Balićžunićite
A valid IMA mineral species
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Formula:
Bi2O(SO4)2
Colour:
colourless, white, pale brown
Lustre:
Vitreous
Specific Gravity:
5.911 (Calculated)
Crystal System:
Triclinic
Name:
Honours Tonci Balić-Žunić (born 1952), Professor of Mineralogy at the Natural History Museum of the University of Copenhagen. He made important contributions in crystal-structure determination from single-crystal and powder techniques and the theoretical crystal-chemistry of minerals. He discovered/codiscovered several volcanic sublimates including kudriavite, mutnovskyite, eldfellite, heklaite, jakobssonite, leonardsenite and oskarssonite.
Known as a synthetic phase (balićžunićite corresponds to the low-temperature stable form of Bi2O(SO4)2, known as alpha form). Chemically the most simple Bi sulfate mineral known; similar to leguernite and Unnamed (Bi Oxysulphate). The only other known purely Bi sulfates, hydrous/hydrated, are cannonite, riomarinaite and tavagnascoite.
Crystal structure details: (1) nearly planar [Bi5O3]9+ clusters with nearly regular trapezoidal shape; (2) O atoms within the clusters located at the trigonal holes of the Bi5 trapezoids; (3) trapezoidal group connected along [100] via sulfate groups -> infinite [Bi5O3(SO4)5]– columns.
Crystal structure details: (1) nearly planar [Bi5O3]9+ clusters with nearly regular trapezoidal shape; (2) O atoms within the clusters located at the trigonal holes of the Bi5 trapezoids; (3) trapezoidal group connected along [100] via sulfate groups -> infinite [Bi5O3(SO4)5]– columns.
Unique Identifiers
Mindat ID:
43864
Long-form identifier:
mindat:1:1:43864:3
GUID
(UUID V4):
(UUID V4):
a06938f2-7e26-408a-a9ff-8853a2179754
IMA Classification of Balićžunićite
Approved
Approval year:
2013
First published:
2014
Classification of Balićžunićite
7.A0.
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
A : Sulfates (selenates, etc.) without additional anions, without H2O
0 :
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
A : Sulfates (selenates, etc.) without additional anions, without H2O
0 :
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Bžć | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Balićžunićite
Vitreous
Transparency:
Transparent
Colour:
colourless, white, pale brown
Streak:
White
Comment:
not measured
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
not observed
Fracture:
None observed
Density:
5.911 g/cm3 (Calculated)
Comment:
not measured
Chemistry of Balićžunićite
Mindat Formula:
Bi2O(SO4)2
Elements listed:
Crystallography of Balićžunićite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 6.7386(3) Å, b = 11.1844(5) Å, c = 14.1754(7) Å
α = 80.082(2)°, β = 88.462(2)°, γ = 89.517(2)°
α = 80.082(2)°, β = 88.462(2)°, γ = 89.517(2)°
Ratio:
a:b:c = 0.602 : 1 : 1.267
Unit Cell V:
1052.01 ų
Z:
6
Morphology:
Prismatic and elongated crystals (∼50 μm across and up to 200 μm long).
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
5.749 Å | (29) |
5.562 Å | (49) |
5.433 Å | (46) |
3.489 Å | (100) |
3.409 Å | (78) |
3.366 Å | (74) |
3.146 Å | (91) |
3.057 Å | (28) |
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
45a : [Sulfates, arsenates, selenates, antimonates] |
Type Occurrence of Balićžunićite
General Appearance of Type Material:
elongated (along [100]) prisms, ca. ~50 x max. 200 μm
Place of Conservation of Type Material:
Type material is deposited in the collections of the C.L. Garavelli Museum, Dipartimento di Scienze della Terra e Geoambientali, Università degli studi di bari Aldo Moro, Italy, sample number 17/nm
Geological Setting of Type Material:
high-temperature (600oC) fumarole (sublimate)
Associated Minerals at Type Locality:
Reference:
Pinto, D., Garavelli, A., Mitolo, D. (2014) Balićžunićite, Bi2O(SO4)2, a new fumarole mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy. Mineralogical Magazine: 78: 1043-1055.
Synonyms of Balićžunićite
Related Minerals - Strunz-mindat Grouping
7.A0. | Leguernite | Bi38O42(SO4)15 |
7.A0. | Zincomenite | ZnSeO3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Balićžunićite
mindat.org URL:
https://www.mindat.org/min-43864.html
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External Links:
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References for Balićžunićite
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No 16. Mineralogical Magazine, 77 (6) 2695-2709 doi:10.1180/minmag.2013.077.6.01
Pinto, D., Garavelli, A., Mitolo, D. (2014) Balićžunićite, Bi2O(SO4)2, a new fumarole mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy. Mineralogical Magazine, 78 (4) 1043-1055 doi:10.1180/minmag.2014.078.4.15
Localities for Balićžunićite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Italy (TL) | |
| Williams et al. (2013) +1 other reference |