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Flurlite

A valid IMA mineral species
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About FlurliteHide

04409690014947075883888.jpg
Mathias von Flurl
Formula:
Zn3Mn2+Fe3+(PO4)3(OH)2 · 9H2O
Colour:
Bright orange red to dark maroon red
Specific Gravity:
2.89
Crystal System:
Monoclinic
Name:
Named by I.E. Grey, E. Keck, W.G. Mumme, A. Pring and C.M. MacRae in 2014 in honor of Mathias von Flurl (5 February 1756, Straubing, Bavaria - 27 July 1823, Kissingen, Bavaria), the founder of mineralogical and geological studies in Bavaria. He created the first geological map of Bavaria.
Related to schoonerite.
A re-evaluation of the site occupancies in flurlite, using BVS calculations, resulted in a change in the dominant cation in the M1 site from Mn2+ to Zn. Consequently, the end-member formula for flurlite becomes [5]Zn[6]Zn3[6]Fe3+(PO4)3(OH)2(H2O)7·2H2O (CNMNC Newsletter No. 42).


Unique IdentifiersHide

Mindat ID:
46498
Long-form identifier:
mindat:1:1:46498:5
GUID
(UUID V4):
dd655e0e-3cd7-4681-a3d8-2e0cb5613efd

IMA Classification of FlurliteHide

Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
Zn2+Zn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2O
Approval year:
2014
First published:
2015
Approval history:
2014: Approved by IMA as a new species (IMA 2014-064) with the formula Zn3Mn2+Fe3+(PO4)3(OH)2·9H2O.
2017: Revised end-member formula for flurlite (Proposal 17-I),[5]Zn[6]3[6]Fe3+(PO4)3(OH)2(H2O)7·2H2O.

Classification of FlurliteHide

8.DB.40

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
B : With only medium-sized cations, (OH, etc.):RO4< 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
FluIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of FlurliteHide

Transparency:
Translucent
Colour:
Bright orange red to dark maroon red
Streak:
Buff
Comment:
Hardness not described.
Tenacity:
Brittle
Cleavage:
Perfect
Parallel to (001).
Fracture:
Irregular/Uneven
Density:
2.89 g/cm3 (Measured)    2.84 g/cm3 (Calculated)

Optical Data of FlurliteHide

Type:
Biaxial (-)
RI values:
nα = 1.600(1) nβ = 1.650(1) nγ = 1.680(1)
2V:
Calculated: 74°
Max Birefringence:
δ = 0.080
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
Weak
Optical Extinction:
Parallel. X ≈ c, Y ≈ a, Z ≈ b.
Pleochroism:
Weak
Comments:
With colours: X = pale yellow, Y = pale orange, Z = orange brown

Chemistry of FlurliteHide

Mindat Formula:
Zn3Mn2+Fe3+(PO4)3(OH)2 · 9H2O

Crystallography of FlurliteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Setting:
P21/m
Cell Parameters:
a = 6.3894(8) Å, b = 11.037(1) Å, c = 13.063(2) Å
β = 99.37(2)°
Ratio:
a:b:c = 0.579 : 1 : 1.184
Unit Cell V:
908.91 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Platelets forming twisted accordion-like aggregates.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
12.900 Å(100)
8.375 Å(10)
6.072 Å(14)
5.567 Å(8)
5.080 Å(7)
4.297 Å(21)
3.221 Å(7)
2.763 Å(35)
Comments:
From Type Description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites

Type Occurrence of FlurliteHide

General Appearance of Type Material:
As ultrathin (<1 μm) translucent platelets that form characteristic twisted accordion-like aggregates, on mitridatite.
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collections of Museum Victoria, Melbourne, Victoria, Australia, registration number M53238.
Geological Setting of Type Material:
Zoned granitic phosphate pegmatite.
Associated Minerals at Type Locality:
Reference:
Grey, I.E., Keck, E., Mumme, W.G., Pring, A., Macrae, C.M., Gable, R.W., Price, J.R. (2015) Flurlite, Zn3Mn2+Fe3+(PO4)3(OH)2·9H2O, a new mineral from the Hagendorf Süd pegmatite, Bavaria, with a schoonerite-related structure. Mineralogical Magazine: 79: 1175-1184.

Synonyms of FlurliteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Flurlite associated with JungiteCa2Zn4Fe3+8(PO4)9(OH)9 · 16H2O
1 photo of Flurlite associated with StewartiteMn2+Fe3+2(PO4)2(OH)2 · 8H2O

Related Minerals - Strunz-mindat GroupingHide

8.DB.ArangasiteAl2F(PO4)(SO4) · 9H2O Mon. 2/m : P2/b
8.DB.Camaronesite[Fe3+(H2O)2(PO3OH)]2(SO4) · 1-2H2OTrig. 3 2 : R3 2
8.DB.HösliteFe3+3(VO4)2(SO4)(OH)(H2O)4 · 3H2OMon. 2/m : P21/b
8.DB.05DiadochiteFe3+2(PO4)(SO4)(OH) · 6H2OAmor.
8.DB.05Pitticite(Fe, AsO4, H2O) (?)Amor.
8.DB.05DestineziteFe3+2(PO4)(SO4)(OH) · 6H2OTric. 1 : P1
8.DB.07WilhelmgümbeliteZnFe2+Fe3+3(PO4)3(OH)4(H2O)5 · 2H2OOrth. mmm (2/m 2/m 2/m)
8.DB.07Schmidite[Zn2(Fe3+,Mn2+)2Fe3+(PO4)3(OH)3(H2O)6] · 2H2OOrth.
8.DB.07WildenaueriteZn(Fe3+,Mn2+)2MnFe3+(PO4)3(OH)3(H2O)6 · 2H2OOrth. mmm (2/m 2/m 2/m) : Pbam
8.DB.10VashegyiteAl11(PO4)9(OH)6 · 38H2OOrth. mmm (2/m 2/m 2/m)
8.DB.15SchooneriteZnMn2+Fe2+2Fe3+(PO4)3(OH)2 · 9H2OOrth. mmm (2/m 2/m 2/m) : Pbam
8.DB.20SinkankasiteMn2+Al(PO3OH)2(OH) · 6H2OTric. 1 : P1
8.DB.25MitryaevaiteAl6(PO4)((P,S)O3(OH,O))2F2(OH)2 · 14.5H2OTric. 1 : P1
8.DB.30SanjuaniteAl2(PO4)(SO4)(OH) · 9H2OTric.
8.DB.35SarmientiteFe3+2(AsO4)(SO4)(OH) · 5H2OMon. 2/m : P21/b
8.DB.40BukovskýiteFe3+2(AsO4)(SO4)(OH) · 9H2OTric. 1 : P1
8.DB.40ManganflurliteZnMn2+3Fe3+(PO4)3(OH)2(H2O)7 · 2H2OMon. 2/m : P21/m
8.DB.42BohuslaviteFe3+4(PO4)3(SO4)(OH) · nH2OTric. 1 : P1
8.DB.45ZýkaiteFe3+4(AsO4)3(SO4)(OH) · 15H2OOrth. 2 2 2 : P2 2 2
8.DB.47LapeyreiteCu3O[AsO3(OH)]2 · 0.75H2OMon. 2/m : B2/m
8.DB.50GiniiteFe2+Fe3+4(PO4)3(OH)5 · 2H2OMon. 2/m : P2/b
8.DB.50RossiantoniteAl3(PO4)(SO4)2(OH)2(H2O)14Tric. 1 : P1
8.DB.52ArctowskiteAl9(PO4)8(OH)3 · 27H2OOrth.
8.DB.55Sasaite(Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2OOrth.
8.DB.60McauslaniteFe3Al2(PO4)3(PO3OH)F · 18H2OTric.
8.DB.65GoldquarryiteCuCd2Al3(PO4)4F2(H2O,F)2 · 10H2OTric. 1 : P1
8.DB.70BirchiteCd2Cu2(PO4)2(SO4) · 5H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.DB.75BraithwaiteiteNaCu5(Ti4+Sb5+)(AsO4)4(HAsO4)2O2 · 8H2OTric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for FlurliteHide

References for FlurliteHide

Localities for FlurliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Germany (TL)
 
  • Bavaria
    • Upper Palatinate
      • Neustadt an der Waldnaab District
        • Waidhaus
          • Hagendorf
Williams et al. (2015) +1 other reference
 
Mineral and/or Locality  
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