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Zincovoltaite

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Formula:
K2Zn5Fe3+3Al(SO4)12 · 18H2O
Colour:
Green-black, oil-green
Lustre:
Resinous, Greasy
Hardness:
3
Specific Gravity:
2.765
Crystal System:
Isometric
Member of:
Name:
Named as the zincian analogue of Voltaite.
Hide all sections | Show all sections

Classification of ZincovoltaiteHide

Approved
Approval Year:
1985
7.CC.25

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
29.9.1.2

29 : HYDRATED ACID AND NORMAL SULFATES
9 : Miscellaneous
25.11.29

25 : Sulphates
11 : Sulphates of Fe and other metals

Physical Properties of ZincovoltaiteHide

Resinous, Greasy
Transparency:
Transparent, Translucent
Colour:
Green-black, oil-green
Streak:
Grey-green
Hardness:
Tenacity:
Brittle
Fracture:
Conchoidal
Density:
2.765 g/cm3 (Measured)    2.767 g/cm3 (Calculated)

Optical Data of ZincovoltaiteHide

Type:
Isotropic
RI values:
n = 1.605(3)
Max Birefringence:
δ = 0.000 - Isotropic minerals have no birefringence
Surface Relief:
Moderate
Comments:
Anomalously uniaxial

Chemical Properties of ZincovoltaiteHide

Formula:
K2Zn5Fe3+3Al(SO4)12 · 18H2O

Crystallography of ZincovoltaiteHide

Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Fd3c
Cell Parameters:
a = 27.18(1) Å
Unit Cell V:
20,079.29 ų (Calculated from Unit Cell)
Z:
16

Type Occurrence of ZincovoltaiteHide

Place of Conservation of Type Material:
Geological Museum, Ministry of Geology, Beijing, China
Geological Setting of Type Material:
Oxidation zone Fe-Pb-Zn sulfide deposit in arid climate.

Synonyms of ZincovoltaiteHide

Other Language Names for ZincovoltaiteHide

Relationship of Zincovoltaite to other SpeciesHide

Member of:
Other Members of this group:
Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
MagnesiovoltaiteK2Mg5Fe3+3Al(SO4)12·18H2OIso. m3m (4/m 3 2/m) : Fd3c
PertlikiteK2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2OTet. 4/mmm (4/m 2/m 2/m) : I41/acd
VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c

Related Minerals - Nickel-Strunz GroupingHide

7.CC.AndychristyitePbCu2+Te6+O5(H2O)Tric. 1 : P1
7.CC.05KrausiteKFe(SO4)2 · H2OMon. 2/m : P21/m
7.CC.10TamarugiteNaAl(SO4)2 · 6H2OMon. 2/m
7.CC.15KaliniteKAl(SO4)2 · 11H2O Not confirmedMon. 2/m : B2/b
7.CC.15MendoziteNaAl(SO4)2 · 11H2OMon. 2/m
7.CC.20Lonecreekite(NH4)Fe3+(SO4)2 · 12H2OIso.
7.CC.20Alum-(K)KAl(SO4)2 · 12H2OIso. m3 (2/m 3)
7.CC.20Alum-(Na)NaAl(SO4)2 · 12H2O
7.CC.20Tschermigite(NH4)Al(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20LanmuchangiteTl+Al(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.25VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.25PertlikiteK2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2OTet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.CC.25Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.30KröhnkiteNa2Cu(SO4)2 · 2H2OMon. 2/m : P21/b
7.CC.35FerrinatriteNa3Fe(SO4)3 · 3H2OTrig. 3 : P3
7.CC.40GoldichiteKFe(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.45LöweiteNa12Mg7(SO4)13 · 15H2OTrig.
7.CC.50BlöditeNa2Mg(SO4)2 · 4H2OMon. 2/m
7.CC.50NickelblöditeNa2(Ni,Mg)(SO4)2 · 4H2O
7.CC.50ChangoiteNa2Zn(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.50ZincblöditeNa2Zn(SO4)2 · 4H2O
7.CC.55LeoniteK2Mg(SO4)2 · 4H2OMon. 2/m
7.CC.55MereiteriteK2Fe(SO4)2 · 4H2OMon.
7.CC.60Boussingaultite(NH4)2Mg(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60CyanochroiteK2Cu(SO4)2 · 6H2OMon. 2/m
7.CC.60Mohrite(NH4)2Fe(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60Nickelboussingaultite(NH4)2Ni(SO4)2 · 6H2O
7.CC.60PicromeriteK2Mg(SO4)2 · 6H2OMon. 2/m
7.CC.65PolyhaliteK2Ca2Mg(SO4)4 · 2H2OTric. 1
7.CC.70LeightoniteK2Ca2Cu(SO4)4 · 2H2OTric.
7.CC.75AmarilliteNaFe(SO4)2 · 6H2OMon. 2/m : B2/b
7.CC.80KonyaiteNa2Mg(SO4)2 · 5H2OMon. 2/m : P21/b
7.CC.85WattevilleiteNa2Ca(SO4)2 · 4H2O (?)Orth.

Related Minerals - Dana Grouping (8th Ed.)Hide

29.9.1.1VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
29.9.1.3PertlikiteK2(Fe2+,Mg)2Mg4Fe3+2Al(SO4)12 · 18H2OTet. 4/mmm (4/m 2/m 2/m) : I41/acd
29.9.1.4Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

25.11.1NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
25.11.2SideronatriteNa2Fe(SO4)2(OH) · 3H2OOrth. 2 2 2 : P21 21 21
25.11.3MetasideronatriteNa2Fe(SO4)2(OH) · H2OOrth. mmm (2/m 2/m 2/m)
25.11.4FerrinatriteNa3Fe(SO4)3 · 3H2OTrig. 3 : P3
25.11.5AmarilliteNaFe(SO4)2 · 6H2OMon. 2/m : B2/b
25.11.6YavapaiiteKFe(SO4)2Mon. 2/m : B2/m
25.11.7KrausiteKFe(SO4)2 · H2OMon. 2/m : P21/m
25.11.8GoldichiteKFe(SO4)2 · 4H2OMon. 2/m : P21/b
25.11.9JarositeKFe3+ 3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
25.11.10VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
25.11.11UngemachiteK3Na8Fe(SO4)6(NO3)2 · 6H2OTrig. 3 : R3
25.11.12MetavoltineNa6K2FeFe6(SO4)12O2 · 18H2OTrig.
25.11.13Sabieite(NH4)Fe3+(SO4)2Trig. 3 2 : P3 2 1
25.11.14Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
25.11.15Clairite(NH4)2Fe3(SO4)4(OH)3 · 3H2OTric.
25.11.16Mohrite(NH4)2Fe(SO4)2 · 6H2OMon. 2/m : P21/b
25.11.17Lonecreekite(NH4)Fe3+(SO4)2 · 12H2OIso.
25.11.18Godovikovite(NH4)Al(SO4)2Trig. 3 2 : P3 2 1
25.11.19BotryogenMgFe3+(SO4)2(OH) · 7H2OMon. 2/m
25.11.21Slavíkite(H3O+)3Mg6Fe15(SO4)21(OH)18 · 98H2OTrig. 3 : R3
25.11.23SturmaniteCa6(Fe3+,Al,Mn3+)2(SO4)2[B(OH)4](OH)12 · 25H2OTrig. 3m : P3 1c
25.11.24Millosevichite(Al,Fe)2(SO4)3Tric.
25.11.25AluminocopiapiteAl2/3Fe3+4(SO4)6(OH)2 · 20H2OTric. 1 : P1
25.11.26HalotrichiteFeAl2(SO4)4 · 22H2OMon. 2 : P2
25.11.27Idrizite(Mg,Fe)(Al,Fe)2(SO4)3(OH)2 · 15H2O or near
25.11.28LishizheniteZnFe2(SO4)4 · 14H2OTric. 1 : P1

Other InformationHide

Notes:
Slowly soluble in water. Decomposes in air.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for ZincovoltaiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Li Wanmao, Chen Guoying, and Sun Shurong (1987) Zincovoltaite - A new sulfate mineral. Acta Mineralogica Sinica (4), 307-12 (in Chinese with English abstract).
Yang Hexiong and Fu Pingqiu (1988) A further study of zincobotryogen. Acta Mineralogica Sinica 7(4), 223-224 (in Chinese with English abstract). - American Mineralogist (1990), 75, 244-45 (abstract).
Majzlan, J., Schlicht, H., Wierzbicka-Wieczorek, M., Giester, G., Pöllmann, H., Brömme, B., Doyle, S., Buth, G., Bender Koch, C. (2013): A contribution to the crystal chemistry of the voltaite group: solid solutions, Mössbauer and infrared spectra, and anomalous anisotropy. Mineralogy and Petrology, 107, 221-233.

Internet Links for ZincovoltaiteHide

Localities for ZincovoltaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
China (TL)
 
  • Qinghai Province
    • Haixi Autonomous Prefecture
      • Da Qaidam Co. (Dachaidan Co.)
        • Xitieshan
Li Wanmao, Chen Guoying, and Sun Shurong (1987): Acta Mineralogica Sinica (4), 307-312.
Mineral and/or Locality  
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