Kainotropite
A valid IMA mineral species
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About Kainotropite
Formula:
Cu4Fe3+O2(V2O7)(VO4)
Colour:
Iron-black to reddish-black
Lustre:
Sub-Metallic
Specific Gravity:
4.10 (Calculated)
Crystal System:
Orthorhombic
Name:
The name is derived from the Greek word καινóτρoπoς, unusual, in allusion to its uncommon (for natural vanadates) anionic composition: it is the first mineral containing both pyrovanadate (V2O7)4– and orthovanadate (VO4)3– anions.
New structure type.
Other minerals containing copper and divanadate group: blossite, engelhauptite, volborthite, ziesite.
Other minerals containing copper and divanadate group: blossite, engelhauptite, volborthite, ziesite.
Unique Identifiers
Mindat ID:
46813
Long-form identifier:
mindat:1:1:46813:0
GUID
(UUID V4):
(UUID V4):
522f6426-3a21-4883-b3cb-26ccc261a04a
Classification of Kainotropite
Approved
Approval year:
2015
First published:
2020
8.F0.05
8 : PHOSPHATES, ARSENATES, VANADATES
F : Polyphosphates, Polyarsenates, [4]-Polyvanadates
0 :
8 : PHOSPHATES, ARSENATES, VANADATES
F : Polyphosphates, Polyarsenates, [4]-Polyvanadates
0 :
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Ktr | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Kainotropite
Optical Data of Kainotropite
Anisotropism:
Weakly
Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
470nm | 18.3% | 17.3% |
546nm | 17.3% | 16.3% |
589nm | 16.9% | 15.7% |
650nm | 16.3% | 15.1% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 18.3%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Grey
Chemical Properties of Kainotropite
Formula:
Cu4Fe3+O2(V2O7)(VO4)
Elements listed:
Crystallography of Kainotropite
Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 14.139(2) Å, b = 6.7102(7) Å, c = 11.418(1) Å
Ratio:
a:b:c = 2.107 : 1 : 1.702
Unit Cell V:
1083.3 ų
Z:
4
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
8.89 Å | (100) |
5.728 Å | (33) |
3.698 Å | (35) |
3.651 Å | (25) |
3.357 Å | (52) |
3.034 Å | (77) |
2.968 Å | (60) |
2.655 Å | (27) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
45b : [Other oxidized fumarolic minerals] |
Type Occurrence of Kainotropite
General Appearance of Type Material:
Prismatic crystals up to 0.2 × 0.2 × 0.5 mm3, isolated or combined in clusters up to 0.7 mm across
Place of Conservation of Type Material:
Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia, registration number 4721/1.
Empirical Formula of Type Material:
Cu3.96Fe3+0.85Al0.19Ti0.03(V2.78As0.15Mo0.04)Σ2.97O13
Chemical Analysis of Type Material:
CuO | 46.69 % |
---|---|
Al2O3 | 1.40 % |
Fe2O3 | 10.04 % |
TiO2 | 0.32 % |
V2O5 | 37.58 % |
As2O5 | 2.55 % |
MoO3 | 0.76 % |
Total: | 99.34 % |
Geological Setting of Type Material:
Found in sublimates of fumaroles
Associated Minerals at Type Locality:
Reference:
Pekov, I.V., Zubkova, N.V., Yapaskurt, V.O., Polekhovsky, Y.S., Britvin, S.N. , Turchkova, A.G., Sidorov, E.G., Pushcharovsky, D.Y. (2020) Kainotropite, Cu4Fe3+O2(V2O7)(VO4), a new mineral with a complex vanadate anion from fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. The Canadian Mineralogist: 58: 155-165.
Synonyms of Kainotropite
Related Minerals - Strunz-mindat Grouping
8.F0. | Medvedevite | KMn2+2V2O6Cl · 2H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Kainotropite
mindat.org URL:
https://www.mindat.org/min-46813.html
Please feel free to link to this page.
Please feel free to link to this page.
External Links:
Mineral Dealers:
References for Kainotropite
Reference List:
Localities for Kainotropite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
| |
|
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia