Seleniospinel Group

A group of related mineral species

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Photos of Seleniospinel Group (26)

Seleniospinel Group Gallery Search Photos of Seleniospinel Group

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Tyrrellite, etc.

Eagle Claims U-Cu-Se occurrence, Beaverlodge Lake area, Saskatchewan, Canada

Tyrrellite, etc.

Eagle Claims U-Cu-Se occurrence, Beaverlodge Lake area, Saskatchewan, Canada

Tyrrellite, etc.

Bukov Mine, Rožná deposit, Rožná, Žďár nad Sázavou District, Vysočina Region, Czech Republic

Tyrrellite, etc.

Eagle Claims U-Cu-Se occurrence, Beaverlodge Lake area, Saskatchewan, Canada

Tyrrellite, etc.

Eagle Claims U-Cu-Se occurrence, Beaverlodge Lake area, Saskatchewan, Canada

Tyrrellite, etc.

Bukov Mine, Rožná deposit, Rožná, Žďár nad Sázavou District, Vysočina Region, Czech Republic

Tyrrellite, etc.

Eagle Claims U-Cu-Se occurrence, Beaverlodge Lake area, Saskatchewan, Canada

Tyrrellite, etc.

Eagle Claims U-Cu-Se occurrence, Beaverlodge Lake area, Saskatchewan, Canada

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About Seleniospinel GroupHide

Formula:

AD₂X₄

A= Co, Ni, Cu
D= Co, Ni
X= Se^2-
Note: the D site is named as B in the IMA Proposal 17-H, to avoid confusion with Boron.

Member of:

Spinel Supergroup

A group within the Spinel Supergroup.
The seleniospinell group can be divided into: bornhardtite subgroup and tyrrellite (CNMNC Newsletter No. 42).

Unique IdentifiersHide

Mindat ID:

52867

Long-form identifier:

mindat:1:1:52867:2

GUID
(UUID V4):

f47caa55-0843-4845-a1d4-c65d18255c19

Classification of Seleniospinel GroupHide

IMA status notes:

IMA Approved Group Name

Approval history:

A classification of spinel supergroup was approved by IMA in march 2018 (Proposal 17-H).

Chemical Properties of Seleniospinel GroupHide

Formula:

AD₂X₄

A= Co, Ni, Cu
D= Co, Ni
X= Se^2-
Note: the D site is named as B in the IMA Proposal 17-H, to avoid confusion with Boron.

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0010334	Tyrrellite	Yang H, Hubler D K, Lavina B, Downs R T, Costin G (2007) Tyrrellite, Cu(Co0.68Ni0.32)2Se4, isostructural with spinel Acta Crystallographica C63 i73-i74		2007	Eagle Claims, Beaverlodge Lake area, Saskatchewan, Canada	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Tyrrellite'
loop_
_publ_author_name
'Yang H'
'Hubler D K'
'Lavina B'
'Downs R T'
'Costin G'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 63 
_journal_year 2007
_journal_page_first i73
_journal_page_last i74
_publ_section_title
;
 Tyrrellite, Cu(Co0.68Ni0.32)2Se4, isostructural with spinel
;
_database_code_amcsd 0010334
_chemical_compound_source 'Eagle Claims, Beaverlodge Lake area, Saskatchewan, Canada'
_chemical_formula_sum 'Cu (Co1.36 Ni.64) Se4'
_cell_length_a 9.98850
_cell_length_b 9.98850
_cell_length_c 9.98850
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 996.554
_exptl_crystal_density_diffrn      6.626
_symmetry_space_group_name_H-M 'F d 3 m'
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_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Cu   0.12500   0.12500   0.12500   1.00000   0.01020
Co   0.50000   0.00000   0.00000   0.68000   0.00624
Ni   0.50000   0.00000   0.00000   0.32000   0.00624
Se   0.26192  -0.01192  -0.01192   1.00000   0.00705
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Cu 0.01020 0.01020 0.01020 0.00000 0.00000 0.00000
Co 0.00624 0.00624 0.00624 -0.00031 -0.00031 -0.00031
Ni 0.00624 0.00624 0.00624 -0.00031 -0.00031 -0.00031
Se 0.00705 0.00705 0.00705 0.00027 0.00027 -0.00027

Relationship of Seleniospinel Group to other SpeciesHide

Member of:

Spinel Supergroup

Other Members of this group:

Oxyspinel Group	AD₂O₄
Thiospinel Group	AD₂X₄

Group Members:

Bornhardtite Subgroup	A²⁺D³⁺₂Se₄
Bornhardtite	Co²⁺Co³⁺₂Se₄	Iso. m3m (4/m 3 2/m) : Fd3m
Trüstedtite	Ni₃Se₄	Iso.
Nickeltyrrellite	CuNi₂Se₄	Iso. m3m (4/m 3 2/m) : Fd3m
Tyrrellite	Cu(Co³⁺,Ni³⁺)₂Se₄	Iso. m3m (4/m 3 2/m) : Fd3m

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Seleniospinel GroupHide

mindat.org URL:

https://www.mindat.org/min-52867.html
Please feel free to link to this page.

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References for Seleniospinel GroupHide

Reference List:

CNMNC Newsletter No. 42, April 2018, page xxx; Mineralogical Magazine: 82: xxx-xxx ( Proposal IMA 17-H).

Brik, M.G., Suchocki, A., Kamińska, A. (2014): Lattice parameters and stability of the spinel compounds in relation to the ionic radii and electronegativities of constituting chemical elements. Inorg. Chem., 53, 5088-5099.

Biagioni, C. & Pasero, M. (2014): The systematics of the spinel-type minerals: an overview. American Mineralogist, 99, 1254-1264.

Localities for Seleniospinel GroupHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Argentina
La Rioja Province General Lamadrid Department Villa Castelli Sierra de Cacho ⓘ Tumiñico Mine	[Tyrrellite] Milka K. de Brodtkorb (2002) Las Especies Minerales de la Republica Argentina. Vol. 1 (elements, sulphides and sulphosalts). (Asociacion Mineralogica Argentina) Paar, W.H., Topa, D., Roberts, A.C., Criddle, A.J., Amann, G., Sureda, R.J. (2002): The new mineral species brodtkorbite, Cu2HgSe2, and the associated selenide assemblage from Tumiñico, Sierra de Cacho, La Rioja, Argentina. Can. Mineral.: 40(1): 225–237 de Brodtkorb, M. K., & Crosta, S. (2010). Reseña de la ubicación geográfica de los seleniuros de la Sierra de Umango, provincia de La Rioja. Revista de la Asociación Geológica Argentina, 67(2), 272-279. Grundmann, G., & Förster, H. J. (2018). The Sierra de Cacheuta Vein-Type Se Mineralization, Mendoza Province, Argentina. Minerals, 8(4), 127.
ⓘ Los Llantenes mining district	[Tyrrellite] Paar, W.H. et al (1996) Revista de la Asociacion Geologica Argentina, 51, #4, 304-312.
Mendoza Province Luján de Cuyo department Cacheuta District ⓘ Sierra de Cacheuta	[Bornhardtite] Grundmann, G., & Förster, H. J. (2018). The Sierra de Cacheuta Vein-Type Se Mineralization, Mendoza Province, Argentina. Minerals, 8(4), 127.
ⓘ Cerro de Cacheuta	[Bornhardtite] Handbook of Mineralogy
ⓘ Cacheuta Mine	[Tyrrellite] Grundmann, G., & Förster, H. J. (2018). The Sierra de Cacheuta Vein-Type Se Mineralization, Mendoza Province, Argentina. Minerals, 8(4), 127.

Bolivia
Potosí Antonio Quijarro Province Porco Municipality ⓘ El Dragón mine	[Nickeltyrrellite] Förster, H.-J., Ma, C. Grundmann, G., Bindi, L., Stanley, C.J. (2019) Nickeltyrrellite, CuNi2Se4, a New Member of the Spinel Supergroup from El Dragón, Bolivia. The Canadian Mineralogist: 57 (5): 637–646. https://doi.org/10.3749/canmin.1900025 Förster, H.-J., Ma, C., Grundmann, G., Bindi, L., and Stanley, C.J. (2019) Nickeltyrrellite, IMA 2018-110. CNMNC Newsletter No. 47, February 2019, page 200. European Journal of Mineralogy, 31: 199–204.

Canada
Saskatchewan Beaverlodge Lake area ⓘ Eagle Claims U-Cu-Se occurrence	[Tyrrellite] ROBINSON, S.C. & BROOKER, E.J. (1952): A cobalt - nickel - copper selenide from the Goldfields district, Saskatchewan, Canada. American Mineralogist 37, 542-544. ROBINSON, S.C. & BROOKER, E.J. (1952): A cobalt - nickel - copper selenide from the Goldfields district, Saskatchewan, Canada. American Mineralogist 37, 542-544. HARRIS, D.C. (1970): New data on tyrrellite. Canadian Mineralogist 10, 731-736. HARRIS, D.C. (1970): New data on tyrrellite. Canadian Mineralogist 10, 731-736.
Goldfields District Beaverlodge Lake ⓘ Ato Bay	[Tyrrellite] ROBINSON, S.C. & BROOKER, E.J. (1952): A cobalt - nickel - copper selenide from the Goldfields district, Saskatchewan, Canada. American Mineralogist 37, 542-544. HARRIS, D.C. (1970): New data on tyrrellite. Canadian Mineralogist 10, 731-736.
ⓘ Hal Lake Selenium Occurrence No. 1	[Tyrrellite] Collected and analyzed by Gunnar Farber.
ⓘ Martin Lake mine	[Tyrrellite] Econ Geol (1997) 92:468-484
ⓘ Pinky Fault Uranium Deposit	[Bornhardtite] Handbook of Mineralogy

China
Sichuan Ngawa Autonomous Prefecture (Aba Autonomous Prefecture) Zoigê Co. (Ruo'ergai Co.) ⓘ Qiongmo Au-Se deposit (Qiongme Au-Se deposit; Quongme Au-Se deposit)	[Trüstedtite] Anthony, J.W. et al.: Handbook of Mineralogy

Czech Republic
Plzeň Region Plzeň-South District Spálené Poříčí ⓘ Kokšín Hill	[Tyrrellite] Scharm, B. & Scharmová, M. (2000) Accessory minerals of siliceous rocks from the Kokšín hill near Mítov (Barrandian Neoproterozoic). Bulletin of Geosciences, 75(3), 307-318.
South Bohemian Region Písek District Kovářov Předbořice ⓘ Předbořice deposit	[Tyrrellite] W. H. Paar, D. Topa, E. Makovický, F. J. Culetto: "Milotaite, PdSbSe, a new palladium mineral, from Př edboř ice, Czech Republic", The Canadian Mineralogist 43, 689-694 (2005) Bindi, L., Förster, H. J., Grundmann, G., Keutsch, F., & Stanley, C. (2016). Petříčekite, CuSe2, a New Member of the Marcasite Group from the Předbořice Deposit, Central Bohemia Region, Czech Republic. Minerals, 6(2), 33.
Vysočina Region Žďár nad Sázavou District Nové Město na Moravě ⓘ Petrovice	[Tyrrellite] Kvaček, M.: Selenides from the deposits of Western Moravia, Czechoslovakia – Part II. Acta Universitatis Carolinae – Geologica, 1979, vol. 23, nos. 1-2, s. 15-38. Econ Geol (1997) 92:468-484
ⓘ Slavkovice	[Tyrrellite] Vavřín, I.: Nové poznatky o selenidech Českého masívu. Bulletin Mineralogicko-petrografického oddělení Národního muzea v Praze, 1994, roč. 2, s. 82-89. Flégr, T., Sejkora, J., Škácha, P., & Dolníček, Z. (2018). New occurrence of kruťaite and petříčekite at the former uranium mine Slavkovice, western Moravia, Czech Republic. Bulletin Mineralogie Petrologie, 26(2), 250-258.
Rožná Rožná deposit ⓘ Bukov Mine	[Tyrrellite] Vavřín, I.: Nové poznatky o selenidech Českého masívu. Bulletin Mineralogicko-petrografického oddělení Národního muzea v Praze, 1994, roč. 2, s. 82-89. Econ Geol (1997) 92:468-484
ⓘ Habři Mine	[Tyrrellite] Kvaček, M. (1979) Selenides from the deposits of Western Moravia, Czechoslovakia – Part II. Acta Universitatis Carolinae – Geologica: 23(1-2): 15-38.

DR Congo
Lualaba Kolwezi ⓘ Musonoi Mine	[Tyrrellite] Wilson, W. E. (2018) The Musonoi mine, Kolwezi District, Lualaba Province, Democratic Republic of the Congo. Mineralogical Record 49:236-304

Finland
North Ostrobothnia ⓘ Kuusamo	[Trüstedtite] Vuorelainen Y, Huhma A, Häkli A (1964): Sederholmite, wilkmanite, kullerudite, mäkinenite, and trüstedtite, five new nickel selenide minerals. Comptes Rendus de la Société Géologique de Finlande. 36, 113-125 Econ Geol (1997) 92:468-484
ⓘ Kitka River Valley	[Trüstedtite] Vuorelainen, Y., Huhma, A., Häkli, A. (1964) Sederholmite, wilkmanite, kullerudite, mäkinenite, and trüstedtite, five new nickel selenide minerals. Comptes Rendus de la Société Géologique de Finlande: 36: 113-125.

Germany
Bavaria Upper Palatinate ⓘ Wölsendorf fluorite mining district	[Tyrrellite] Seeliger, E. & Strunz, H. (1965): Erzpetrographie der Uranmineralien von Wölsendorf. II. Brannerit, Lermontovit(?), Selen und Selenide, Ni- and Bi-Begleitmineralien etc. Neues Jahrbuch für Mineralogie, Abhandlungen 103, 163-178. Dill, H.G., Weber, B. (2010) Accessory minerals of fluorite and their implication regarding the environment of formation (Nabburg–Wölsendorf fluorite district, SE Germany), with special reference to fetid fluorite (“Stinkspat”). Ore Geology Reviews, 37 (2). 65-86 doi:10.1016/j.oregeorev.2010.01.004
Lower Saxony Goslar District Harz (Landkreis Goslar) ⓘ Trogtal Quarries	[Bornhardtite] Ramdohr, P., Schmitt, M. (1955) Vier neue natürliche Kobaltselenide vom Steinbruch Trogtal bei Laufenthal im Harz. Neues Jahrbuch für Mineralogie, Monatshefte: 1955: 133-142. Am. Mineral. (1956) 41, 164-165 Weiss, S. (1990) Mineralfundstellen Atlas, Deutschland West. Weise Verlag, München, 320 pages. Cabral, A. R., Koglin, N., & Bratz, H. (2012). Gold-bearing ferroselite (FeSe2) from Trogtal, Harz, Germany, and significance of its Co/Ni ratio. Journal of Geosciences, 57(4), 265-272.
Göttingen District Harz (Landkreis Göttingen) ⓘ Weintraube Mine	[Bornhardtite] Weiss, S. (1990) Mineralfundstellen Atlas, Deutschland West. Weise Verlag, München, 320 pages.
Saxony-Anhalt Harz Ballenstedt Rieder ⓘ Greywacke quarry	[Tyrrellite] Heider, J. & Siemroth, J. (2012): Die Selenidmineralisation im Grauwacke-Tagebau Rieder bei Gernrode, Harz. Aufschluss, 63, 213-223.
Mansfeld-Südharz Mansfeld ⓘ Tilkerode mining district	[Bornhardtite] Tischendorf, G. (1969). Sources of elements in selenide mineralization near Tilkerode (Harz). International Geology Review, 11(11), 1298-1301. *Wittern, Artur (2001) Mineralfundorte und ihre Minerale in Deutschland* (1st ed.) Schweizerbart, Stuttgart.**

Spain
Castile and Leon León Cármenes Villanueva de Pontedo ⓘ Providencia Mine	[Tyrrellite] Econ Geol (1997) 92:468-484

UK
England Devon Torbay Torquay ⓘ Hope's Nose	[Trüstedtite] C. J. Stanley, A. J. Criddle and D. Lloyd (1990) Precious and Base Metal Selenide Mineralization at Hope's Nose, Torquay, Devon. Mineralogical Magazine 54:485-493 *Camm, Simon (1995) Gold in the Counties of Cornwall & Devon. Cornish Hillside Publications, St. Austell, Cornwall.*

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