazê Prefecture, Tibet, China
Formula:
Li2CO3
Colour:
Colourless
Lustre:
Sub-Vitreous
Hardness:
3
Specific Gravity:
2.09
Crystal System:
Monoclinic
Name:
Named in 1987 by Mianping Zheng and Wengao Liu for the type locality, the Zhabuye Salt Lake, Nagri, Tibet, China.
Has been found as very tiny microscopic colorless inclusions in microscopic fluid-bearing inclusions in spodumene.
Unique Identifiers
Mindat ID:
4380
Long-form identifier:
mindat:1:1:4380:5
GUID
(UUID V4):
(UUID V4):
b392a76f-73e3-4a64-be43-15712bf5b699
IMA Classification of Zabuyelite
Classification of Zabuyelite
5.AA.05
5 : CARBONATES (NITRATES)
A : Carbonates without additional anions, without H2O
A : Alkali carbonates
5 : CARBONATES (NITRATES)
A : Carbonates without additional anions, without H2O
A : Alkali carbonates
14.1.6.2
14 : ANHYDROUS NORMAL CARBONATES
1 : A(XO3)
14 : ANHYDROUS NORMAL CARBONATES
1 : A(XO3)
11.1.1
11 : Carbonates
1 : Carbonates of the alkali metals and ammonium
11 : Carbonates
1 : Carbonates of the alkali metals and ammonium
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Zab | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Zabuyelite
Sub-Vitreous
Transparency:
Transparent
Colour:
Colourless
Streak:
White
Hardness:
3 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
Perfect {100} and moderate {011}.
Perfect {100} and moderate {011}.
Density:
2.09(1) g/cm3 (Measured) 2.096 g/cm3 (Calculated)
Comment:
Zemann (1957)
Optical Data of Zabuyelite
Type:
Biaxial (-)
RI values:
nα = 1.429 nβ = 1.567 nγ = 1.574
2V:
Measured: 25° , Calculated: 22°
Max Birefringence:
δ = 0.146
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
none
Optical Extinction:
Y = b, Z ∧ c = 10°.
Chemistry of Zabuyelite
Mindat Formula:
Li2CO3
Elements listed:
Crystallography of Zabuyelite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 8.361(1) Å, b = 4.976(2) Å, c = 6.193(3) Å
β = 114.69(3)°
β = 114.69(3)°
Ratio:
a:b:c = 1.68 : 1 : 1.245
Unit Cell V:
234.10 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Pyramidal-terminated prismatic crystals.
Twinning:
(100)
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0010813 | Zabuyelite | Effenberger H, Zemann J (1979) Verfeinerung der kristallstruktur des lithiumkarbonates, Li2CO3 Zeitschrift fur Kristallographie 150 133-138 |  | 1979 | 0 | 293 | |
| 0013246 | Zabuyelite | Idemoto Y, Richardson J W, Koura N, Kohara S, Loong C K (1998) Crystal structure of (LixK1-x)2CO3 (x = 0,0.43,0.5,0.62,1) by neutron powder diffraction analysis Journal of Physics and Chemistry of Solids 59 363-376 | 1998 | synthetic | 0 | 293 | |
| 0013247 | Zabuyelite | Idemoto Y, Richardson J W, Koura N, Kohara S, Loong C K (1998) Crystal structure of (LixK1-x)2CO3 (x = 0,0.43,0.5,0.62,1) by neutron powder diffraction analysis Journal of Physics and Chemistry of Solids 59 363-376 | 1998 | synthetic | 0 | 293 | |
| 0013248 | Zabuyelite | Idemoto Y, Richardson J W, Koura N, Kohara S, Loong C K (1998) Crystal structure of (LixK1-x)2CO3 (x = 0,0.43,0.5,0.62,1) by neutron powder diffraction analysis Journal of Physics and Chemistry of Solids 59 363-376 | 1998 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.164 Å | (85) |
| 3.797 Å | (19) |
| 3.029 Å | (25) |
| 2.918 Å | (80) |
| 2.812 Å | (100) |
| 2.627 Å | (30) |
| 2.488 Å | (18) |
| 2.431 Å | (40) |
| 2.276 Å | (20) |
| 2.256 Å | (12) |
| 2.116 Å | (4) |
| 2.081 Å | (7) |
| 2.012 Å | (2) |
| 1.910 Å | (2) |
| 1.893 Å | (2) |
| 1.867 Å | (17) |
| 1.8205 Å | (1) |
| 1.8121 Å | (4) |
| 1.6208 Å | (4) |
| 1.5959 Å | (7) |
| 1.5858 Å | (2) |
| 1.5804 Å | (4) |
| 1.5723 Å | (4) |
| 1.5652 Å | (8) |
| 1.5469 Å | (10) |
Comments:
Synthetic material. Zemann, J. (1957) Die Kristallstruktur von Li2CO3. Acta Crystallographica, v. 10, p. 664-666. ICDD 9-359
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Zabuyelite
General Appearance of Type Material:
Crystals 1.5 to 20 µm long embedded in halite in rock-salt layers, and as doubly terminated crystals in precipitates. Typically 0.1 to 0.5 mm long, 0.03 to 0.15 mm wide, and 0.02 to 0.5 mm thick; crystals up to 1.2 mm long have been observed.
Place of Conservation of Type Material:
National Museum for Geology, Beijing, China, number M09542.
Geological Setting of Type Material:
Periphery of a Li-rich salt lake.
Associated Minerals at Type Locality:
Synonyms of Zabuyelite
Other Language Names for Zabuyelite
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 5.AA.10 | Natrite | Na2CO3 |
| 5.AA.10 | Gregoryite | (Na2,K2,Ca)CO3 |
| 5.AA.15 | Nahcolite | NaHCO3 |
| 5.AA.20 | Kalicinite | KHCO3 |
| 5.AA.25 | Teschemacherite | (NH4)HCO3 |
| 5.AA.30 | Wegscheiderite | Na5H3(CO3)4 |
Fluorescence of Zabuyelite
Not fluorescent.
Other Information
Notes:
Slightly soluble in water, reacts vigorously with dilute HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Zabuyelite
mindat.org URL:
https://www.mindat.org/min-4380.html
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Please feel free to link to this page.
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References for Zabuyelite
Reference List:
Localities for Zabuyelite
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Brazil | |
| Thomas et al. (2011) |
Canada | |
| 153-155. +3 other references |
China | |
| Li et al. (2009, December) |
| Qian Wu et al. (2013) |
| Mianping Zheng and Wengao Liu (1987) +2 other references |
Denmark | |
| Thomas et al. (2011) |
Mozambique | |
| Thomas et al. (2010) |
Portugal | |
| Lima et al. (2003) |
USA | |
| Anderson et al. (1994) |
Zimbabwe | |
| Anderson et al. (2001) |
| Anderson et al. (2001) |
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Tanco Mine, Bernic Lake, Lac-du-Bonnet area, Manitoba, Canada