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Kainotropite

A valid IMA mineral species
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About KainotropiteHide

Formula:
Cu4Fe3+O2(V2O7)(VO4)
Colour:
Iron-black to reddish-black
Lustre:
Sub-Metallic
Specific Gravity:
4.10 (Calculated)
Crystal System:
Orthorhombic
Name:
The name is derived from the Greek word καινóτρoπoς, unusual, in allusion to its uncommon (for natural vanadates) anionic composition: it is the first mineral containing both pyrovanadate (V2O7)4– and orthovanadate (VO4)3– anions.
New structure type.
Other minerals containing copper and divanadate group: blossite, engelhauptite, volborthite, ziesite.


Unique IdentifiersHide

Mindat ID:
46813
Long-form identifier:
mindat:1:1:46813:0
GUID
(UUID V4):
522f6426-3a21-4883-b3cb-26ccc261a04a

Classification of KainotropiteHide

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KtrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KainotropiteHide

Sub-Metallic
Colour:
Iron-black to reddish-black
Density:
4.10 g/cm3 (Calculated)

Optical Data of KainotropiteHide

Anisotropism:
Weakly
Reflectivity:
WavelengthR1R2
470nm18.3%17.3%
546nm17.3%16.3%
589nm16.9%15.7%
650nm16.3%15.1%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 18.3%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Grey

Chemical Properties of KainotropiteHide

Formula:
Cu4Fe3+O2(V2O7)(VO4)

Crystallography of KainotropiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pnma
Setting:
Pnma
Cell Parameters:
a = 14.139(2) Å, b = 6.7102(7) Å, c = 11.418(1) Å
Ratio:
a:b:c = 2.107 : 1 : 1.702
Unit Cell V:
1083.3 ų
Z:
4

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
8.89 Å(100)
5.728 Å(33)
3.698 Å(35)
3.651 Å(25)
3.357 Å(52)
3.034 Å(77)
2.968 Å(60)
2.655 Å(27)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45b : [Other oxidized fumarolic minerals]

Type Occurrence of KainotropiteHide

General Appearance of Type Material:
Prismatic crystals up to 0.2 × 0.2 × 0.5 mm3, isolated or combined in clusters up to 0.7 mm across
Place of Conservation of Type Material:
Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia, registration number 4721/1.
Empirical Formula of Type Material:
Cu3.96Fe3+0.85Al0.19Ti0.03(V2.78As0.15Mo0.04)Σ2.97O13
Chemical Analysis of Type Material:
CuO46.69 %
Al2O31.40 %
Fe2O310.04 %
TiO20.32 %
V2O537.58 %
As2O52.55 %
MoO30.76 %
Total:99.34 %
Geological Setting of Type Material:
Found in sublimates of fumaroles
Associated Minerals at Type Locality:
Reference:
Pekov, I.V., Zubkova, N.V., Yapaskurt, V.O., Polekhovsky, Y.S., Britvin, S.N. , Turchkova, A.G., Sidorov, E.G., Pushcharovsky, D.Y. (2020) Kainotropite, Cu4Fe3+O2(V2O7)(VO4), a new mineral with a complex vanadate anion from fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. The Canadian Mineralogist: 58: 155-165.

Synonyms of KainotropiteHide

Related Minerals - Strunz-mindat GroupingHide

8.F0.MedvedeviteKMn2+2V2O6Cl · 2H2OMon. 2/m : P21/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KainotropiteHide

References for KainotropiteHide

Reference List:

Localities for KainotropiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Kamchatka Krai
    • Milkovsky District
      • Tolbachik Volcanic field
        • Great Fissure eruption (Main Fracture)
          • Northern Breakthrough (North Breach)
            • Second scoria cone
        • Mountain 1004
 
Mineral and/or Locality  
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