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Leesite

A valid IMA mineral species
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About LeesiteHide

02771190017058794014899.jpg
Bryan K. Lees
Formula:
K(H2O)2[(UO2)4O2(OH)5] · 3H2O
Colour:
Orange-yellow
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
3.256 (Calculated)
Crystal System:
Orthorhombic
Name:
Named in honor of Bryan K. Lees (b. 31 August 1957, Decatur, Illinois, USA), American mineral dealer and collector. Founder and president of Collector's Edge Minerals Inc., he has conducted extensive specimen mining operations including the famous Sweet Home mine rhodocrosite.
The second purely K-U oxide/hydroxide mineral after compreignacite.

A synthetic Na analogue is known.


Unique IdentifiersHide

Mindat ID:
50774
Long-form identifier:
mindat:1:1:50774:9
GUID
(UUID V4):
de9d6891-a868-4dc8-9312-d1b11d70b94f

IMA Classification of LeesiteHide

Classification of LeesiteHide

4.GB.90

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
B : With additional cations (K, Ca, Ba, Pb, etc.); with mainly UO2(O,OH)5 pentagonal polyhedra

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
LeeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LeesiteHide

Vitreous
Transparency:
Translucent
Colour:
Orange-yellow
Streak:
Light yellow
Hardness:
Tenacity:
Brittle
Cleavage:
Perfect
{100}
Fracture:
Irregular/Uneven
Density:
3.256 g/cm3 (Calculated)

Optical Data of LeesiteHide

Type:
Biaxial (-)
RI values:
nα = 1.745(2) nβ = 1.761(2) nγ = 1.765(2)
2V:
Measured: 50° (2), Calculated: 52.7°
Max Birefringence:
δ = 0.020
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
Strong, r > v.
Optical Extinction:
X = a; Y = c; Z = b.
Pleochroism:
Weak
Comments:
X = colorless; Y = Z = orange yellow.
Comments:
Absorption: X < Y ≃ Z.

Chemistry of LeesiteHide

Mindat Formula:
K(H2O)2[(UO2)4O2(OH)5] · 3H2O

Crystallography of LeesiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pbca
Setting:
Pbca
Cell Parameters:
a = 14.866(7) Å, b = 14.126(7) Å, c = 16.772(8) Å
Ratio:
a:b:c = 1.052 : 1 : 1.187
Unit Cell V:
3,522.07 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Tablets, flattened and stacked on {100}, the only well-developed crystal form.
Twinning:
None observed.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.45 Å(92)
3.713 Å(24)
3.566 Å(65)
3.219 Å(100)
2.578 Å(28)
2.043 Å(36)
1.982 Å(25)
1.801 Å(18)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47f : [Uranyl (U⁶⁺) minerals]

Type Occurrence of LeesiteHide

General Appearance of Type Material:
Aggregates of orange-yellow tablets up to 1 mm in diameter. Also as powdery masses in the interstices of gypsum crystals.
Place of Conservation of Type Material:
Cotypes: mineralogical collections of (1) the Natural History Museum of Los Angeles County, Los Angeles, USA (catalogue numbers 66285, 66286 and 66287), and (2) the New Mexico Bureau of Geology and Mineral Resources Socorro, USA (catalogue number 19029)
Associated Minerals at Type Locality:
Reference:
Olds, T.A., Plášil, J., Kampf, A.R., Spano, T., Haynes, P., Carlson, S.M., Burns, P.C., Simonetti, A., Mills, O.P. (2018): Leesite, K(H2O)2[(UO2)4O2(OH)5]∙3H2O, a new K-bearing schoepite-family mineral from the Jomac mine, San Juan County, Utah, U.S.A. American Mineralogist, 103, 143-150.

Synonyms of LeesiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
4 photos of Leesite associated with GypsumCaSO4 · 2H2O
2 photos of Leesite associated with CompreignaciteK2(UO2)6O4(OH)6 · 7H2O
2 photos of Leesite associated with MagnesiozippeiteMg(UO2)2(SO4)O2 · 3.5H2O
1 photo of Leesite associated with SklodowskiteMg(UO2)2(SiO3OH)2 · 6H2O
1 photo of Leesite associated with Blatonite(UO2)CO3 · H2O

Related Minerals - Strunz-mindat GroupingHide

4.GB.05AgrinieriteK2(Ca,Sr)[(UO2)3O3(OH)2]2 · 5H2OMon. m : Bm
4.GB.05CompreignaciteK2(UO2)6O4(OH)6 · 7H2OOrth. mmm (2/m 2/m 2/m) : Pnnm
4.GB.05RameauiteK2Ca(UO2)6O6(OH)4 · 6H2OMon. m : Bb
4.GB.10BecquereliteCa(UO2)6O4(OH)6 · 8H2OOrth. mm2 : Pna21
4.GB.10BillietiteBa(UO2)6O4(OH)6 · 4-8H2OOrth. mm2
4.GB.10ProtasiteBa(UO2)3O3(OH)2 · 3H2OMon. m
4.GB.15Richetite(Fe3+,Mg)Pb 8.6(UO2)36O36(OH)24 · 41H2O Tric. 1 : P1
4.GB.20BauranoiteBa(UO2)2(OH)6 · 1-2H2O
4.GB.20Calciouranoite(Ca,Ba,Pb)U2O7 · 5H2O
4.GB.20Metacalciouranoite(Ca,Ba,Pb,K2)U2O7 · 2H2O
4.GB.25FourmarieritePb(UO2)4O3(OH)4 · 4H2OOrth. mm2
4.GB.30WölsendorfitePb7(UO2)14O19(OH)4 · 12H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
4.GB.35MasuyitePb(UO2)3O3(OH)2 · 3H2OOrth. mmm (2/m 2/m 2/m)
4.GB.40MetavandendriesscheitePbU7O22 · nH2O n < 12Orth.
4.GB.40VandendriesscheitePbU7O22 · 12H2OOrth. mmm (2/m 2/m 2/m) : Pbca
4.GB.45VandenbrandeiteCu(UO2)(OH)4Tric. 1 : P1
4.GB.50SayritePb2(UO2)5O6(OH)2 · 4H2OMon. 2/m
4.GB.55CuritePb3(H2O)2[(UO2)4O4(OH)3]2Orth. mmm (2/m 2/m 2/m) : Pnma
4.GB.60Iriginite(UO2)Mo2O7 · 3H2OOrth. mmm (2/m 2/m 2/m) : Pbcm
4.GB.65UranosphaeriteBi(UO2)O2(OH)Mon. 2/m
4.GB.70HolfertiteCaxU6+2-xTi(O8-xOH4x) · 3H2OTrig. 3 : P3
4.GB.75Carlosbarbosaite(UO2)2Nb2O6(OH)2 · 2H2OOrth. mmm (2/m 2/m 2/m) : Cmcm
4.GB.80GauthieriteKPb[(UO2)7O5(OH)7] · 8H2OMon. 2/m : P21/b
4.GB.85KroupaiteKPb0.5[(UO2)8O4(OH)10] · 10H2OOrth. mmm (2/m 2/m 2/m) : Pbca
4.GB.95ShinkolobweitePb1.25[U5+(H2O)2(U6+O2)5O8(OH)2](H2O)5Orth. mmm (2/m 2/m 2/m) : Pnnm
4.GB.95NollmotziteMg[U5+(U6+O2)2O4F3] · 4H2OMon. m : Bm

Fluorescence of LeesiteHide

Other InformationHide

Notes:
Readily soluble in dilute HCl and HNO3, with no effervescence.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LeesiteHide

References for LeesiteHide

Localities for LeesiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Czech Republic
 
  • Karlovy Vary Region
    • Karlovy Vary District
      • Jáchymov
Möhn et al. (12/2021)
Slovakia
 
  • Košice Region
    • Rožňava District
      • Gemerská Poloma
Ferenc Š. et al. (2018)
USA (TL)
 
  • Utah
    • San Juan County
      • White Canyon Mining District
Mineralogical Magazine +2 other references
 
Mineral and/or Locality  
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